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不同水文路径下岩溶洞穴水DOC动态变化的驱动因素及水文响应
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作者 王小朵 周忠发 +5 位作者 董慧 熊勇 丁圣君 汪继娟 张叶 黄义 《地球与环境》 北大核心 2025年第5期701-712,共12页
为了探究洞穴水中溶解有机碳(DOC)在不同运移路径下的水文响应,本研究对麻黄洞中5个洞穴水点进行了系统的野外监测。研究分析了不同水文路径下洞穴水DOC动态变化的驱动因素,并探讨了其对古气候重建的潜在意义。研究结果表明,不同水文路... 为了探究洞穴水中溶解有机碳(DOC)在不同运移路径下的水文响应,本研究对麻黄洞中5个洞穴水点进行了系统的野外监测。研究分析了不同水文路径下洞穴水DOC动态变化的驱动因素,并探讨了其对古气候重建的潜在意义。研究结果表明,不同水文路径的洞穴水DOC表现为MH2(1.81 mg/L)>MHJJ(1.66 mg/L)>MH5(1.46 mg/L)>MH3(1.26 mg/L)>MH4(1.17 mg/L),即洞穴滴水>地下河流水>裂隙水的特征;洞穴水DOC的动态变化主要受气象因素如降雨和气温的驱动,同时还与气候条件改变引起的水-岩过程密切相关;不同水文路径下,洞穴水的滞留时间、非均质含水层的储水和补给能力、岩溶管道的连通性以及岩溶水的来源补给等都存在差异,导致洞穴水DOC对外界水文变化有不同的响应。其中,慢速渗透流滴水点MH2的DOC对外界环境变化响应较慢,快速渗流滴水点MH3和竖井流滴水点MH4对外界环境变化响应明显,而季节性滴水点MHJJ和地下河MH5对外界气候响应较迅速。此外,不同水文路径下洞穴水DOC浓度峰值的差异可能会影响石笋中有机质层的形成,因此在根据石笋纹层重建古气候时需要考虑非均质含水层的水文路径对DOC的影响。 展开更多
关键词 不同水文路径 洞穴水doc 水文响应 双河洞
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Doc2Vec模型驱动的芯片竞争话语研究:主题意义与话语策略
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作者 续雨媛 卫乃兴 《外语研究》 北大核心 2025年第5期27-35,共9页
基于分布式表示的Doc2Vec向量空间模型将抽象的语义关系表征为语义空间中的向量距离,可用于话语研究中的主题挖掘。本研究基于自建的中美媒体芯片竞争语料库,采用Doc2Vec模型进行主题挖掘,探讨中美媒体话语的主题意义与博弈策略。向量... 基于分布式表示的Doc2Vec向量空间模型将抽象的语义关系表征为语义空间中的向量距离,可用于话语研究中的主题挖掘。本研究基于自建的中美媒体芯片竞争语料库,采用Doc2Vec模型进行主题挖掘,探讨中美媒体话语的主题意义与博弈策略。向量数据表明,中美媒体围绕“芯片管制”“国际关系”“国家立法”“技术发展”等4个主题展开话语建构。在共享的“芯片管制”与“国际关系”主题下,双方话语策略迥异,呈现极强对抗态势:美方基于所谓“道义伦理学”合法化对华芯片管制,中方则从后果主义伦理原则发力,批判美方扰乱全球经济秩序,对之去合法化;美方借助危机叙事构建阵营对立,中方则以立足全人类共同价值的团结话语来消解。“国家立法”和“技术发展”分别为双方特有的主题,即美方通过零和博弈叙事,动员不同利益集团借助强制性法案遏制中国芯片发展;中方则聚焦技术自主创新,以事实性数据表征对芯片发展的信心。方法论上,本研究揭示,Doc2Vec模型、语料库方法与传统话语分析结合使用,对洞悉博弈双方的区别性话语建构及话语策略可产生协同效应,有助于拓展话语研究方法。 展开更多
关键词 doc2Vec模型 词嵌入 芯片竞争话语 对抗性话语 语料库话语研究
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On Numerical Modelling of Industrial Powder Compaction Processes for Large Deformation of Endochronic Plasticity at Finite Strains
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作者 A R Khoei A Bakhshiani M Mofid 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期95-96,共2页
Compaction processes are one the most important par ts of powder forming technology. The main applications are focused on pieces for a utomotive, aeronautic, electric and electronic industries. The main goals of the c... Compaction processes are one the most important par ts of powder forming technology. The main applications are focused on pieces for a utomotive, aeronautic, electric and electronic industries. The main goals of the compaction processes are to obtain a compact with the geometrical requirements, without cracks, and with a uniform distribution of density. Design of such proc esses consist, essentially, in determine the sequence and relative displacements of die and punches in order to achieve such goals. A.B. Khoei presented a gener al framework for the finite element simulation of powder forming processes based on the following aspects; a large displacement formulation, centred on a total and updated Lagrangian formulation; an adaptive finite element strategy based on error estimates and automatic remeshing techniques; a cap model based on a hard ening rule in modelling of the highly non-linear behaviour of material; and the use of an efficient contact algorithm in the context of an interface element fo rmulation. In these references, the non-linear behaviour of powder was adequately desc ribed by the cap plasticity model. However, it suffers from a serious