To address the negative impact of an internal curing agent on strength while preserving its ability to resist autogenous shrinkage,we investigated the incorporation of triethanolamine and triisopropanolamine as early-...To address the negative impact of an internal curing agent on strength while preserving its ability to resist autogenous shrinkage,we investigated the incorporation of triethanolamine and triisopropanolamine as early-strength components.These additives were combined with an internal curing agent to prepare a compound early-strength internal curing agent so as to investigate how compound early-strength internal curing agents affect the mechanical characteristics and volume stability of mortar.This was assessed using a battery of tests,including strength,autogenous shrinkage,internal relative humidity,mercury intrusion porosimetry,X-ray powder diffraction,and scanning electron microscopy.These results indicate that the compound early-strength internal curing agent effectively maintains the volume stability of the mortar without compromising its early mechanical properties.The compressive strength ratios of the mortar mixed with the compound early-strength internal curing agent were 109.45% at 3 days and 119% at 7 days,indicating significant improvement compared with the internal curing agent.Furthermore,the 7-day autogenous shrinkage rate of the mortar was-56.78μm/m.The proportion of hazardous-grade pores larger than 100 nm was reduced to 3.54%,and the pore distribution was uniform.This study introduces innovative ideas and methods for mitigating the adverse effects of internal curing agents on the early strength of mortar.展开更多
Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using ...Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using sodium carboxymethyl starch (CMS) with high hydrophilicity,acrylic acid (AA) containing anionic carboxylic group and acrylamide (AM) containing non-ionic amide group as the main raw materials.The results show that the ratio of CAA-ICA alkali absorption solution is higher than that existing ICA,which solves the low water absorption ratio of the ICA in alkali environment.The water absorption ratio of CAA-ICA in saturated Ca(OH)_(2) solution is 95.8 g·g^(-1),and the alkali tolerance coefficient is 3.4.The application of CAA-ICA in cement-based materials can increase the internal relative humidity and miniaturize the pore structure.The compressive strength of mortar increases up to 12.95%at 28 d,which provids a solution to overcome the reduction of the early strength.展开更多
By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual...By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual hydrophilic modified polyurethane curing agent.Research revealed that introducing PEG400 for hydrophilic chain segments and sodium hydroxyethyl sulfonate for hydrophilic ionic groups in the polyurethane curing agent component leads to a uniform distribution of hydrophilic components,significantly enhancing compatibility with the aqueous polyol component,and results in excellent film performance.The synthesis process and film were characterized using Fourier transform infrared spectroscopy and high-resolution scanning electron microscopy in the study.展开更多
A novel waterborne epoxy curing agent was prepared using 3-glycidoxypropyl trimethoxysilane （GPTMS） as a termination agent of adduct, which was synthesized by triethylene tetramine （TETA） and liquid epoxy resin （...A novel waterborne epoxy curing agent was prepared using 3-glycidoxypropyl trimethoxysilane （GPTMS） as a termination agent of adduct, which was synthesized by triethylene tetramine （TETA） and liquid epoxy resin （E-51）. The effects of the reaction temperature and time on the synthesis process were investigated experimentally. The particle size and the distribution of water dispersion of the curing agent were measured by dynamic light scattering（DLS）. The structure of the products was characterized by Fourier transform infrared spec-trometer （FTIR） and ^1H-nuclear magnetic resonance （^1H NMR）. The properties of the synthesized curing agent and the epoxy resin film cured by it were also measured. The results showed that the appropriate temperature for the synthesis of adduct was at 65-75℃ and the reaction time was 4-5h, and that the suitable reaction temperature of curing agent synthesis was 75-85℃ and the reaction time was 3-4h. When the mass ratios of GPTMS and acetic acid were 3%-5% and 5%-10% respectively, the hardness, water resistance and adhesion of the cured film were improved significantly.展开更多
