This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materi...This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.展开更多
We investigated the adsorption mechanisms including physical and chemical adsorption for heavy metals(Cd,Pb,Zn,Co,Cu)on C-lignin using density functional theory(DFT)simulations.Physical adsorption,involving metal atom...We investigated the adsorption mechanisms including physical and chemical adsorption for heavy metals(Cd,Pb,Zn,Co,Cu)on C-lignin using density functional theory(DFT)simulations.Physical adsorption,involving metal atoms near carbon atoms,is found to be endothermic;meanwhile,chemical adsorption,where hydroxyl groups replace metal ions,is exothermic and spontaneous.Pb exhibits the highest physical adsorption potential,while Cu and Co demonstrate the strongest chemical adsorption due to their highly negative adsorption energies.These findings provide valuable insights into the design of eco-friendly nano lignocellulosic composite films for effective heavy metal removal from contaminated water sources.Key words:C-lignin;adsorption;We investigated the adsorption mechanisms including physical and chemical adsorption for heavy metals(Cd,Pb,Zn,Co,Cu)on C-lignin using density functional theory(DFT)simulations.Physical adsorption,involving metal atoms near carbon atoms,is found to be endothermic;meanwhile,chemical adsorption,where hydroxyl groups replace metal ions,is exothermic and spontaneous.Pb exhibits the highest physical adsorption potential,while Cu and Co demonstrate the strongest chemical adsorption due to their highly negative adsorption energies.These findings provide valuable insights into the design of eco-friendly nano lignocellulosic composite films for effective heavy metal removal from contaminated water sources.展开更多
Traditional constitutional theory holds that Article 33,Paragraph 4 of the Chinese Constitution establishes the principle of the consistency of rights and obligations.However,with the evolution of constitutional theor...Traditional constitutional theory holds that Article 33,Paragraph 4 of the Chinese Constitution establishes the principle of the consistency of rights and obligations.However,with the evolution of constitutional theory and practice,its interpretation has shifted.It is increasingly viewed as a concretization of the principle of equality,although this perspective has not been thoroughly substantiated in academic circles.Upon closer analysis,interpreting this provision as the“consistency of rights and obligations”reveals several issues,including counterevidence from the constitutional drafting history,a lack of internal coherence,and a misalignment with the functions of the Constitution.By revisiting the specific context of this provision,it can be understood as an anti-privilege clause,serving as a special annotation of the equality principle.This approach enables a harmonious interpretation of this provision alongside other constitutional provisions.展开更多
Over 70 years ago,China proposed the Five Principles of Peaceful Coexistence,which were first embraced by countries such as Myanmar and gradually gained traction across Asia.The Five Principles eventually became widel...Over 70 years ago,China proposed the Five Principles of Peaceful Coexistence,which were first embraced by countries such as Myanmar and gradually gained traction across Asia.The Five Principles eventually became widely recognized norms in international relations and foundational principles of international law,contributing significantly to the post-World War II international order.Decades on,the Five Principles have not faded into history.Rather,they have demonstrated renewed relevance in today’s complex global landscape.展开更多
TiO_(2)is a well-known photocatalyst with a band gap of 3.2 eV,yet its ability to absorb light is limited to the short wavelengths of ultraviolet light.To achieve a more effective photocatalytic material,we have desig...TiO_(2)is a well-known photocatalyst with a band gap of 3.2 eV,yet its ability to absorb light is limited to the short wavelengths of ultraviolet light.To achieve a more effective photocatalytic material,we have designed two-dimensional semiconductor TiOS materials using swarm intelligence algorithms combined with first-principles calculations.Three stable low-energy structures with space groups of P2_(1)/m,P3m1 and P2_(1)/c are identified.Among these structures,the Janus P3m1 phase is a direct bandgap semiconductor,while the P2_(1)/m and P2_(1)/c phases are indirect bandgap semiconductors.Utilizing the accurate hybrid density functional HSE06 method,the band gaps of the three structures are calculated to be 2.34 eV(P2_(1)/m),2.24 eV(P3m1)and 3.22 eV(P2_(1)/c).Optical calculations reveal that TiOS materials exhibit a good light-harvesting capability in both visible and ultraviolet spectral ranges.Moreover,the photocatalytic calculations also indicate that both P2_(1)/m and P3m1 TiOS can provide a strong driving force for converting H_(2)O to H_(2)and O_(2)in an acidic environment with pH=0.The structural stabilities,mechanical properties,electronic structures and hydrogen evolution reaction activities are also discussed in detail.Our research suggests that two-dimensional TiOS materials have potential applications in both semiconductor devices and photocatalysis.展开更多
The structural,relative stability,and electronic properties of two-dimensional AsP_(2)X_(6)(X=S,Se)were predicted and studied using the particle-swarm optimization method and first principles calculations.We proposed ...The structural,relative stability,and electronic properties of two-dimensional AsP_(2)X_(6)(X=S,Se)were predicted and studied using the particle-swarm optimization method and first principles calculations.We proposed two low energy structures with P312 and P-31m phases,both of which the structures are hexagonal in shape and show non-centrosymmetry for the P312 phase and centrosymmetry for the P-31m phase.According to our results,two structural phases are found to be stable thermally and dynamically.The P312 phase of AsP_(2)X_(6)(X=S,Se)are indirect semiconductors with band gaps of 2.44 eV(AsP2S6)and 2.18 eV(AsP2Se6)at the HSE06 level,and their absorption coefficients are predicted to reach the order of 10^(5)cm^(-1)from visible light to ultraviolet region,but the main absorption is manly in the ultraviolet region.The P-31m phase of AsP_(2)X_(6)(X=S,Se)exhibits metal character with the Fermi surface mainly occupied by the p orbital of S/Se.Remarkably,estimated by first principles calculations,the P-31m AsP2S6 is found to be an intrinsic phonon-mediated superconductor with a relatively high critical superconducting temperature of about 13.4 K,and the P-31m AsP2Se6 only has a superconducting temperature of 1.4 K,which suggest that the P-31m AsP2S6 may be a good candidate for a nanoscale superconductor.展开更多