deficiency when the stress-point reaches a yield surface. In the flow theory of plasticit y, the transition from an elastic state to an elasto-plastic state appears more or less abruptly. For powder material it is very difficult to define the locati on of yield surface, because there is no distinct transition from elastic to ela stic-plastic behaviour. Results of experimental test on some hard met al powder show that the plastic effects were begun immediately upon loading. In such mater ials the domain of the yield surface would collapse to a point, so making the di rection of plastic increment indeterminate, because all directions are normal to a point. Thus, the classical plasticity theory cannot deal with such materials and an advanced constitutive theory is necessary. In the present paper, the constitutive equations of powder materials will be discussed via an endochronic theory of plasticity. This theory provides a unifi ed point of view to describe the elastic-plastic behaviour of material since it places no requirement for a yield surface and a ’loading function’ to disting uish between loading an unloading. Endochronic theory of plasticity has been app lied to a number of metallic materials, concrete and sand, but to the knowledge of authors, no numerical scheme of the model has been applied to powder material . In the present paper, a new approach is developed based on an endochronic rate independent, density-dependent plasticity model for describing the isothermal deformation behavior of metal powder at low homologous temperature. Although the concept of yield surface has not been explicitly assumed in endochronic theory, it is shown that the cone-cap plasticity yield surface (Fig.1), which is the m ost commonly used plasticity models for describing the behavior of powder materi al can be easily derived as a special case of the proposed endochronic theory. Fig.1 Trace of cone-cap yield function on the meridian pl ane for different relative density As large deformation is observed in powder compaction process, a hypoelastic-pl astic formulation is developed in the context of finite deformation plasticity. Constitutive equations are stated in unrotated frame of reference that greatly s implifies endochronic constitutive relation in finite plasticity. Constitutive e quations of the endochronic theory and their numerical integration are establish ed and procedures for determining material parameters of the model are demonstra ted. Finally, the numerical schemes are examined for efficiency in the model ling of a tip shaped component, as shown in Fig.2. Fig.2 A shaped tip component. a) Geometry, boundary conditio n and finite element mesh; b) density distribution at final stage of 展开更多
关键词 In On Numerical Modelling of Industrial Powder compaction Processes for Large Deformation of Endochronic Plasticity at Finite Strains
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Study on the optimal test parameters for vibration compaction based on the control of physical-mechanical indicators
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作者 Zhongrui Chen Yanxi Xiong +3 位作者 Ronghui Yan Zhibo Cheng Taifeng Li Hongfu Tan 《Railway Sciences》 2025年第3期388-409,共22页