A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Four...A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Fourier transform infrared spectroscopy, nuclear magnetic resonance, mass spectrometry, and gel permeation chro-matography analyses. The thermal properties of the resulting polymer from diglycidyl ether of bisphenol A epoxy resin cured with the novel curing agent were evaluated using dynamic mechanical thermal analysis and thermogra-vimetric analysis. Compared with the conventional curing agent, the resulting polymer cured with naphtha-lene/DCPD navolac shows considerable improvement in heat resistant properties such as higher glass transition temperature (Tg) and thermal stability. The result also shows better moisture resistance because of the hydrophobic nature of naphthalene/DCPD structure.展开更多
To obtain high-efficiency flame retardancy of epoxy resins,a cyclophosphazene derivative tri-(ohenylenediamino)cyclotriphosphazene(3 ACP)was successfully synthesized and used as a curing agent for the thermosetting of...To obtain high-efficiency flame retardancy of epoxy resins,a cyclophosphazene derivative tri-(ohenylenediamino)cyclotriphosphazene(3 ACP)was successfully synthesized and used as a curing agent for the thermosetting of an epoxy resin system.The flame retardant properties,thermal stability,and pyrolysis mechanism of the resultant thermosets were investigated in detail.The experiments indicated that the synthesized thermoset achieved a UL-94 V-0 rate under a vertical burning test as well as a limiting oxygen index(LOI)of 29.2%,which was able to reach V-0 even when a small amount of 3 ACP was incorporated.Scanning electronic microscopic observation demonstrated that the char residue of the thermosets was extremely expanded after the vertical flame test.Thermal analysis showed that the samples had a lower initial decomposition temperature when 3 ACP was introduced into the epoxy resin systems.This indicates that the carbonization ability of the thermosets was significantly improved at elevated temperatures.In addition,the incorporation of 3 ACP can effectively suppress the release of combustible gases during the pyrolysis process,and the decomposition of E-44/DDS-3 ACP curing systems also promotes the formation of polyphosphoramides charred layer in the condensed phase.The investigation on the chemical structures of both the gaseous and condensed phase pyrolysis process confirmed the flame-retardant mechanism of the 3 ACP-cured epoxy resins.Therefore,the nonflammable halogen-free epoxy resin developed in this study has potential applications in electric and electronic fields for environment protection and human health.展开更多
Combined with the advantages of low melting point,high thermal stability and strong acidity,a multipleSO_3H functioned ionic liquid（MIL） was developed successfully as a curing agent to promote the curing reaction of...Combined with the advantages of low melting point,high thermal stability and strong acidity,a multipleSO_3H functioned ionic liquid（MIL） was developed successfully as a curing agent to promote the curing reaction of phthalonitrile-terminated poly（phthalazinone ether nitrile）（PPEN-Ph）.The curing kinetics over differential scanning calorimetry（DSC） showed that both the initial curing temperature Tp0＇ and apparent activation energy Ea＇（based on Kissinger equation） were reduced significantly over MIL（207.9℃ and 101.5 kJ/mol） compared to the common curing agent ZnCl_2（268.5℃ and 201.5 kJ/mol）.Moreover,under identical curing conditions,the resulting thermosetting resin over former（Td5%=526.1℃） showed better thermal stability than that over latter（Td5%=512.1 ℃）.These results indicated that MIL should be a good candidate as a curing agent for phthalonitrile resins.展开更多
One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage ...One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.展开更多
Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability o...Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability of the titanium-oxo-cluster was examined using a microdielectric analytical(DEA)curing monitor,Fourier transformed infrared spectroscopy(FTIR),and Soxhlet extraction experiments,and the properties of the resulted coatings were investigated with pendulum hardness tester,dynamic mechanical analysis(DMA),thermogravimetric analysis(TGA)and ultraviolet-visible spectrometer.The effect of titania-oxo-cluster in leading acrylic oligomers to form thermosetting acrylic coatings was confirmed.An increasing pendulum hardness and modulus of acrylic coatings with increasing titania content was observed, which resulted from the increment of crosslinking degree rather than of the titania content.The thermosetting acrylic/titania coatings also showed better thermal stability and higher UV-blocking properties than those coatings using organic curing agent.展开更多