In this paper,inspired by the running motion gait of a cheetah,an H-shaped bionic piezoelectric robot(H-BPR)based on the standing wave principle is proposed and designed.The piezoelectric robot realizes linear motion,...In this paper,inspired by the running motion gait of a cheetah,an H-shaped bionic piezoelectric robot(H-BPR)based on the standing wave principle is proposed and designed.The piezoelectric robot realizes linear motion,turning motion,and turning motion with different radi by the voltage differential driving method.A prototype with a weight of 38 g and dimensions of 150×80×31 mm^(3) was fabricated.Firstly,the dynamics and kinematics of the piezoelectric robot were analyzed to obtain the trajectory of a point at the end of the piezoelectric robot leg.The motion principle of the piezo-electric robot was analyzed,and then the piezoelectric robot's modal analysis and harmonic response analysis were carried out using finite element analysis software.Finally,an experimental setup was built to verify the effectiveness and high efficiency of the robot's motion,and the effects of frequency,voltage,load,and height of the driving leg on the robot's motion performance were discussed.The performance test results show that the piezoelectric robot has a maximum veloc-ity of 66.79 mm/s at an excitation voltage of 320 V and a load capacity of 55 g.In addition,the H-BPR with unequal drive legs has better climbing performance,and the obtained conclusions are informative for selecting leg heights for piezoelectric robots.展开更多
In interpersonal communication,the principle of politeness is an important communicative principle that is widely applied in people’s daily life.However,the communication patterns of the principle of politeness and f...In interpersonal communication,the principle of politeness is an important communicative principle that is widely applied in people’s daily life.However,the communication patterns of the principle of politeness and face theory in the travel planning process among friends still need further exploration.This study aims to analyze the specific manifestations of these principles in the communication patterns of travel planning among friends through a pragmatic interpretation of the principle of politeness and face theory,providing a new perspective for understanding linguistic behavior in interpersonal relationships.展开更多
This paper analyzes the humorous effects generated through the non-observance of Grice’s Cooperative Principle(CP)in the Chinese crosstalk Learning Manchu.Focusing on violations of the Quantity,Quality,Relation,and M...This paper analyzes the humorous effects generated through the non-observance of Grice’s Cooperative Principle(CP)in the Chinese crosstalk Learning Manchu.Focusing on violations of the Quantity,Quality,Relation,and Manner maxims,it examines how deliberate pragmatic deviations create comedy.The study also incorporates the unique crosstalk mechanism of“Baofu”(packaging and delivering jokes)and emphasizes the essential role of audience cooperation in humor reception.It argues that humor in crosstalk arises not only from performers’non-cooperation but also from active audience engagement within a shared cultural context.展开更多
A stacked piezoelectric micropump based on the synthetic jet principle with a size of 22×22×5 mm^(3) is designed and fabricated.Through theoretical and finite element method(FEM)analysis,the conditions for a...A stacked piezoelectric micropump based on the synthetic jet principle with a size of 22×22×5 mm^(3) is designed and fabricated.Through theoretical and finite element method(FEM)analysis,the conditions for achieving a synthetic jet structure are obtained,and the gas flow properties inside the chamber are analyzed.The first-order mode and resonant frequency of the piezoelectric actuator are simulated.At a resonant frequency of 22.5 kHz,the maximum central displacement of the actuator can reach 12.3μm.In addition,the key dimensions of the micropump are optimized to improve the output flow rate.Experiments on the prototype of the micropump show that it can reach a maximum output flow rate of 618 mL/min when driven by a sine wave signal of 42 Vpp and 22.5 kHz.The power dissipation does not exceed 600 mW.展开更多
To ameliorate the difficulties of on-site dynamic disaster control in the end-mining stage of traditional mining engineering,this paper introduces the mathematical research and engineering application of the end-minin...To ameliorate the difficulties of on-site dynamic disaster control in the end-mining stage of traditional mining engineering,this paper introduces the mathematical research and engineering application of the end-mining technology system with non-pillar in mines(ETSNM)in recent years.The petal warning criterion for the stability of the surrounding rock of the roadway at the end-mining stage was obtained by studying the inverse problem of the petal theorem.A conformal mathematical model of the end-mining stage was established using the conformal mapping method,and the limit theorem of the peak point of mine pressure(LTPPMP)in the end-mining stage was demonstrated.Based on the cross-fusion of the above basic mathematical theory and the LTPPMP,a new ETSNM model was proposed,which includes no coal pillar,no dedicated retracement roadways,and fast retracement equipment(NNF).The mathematical principles of engineering technology for height control,speed limit,and roof cutting in the end-mining stage with non-pillar were revealed.The scientific and application values of the ETSNM were confirmed through engineering applications.Based on this,a new non-pillar control technology for dynamic disasters in the end-mining stage was proposed.The above research will play an active role in promoting the engineering application of ETSNM driven by mathematical theory.展开更多