Purpose-The indoor vibration compaction test(IVCT)was a key step in controlling the compaction quality for high-speed railway graded aggregate(HRGA),which currently had a research gap on the assessment indicators and ... Purpose-The indoor vibration compaction test(IVCT)was a key step in controlling the compaction quality for high-speed railway graded aggregate(HRGA),which currently had a research gap on the assessment indicators and compaction parameters.Design/methodology/approach-To address these issues,a novel multi-indicator IVCT method was proposed,including physical indicator dry density(ρd)and mechanical indicators dynamic stiffness(Krb)and bearing capacity coefficient(K20).Then,a series of IVCTs on HRGA under different compaction parameters were conducted with an improved vibration compactor,which could monitor the physical-mechanical indicators in real-time.Finally,the optimal vibration compaction parameters,including the moisture content(ω),the diameter-to-maximum particle size ratio(Rd),the thickness-to-maximum particle size ratio(Rh),the vibration frequency(f),the vibration mass(Mc)and the eccentric distance(re),were determined based on the evolution characteristics for the physical-mechanical indicators during compaction.Findings-All results indicated that theρd gradually increased and then stabilized,and the Krb initially increased and then decreased.Moreover,the inflection time of the Krb was present as the optimal compaction time(Tlp)during compaction.Additionally,optimal compaction was achieved whenωwas the water-holding content after mud pumping,Rd was 3.4,Rh was 3.5,f was the resonance frequency,and the ratio between the excitation force and the Mc was 1.8.Originality/value-The findings of this paper were significant for the quality control of HRGA compaction. 展开更多
关键词 High-speed railway subgrade Graded aggregates Vibratory compaction test Optimal vibration compaction parameters Physical-mechanical indicator
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Structure of myelin in the central nervous system and another possible driving force for its formation—myelin compaction
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作者 Qi SHAO Simin CHEN +5 位作者 Tian XU Yuyu SHI Zijin SUN Qingguo WANG Xueqian WANG Fafeng CHENG 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 2025年第4期303-316,共14页
Myelin formation is considered the last true“invention”in the evolution of vertebrate nervous system cell structure.The rapid jumping pulse propagation achieved by myelin enables the high conduction speed that is th... Myelin formation is considered the last true“invention”in the evolution of vertebrate nervous system cell structure.The rapid jumping pulse propagation achieved by myelin enables the high conduction speed that is the basis of human movement,sensation,and cognitive function.As a key structure in the brain,white matter is the gathering place of myelin.However,with age,white matter-associated functions become abnormal and a large number of myelin sheaths undergo degenerative changes,causing serious neurological and cognitive disorders.Despite the extensive time and effort invested in exploring myelination and its functions,numerous unresolved issues and challenges persist.In-depth exploration of the functional role of myelin may bring new inspiration for the treatment of central nervous system(CNS)diseases and even mental illnesses.In this study,we conducted a comprehensive examination of the structure and key molecules of the myelin in the CNS,delving into its formation process.Specifically,we propose a new hypothesis regarding the source of power for myelin expansion in which membrane compaction may serve as a driving force for myelin extension.The implications of this hypothesis could provide valuable insights into the pathophysiology of diseases involving myelin malfunction and open new avenues for therapeutic intervention in myelin-related disorders. 展开更多
