Gold（Au） nanoclusters have recently emerged as ideal models for understanding Au catalysis, because the nanosized Au particles have precise atomic numbers and uniform size. In this work, we studied for the first tim...Gold（Au） nanoclusters have recently emerged as ideal models for understanding Au catalysis, because the nanosized Au particles have precise atomic numbers and uniform size. In this work, we studied for the first time the support shape effect on the catalysis of Au nanoclusters by using CO oxidation as a model reaction. Au22（L8）6（L = 1,8-bis（diphenylphosphino） octane） nanoclusters were supported on CeO2 rods or cubes, then pretreated at different temperatures（up to 673 K）, allowing the gradual removal of the organic phosphine ligands. CO oxidation test over these differently pretreated samples shows that CeO2 rods are much better supports than cubes for Au22 nanoclusters in enhancing the reaction rate. In situ IR spectroscopy coupled with CO adsorption indicates that the shape of CeO2 support can impact the nature and quantity of exposed Au sites, as well as the efficiency of organic ligand removal. Although CeO2 rods are helpful in exposing a greater percentage of total Au sites upon ligands removal, the percentage of active Au sites（denoted by Au d＋, 0 〈 d 〈 1） is lower than that on CeO2 cubes. The in situ extended X-ray absorption spectroscopy（EXAFS） and high-angle annular dark-field scanning transmission electron microscopy（HAADF-STEM） results show that the Au nanoclusters bound more strongly to the CeO2 rods than to the cubes where the Au nanoclusters show more sintering. Considering the typical redox mechanism for CO oxidation over supported Au nanoclusters and nanoparticles, it is concluded that the reactivity of the lattice oxygen of CeO2 is the determining factor for CO oxidation over Au22/CeO2. CeO2 rods offer more reactive lattice oxygen and abundant oxygen vacancies than the cubes and thus make the rods a superior support for Au nanoclusters in catalyzing low temperature CO oxidation.展开更多
An exact-designed mesh shape with favorable surface accuracy is of practical significance to the performance of large cable-network antenna reflectors. In this study, a novel design approach that could guide the gener...An exact-designed mesh shape with favorable surface accuracy is of practical significance to the performance of large cable-network antenna reflectors. In this study, a novel design approach that could guide the generation of exact spatial parabolic mesh configurations of such reflector was proposed. By incorporating the traditional force density method with the standard finite element method, this proposed approach had taken the deformation effects of flexible ring truss supports into consideration, and searched for the desired mesh shapes that can satisfy the requirement that all the free nodes are exactly located on the objective paraboloid. Compared with the conventional design method,a remarkable improvement of surface accuracy in the obtained mesh shapes had been demonstrated by numerical examples. The present work would provide a helpful technical reference for the mesh shape design of such cable-network antenna reflector in engineering practice.展开更多
This paper presents a new method for solving the vibration of arbitrarily shaped membranes with ela.stical supports at points. The reaction forces of elastical supports at points are regarded as unknown external force...This paper presents a new method for solving the vibration of arbitrarily shaped membranes with ela.stical supports at points. The reaction forces of elastical supports at points are regarded as unknown external forces acting on the membranes. The exact solution of the equation of motion is given which includes terms representing the unknown reaction forces. The frequency equation is derived by the use of the linear relationship of the displacements with the reaction forces of elastical supports at points. Finally the calculating formulae of the frequency equation of circular membranes are analytically performed as examples and the inherent frequencies of circular membranes with symmetric elastical supports at two points are numerically calculated.展开更多
A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintil...A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintillator with pulse-shape discrimination(PSD) property. The SVM algorithm is implemented in field programmable gate array(FPGA) to carry out the real-time sifting of neutrons in neutron-gamma mixed radiation fields. This study compares the ability of the pulse gradient analysis method and the SVM method. The results show that this SVM discriminator can provide a better discrimination accuracy of 99.1%. The accuracy and performance of the SVM discriminator based on FPGA have been evaluated in the experiments. It can get a figure of merit of 1.30.展开更多
To improve the cooling performance, shape optimization of a laidback fan-shaped film cooling hole was performed. Three geometric parameters, including hole length, lateral expansion angle and forward expansion angle, ...To improve the cooling performance, shape optimization of a laidback fan-shaped film cooling hole was performed. Three geometric parameters, including hole length, lateral expansion angle and forward expansion angle, were selected as the design parameters. Numerical model of the film cooling system was established, validated, and used to generate 32 groups of training samples. Least square support vector machine(LS-SVM) was applied for surrogate model, and the optimal design parameters were determined by a kind of chaotic optimization algorithm. As hole length, lateral expansion angle and forward expansion angle are 90 mm, 20° and 5°, the area-averaged film cooling effectiveness can reach its maximum value in the design space. LS-SVM coupled with chaotic optimization algorithm is a promising scheme for the optimization of shaped film cooling holes.展开更多
304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped s...304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped stainless steel. Finite element method simulation is herein used to analyze metal flow characteristics, optimize the extrusion die, and predict the extrusion force at different temperatures and speeds. A Φ400-mm container and Φ388-mm forging billet are selected, and the 304L H-shaped stainless steel is successfully manufactured using a Germany SMS 60 MN horizontal extruder. The mechanical properties and microstructure of the manufactured 304L H-shaped stainless steel meet the requirements of the PRHR HX, and the surfaces of the product pass the dye penetration test. The H-shaped stainless steels are used in Haiyang nuclear power plant in Shandong Province.展开更多