Gold-platinum(Au-Pt)alloy has aroused considerable attention due to its ultra-low magnetic susceptibility(MS)in testing mass(TM)on spacecraft.However,the effect of Au content on the properties of the alloy has not yet...Gold-platinum(Au-Pt)alloy has aroused considerable attention due to its ultra-low magnetic susceptibility(MS)in testing mass(TM)on spacecraft.However,the effect of Au content on the properties of the alloy has not yet been understood.In this study,the composition design of Au-Pt alloy with ultra-low MS was achieved through density functional theory(DFT)and experimental methods.The elastic,thermal properties and electronic structure were systematically investigated,the composition range was further optimized and Au75Pt25 was determined to be the most suitable alloy for TM material.The phase composition of this alloy after cold rolling and solid solution was characterized,indicating a single-phase FCC structure.In addition,there is a good validation between the experimental Vickers hardness and the DFT results.This work provides new insights into the compositional optimization of Au-Pt alloys and lays the foundation for alloy development.展开更多
Thermal Protection System(TPS)with thick tiles,low thermal conductivity,and a short re-entry stage stands as a critical element within reusable aircraft,whose reliability is related to the function and changes with th...Thermal Protection System(TPS)with thick tiles,low thermal conductivity,and a short re-entry stage stands as a critical element within reusable aircraft,whose reliability is related to the function and changes with their physical properties,external conditions,and degradation.Meanwhile,due to the limitation of testing resources,epistemic uncertainties stemming from the small samples are present in TPS reliability modeling.However,current TPS reliability modeling methods face challenges in characterizing the relationships among reliability and physical properties,external conditions,degradation,and epistemic uncertainties.Therefore,under the framework of belief reliability theory,a TPS reliability model is constructed,which takes into account the physical principle,external conditions,performance degradation,and epistemic uncertainties.A reliability simulation algorithm is proposed to calculate TPS reliability.Through a case study and comparison analysis,the proposed method is validated as more effective than the existing method.Additionally,reliability sensitivity analysis is conducted to identify the sensitive factors of reliability under the condition of small samples,through which suggestions are provided for TPS functional design and improvement.展开更多
This paper offers a comprehensive overview of the operational principles of current therapeutic devices for diabetic foot management and further analyzes technological innovations and developmental trends,aiming to pr...This paper offers a comprehensive overview of the operational principles of current therapeutic devices for diabetic foot management and further analyzes technological innovations and developmental trends,aiming to promote research and development in the field of technological convergence.The ultimate goal is to enhance the cure rate for diabetic foot conditions and to decrease the incidence of amputations.The paper discusses the novel applications of ultrasound and optical therapeutic devices within the field of physiotherapy,the numerous advantages of chitosan dressings in biotechnology,the ongoing advancements and broader combined use of vacuum sealing drainage techniques,and the distinctive effects and innovations associated with micro-oxygen diffusion techniques.It thoroughly examines various technological mechanisms that facilitate wound healing,highlighting the clinical applications of ultrasonic atomized medicinal solutions,novel dressing graft copolymerization,continuous hypoxia diffusion,and the functions of vacuum drainage.These advancements facilitate the integration of drainage and dressing changes,with the potential to enhance the therapeutic effects of diabetic foot treatment and provide valuable insights for clinical application.展开更多
The all-vanadium redox flow battery(VRFB)plays an important role in the energy transition toward renewable technologies by providing grid-scale energy storage.Their deployment,however,is limited by the lack of membran...The all-vanadium redox flow battery(VRFB)plays an important role in the energy transition toward renewable technologies by providing grid-scale energy storage.Their deployment,however,is limited by the lack of membranes that provide both a high energy efficiency and capacity retention.Typically,the improvement of the battery’s energy efficiency comes at the cost of its capacity retention.Herein,novel N-alkylated and N-benzylated meta-polybenzimidazole(m-PBI)membranes are used to understand the molecular requirements of the polymer electrolyte in a vanadium redox flow battery,providing an important toolbox for future research toward next-generation membrane materials in energy storage devices.The addition of an ethyl side chain to the m-PBI backbone increases its affinity toward the acidic electrolyte,thereby increasing its ionic conductivity and the corresponding energy efficiency of the VRFB cell from 70%to 78%at a current density of 200 mA cm^(-2).In addition,cells equipped with ethylated m-PBI showed better capacity retention than their pristine counterpart,respectively 91%versus 87%,over 200 cycles at 200 mA cm^(-2).The outstanding VRFB cycling performance,together with the low-cost and fluorine-free chemistry of the N-alkylated m-PBI polymer,makes this material a promising membrane to be used in next-generation VRFB systems.展开更多
