To reveal the deterioration mechanism of coal-rock assemblages under chemical corrosion and dynamic loading,chemical corrosion and dynamic impact experiments were conducted.Under different chemical corrosion condition...To reveal the deterioration mechanism of coal-rock assemblages under chemical corrosion and dynamic loading,chemical corrosion and dynamic impact experiments were conducted.Under different chemical corrosion conditions,the weakening characteristics,observable characteristics,softening characteristics of the dynamic parameters,dynamic failure characteristics,dynamic failure forms and dynamic microscopic characteristics were analyzed.Under each corrosion condition,the dynamic elastic modulus,dynamic deformation modulus and dynamic peak intensity tended to decrease with immersing time.The dynamic elastic modulus,dynamic deformation modulus and dynamic peak intensity exhibited an inverted U-shaped trend.Under dynamic impact,the failure process of acidly corroded samples can be divided into the following stages:the initial stage,elastic energy accumulation stage,local failure of coal and secondary rock crack expansion stage,coal fragment ejection stage,rock spalling stage and complete instability stage.Under dynamic impact,failure modes exist:coal crushing failure,rock fragmenting failure,rock splitting failure and full splitting failure.After impact failure,sample fragments are distributed in powder,granular,cone and block forms.Based on Zhu-Wang-Tang nonlinear viscoelastic properties,a model considering chemical corrosion and impact damage was proposed.The combined effects of chemical and impact-induced damage on the dynamic mechanical properties of coal-rock assemblages were systematically analyzed.展开更多
The marine-continental transitional shale of the Upper Permian Longtan Formation is widely distributed in Hunan and shows significant exploration potential.Frequent changes in lithofacies have however notably influenc...The marine-continental transitional shale of the Upper Permian Longtan Formation is widely distributed in Hunan and shows significant exploration potential.Frequent changes in lithofacies have however notably influenced the shale gas enrichment.The strata of the Longtan Formation in the Shaoyang Depression,central Hunan,were taken as the study object for this project.Three lithofacies assemblages were identified:shale interbedded with sandstone layer(SAL),sandstone interbedded with shale layer(ASL)and laminated shale layer(LSL).The SAL shale shows significant variability in hydrocarbon generation potential,which leads to shale gas characterized by'hydrocarbon generation in high total organic carbon(TOC)shale,retention in low TOC shale and accumulation in sandstone'.The ASL shale,influenced by the redox conditions of the depositional environment,shows a lower concentration of organic matter.This results in an enrichment model of'hydrocarbon generation and accumulation in shale,with sealing by sandstone'.The laminar structure of LSL shale causes both quartz and clay minerals to control the reservoir.Shale gas is characterized by'hydrocarbon generation in mud laminae,retention and accumulation in silty laminae,with multiple intra-source migration paths'.In the marine-continental transitional shale gas system,the enrichment intervals of different types of shale gas reservoirs exhibit significant variability.展开更多
0 INTRODUCTION The Andean orogenic belt,a globally significant active continental margin(Lamb et al.,1997),extends in a north-south direction along the western coast of South America.The Colombian Andes,located in the...0 INTRODUCTION The Andean orogenic belt,a globally significant active continental margin(Lamb et al.,1997),extends in a north-south direction along the western coast of South America.The Colombian Andes,located in the northern segment of this orogen,constitute a vital component and host abundant Au-Cu resources.Three principal Au-Cu metallogenic belts(Chocó,Middle Cauca,and Antioquia)are developed from west to east across Colombia(Lesage et al.,2013;Sillitoe,2008;Figure 1a).展开更多
基金supported by the National Natural Science Foundation of China(Nos.52034009 and 52174093)the Fundamental Research Funds for the Central Universities(Nos.2024ZKPYNY01,2023ZKPYNY03,and 2023YQTD02).