关键词 MYELIN Central nervous system White matter Myelin compaction
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Loess compaction at different water contents:Effects on hydraulic conductivity,compression behavior,microstructure,and water distribution
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作者 Kangze Yuan Wankui Ni +3 位作者 Xiangfei Lü Haiman Wang Yongpeng Nie Gabriele Della Vecchia 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第8期5307-5317,共11页
In this study,compacted loess samples with varying compaction water content but identical dry density were prepared to investigate the evolution of their hydraulic conductivity and compression behavior.Additionally,en... In this study,compacted loess samples with varying compaction water content but identical dry density were prepared to investigate the evolution of their hydraulic conductivity and compression behavior.Additionally,environmental scanning electron microscopy(ESEM)and nuclear magnetic resonance(NMR)analyses were conducted to gain microstructural insights into loess behavior at the laboratory scale.The results indicate that the maximum saturated hydraulic conductivity is observed at the lowest compaction water content,particularly in the early stage of permeability tests.In particular,for loess compacted at water contents below the optimum(as determined by the modified Proctor compaction test),the hydraulic conductivity decreases throughout the permeability tests.Conversely,when the water content exceeds the optimum level,the hydraulic conductivity shows an increasing trend.In terms of compression behavior,when the as-compacted samples are loaded in oedometer conditions,an increase in material compressibility is observed with increasing compaction water content.Again,a different phenomenological behavior was observed when the compaction water content exceeded the optimum,i.e.an abrupt increase in loess compressibility.ESEM tests provide microstructural confirmation of this evidence,as the surface morphology of the compacted loess changes significantly with increasing compaction water content.The microstructural evolution was also quantified in terms of area ratio using image processing software.Finally,NMR was used to quantify the intra-and inter-aggregate water at different compaction water contents,once again highlighting a threshold for the presence or absence of inter-aggregate water similar to the optimum water content. 展开更多
关键词 Compacted loess Water content COMPRESSIBILITY Hydraulic conductivity MICROSTRUCTURE
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Compressive damage constitutive model for brittle coal based on the compaction effect and linear energy dissipation law
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作者 Fengqiang Gong Lei Xu +2 位作者 Mingzhong Gao Yingjie Zhao Peilei Zhang 《International Journal of Coal Science & Technology》 2025年第3期225-247,共23页