This paper comprehensively explores the technical principles and application practice of Sainaoning absorbable dural sealant medical adhesive in dural closure.It elaborates on the research and development background o...This paper comprehensively explores the technical principles and application practice of Sainaoning absorbable dural sealant medical adhesive in dural closure.It elaborates on the research and development background of Sainaoning,analyzes its composition,action mechanism,and product characteristics in detail,and presents the results of pre-clinical and clinical studies.The application of Sainaoning in different craniotomy surgeries is discussed,and its effectiveness and safety are evaluated.The paper also analyzes the challenges in its application and proposes corresponding countermeasures,aiming to provide a comprehensive understanding and reference for the clinical use and further development of Sainaoning.展开更多
The contact characteristics between cycloidal gear teeth and pinwheel teeth significantly impact the operational performance of cycloidal pinwheel mechanisms.Current research methods tend to rely primarily on theoreti...The contact characteristics between cycloidal gear teeth and pinwheel teeth significantly impact the operational performance of cycloidal pinwheel mechanisms.Current research methods tend to rely primarily on theoretical calculations,with limited use of experimental methods for detecting dynamic contact properties.We propose a novel method for testing the dynamic contact characteristics of cycloidal pinwheel mechanisms.By combining Hertzian contact theory and contact strength theory,we establish a force and meshing stiffness model for the cycloidal and pinwheel gears,and determine the maximum contact stress and variations in pinwheel gear force and meshing stiffness.Based on the principle of photoelasticity,we built a testing platform for the cycloidal pinwheel mechanism to assess its contact characteristics.This platform provides the stress distribution of the cycloidal pinwheel mechanism and allows us to deduce key parameters such as the number of meshing teeth and the meshing interval.This study provides an experimental method for investigating the contact characteristics of cycloidal pinwheel mechanisms.展开更多
Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexib...Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexible fiber sensors.Through the preform-tofiber manufacturing technique,a variety of fiber sensors with complex functionalities spanning from the nanoscale to kilometer scale can be automated in a short time.Examples include temperature,acoustic,mechanical,chemical,biological,optoelectronic,and multifunctional sensors,which operate on diverse sensing principles such as resistance,capacitance,piezoelectricity,triboelectricity,photoelectricity,and thermoelectricity.This review outlines the principles of the thermal drawing process and provides a detailed overview of the latest advancements in various thermally drawn fiber sensors.Finally,the future developments of thermally drawn fiber sensors are discussed.展开更多
Requirements for the ideological and political construction of university courses in the new era stipulate that professional courses should proceed in the same direction as ideological and political courses,forming an...Requirements for the ideological and political construction of university courses in the new era stipulate that professional courses should proceed in the same direction as ideological and political courses,forming an educational pattern that involves all personnel,covers the entire process,and integrates across all courses.Taking the course of Principles of Tourism as an example,this paper discusses the significance,content,and objectives of ideological and political construction in the Principles of Tourism course based on an analysis of its current status.Furthermore,practical strategies for ideological and political construction in the Principles of Tourism course are proposed from four aspects:teaching philosophy,teaching design,teaching methods,and teaching evaluation.The aim is to fully leverage the educational function of tourism-related professional courses and enhance the quality of teaching in the Principles of Tourism course through its ideological and political construction.展开更多
Gene Engineering Principles is a fundamental professional course for majors such as bioengineering and biotechnology.It integrates theoretical knowledge with experimental practice and engineering applications.It is ch...Gene Engineering Principles is a fundamental professional course for majors such as bioengineering and biotechnology.It integrates theoretical knowledge with experimental practice and engineering applications.It is characterized by its comprehensive and highly practical nature.Aligning with the new-era higher education philosophy of‘competency-oriented,value-driven’teaching,this study presented a systematic exploration and practice based on undergraduate cohorts from 2018 to 2020 in Chengdu University.The reform focused on teaching methodology,formative assessment,and the integration of ideological and political education.Key strategies included the introduction of classical experimental cases,emphasis on pre-class preparation,enhancement of classroom interaction,focus on engineering-oriented applications,optimization of assessment mechanisms,and the incorporation of national strategic needs into the curriculum.These measures effectively stimulated students’learning motivation and research potential,thereby improving the overall teaching quality and educational effectiveness of the course.The results of the teaching reform demonstrate significant improvements in students’ability to apply theoretical knowledge to practical engineering problems,scientific thinking,experimental research skills,scientific reasoning,and professional identity.Reformed classes outperformed control groups across various instructional metrics,achieving notable educational outcomes.展开更多
文摘This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.