文摘To reveal the deterioration mechanism of coal-rock assemblages under chemical corrosion and dynamic loading,chemical corrosion and dynamic impact experiments were conducted.Under different chemical corrosion conditions,the weakening characteristics,observable characteristics,softening characteristics of the dynamic parameters,dynamic failure characteristics,dynamic failure forms and dynamic microscopic characteristics were analyzed.Under each corrosion condition,the dynamic elastic modulus,dynamic deformation modulus and dynamic peak intensity tended to decrease with immersing time.The dynamic elastic modulus,dynamic deformation modulus and dynamic peak intensity exhibited an inverted U-shaped trend.Under dynamic impact,the failure process of acidly corroded samples can be divided into the following stages:the initial stage,elastic energy accumulation stage,local failure of coal and secondary rock crack expansion stage,coal fragment ejection stage,rock spalling stage and complete instability stage.Under dynamic impact,failure modes exist:coal crushing failure,rock fragmenting failure,rock splitting failure and full splitting failure.After impact failure,sample fragments are distributed in powder,granular,cone and block forms.Based on Zhu-Wang-Tang nonlinear viscoelastic properties,a model considering chemical corrosion and impact damage was proposed.The combined effects of chemical and impact-induced damage on the dynamic mechanical properties of coal-rock assemblages were systematically analyzed.
基金financial support from the National Natural Science Foundation of China(Grant Nos.U23B20155 and 42202140)the Science and Technology Innovation Program of Hunan Province(2023RC1021)+1 种基金the China Geological Survey(DD20221659)the Science and Technology Bureau,Changsha,China(kq2208261)。
文摘The marine-continental transitional shale of the Upper Permian Longtan Formation is widely distributed in Hunan and shows significant exploration potential.Frequent changes in lithofacies have however notably influenced the shale gas enrichment.The strata of the Longtan Formation in the Shaoyang Depression,central Hunan,were taken as the study object for this project.Three lithofacies assemblages were identified:shale interbedded with sandstone layer(SAL),sandstone interbedded with shale layer(ASL)and laminated shale layer(LSL).The SAL shale shows significant variability in hydrocarbon generation potential,which leads to shale gas characterized by'hydrocarbon generation in high total organic carbon(TOC)shale,retention in low TOC shale and accumulation in sandstone'.The ASL shale,influenced by the redox conditions of the depositional environment,shows a lower concentration of organic matter.This results in an enrichment model of'hydrocarbon generation and accumulation in shale,with sealing by sandstone'.The laminar structure of LSL shale causes both quartz and clay minerals to control the reservoir.Shale gas is characterized by'hydrocarbon generation in mud laminae,retention and accumulation in silty laminae,with multiple intra-source migration paths'.In the marine-continental transitional shale gas system,the enrichment intervals of different types of shale gas reservoirs exhibit significant variability.
基金supported by the National Natural Science Foundation of China(No.42572076)the Continental Gold Ltd.,Colombian Branch(No.CG-EXP-041-23).
文摘0 INTRODUCTION The Andean orogenic belt,a globally significant active continental margin(Lamb et al.,1997),extends in a north-south direction along the western coast of South America.The Colombian Andes,located in the northern segment of this orogen,constitute a vital component and host abundant Au-Cu resources.Three principal Au-Cu metallogenic belts(Chocó,Middle Cauca,and Antioquia)are developed from west to east across Colombia(Lesage et al.,2013;Sillitoe,2008;Figure 1a).
文摘24只雄性SD(Sprague dawley)大鼠在低盐饮食的基础上,随机分为3组:对照组、模型组、治疗组。模型组给予环孢素A(Cyclosporin A,Cs A)30 mg/kg/d腹腔注射共28 d建立慢性肾毒性大鼠模型;治疗组在给予等量Cs A的基础上腹腔注射给予重组可溶性Klotho蛋白(0.02 mg/kg/d腹腔注射,隔日一次)。28 d后处死大鼠,收集肾组织标本;行Masson染色观察肾脏病理损害;TUNEL(Td T-mediated d UTP nick end labeling)染色观察细胞凋亡情况;Western-blot检测肾组织内质网应激标志物兔抗葡萄糖调节蛋白78(glucose regulated protein78,GRP78)及CCAAT/增强子结合蛋白同源蛋白(pro-apoptotic protein CCAAT/enhancer binding protein homologous protein,CHOP)的表达情况。分析发现,模型组大鼠肾脏病理损害明显加重,肾小管上皮细胞大量凋亡,GRP78及CHOP表达显著上调,而Klotho治疗组大鼠肾脏病理损害明显减轻,细胞凋亡减少,GRP78及CHOP的表达明显降低。表明Klotho蛋白可通过抑制内质网应激诱导的凋亡缓解Cs A慢性肾毒性的发生。