Cracks easily generate in concrete at early age owing to the shrinkage deformation.CaO-based expansion agent(CEA)and superabsorbent polymers(SAP)have been extensively used for the mitigation of concrete shrinkage.The ...Cracks easily generate in concrete at early age owing to the shrinkage deformation.CaO-based expansion agent(CEA)and superabsorbent polymers(SAP)have been extensively used for the mitigation of concrete shrinkage.The macroscopic properties of concrete are highly determined by the microstructure.In this study,the influence of CEA and SAP addition on the pore structure evolution of cement paste under different curing temperatures was evaluated via low-field nuclear magnetic resonance spectroscopy.Test results indicated that,in cement paste,a higher CEA content led to a higher porosity and a larger most probable pore diameter(MPPD).Meanwhile,SAP addition increased the porosity and MPPD of CEA cement paste at early age but decreased them after 7 d,and a higher SAP content always brought a higher porosity and MPPD.Furthermore,the addition of SAP led to a lower porosity and MPPD of CEA cement paste than that of plain cement paste after 14 d.Moreover,the porosity and MPPD of CEA cement paste decreased first and subsequently increased as the curing temperature raised.展开更多
为实现工业固废在道路与铁道路基工程中的高值化利用,助力双碳目标在交通运输工程领域中的达成,采用钢渣、矿渣与2种脱硫产物(DP-1、DP-2)等工业固废制备再生胶凝固化剂。基于响应面法考察不同工业固废的交互作用并得到其最优组配。采...为实现工业固废在道路与铁道路基工程中的高值化利用,助力双碳目标在交通运输工程领域中的达成,采用钢渣、矿渣与2种脱硫产物(DP-1、DP-2)等工业固废制备再生胶凝固化剂。基于响应面法考察不同工业固废的交互作用并得到其最优组配。采用最优组配下的固化剂对粉土进行改良固化,并表征本研究固化粉土微观结构。与水泥固化粉土作对比,探究了固化剂掺量、养护龄期对固化粉土力学性能和耐久性的影响规律,并分析2种固化粉土的矿物成分,探究再生胶凝固化剂的粉土固化机理。研究结果表明:7 d无侧限抗压强度(p_(usc))响应面模型经残差正态概率分布检验,模型可靠度较高。钢渣与矿渣、钢渣与DP-2交互作用对7 d p_(usc)值的影响极其显著,再生胶凝固化剂最优配比(%)为钢渣∶矿渣∶DP-1∶DP-2=52.1∶19.9∶19.5∶8.5。研究可知,固化粉土具有良好的力学性能和耐久性,在养护后期(28 d)与水泥固化粉土p_(usc)值、加州承载比值、水稳性能系数值、冻融循环系数值分别相差1.9%、0.5%、1.0%、2.3%。再生胶凝固化剂组分在碱性环境中发挥协同作用,水化产物交错生长填充了粉土颗粒之间的孔隙,从而提高了固化粉土的力学性能。同掺量的再生胶凝固化剂碳排放仅为水泥的1.66%,推荐再生胶凝固化剂路床固化工程最优掺量为6%~8%,该技术的推广应用具有重要环保和社会意义。展开更多
基金Funded by the Guangxi Key Research and Development Program(No.GK AB19259008)the Director's Fund of Key Laboratory of Non-ferrous Metals and Materials Processing New Technology of Ministry of Education(No.22AA-6)。
文摘To address the negative impact of an internal curing agent on strength while preserving its ability to resist autogenous shrinkage,we investigated the incorporation of triethanolamine and triisopropanolamine as early-strength components.These additives were combined with an internal curing agent to prepare a compound early-strength internal curing agent so as to investigate how compound early-strength internal curing agents affect the mechanical characteristics and volume stability of mortar.This was assessed using a battery of tests,including strength,autogenous shrinkage,internal relative humidity,mercury intrusion porosimetry,X-ray powder diffraction,and scanning electron microscopy.These results indicate that the compound early-strength internal curing agent effectively maintains the volume stability of the mortar without compromising its early mechanical properties.The compressive strength ratios of the mortar mixed with the compound early-strength internal curing agent were 109.45% at 3 days and 119% at 7 days,indicating significant improvement compared with the internal curing agent.Furthermore,the 7-day autogenous shrinkage rate of the mortar was-56.78μm/m.The proportion of hazardous-grade pores larger than 100 nm was reduced to 3.54%,and the pore distribution was uniform.This study introduces innovative ideas and methods for mitigating the adverse effects of internal curing agents on the early strength of mortar.
基金Funded by the National Key Research and Development Program of China (No.2019YFC1906202)the Guangxi Key Research and Development Plan (Nos.Guike AA18242007-3, Guike AB19259008, and Guike AB20297014)。
文摘Internal curing agents (ICA) based on super absorbent polymer have poor alkali tolerance and reduce the early strength of concrete.An alkali tolerate internal curing agent (CAA-ICA) was designed and prepared by using sodium carboxymethyl starch (CMS) with high hydrophilicity,acrylic acid (AA) containing anionic carboxylic group and acrylamide (AM) containing non-ionic amide group as the main raw materials.The results show that the ratio of CAA-ICA alkali absorption solution is higher than that existing ICA,which solves the low water absorption ratio of the ICA in alkali environment.The water absorption ratio of CAA-ICA in saturated Ca(OH)_(2) solution is 95.8 g·g^(-1),and the alkali tolerance coefficient is 3.4.The application of CAA-ICA in cement-based materials can increase the internal relative humidity and miniaturize the pore structure.The compressive strength of mortar increases up to 12.95%at 28 d,which provids a solution to overcome the reduction of the early strength.