基金supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Divisionsupported by the U.S. Department of Energy, Office of Science, Office of Basic Energy, Sciences under Contract No. DE-AC02-76SF00515the facilities support at the beamline BL 2-2 provided by the Synchrotron Catalysis Consortium U.S. DOE (No. De-SC0012335)
文摘Gold（Au） nanoclusters have recently emerged as ideal models for understanding Au catalysis, because the nanosized Au particles have precise atomic numbers and uniform size. In this work, we studied for the first time the support shape effect on the catalysis of Au nanoclusters by using CO oxidation as a model reaction. Au22（L8）6（L = 1,8-bis（diphenylphosphino） octane） nanoclusters were supported on CeO2 rods or cubes, then pretreated at different temperatures（up to 673 K）, allowing the gradual removal of the organic phosphine ligands. CO oxidation test over these differently pretreated samples shows that CeO2 rods are much better supports than cubes for Au22 nanoclusters in enhancing the reaction rate. In situ IR spectroscopy coupled with CO adsorption indicates that the shape of CeO2 support can impact the nature and quantity of exposed Au sites, as well as the efficiency of organic ligand removal. Although CeO2 rods are helpful in exposing a greater percentage of total Au sites upon ligands removal, the percentage of active Au sites（denoted by Au d＋, 0 〈 d 〈 1） is lower than that on CeO2 cubes. The in situ extended X-ray absorption spectroscopy（EXAFS） and high-angle annular dark-field scanning transmission electron microscopy（HAADF-STEM） results show that the Au nanoclusters bound more strongly to the CeO2 rods than to the cubes where the Au nanoclusters show more sintering. Considering the typical redox mechanism for CO oxidation over supported Au nanoclusters and nanoparticles, it is concluded that the reactivity of the lattice oxygen of CeO2 is the determining factor for CO oxidation over Au22/CeO2. CeO2 rods offer more reactive lattice oxygen and abundant oxygen vacancies than the cubes and thus make the rods a superior support for Au nanoclusters in catalyzing low temperature CO oxidation.
文摘An exact-designed mesh shape with favorable surface accuracy is of practical significance to the performance of large cable-network antenna reflectors. In this study, a novel design approach that could guide the generation of exact spatial parabolic mesh configurations of such reflector was proposed. By incorporating the traditional force density method with the standard finite element method, this proposed approach had taken the deformation effects of flexible ring truss supports into consideration, and searched for the desired mesh shapes that can satisfy the requirement that all the free nodes are exactly located on the objective paraboloid. Compared with the conventional design method,a remarkable improvement of surface accuracy in the obtained mesh shapes had been demonstrated by numerical examples. The present work would provide a helpful technical reference for the mesh shape design of such cable-network antenna reflector in engineering practice.
文摘This paper presents a new method for solving the vibration of arbitrarily shaped membranes with ela.stical supports at points. The reaction forces of elastical supports at points are regarded as unknown external forces acting on the membranes. The exact solution of the equation of motion is given which includes terms representing the unknown reaction forces. The frequency equation is derived by the use of the linear relationship of the displacements with the reaction forces of elastical supports at points. Finally the calculating formulae of the frequency equation of circular membranes are analytically performed as examples and the inherent frequencies of circular membranes with symmetric elastical supports at two points are numerically calculated.
基金partially supported by the National Science and Technology Major Project of Ministry of Science and Technology of China (Grant Nos. 2014GB109003 and 2015GB111002)National Natural Science Foundation of China (Grant Nos. 11375195, 11575184, 11375004 and 11775068)
文摘A new neutron-gamma discriminator based on the support vector machine(SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintillator with pulse-shape discrimination(PSD) property. The SVM algorithm is implemented in field programmable gate array(FPGA) to carry out the real-time sifting of neutrons in neutron-gamma mixed radiation fields. This study compares the ability of the pulse gradient analysis method and the SVM method. The results show that this SVM discriminator can provide a better discrimination accuracy of 99.1%. The accuracy and performance of the SVM discriminator based on FPGA have been evaluated in the experiments. It can get a figure of merit of 1.30.
基金Project(U1508212)supported by the National Natural Science Foundation of ChinaProject(2015M570448)supported by the Postdoctoral Science Foundation of China
文摘To improve the cooling performance, shape optimization of a laidback fan-shaped film cooling hole was performed. Three geometric parameters, including hole length, lateral expansion angle and forward expansion angle, were selected as the design parameters. Numerical model of the film cooling system was established, validated, and used to generate 32 groups of training samples. Least square support vector machine(LS-SVM) was applied for surrogate model, and the optimal design parameters were determined by a kind of chaotic optimization algorithm. As hole length, lateral expansion angle and forward expansion angle are 90 mm, 20° and 5°, the area-averaged film cooling effectiveness can reach its maximum value in the design space. LS-SVM coupled with chaotic optimization algorithm is a promising scheme for the optimization of shaped film cooling holes.
基金supported by the State Key Laboratory for Mechanical Behavior of Materials(No.20171909)
文摘304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped stainless steel. Finite element method simulation is herein used to analyze metal flow characteristics, optimize the extrusion die, and predict the extrusion force at different temperatures and speeds. A Φ400-mm container and Φ388-mm forging billet are selected, and the 304L H-shaped stainless steel is successfully manufactured using a Germany SMS 60 MN horizontal extruder. The mechanical properties and microstructure of the manufactured 304L H-shaped stainless steel meet the requirements of the PRHR HX, and the surfaces of the product pass the dye penetration test. The H-shaped stainless steels are used in Haiyang nuclear power plant in Shandong Province.
