The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with t...The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with the conventional hot-press sintering, microwave sintering to W-2OCu composites could be achieved with lower sintering temperature and shorter sintering time. Furthermore, microwave sintered W-Cu composites with high densification, homogenous microstructure and excellent properties were obtained. Microwave sintering could also result in finer microstructures. ：~展开更多
W-2 wt.%Y2O3 composite material with uniform distribution of yttrium element was fabricated through processes of mechanical alloying （MA） and spark plasma sintering （SPS）. The relevant productions were characteriz...W-2 wt.%Y2O3 composite material with uniform distribution of yttrium element was fabricated through processes of mechanical alloying （MA） and spark plasma sintering （SPS）. The relevant productions were characterized by scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. The XRD showed that the W-2 wt.%Y2O3 composite powder, including tungsten matrix and Y2O3 particles, was refined to nanometer sizes during the MA process. The SEM and TEM micrographs showed that the MA produced composite powder presented a lamellar morphology and contained many dislocations and microcracks. The EDS showed that the Y and O elements were uniformly distributed in the W matrix after mechanically alloying for 15 h. The W-2 wt.%Y2O3 composite material with uniform distribution of yttrium was obtained by sintering of the MA produced composite powder.展开更多
为了实现激光粉末床熔化技术(Laser Powder Bed Fusion,LPBF)成形钨的裂纹抑制,本研究通过添加铼元素和碳元素,成功制备了W-21Re-C合金,并对其成形性、微观组织和力学性能进行了研究。结果发现,LPBF制备W-21Re-C合金的成形窗口较窄,并...为了实现激光粉末床熔化技术(Laser Powder Bed Fusion,LPBF)成形钨的裂纹抑制,本研究通过添加铼元素和碳元素,成功制备了W-21Re-C合金,并对其成形性、微观组织和力学性能进行了研究。结果发现,LPBF制备W-21Re-C合金的成形窗口较窄,并存在一定数量的孔洞和裂纹缺陷,但相较于纯钨裂纹有所减少。LPBF成形W-21Re-C合金中形成了大量六方W_(2)C亚结构,在快速凝固的作用下,体系中微纳尺度亚结构呈现为枝晶结构和胞状结构。合金中铼元素主要以固溶形式存在于钨基体中,W_(2)C亚结构的枝晶臂间隙和胞壁处也存在一定的铼元素偏聚。在铼对钨基体固溶强化和W_(2)C胞状结构的共同作用下,LPBF成形W-21Re-C合金的显微硬度显著高于良好LPBF成形的纯钨。展开更多
基金the Project for Science and Technology Plan of Wuhan City (No. 200910321092)the Youth Science Plan for Light of the Morning Sun of Wuhan City (No. 200750731270)the Fundamental Research Funds for the Central Universities (No. 2010-Ⅱ-020)
文摘The effects of microwave sintering on the properties, phases and microstructure of W-2OCu alloy, using composite powder fabricated by spray pyrolysis-continuous reduction technology, were investigated. Compared with the conventional hot-press sintering, microwave sintering to W-2OCu composites could be achieved with lower sintering temperature and shorter sintering time. Furthermore, microwave sintered W-Cu composites with high densification, homogenous microstructure and excellent properties were obtained. Microwave sintering could also result in finer microstructures. ：~
文摘W-2 wt.%Y2O3 composite material with uniform distribution of yttrium element was fabricated through processes of mechanical alloying （MA） and spark plasma sintering （SPS）. The relevant productions were characterized by scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. The XRD showed that the W-2 wt.%Y2O3 composite powder, including tungsten matrix and Y2O3 particles, was refined to nanometer sizes during the MA process. The SEM and TEM micrographs showed that the MA produced composite powder presented a lamellar morphology and contained many dislocations and microcracks. The EDS showed that the Y and O elements were uniformly distributed in the W matrix after mechanically alloying for 15 h. The W-2 wt.%Y2O3 composite material with uniform distribution of yttrium was obtained by sintering of the MA produced composite powder.
文摘为了实现激光粉末床熔化技术(Laser Powder Bed Fusion,LPBF)成形钨的裂纹抑制,本研究通过添加铼元素和碳元素,成功制备了W-21Re-C合金,并对其成形性、微观组织和力学性能进行了研究。结果发现,LPBF制备W-21Re-C合金的成形窗口较窄,并存在一定数量的孔洞和裂纹缺陷,但相较于纯钨裂纹有所减少。LPBF成形W-21Re-C合金中形成了大量六方W_(2)C亚结构,在快速凝固的作用下,体系中微纳尺度亚结构呈现为枝晶结构和胞状结构。合金中铼元素主要以固溶形式存在于钨基体中,W_(2)C亚结构的枝晶臂间隙和胞壁处也存在一定的铼元素偏聚。在铼对钨基体固溶强化和W_(2)C胞状结构的共同作用下,LPBF成形W-21Re-C合金的显微硬度显著高于良好LPBF成形的纯钨。