文摘By using HDI and TMP as the main raw materials,polyethylene glycol 400(PEG400)is used as a non-ionic hydrophilic modifier,and sodium hydroxyethyl sulfonate is used as an ionic hydrophilic modifier to synthesize a dual hydrophilic modified polyurethane curing agent.Research revealed that introducing PEG400 for hydrophilic chain segments and sodium hydroxyethyl sulfonate for hydrophilic ionic groups in the polyurethane curing agent component leads to a uniform distribution of hydrophilic components,significantly enhancing compatibility with the aqueous polyol component,and results in excellent film performance.The synthesis process and film were characterized using Fourier transform infrared spectroscopy and high-resolution scanning electron microscopy in the study.
文摘A novel waterborne epoxy curing agent was prepared using 3-glycidoxypropyl trimethoxysilane （GPTMS） as a termination agent of adduct, which was synthesized by triethylene tetramine （TETA） and liquid epoxy resin （E-51）. The effects of the reaction temperature and time on the synthesis process were investigated experimentally. The particle size and the distribution of water dispersion of the curing agent were measured by dynamic light scattering（DLS）. The structure of the products was characterized by Fourier transform infrared spec-trometer （FTIR） and ^1H-nuclear magnetic resonance （^1H NMR）. The properties of the synthesized curing agent and the epoxy resin film cured by it were also measured. The results showed that the appropriate temperature for the synthesis of adduct was at 65-75℃ and the reaction time was 4-5h, and that the suitable reaction temperature of curing agent synthesis was 75-85℃ and the reaction time was 3-4h. When the mass ratios of GPTMS and acetic acid were 3%-5% and 5%-10% respectively, the hardness, water resistance and adhesion of the cured film were improved significantly.
文摘A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Fourier transform infrared spectroscopy, nuclear magnetic resonance, mass spectrometry, and gel permeation chro-matography analyses. The thermal properties of the resulting polymer from diglycidyl ether of bisphenol A epoxy resin cured with the novel curing agent were evaluated using dynamic mechanical thermal analysis and thermogra-vimetric analysis. Compared with the conventional curing agent, the resulting polymer cured with naphtha-lene/DCPD navolac shows considerable improvement in heat resistant properties such as higher glass transition temperature (Tg) and thermal stability. The result also shows better moisture resistance because of the hydrophobic nature of naphthalene/DCPD structure.
基金financially supported by the National Natural Science Foundation of China(No.51773010)the Fundamental Research Funds for the Central Universities(No.XK1802-2)。
文摘To obtain high-efficiency flame retardancy of epoxy resins,a cyclophosphazene derivative tri-(ohenylenediamino)cyclotriphosphazene(3 ACP)was successfully synthesized and used as a curing agent for the thermosetting of an epoxy resin system.The flame retardant properties,thermal stability,and pyrolysis mechanism of the resultant thermosets were investigated in detail.The experiments indicated that the synthesized thermoset achieved a UL-94 V-0 rate under a vertical burning test as well as a limiting oxygen index(LOI)of 29.2%,which was able to reach V-0 even when a small amount of 3 ACP was incorporated.Scanning electronic microscopic observation demonstrated that the char residue of the thermosets was extremely expanded after the vertical flame test.Thermal analysis showed that the samples had a lower initial decomposition temperature when 3 ACP was introduced into the epoxy resin systems.This indicates that the carbonization ability of the thermosets was significantly improved at elevated temperatures.In addition,the incorporation of 3 ACP can effectively suppress the release of combustible gases during the pyrolysis process,and the decomposition of E-44/DDS-3 ACP curing systems also promotes the formation of polyphosphoramides charred layer in the condensed phase.The investigation on the chemical structures of both the gaseous and condensed phase pyrolysis process confirmed the flame-retardant mechanism of the 3 ACP-cured epoxy resins.Therefore,the nonflammable halogen-free epoxy resin developed in this study has potential applications in electric and electronic fields for environment protection and human health.
基金supported by National Natural Science Foundation of China(No.51273029)the Fundamental Research Funds for the Central Universities(No.DUT15RC(3)032)+1 种基金General Project of Scientific Research of the Education Department of Liaoning Province(No.L2015116)a collaborative project from Guangdong Provincial Key Laboratory of Mineral Physics and Materials(No.GLMPM-010)
文摘Combined with the advantages of low melting point,high thermal stability and strong acidity,a multipleSO_3H functioned ionic liquid（MIL） was developed successfully as a curing agent to promote the curing reaction of phthalonitrile-terminated poly（phthalazinone ether nitrile）（PPEN-Ph）.The curing kinetics over differential scanning calorimetry（DSC） showed that both the initial curing temperature Tp0＇ and apparent activation energy Ea＇（based on Kissinger equation） were reduced significantly over MIL（207.9℃ and 101.5 kJ/mol） compared to the common curing agent ZnCl_2（268.5℃ and 201.5 kJ/mol）.Moreover,under identical curing conditions,the resulting thermosetting resin over former（Td5%=526.1℃） showed better thermal stability than that over latter（Td5%=512.1 ℃）.These results indicated that MIL should be a good candidate as a curing agent for phthalonitrile resins.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51408159)the China Postdoctoral Science Foundation of China(Grant No.2013T60375 and 2012M520744)
文摘One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.