The study of the mechanical property and damage state of coal materials under compression is a fundamental area of research in underground mining engineering.Drawing upon the compaction effect and linear energy dissip... The study of the mechanical property and damage state of coal materials under compression is a fundamental area of research in underground mining engineering.Drawing upon the compaction effect and linear energy dissipation(LED)law,a novel compressive damage constitutive model for brittle coal is proposed.Utilizing the energy-defined damage method for mate-rials,the LED law is innovatively introduced to accurately characterize the energy dissipation during the loading process,and a novel formula for characterizing the damage variable of brittle coal is proposed.On this basis,considering that the constitutive model based on the hypothesis of strain equivalence is incapable of accurately describing the compaction effect exhibited by coal material during the compression process,a correction coefficient is proposed and apply it in the novel damage constitutive model.The established conventional monotone loading and single-cyclic loading-unloading uniaxial compression damage constitutive models have been validated using experimental data from cylindrical and cuboid coal specimens.In addition,compared with the constitutive model obtained via the traditional energy calculation method based on the hypothesis that the unloading curve is a straight line,the constitutive model employing LED law can describe the stress-strain state of brittle coal more precisely.This approach introduces a new perspective and enhances the convenience for constructing the constitutive model based on energy theory. 展开更多
关键词 DAMAGE Constitutive model compaction effect Brittle coal Linear energy dissipation law
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Evaluating densification effect of ideal compaction grouting in unsaturated soils by volumetric water content
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作者 Qiong Wang Guang Hu +2 位作者 Shanyong Wang Wei Su Weimin Ye 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第8期5089-5098,共10页
Compaction grouting is primarily applied based on empiricism,and it is challenging to quantify its densification effect.To address this issue,five sets of laboratory model tests on ideal compaction grouting were condu... Compaction grouting is primarily applied based on empiricism,and it is challenging to quantify its densification effect.To address this issue,five sets of laboratory model tests on ideal compaction grouting were conducted,with varying pressures from 400 kPa to 800 kPa,to quantitatively evaluate the densification effect in unsaturated soils.The response of surrounding soil during compaction grouting was monitored.The changes in dry density and void ratio induced by compaction grouting were obtained by monitoring volumetric water content to determine compaction efficiency.In addition,a model was developed and validated to predict the effective compaction range.The results show that soil dry density increased rapidly during compaction grouting before being stabilized at a consistent level.As expected,it is positively correlated with grouting pressures(GPs)and negatively correlated with the distance from the injection point.At higher GPs,the difference in densification effect around the injection point after compaction grouting was significant.Interestingly,variations in ultimate dry density and peak earth pressures perpendicular to the injection direction exhibited