基金Funded by the Hubei Province Key Research Foundation for Water Resources,China(No.HBSLKY2023035)the National College Students’Innovation and Entrepreneurship Training Program,China(No.202310500012)the Wuhan Talents Outstanding Young Talents Program。
文摘We investigated the adsorption mechanisms including physical and chemical adsorption for heavy metals(Cd,Pb,Zn,Co,Cu)on C-lignin using density functional theory(DFT)simulations.Physical adsorption,involving metal atoms near carbon atoms,is found to be endothermic;meanwhile,chemical adsorption,where hydroxyl groups replace metal ions,is exothermic and spontaneous.Pb exhibits the highest physical adsorption potential,while Cu and Co demonstrate the strongest chemical adsorption due to their highly negative adsorption energies.These findings provide valuable insights into the design of eco-friendly nano lignocellulosic composite films for effective heavy metal removal from contaminated water sources.Key words:C-lignin;adsorption;We investigated the adsorption mechanisms including physical and chemical adsorption for heavy metals(Cd,Pb,Zn,Co,Cu)on C-lignin using density functional theory(DFT)simulations.Physical adsorption,involving metal atoms near carbon atoms,is found to be endothermic;meanwhile,chemical adsorption,where hydroxyl groups replace metal ions,is exothermic and spontaneous.Pb exhibits the highest physical adsorption potential,while Cu and Co demonstrate the strongest chemical adsorption due to their highly negative adsorption energies.These findings provide valuable insights into the design of eco-friendly nano lignocellulosic composite films for effective heavy metal removal from contaminated water sources.
基金This paper is an phased result of the“Research on Constitutional Review Methods of fundamental rights Restrictions”(Project Number 21BFX040),a general project of 2021 supported by National Social Science Fund of China.
文摘Traditional constitutional theory holds that Article 33,Paragraph 4 of the Chinese Constitution establishes the principle of the consistency of rights and obligations.However,with the evolution of constitutional theory and practice,its interpretation has shifted.It is increasingly viewed as a concretization of the principle of equality,although this perspective has not been thoroughly substantiated in academic circles.Upon closer analysis,interpreting this provision as the“consistency of rights and obligations”reveals several issues,including counterevidence from the constitutional drafting history,a lack of internal coherence,and a misalignment with the functions of the Constitution.By revisiting the specific context of this provision,it can be understood as an anti-privilege clause,serving as a special annotation of the equality principle.This approach enables a harmonious interpretation of this provision alongside other constitutional provisions.
基金phased achievement of the Yunnan Provincial Philosophy and Social Sciences Innovation Team project titled Research on Ethnic Issues and Their Impact in Northern Myanmar(No.2025CX09).
文摘Over 70 years ago,China proposed the Five Principles of Peaceful Coexistence,which were first embraced by countries such as Myanmar and gradually gained traction across Asia.The Five Principles eventually became widely recognized norms in international relations and foundational principles of international law,contributing significantly to the post-World War II international order.Decades on,the Five Principles have not faded into history.Rather,they have demonstrated renewed relevance in today’s complex global landscape.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272219 and U1904612)the Natural Science Foundation of Henan Province(Grant No.242300421191).
文摘TiO_(2)is a well-known photocatalyst with a band gap of 3.2 eV,yet its ability to absorb light is limited to the short wavelengths of ultraviolet light.To achieve a more effective photocatalytic material,we have designed two-dimensional semiconductor TiOS materials using swarm intelligence algorithms combined with first-principles calculations.Three stable low-energy structures with space groups of P2_(1)/m,P3m1 and P2_(1)/c are identified.Among these structures,the Janus P3m1 phase is a direct bandgap semiconductor,while the P2_(1)/m and P2_(1)/c phases are indirect bandgap semiconductors.Utilizing the accurate hybrid density functional HSE06 method,the band gaps of the three structures are calculated to be 2.34 eV(P2_(1)/m),2.24 eV(P3m1)and 3.22 eV(P2_(1)/c).Optical calculations reveal that TiOS materials exhibit a good light-harvesting capability in both visible and ultraviolet spectral ranges.Moreover,the photocatalytic calculations also indicate that both P2_(1)/m and P3m1 TiOS can provide a strong driving force for converting H_(2)O to H_(2)and O_(2)in an acidic environment with pH=0.The structural stabilities,mechanical properties,electronic structures and hydrogen evolution reaction activities are also discussed in detail.Our research suggests that two-dimensional TiOS materials have potential applications in both semiconductor devices and photocatalysis.