基金supported by the National Natural Science Foundation of China(No.20774023)Shanghai Leading Academic Discipline Project(No.B113).
文摘Thermosetting acrylic coatings were prepared by using carboxyl acid group-containing acrylic oligomer and curing with titanium-oxo-clusters which were first pre-hydrolyzed from titanium n-butoxide.The curing ability of the titanium-oxo-cluster was examined using a microdielectric analytical(DEA)curing monitor,Fourier transformed infrared spectroscopy(FTIR),and Soxhlet extraction experiments,and the properties of the resulted coatings were investigated with pendulum hardness tester,dynamic mechanical analysis(DMA),thermogravimetric analysis(TGA)and ultraviolet-visible spectrometer.The effect of titania-oxo-cluster in leading acrylic oligomers to form thermosetting acrylic coatings was confirmed.An increasing pendulum hardness and modulus of acrylic coatings with increasing titania content was observed, which resulted from the increment of crosslinking degree rather than of the titania content.The thermosetting acrylic/titania coatings also showed better thermal stability and higher UV-blocking properties than those coatings using organic curing agent.
基金Projects(51878245,U1965105)supported by the National Natural Science Foundation of ChinaProject(2019GSF110006)supported by the Key Research and Development Program of Shandong Province,China+2 种基金Project(2020Z035)supported by the Ningbo 2025 Science and Technology Major Project,ChinaProject(KJ2017B01)supported by the Scientific Research Project of Department of Education of Anhui Province,ChinaProject(2019CEM001)supported by the State Key Laboratory of High Performance Civil Engineering Materials,China。
文摘Cracks easily generate in concrete at early age owing to the shrinkage deformation.CaO-based expansion agent(CEA)and superabsorbent polymers(SAP)have been extensively used for the mitigation of concrete shrinkage.The macroscopic properties of concrete are highly determined by the microstructure.In this study,the influence of CEA and SAP addition on the pore structure evolution of cement paste under different curing temperatures was evaluated via low-field nuclear magnetic resonance spectroscopy.Test results indicated that,in cement paste,a higher CEA content led to a higher porosity and a larger most probable pore diameter(MPPD).Meanwhile,SAP addition increased the porosity and MPPD of CEA cement paste at early age but decreased them after 7 d,and a higher SAP content always brought a higher porosity and MPPD.Furthermore,the addition of SAP led to a lower porosity and MPPD of CEA cement paste than that of plain cement paste after 14 d.Moreover,the porosity and MPPD of CEA cement paste decreased first and subsequently increased as the curing temperature raised.
文摘为实现工业固废在道路与铁道路基工程中的高值化利用,助力双碳目标在交通运输工程领域中的达成,采用钢渣、矿渣与2种脱硫产物(DP-1、DP-2)等工业固废制备再生胶凝固化剂。基于响应面法考察不同工业固废的交互作用并得到其最优组配。采用最优组配下的固化剂对粉土进行改良固化,并表征本研究固化粉土微观结构。与水泥固化粉土作对比,探究了固化剂掺量、养护龄期对固化粉土力学性能和耐久性的影响规律,并分析2种固化粉土的矿物成分,探究再生胶凝固化剂的粉土固化机理。研究结果表明:7 d无侧限抗压强度(p_(usc))响应面模型经残差正态概率分布检验,模型可靠度较高。钢渣与矿渣、钢渣与DP-2交互作用对7 d p_(usc)值的影响极其显著,再生胶凝固化剂最优配比(%)为钢渣∶矿渣∶DP-1∶DP-2=52.1∶19.9∶19.5∶8.5。研究可知,固化粉土具有良好的力学性能和耐久性,在养护后期(28 d)与水泥固化粉土p_(usc)值、加州承载比值、水稳性能系数值、冻融循环系数值分别相差1.9%、0.5%、1.0%、2.3%。再生胶凝固化剂组分在碱性环境中发挥协同作用,水化产物交错生长填充了粉土颗粒之间的孔隙,从而提高了固化粉土的力学性能。同掺量的再生胶凝固化剂碳排放仅为水泥的1.66%,推荐再生胶凝固化剂路床固化工程最优掺量为6%~8%,该技术的推广应用具有重要环保和社会意义。