axisymmetric behavior around the injection point when comparing the dry density and earth pressure results.Furthermore,soil densification resulted in a decrease in suction.However,no significant effect of GP on suction at different soil positions was observed.Moreover,compaction efficiency decreased with increasing distance from the injection point,showing a strong linear relationship.In addition,the model results for the effective compaction range were basically consistent with the extrapolated values from the experimental results. 展开更多
关键词 compaction grouting Densification effect Dry density Void ratio Volumetric water content Unsaturated soil
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Advanced intelligent compaction strategy for subgrade soil considering heterogeneous database
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作者 Xuefei Wang Jianhua Li +2 位作者 Jiale Li Jianmin Zhang Guowei Ma 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第5期3265-3279,共15页
Real-time assessment of subgrade compaction quality poses a significant challenge in the implementation of intelligent compaction(IC).Current compaction evaluation models are confined to specific scenarios and lack ro... Real-time assessment of subgrade compaction quality poses a significant challenge in the implementation of intelligent compaction(IC).Current compaction evaluation models are confined to specific scenarios and lack robustness.This study proposes a subgrade compaction strategy that utilizes a heterogeneous dataset to estimate compaction quality across diverse scenarios while maintaining model accuracy.Field compaction tests are conducted in four distinct scenarios,considering various construction parameters.Compaction models are developed using several machine learning algorithms.The datasets are thoroughly assessed in terms of quality,diversity and similarity.The proposed model exhibits good performance in new scenarios by incorporating an additional 5%e8%of new data for retraining.The model's generalization capability is enhanced by conducting a limited number of field tests,which are labor-saving and time-efficient.The model's accuracy consistently improves across diverse scenarios and optimal algorithms.The proposed compaction strategy adopts a physics-and-data dual-driven approach,aimed at practical engineering applications and guiding the compaction procedure. 展开更多
关键词 Intelligent compaction Subgrade construction Machine learning algorithms Heterogeneous scenarios Quality evaluation Training strategy
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高密实石墨-膨润土块体的“两步压实”制备方法
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作者 谈云志 赵凌晖 +2 位作者 张金生 祝雨 明华军 《岩土工程学报》 北大核心 2026年第1期217-224,共8页
膨润土和石墨细腻如粉,压成高密实大型块体,需要超大吨位的加载设备。为破解该难题,提出“两步压实”法,即先把细腻的粉粒压成高密实块体,再破碎成团;然后,团粒与粉粒再混合,以较低的荷载压成尺寸更大的高密实块体。研究表明,相较于用... 膨润土和石墨细腻如粉,压成高密实大型块体,需要超大吨位的加载设备。为破解该难题,提出“两步压实”法,即先把细腻的粉粒压成高密实块体,再破碎成团;然后,团粒与粉粒再混合,以较低的荷载压成尺寸更大的高密实块体。研究表明,相较于用纯粉粒膨润土直接压实,“两步压实”法可以实现用相同吨位压力机制备出更高密实度的块体,提升块体密度超4%。当目标干密度为1.93 g/cm3时,压实应力可减少4 MPa。压实过程中,团粒经历“重排、破碎、压密”的变化,当团粒含量在30%时,复压块体能更好地发挥压实力效益、具备更优的成型能力和均匀性。微观试验也表明:“两步压实法”能够减小复压块体中的孔径,提高块体的密实度。 展开更多
关键词 球状石墨 膨润土 压实 块体 缓冲层
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秸秆还田对稻田渗漏液DOC含量及土壤Cd活度的影响 被引量:20
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作者 柏彦超 陈国华 +3 位作者 路平 陶天云 封克 单玉华 《农业环境科学学报》 CAS CSCD 北大核心 2011年第12期2491-2495,共5页
