Silica is becoming more attractive as plant nutrient for non-graminae crops particularly in relation with drought-stress tolerant. Many efforts have been conducted to obtain an efficient technique to produce silica fe...Silica is becoming more attractive as plant nutrient for non-graminae crops particularly in relation with drought-stress tolerant. Many efforts have been conducted to obtain an efficient technique to produce silica fertilizer worldwide, but the results are varying considerably due to various factors including raw material and extraction technique. This study was carried out to develop an efficient extraction technique for ortho-silicic acid (OSA-H4SiO4) from a Bangka-Belitung quartz sand by employing acid-base dissolution method. A 325-mesh size quartz sand was boiled in HCl solution at various concentrations. The optimum concentration was then used in the following experiment at several different volumes of solution. The sand obtained from optimum concentration and volume of HCl solution was then reacted with different amounts of NaOH (s), and heated until a wet mixture was obtained. As a reference the best extraction conditions were applied to a natural zeolite sample. All OSA analyses were done in triplicates with spectrophotometric method. Supporting evidences were collected from x-ray diffraction and scanning-electron-microscopy analyses of the treated samples. The yield of quartz sand-originated OSA was 183 g·kg-1 and significantly increased linearly with increasing weight of NaOH (R2 = 0.99**), whereas that from zeolite was only 104.2 g·kg-1 at 80 g NaOH. XRD and SEM data confirmed the evidences that the acid-base extraction disrupted the quartz mineral structure and as a consequence releasing more water soluble OSA.展开更多
The strength of the mould cavity in sand casting is very much significant to attain high-quality castings. Optimization of green sand process parameters plays a vital role in minimizing casting defects. In the present...The strength of the mould cavity in sand casting is very much significant to attain high-quality castings. Optimization of green sand process parameters plays a vital role in minimizing casting defects. In the present research work, the effect of process parameters such as AFS grain fineness number, water, molasses, bentonite, fly ash, and ramming, and their levels on the resultant mould properties were investigated and optimized using Taguchi based grey relational analysis. The Taguchi L18 orthogonal array and analysis of variance(ANOVA) were used. The quality characteristics viz., green compression strength, permeability, bulk density, mould hardness and shatter index of green sand mould were optimized using grey relational grade, based on the experiments designed using Taguchi's Design of Experiments. ANOVA analysis indicated that water content is the most influential parameter followed by bentonite, and degree of ramming that contributes to the quality characteristics. The results are confirmed by calculating confidence intervals, which lies within the interval limits. Finally, microstructure observations and X-ray diffraction analysis have been performed for the optimal sand parametric combination. Results show that presence of maximum amount of SiO_2, which might be the reason for enhancement of the physical properties of the sand.展开更多
Free opening rate is mainly determined by the performance of the ladle filler sand. High free opening rates of ladles are required in steel making to improve steel quality. Chromite ladle filler sands are one of the m...Free opening rate is mainly determined by the performance of the ladle filler sand. High free opening rates of ladles are required in steel making to improve steel quality. Chromite ladle filler sands are one of the most widely used ladle filler sand. Several operative variables and materials characteristics affect the performance of the sands. Three sets of chromite ladle filler sands were selected and researches were focused on the sintering hehaviour and per- formance of the sands under operative conditions. The effect of particle size distribution on sintering, microstruc- ture, flowability, and permeability were presented. In all cases, the particle size varies from 0.1 to 1.5 mm corre- sponding to free flowing powders. One of the samples has higher permeability factor in comparison with others due to low particle size distribution. The other sample presents very good free opening due to its very good flowability and permeability factor.展开更多
The paper describes an energy-based constitutive model for sand, which is modified based on the modified plastic strain energy approach, represented by a unique relationship between the modified plastic strain energy ...The paper describes an energy-based constitutive model for sand, which is modified based on the modified plastic strain energy approach, represented by a unique relationship between the modified plastic strain energy and a stress parameter, independent of stress history. The modified plastic strain energy approach was developed based on results from a series of drained plastic strain compression tests along various stress paths on saturated dense Toyoura sand with accurate stress and strain measurements. The proposed model is coupled with an isotropically work-hardening and softening, non-associtated, elasto-plastic material description. The constitutive model concerns the inherent and stress system-induced cross-anisotropic elastic deformation properties of sand. It is capable of simulating the deformation characteristics of stress history and stress path, the effects of pressure level, anisotropic strength and void ratio, and the strain localization.展开更多