基金Funded by the National Natural Science Foundation of China(No.U1904612)the Natural Science Foundation of Henan Province(No.222300420506)。
文摘The structural,relative stability,and electronic properties of two-dimensional AsP_(2)X_(6)(X=S,Se)were predicted and studied using the particle-swarm optimization method and first principles calculations.We proposed two low energy structures with P312 and P-31m phases,both of which the structures are hexagonal in shape and show non-centrosymmetry for the P312 phase and centrosymmetry for the P-31m phase.According to our results,two structural phases are found to be stable thermally and dynamically.The P312 phase of AsP_(2)X_(6)(X=S,Se)are indirect semiconductors with band gaps of 2.44 eV(AsP2S6)and 2.18 eV(AsP2Se6)at the HSE06 level,and their absorption coefficients are predicted to reach the order of 10^(5)cm^(-1)from visible light to ultraviolet region,but the main absorption is manly in the ultraviolet region.The P-31m phase of AsP_(2)X_(6)(X=S,Se)exhibits metal character with the Fermi surface mainly occupied by the p orbital of S/Se.Remarkably,estimated by first principles calculations,the P-31m AsP2S6 is found to be an intrinsic phonon-mediated superconductor with a relatively high critical superconducting temperature of about 13.4 K,and the P-31m AsP2Se6 only has a superconducting temperature of 1.4 K,which suggest that the P-31m AsP2S6 may be a good candidate for a nanoscale superconductor.
基金supported by the National Natural Science Foundation of China(No.12372005)the Aeronautical Science Foundation of China(No.ASFC-2024Z070050001)the Natural Science Foundation of Liaoning Province(2024-MSBA-32).
文摘In this paper,inspired by the running motion gait of a cheetah,an H-shaped bionic piezoelectric robot(H-BPR)based on the standing wave principle is proposed and designed.The piezoelectric robot realizes linear motion,turning motion,and turning motion with different radi by the voltage differential driving method.A prototype with a weight of 38 g and dimensions of 150×80×31 mm^(3) was fabricated.Firstly,the dynamics and kinematics of the piezoelectric robot were analyzed to obtain the trajectory of a point at the end of the piezoelectric robot leg.The motion principle of the piezo-electric robot was analyzed,and then the piezoelectric robot's modal analysis and harmonic response analysis were carried out using finite element analysis software.Finally,an experimental setup was built to verify the effectiveness and high efficiency of the robot's motion,and the effects of frequency,voltage,load,and height of the driving leg on the robot's motion performance were discussed.The performance test results show that the piezoelectric robot has a maximum veloc-ity of 66.79 mm/s at an excitation voltage of 320 V and a load capacity of 55 g.In addition,the H-BPR with unequal drive legs has better climbing performance,and the obtained conclusions are informative for selecting leg heights for piezoelectric robots.
文摘In interpersonal communication,the principle of politeness is an important communicative principle that is widely applied in people’s daily life.However,the communication patterns of the principle of politeness and face theory in the travel planning process among friends still need further exploration.This study aims to analyze the specific manifestations of these principles in the communication patterns of travel planning among friends through a pragmatic interpretation of the principle of politeness and face theory,providing a new perspective for understanding linguistic behavior in interpersonal relationships.
文摘This paper analyzes the humorous effects generated through the non-observance of Grice’s Cooperative Principle(CP)in the Chinese crosstalk Learning Manchu.Focusing on violations of the Quantity,Quality,Relation,and Manner maxims,it examines how deliberate pragmatic deviations create comedy.The study also incorporates the unique crosstalk mechanism of“Baofu”(packaging and delivering jokes)and emphasizes the essential role of audience cooperation in humor reception.It argues that humor in crosstalk arises not only from performers’non-cooperation but also from active audience engagement within a shared cultural context.
基金funded by National Natural Science Foundation of China(Nos.U20A20172,U24A20222)Zhejiang Province Key R&D programs(No.2023C01192)supported by the Fundamental Research Funds for the Provincial Universities of Zhejiang(No.GK239909299001).
文摘A stacked piezoelectric micropump based on the synthetic jet principle with a size of 22×22×5 mm^(3) is designed and fabricated.Through theoretical and finite element method(FEM)analysis,the conditions for achieving a synthetic jet structure are obtained,and the gas flow properties inside the chamber are analyzed.The first-order mode and resonant frequency of the piezoelectric actuator are simulated.At a resonant frequency of 22.5 kHz,the maximum central displacement of the actuator can reach 12.3μm.In addition,the key dimensions of the micropump are optimized to improve the output flow rate.Experiments on the prototype of the micropump show that it can reach a maximum output flow rate of 618 mL/min when driven by a sine wave signal of 42 Vpp and 22.5 kHz.The power dissipation does not exceed 600 mW.
基金supported by the National Natural Science Foundation of China(No.12071047,51774289,52074291).