通过盆栽试验,研究了秸秆还田对稻田渗漏液DOC含量及重金属污染土壤Cd溶出的影响。结果表明,秸秆还田增加了稻田渗漏液的DOC含量,提高了土壤Cd的活度。稻田渗漏水DOC的浓度随秸秆还田量的增加而增大。秸秆还田增加了Cd随稻田渗漏水的流... 通过盆栽试验,研究了秸秆还田对稻田渗漏液DOC含量及重金属污染土壤Cd溶出的影响。结果表明,秸秆还田增加了稻田渗漏液的DOC含量,提高了土壤Cd的活度。稻田渗漏水DOC的浓度随秸秆还田量的增加而增大。秸秆还田增加了Cd随稻田渗漏水的流失,使得稻田土壤Cd全量、有效态Cd量均随秸秆还田量的增加而降低,部分处理降低幅度达显著水平。本试验条件下由于较多的秸秆还田影响了水稻生长,使水稻植株Cd浓度、累积量均随秸秆还田量的增加呈先上升后下降的趋势。秸秆还田0.5%处理的水稻植株Cd浓度、累积量最高,分别为45.10mg·kg-1、1858.1μg·pot-1。 展开更多
关键词 秸秆还田 渗漏液 doc Cd
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基于DOC+CDPF+SCR技术的国Ⅴ排放重型柴油机气态物排放特性研究 被引量:15
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作者 楼狄明 严嵘 +2 位作者 胡志远 谭丕强 姚笛 《环境工程》 CAS CSCD 北大核心 2014年第10期79-84,共6页
基于DOC+CDPF+SCR后处理技术,在国V排放重型柴油机平台上研究了后处理装置三个测点:本机后、DOC+CDPF后以及SCR后的NOx、THC、CO、SO2、CO2以及醛类等气态物排放特性。研究结果表明:DOC+CDPF+SCR联合工作能够有效降低柴油机的NOx、THC... 基于DOC+CDPF+SCR后处理技术,在国V排放重型柴油机平台上研究了后处理装置三个测点:本机后、DOC+CDPF后以及SCR后的NOx、THC、CO、SO2、CO2以及醛类等气态物排放特性。研究结果表明:DOC+CDPF+SCR联合工作能够有效降低柴油机的NOx、THC、CO及SO2的排放,转化率分别达到91.8%、96.9%、99.9%和90.5%。SCR对柴油机排放中的NOx和SO2净化起主导作用,DOC+CDPF对THC和CO净化起主导作用。SCR对发动机背压的影响以及尿素的分解引起柴油机的CO2和醛类排放上升分别为3.1%和22.8%。 展开更多
关键词 柴油机 SCR doc CDPF 气态排放
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DOC技术对柴油机排放颗粒物数浓度的影响 被引量:22
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作者 王军方 丁焰 +4 位作者 尹航 葛蕴珊 王小臣 谭建伟 何超 《环境科学研究》 EI CAS CSCD 北大核心 2011年第7期711-715,共5页
利用ELPI(电子低压冲击器)对不同转速、不同负荷以及安装DOC(氧化催化转化器)前后颗粒物排放及粒径分布进行了研究.结果表明:无论安装DOC与否,柴油机排放颗粒物数浓度均随发动机转速的增加而增加.增大负荷,颗粒物数浓度峰值处的粒径也... 利用ELPI(电子低压冲击器)对不同转速、不同负荷以及安装DOC(氧化催化转化器)前后颗粒物排放及粒径分布进行了研究.结果表明:无论安装DOC与否,柴油机排放颗粒物数浓度均随发动机转速的增加而增加.增大负荷,颗粒物数浓度峰值处的粒径也随之增大.经过DOC催化转化后,柴油机排放颗粒物的大部分仍呈单峰正态分布,且DOC对核模态粒子的氧化转化效率较高.经过DOC后,在低转速下,不同粒径的颗粒物数浓度均有所降低;中、高转速下,DOC对粒径大于120 nm的颗粒物数浓度无明显降低作用. 展开更多
关键词 柴油机 氧化催化转化器(doc) 颗粒物 数浓度 粒径分布
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甲醇柴油双燃料燃烧结合DOC/POC耦合大幅度减少发动机微粒排放的研究 被引量:12
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作者 姚春德 刘辰 +5 位作者 耿鹏 王全刚 潘望 韩国鹏 余海涛 王建云 《环境科学学报》 CAS CSCD 北大核心 2014年第11期2918-2924,共7页
对一台四缸增压中冷柴油机采用甲醇柴油双燃料模式,研究了甲醇替代率和柴油机氧化催化转化器耦合微粒催化转化器(DOC+POC)后处理装置对该发动机烟度和微粒数量、质量浓度的粒径分布特性的影响.试验结果表明,随甲醇替代率的增加,发动机... 对一台四缸增压中冷柴油机采用甲醇柴油双燃料模式,研究了甲醇替代率和柴油机氧化催化转化器耦合微粒催化转化器(DOC+POC)后处理装置对该发动机烟度和微粒数量、质量浓度的粒径分布特性的影响.试验结果表明,随甲醇替代率的增加,发动机烟度和微粒数浓度、质量浓度均有不同程度的降低,核态微粒浓度显著降低,聚集态微粒浓度基本保持不变.相比于DOC+POC对纯柴油发动机排气烟度25%左右的净化效率,在甲醇柴油双燃料模式下DOC+POC对排气烟度的平均净化效率在60%以上,最大达到96%,显示了该后处理技术在甲醇柴油双燃料模式下清洁排放的良好应用前景. 展开更多
关键词 甲醇/柴油 烟度 微粒 粒径分布 doc+POC
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DOC对燃用调合生物柴油发动机PM排放的影响 被引量:7
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作者 杜家益 周仁双 +3 位作者 张登攀 周小强 夏群 袁银男 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2017年第2期497-502,共6页
为研究氧化催化转化器(DOC)对柴油机燃用不同调合生物柴油(BO、B10、B20)后排气颗粒物粒径分布及组分的影响规律,利用MOUDI对颗粒物进行分级采样,对分级颗粒称重得到质量浓度分布,利用热重分析仪分析颗粒物热重特性及组分变化.结果表明... 为研究氧化催化转化器(DOC)对柴油机燃用不同调合生物柴油(BO、B10、B20)后排气颗粒物粒径分布及组分的影响规律,利用MOUDI对颗粒物进行分级采样,对分级颗粒称重得到质量浓度分布,利用热重分析仪分析颗粒物热重特性及组分变化.结果表明:未加装DOC时,随着生物柴油比例的增加,各粒径级颗粒物质量浓度均降低,B20降幅最大;颗粒物质量浓度峰值范围内的粒径大小处于0.18~0.32μm,SOF质量分数依次升高,无机盐和Soot质量分数依次降低.加装DOC后,颗粒物质量浓度降低,DOC对粒径大于1μm颗粒转化效果不明显,聚集态颗粒质量浓度转化效率明显高于粗粒子态颗粒,B20聚集态转化效率最高,可达61.6%.随着转速的升高,转化效率明显降低,颗粒中SOF质量分数降低,H_2O、Soot,无机盐质量分数均增大. 展开更多
关键词 doc 生物柴油 颗粒物 粒径分布 组分
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利用CDOM吸收系数估算太湖水体表层DOC浓度 被引量:20
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作者 姜广甲 马荣华 段洪涛 《环境科学》 EI CAS CSCD 北大核心 2012年第7期2235-2243,共9页