文摘Silica is becoming more attractive as plant nutrient for non-graminae crops particularly in relation with drought-stress tolerant. Many efforts have been conducted to obtain an efficient technique to produce silica fertilizer worldwide, but the results are varying considerably due to various factors including raw material and extraction technique. This study was carried out to develop an efficient extraction technique for ortho-silicic acid (OSA-H4SiO4) from a Bangka-Belitung quartz sand by employing acid-base dissolution method. A 325-mesh size quartz sand was boiled in HCl solution at various concentrations. The optimum concentration was then used in the following experiment at several different volumes of solution. The sand obtained from optimum concentration and volume of HCl solution was then reacted with different amounts of NaOH (s), and heated until a wet mixture was obtained. As a reference the best extraction conditions were applied to a natural zeolite sample. All OSA analyses were done in triplicates with spectrophotometric method. Supporting evidences were collected from x-ray diffraction and scanning-electron-microscopy analyses of the treated samples. The yield of quartz sand-originated OSA was 183 g·kg-1 and significantly increased linearly with increasing weight of NaOH (R2 = 0.99**), whereas that from zeolite was only 104.2 g·kg-1 at 80 g NaOH. XRD and SEM data confirmed the evidences that the acid-base extraction disrupted the quartz mineral structure and as a consequence releasing more water soluble OSA.
基金financially supported by the National Institute of Technology,Manipur,India
文摘The strength of the mould cavity in sand casting is very much significant to attain high-quality castings. Optimization of green sand process parameters plays a vital role in minimizing casting defects. In the present research work, the effect of process parameters such as AFS grain fineness number, water, molasses, bentonite, fly ash, and ramming, and their levels on the resultant mould properties were investigated and optimized using Taguchi based grey relational analysis. The Taguchi L18 orthogonal array and analysis of variance(ANOVA) were used. The quality characteristics viz., green compression strength, permeability, bulk density, mould hardness and shatter index of green sand mould were optimized using grey relational grade, based on the experiments designed using Taguchi's Design of Experiments. ANOVA analysis indicated that water content is the most influential parameter followed by bentonite, and degree of ramming that contributes to the quality characteristics. The results are confirmed by calculating confidence intervals, which lies within the interval limits. Finally, microstructure observations and X-ray diffraction analysis have been performed for the optimal sand parametric combination. Results show that presence of maximum amount of SiO_2, which might be the reason for enhancement of the physical properties of the sand.
文摘Free opening rate is mainly determined by the performance of the ladle filler sand. High free opening rates of ladles are required in steel making to improve steel quality. Chromite ladle filler sands are one of the most widely used ladle filler sand. Several operative variables and materials characteristics affect the performance of the sands. Three sets of chromite ladle filler sands were selected and researches were focused on the sintering hehaviour and per- formance of the sands under operative conditions. The effect of particle size distribution on sintering, microstruc- ture, flowability, and permeability were presented. In all cases, the particle size varies from 0.1 to 1.5 mm corre- sponding to free flowing powders. One of the samples has higher permeability factor in comparison with others due to low particle size distribution. The other sample presents very good free opening due to its very good flowability and permeability factor.
基金The project supported by the Association of International Education of Japan
文摘The paper describes an energy-based constitutive model for sand, which is modified based on the modified plastic strain energy approach, represented by a unique relationship between the modified plastic strain energy and a stress parameter, independent of stress history. The modified plastic strain energy approach was developed based on results from a series of drained plastic strain compression tests along various stress paths on saturated dense Toyoura sand with accurate stress and strain measurements. The proposed model is coupled with an isotropically work-hardening and softening, non-associtated, elasto-plastic material description. The constitutive model concerns the inherent and stress system-induced cross-anisotropic elastic deformation properties of sand. It is capable of simulating the deformation characteristics of stress history and stress path, the effects of pressure level, anisotropic strength and void ratio, and the strain localization.