文摘To ameliorate the difficulties of on-site dynamic disaster control in the end-mining stage of traditional mining engineering,this paper introduces the mathematical research and engineering application of the end-mining technology system with non-pillar in mines(ETSNM)in recent years.The petal warning criterion for the stability of the surrounding rock of the roadway at the end-mining stage was obtained by studying the inverse problem of the petal theorem.A conformal mathematical model of the end-mining stage was established using the conformal mapping method,and the limit theorem of the peak point of mine pressure(LTPPMP)in the end-mining stage was demonstrated.Based on the cross-fusion of the above basic mathematical theory and the LTPPMP,a new ETSNM model was proposed,which includes no coal pillar,no dedicated retracement roadways,and fast retracement equipment(NNF).The mathematical principles of engineering technology for height control,speed limit,and roof cutting in the end-mining stage with non-pillar were revealed.The scientific and application values of the ETSNM were confirmed through engineering applications.Based on this,a new non-pillar control technology for dynamic disasters in the end-mining stage was proposed.The above research will play an active role in promoting the engineering application of ETSNM driven by mathematical theory.
基金financially supported by the National Key R&D Program of China(No.2021YFC2202300)the National Natural Science Foundation of China(NSFC)(No.51974258)the National College Students Innovation and Entrepreneurship Training Program(No.S202210699134).
文摘Gold-platinum(Au-Pt)alloy has aroused considerable attention due to its ultra-low magnetic susceptibility(MS)in testing mass(TM)on spacecraft.However,the effect of Au content on the properties of the alloy has not yet been understood.In this study,the composition design of Au-Pt alloy with ultra-low MS was achieved through density functional theory(DFT)and experimental methods.The elastic,thermal properties and electronic structure were systematically investigated,the composition range was further optimized and Au75Pt25 was determined to be the most suitable alloy for TM material.The phase composition of this alloy after cold rolling and solid solution was characterized,indicating a single-phase FCC structure.In addition,there is a good validation between the experimental Vickers hardness and the DFT results.This work provides new insights into the compositional optimization of Au-Pt alloys and lays the foundation for alloy development.
基金supported by the steady supports scientific research of Key Laboratory of Defense Science and Technology,China(No.WDZC20220105)the National Natural Science Foundation of China(Nos.51775020,62073009,U20B2002)the Science Challenge Project,China(No.TZ2018007)。
文摘Thermal Protection System(TPS)with thick tiles,low thermal conductivity,and a short re-entry stage stands as a critical element within reusable aircraft,whose reliability is related to the function and changes with their physical properties,external conditions,and degradation.Meanwhile,due to the limitation of testing resources,epistemic uncertainties stemming from the small samples are present in TPS reliability modeling.However,current TPS reliability modeling methods face challenges in characterizing the relationships among reliability and physical properties,external conditions,degradation,and epistemic uncertainties.Therefore,under the framework of belief reliability theory,a TPS reliability model is constructed,which takes into account the physical principle,external conditions,performance degradation,and epistemic uncertainties.A reliability simulation algorithm is proposed to calculate TPS reliability.Through a case study and comparison analysis,the proposed method is validated as more effective than the existing method.Additionally,reliability sensitivity analysis is conducted to identify the sensitive factors of reliability under the condition of small samples,through which suggestions are provided for TPS functional design and improvement.
基金Supported by Undergraduate Innovation and Entrepreneurship Training Program(S202410599085).
文摘This paper offers a comprehensive overview of the operational principles of current therapeutic devices for diabetic foot management and further analyzes technological innovations and developmental trends,aiming to promote research and development in the field of technological convergence.The ultimate goal is to enhance the cure rate for diabetic foot conditions and to decrease the incidence of amputations.The paper discusses the novel applications of ultrasound and optical therapeutic devices within the field of physiotherapy,the numerous advantages of chitosan dressings in biotechnology,the ongoing advancements and broader combined use of vacuum sealing drainage techniques,and the distinctive effects and innovations associated with micro-oxygen diffusion techniques.It thoroughly examines various technological mechanisms that facilitate wound healing,highlighting the clinical applications of ultrasonic atomized medicinal solutions,novel dressing graft copolymerization,continuous hypoxia diffusion,and the functions of vacuum drainage.These advancements facilitate the integration of drainage and dressing changes,with the potential to enhance the therapeutic effects of diabetic foot treatment and provide valuable insights for clinical application.
基金supported by the Swiss National Science Foundation(grant number 188631).
文摘The all-vanadium redox flow battery(VRFB)plays an important role in the energy transition toward renewable technologies by providing grid-scale energy storage.Their deployment,however,is limited by the lack of membranes that provide both a high energy efficiency and capacity retention.Typically,the improvement of the battery’s energy efficiency comes at the cost of its capacity retention.Herein,novel N-alkylated and N-benzylated meta-polybenzimidazole(m-PBI)membranes are used to understand the molecular requirements of the polymer electrolyte in a vanadium redox flow battery,providing an important toolbox for future research toward next-generation membrane materials in energy storage devices.The addition of an ethyl side chain to the m-PBI backbone increases its affinity toward the acidic electrolyte,thereby increasing its ionic conductivity and the corresponding energy efficiency of the VRFB cell from 70%to 78%at a current density of 200 mA cm^(-2).In addition,cells equipped with ethylated m-PBI showed better capacity retention than their pristine counterpart,respectively 91%versus 87%,over 200 cycles at 200 mA cm^(-2).The outstanding VRFB cycling performance,together with the low-cost and fluorine-free chemistry of the N-alkylated m-PBI polymer,makes this material a promising membrane to be used in next-generation VRFB systems.