溶解有机碳(DOC)是水体中最大的有机碳库,在水体碳循环中起着重要作用.有色溶解有机物(CDOM)是DOC的重要组成部分,其吸光作用改变着水下光场结构,是水色遥感监测的重要因子之一,建立两者的联系为利用遥感技术估算湖泊水体表层DOC浓度提... 溶解有机碳(DOC)是水体中最大的有机碳库,在水体碳循环中起着重要作用.有色溶解有机物(CDOM)是DOC的重要组成部分,其吸光作用改变着水下光场结构,是水色遥感监测的重要因子之一,建立两者的联系为利用遥感技术估算湖泊水体表层DOC浓度提供有效的技术方法.基于2010年5月、2011年1月、2011年3月和2011年5月的太湖4期实验数据(183个采样点),利用CDOM特征波长吸收系数[ag(250)和ag(365)]建立多元线性模型估算太湖水体DOC浓度,同时利用2011年8月29日~9月2日的数据(n=27)对模型进行验证评价,并构建了湖泊水体DOC浓度的遥感反演模式.结果表明,该模型能够有效估算太湖水体的DOC浓度;2011年1月DOC和CDOM的源和汇有较大差异,估算效果较差;其他3期数据的模型估算效果显著(R2=0.64,RMSE=14.31%,n=164),并在201108期数据中得到了验证(R2=0.67,RMSE=10.58%,n=27).模型形式虽具有一定的通用性,但系数在不同的水域中有所差异,模型系数的区域化成为下一步研究的重点. 展开更多
关键词 遥感 CDOM比吸收系数 光谱斜率 doc 太湖
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原位土壤溶液采样及可溶性有机碳(DOC)的紫外吸收光谱直接测定探讨 被引量:30
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作者 罗小三 仓龙 +2 位作者 郝秀珍 李连祯 周东美 《土壤》 CAS CSCD 北大核心 2007年第6期943-947,共5页
首次采用管壁过滤孔径为微米级(0.1~O.3 μm)的水处理用多孔聚丙烯(腈)空心纤维细管,与注射器或真空管相连,自制成土壤溶液采样器,将空心纤维管埋置或插入土壤中抽取层面土壤溶液,所得溶液无须过滤即可进行各种理化分析和测定,且可连... 首次采用管壁过滤孔径为微米级(0.1~O.3 μm)的水处理用多孔聚丙烯(腈)空心纤维细管,与注射器或真空管相连,自制成土壤溶液采样器,将空心纤维管埋置或插入土壤中抽取层面土壤溶液,所得溶液无须过滤即可进行各种理化分析和测定,且可连续采样,提出了一种价廉实用的原位土壤溶液取样方法.并根据可溶性有机碳(DOC)在紫外光区的吸收特征,将土壤溶液在254 nm波长处的吸光度(UVA254)与DOC浓度(TOC仪法)进行比较,发现两者有较好的相关性(DOC=38.84×UVA254,n=37,R2=O.82),即直接测定土壤溶液的UVA254,再乘以系数38.84可以估算DOC浓度.与复杂的氧化-比色和昂贵的TOC仪测定法对比,UVA254能快速便捷地估计土壤溶液中DOC的浓度.UVA254也适用于水体DOC的估计. 展开更多
关键词 原位土壤溶液采样器 可溶性有机碳(doc) 紫外分光光度法 UVA254
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DOC对柴油机颗粒物排放影响的试验研究 被引量:9
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作者 孟忠伟 张川 +2 位作者 李路 张文强 陈超 《内燃机工程》 EI CAS CSCD 北大核心 2017年第2期67-72,共6页
基于柴油机台架试验,在一款柴油机上加装了DOC装置,研究了DOC前后颗粒数量浓度、DOC前后颗粒SOF含量和活化能变化趋势。研究结果表明:DOC能降低核模态颗粒数量浓度和积聚态颗粒数量浓度,但随着转矩增加,DOC反而会使积聚态颗粒数量浓度... 基于柴油机台架试验,在一款柴油机上加装了DOC装置,研究了DOC前后颗粒数量浓度、DOC前后颗粒SOF含量和活化能变化趋势。研究结果表明:DOC能降低核模态颗粒数量浓度和积聚态颗粒数量浓度,但随着转矩增加,DOC反而会使积聚态颗粒数量浓度增加。DOC对颗粒总数量浓度的影响随柴油机转矩的增加呈现先降低后增加的趋势。在转矩为50N·m和100N·m工况下,DOC能使颗粒SOF组分含量降低,使颗粒的表观氧化活化能升高。此外,排气颗粒的表观氧化活化能随SOF含量的增加整体上呈下降趋势。 展开更多
关键词 doc 柴油机颗粒 颗粒数量浓度 SOF含量 表观活化能
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柴油尾气DOC催化剂Pt-Pd/CeO_2的活性和抗硫性 被引量:10
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作者 黄海凤 王庐云 +1 位作者 漆仲华 卢晗锋 《燃料化学学报》 EI CAS CSCD 北大核心 2013年第11期1401-1408,共8页
采用浸渍法制备了不同Pt、Pd比例的Pt-Pd/CeO2催化剂,考察了其催化氧化模拟柴油车尾气的活性,并测试了抗硫性。活性测试结果表明,Pt、Pd协同降低了催化剂的起燃温度,其比例对催化剂性能影响很大,其中,Pt0.2Pd0.8/CeO2催化剂在模拟柴油... 采用浸渍法制备了不同Pt、Pd比例的Pt-Pd/CeO2催化剂,考察了其催化氧化模拟柴油车尾气的活性,并测试了抗硫性。活性测试结果表明,Pt、Pd协同降低了催化剂的起燃温度,其比例对催化剂性能影响很大,其中,Pt0.2Pd0.8/CeO2催化剂在模拟柴油车尾气(丙烯(C3H6)、一氧化碳(CO)和一氧化氮(NO))中的催化活性最高;C3H6的t50降到170℃,CO的t50降到了150℃,显示了良好的Pt、Pd协同效应;H2-TPR表征和抗硫性结果分析表明,高比例Pt/Pd催化剂具有更多的表面活性氧,其相对数值与催化剂抗硫性能的关联度高,在催化剂硫酸盐中毒的条件下,更有利于催化反应的进行。 展开更多
关键词 doc催化剂 Pt-Pd协同 柴油尾气 抗硫性
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季节性冻融格局变化对高山森林土壤DOC淋洗的影响 被引量:9
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作者 苟小林 吴福忠 +5 位作者 杨万勤 谭波 徐振锋 刘金铃 李志萍 黄莉 《水土保持学报》 CSCD 北大核心 2013年第6期205-210,共6页
采用土柱培养实验,利用海拔形成的温度差异模拟气候变暖过程,将高山森林(海拔3 600m)土壤分别培养在海拔3 600m(A1),3 300m(A2)和3 000m(A3)的森林地表,研究生长季节与非生长季节内5个关键时期的土壤可溶性有机碳(DOC)淋溶特征。结果表... 采用土柱培养实验,利用海拔形成的温度差异模拟气候变暖过程,将高山森林(海拔3 600m)土壤分别培养在海拔3 600m(A1),3 300m(A2)和3 000m(A3)的森林地表,研究生长季节与非生长季节内5个关键时期的土壤可溶性有机碳(DOC)淋溶特征。结果表明:川西高山输入土壤和土壤输出的DOC集中于生长季节末期至深冻期,DOC淋溶量表现为非生长季节>生长季节,非生长季节最高淋溶输入量可达7.30kg/hm2,最高淋溶输出量达8.69kg/hm2。冻融循环促进了土壤DOC的淋溶,且初冻期(OF)的冻融循环使得DOC大量淋溶。整个土层DOC淋溶量在生长季节为A1(5.91kg/hm2)>A2(2.99kg/hm2)>A3(1.79kg/hm2),非生长季节为A1(3.77kg/hm2)<A2(5.11kg/hm2)<A3(7.24kg/hm2)。这些结果意味着气候变暖将加速高山森林土壤DOC的淋溶,导致高山森林土壤碳库减小,水体和溪流DOC增加。 展开更多
关键词 季节性冻融 doc淋溶 森林土壤 高山森林
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