文摘This paper comprehensively explores the technical principles and application practice of Sainaoning absorbable dural sealant medical adhesive in dural closure.It elaborates on the research and development background of Sainaoning,analyzes its composition,action mechanism,and product characteristics in detail,and presents the results of pre-clinical and clinical studies.The application of Sainaoning in different craniotomy surgeries is discussed,and its effectiveness and safety are evaluated.The paper also analyzes the challenges in its application and proposes corresponding countermeasures,aiming to provide a comprehensive understanding and reference for the clinical use and further development of Sainaoning.
基金Sponsored by Natural Science Foundation of Hebei Province(Grant No.E2019209153)Tangshan Science and Technology Program(Grant No.22130219G).
文摘The contact characteristics between cycloidal gear teeth and pinwheel teeth significantly impact the operational performance of cycloidal pinwheel mechanisms.Current research methods tend to rely primarily on theoretical calculations,with limited use of experimental methods for detecting dynamic contact properties.We propose a novel method for testing the dynamic contact characteristics of cycloidal pinwheel mechanisms.By combining Hertzian contact theory and contact strength theory,we establish a force and meshing stiffness model for the cycloidal and pinwheel gears,and determine the maximum contact stress and variations in pinwheel gear force and meshing stiffness.Based on the principle of photoelasticity,we built a testing platform for the cycloidal pinwheel mechanism to assess its contact characteristics.This platform provides the stress distribution of the cycloidal pinwheel mechanism and allows us to deduce key parameters such as the number of meshing teeth and the meshing interval.This study provides an experimental method for investigating the contact characteristics of cycloidal pinwheel mechanisms.
基金supported by the National Key Research and Development Program of China(2023YFB3809800)the National Natural Science Foundation of China(52172249,52525601)+2 种基金the Chinese Academy of Sciences Talents Program(E2290701)the Jiangsu Province Talents Program(JSSCRC2023545)the Special Fund Project of Carbon Peaking Carbon Neutrality Science and Technology Innovation of Jiangsu Province(BE2022011).
文摘Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexible fiber sensors.Through the preform-tofiber manufacturing technique,a variety of fiber sensors with complex functionalities spanning from the nanoscale to kilometer scale can be automated in a short time.Examples include temperature,acoustic,mechanical,chemical,biological,optoelectronic,and multifunctional sensors,which operate on diverse sensing principles such as resistance,capacitance,piezoelectricity,triboelectricity,photoelectricity,and thermoelectricity.This review outlines the principles of the thermal drawing process and provides a detailed overview of the latest advancements in various thermally drawn fiber sensors.Finally,the future developments of thermally drawn fiber sensors are discussed.
基金2023 Ideological and Political Demonstration Course Construction Project of Guangxi University“Principles of Tourism:An Ideological and Political Demonstration Course”(ZX02020034224005)。
文摘Requirements for the ideological and political construction of university courses in the new era stipulate that professional courses should proceed in the same direction as ideological and political courses,forming an educational pattern that involves all personnel,covers the entire process,and integrates across all courses.Taking the course of Principles of Tourism as an example,this paper discusses the significance,content,and objectives of ideological and political construction in the Principles of Tourism course based on an analysis of its current status.Furthermore,practical strategies for ideological and political construction in the Principles of Tourism course are proposed from four aspects:teaching philosophy,teaching design,teaching methods,and teaching evaluation.The aim is to fully leverage the educational function of tourism-related professional courses and enhance the quality of teaching in the Principles of Tourism course through its ideological and political construction.
基金Supported by Sichuan Province Germplasm Resource Precision Identification Project(2025 Provincial Finance Agricultural High Quality Development Joint Financial Transfer Payment Fund Project)Longquanyi District Science and Technology Plan Project in 2025(2081923007)School Level Horizontal Project in 2025(2502180).
文摘Gene Engineering Principles is a fundamental professional course for majors such as bioengineering and biotechnology.It integrates theoretical knowledge with experimental practice and engineering applications.It is characterized by its comprehensive and highly practical nature.Aligning with the new-era higher education philosophy of‘competency-oriented,value-driven’teaching,this study presented a systematic exploration and practice based on undergraduate cohorts from 2018 to 2020 in Chengdu University.The reform focused on teaching methodology,formative assessment,and the integration of ideological and political education.Key strategies included the introduction of classical experimental cases,emphasis on pre-class preparation,enhancement of classroom interaction,focus on engineering-oriented applications,optimization of assessment mechanisms,and the incorporation of national strategic needs into the curriculum.These measures effectively stimulated students’learning motivation and research potential,thereby improving the overall teaching quality and educational effectiveness of the course.The results of the teaching reform demonstrate significant improvements in students’ability to apply theoretical knowledge to practical engineering problems,scientific thinking,experimental research skills,scientific reasoning,and professional identity.Reformed classes outperformed control groups across various instructional metrics,achieving notable educational outcomes.
