The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts ...The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained：64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories：the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous（about 90 Ma）, while the latter, closely related to the granite porphyry, formed at early Paleogene（about 60 Ma）. And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.展开更多
Due to the complicated lithology in the ES3 Member of the Shahejie Formation in the Shulu sag,Jizhong depression,it is difficult to classify the rock types and characterize the reservoirs at the marl intervals.In this...Due to the complicated lithology in the ES3 Member of the Shahejie Formation in the Shulu sag,Jizhong depression,it is difficult to classify the rock types and characterize the reservoirs at the marl intervals.In this paper,a four-element classification method has been proposed,and seven rock types have been identified by analyzing the mineral composition.The primary rock types are medium-high organic carbonate rocks and medium-high organic shaly-siliceous carbonate rocks.With the methods of field emission scanning electron microscopy,high-pressure mercury intrusion,nitrogen adsorption,and nano-CT,four types of reservoir spaces have been identified,including intra-granular pores,intergranular pores(inter-crystalline pores),organic pores,and micro-fractures.By combining the method of high-pressure mercury intrusion with the method of the nitrogen adsorption,the porosity of the marl has been measured,ranging from 0.73%to 5.39%.The distribution of the pore sizes is bimodal,and the pore types are dominated by micron pores.Through this study,it has been concluded that the sag area to the east of Well ST1H is the favorable area for the development of self-sourced and self-reservoired shale oil.According to the results of geochemical and reservoir analysis,the III Oil Group may have sweet spot layers.展开更多
Rock typing is an important tool in evaluation and performance prediction of reservoirs.Different techniques such as flow zone indicator(FZI),FZI~*and Winland methods are used to categorize reservoir rocks into distin...Rock typing is an important tool in evaluation and performance prediction of reservoirs.Different techniques such as flow zone indicator(FZI),FZI~*and Winland methods are used to categorize reservoir rocks into distinct rock types.Generally,these methods are applied to petrophysical data that are measured at a pressure other than reservoir pressure.Since the pressure changes the pore structure of rock,the effect of overburden pressure on rock typing should be considered.In this study,porosity and permeability of 113 core samples were measured at five different pressures.To investigate the effect of pressure on determination of rock types,FZI,FZI~*and Winland methods were applied.Results indicated that although most of the samples remain in the same rock type when pressure changes,some of them show different trends.These are related to the mineralogy and changes in pore system of the samples due to pressure change.Additionally,the number of rock types increases with increasing pressure.Furthermore,the effect of overburden pressure on determination of rock types is more clearly observed in the Winland and FZI~*methods.Also,results revealed that a more precise reservoir dynamic simulation can be obtained by considering the reservoir rock typing process at reservoir conditions.展开更多
Dariyan (Shuaiba) Formation is one of the main reservoir units in the Persian Gulf and South Western Iran. The microfacies and depositional environment of this formation is been investigated in the current study and i...Dariyan (Shuaiba) Formation is one of the main reservoir units in the Persian Gulf and South Western Iran. The microfacies and depositional environment of this formation is been investigated in the current study and influencing factors in reservoir characteristics have been discussed for Dariyan reservoir in the Soroush oil field. Facies analysis conducted on core and cutting samples indicated that Dariyan Formation is mainly deposited on a carbonate ramp setting with a shallow intra shelf basin. In addition, it has been demonstrated that facies changes reflect the main controls of the tectonic and climate (sea level fluctuations) during the deposition of these sediments. To determine the reservoir unites in this formation, 5 electrofacies were determined by neural network method that it is using different petrophysical logs (i.e. GR, PHIE and SWE). Using rock typing as the best way to establish an association between the various collected data (e.g. logs and cores) and geological descriptions 4 hydraulic flow units or rock types, determined on the basis of the Flow Zone Indicator (FZI) method in the Dariyan Formation of the Soroush field. Establishing a correlation between microfacies and rock types, the carbonate zones with moderate to good reservoir properties and also the intervals with the highest reservoir quality were determined.展开更多
"Rocking chair"type lithium-ion batteries with lithium metal-free anodes have been successfully com-mercialized over the past few decades.Zinc-ion batteries(zIBs)have gained increasing attention in recent ye..."Rocking chair"type lithium-ion batteries with lithium metal-free anodes have been successfully com-mercialized over the past few decades.Zinc-ion batteries(zIBs)have gained increasing attention in recent years given their safety,greenness,ease of manufacture,and cost-efficiency.Nevertheless,the practical application of ZIBs is largely hindered by the dendritic growth of the Zn metal anode,low Coulombic eficiency,great harm,and existence of various side reactions.Herein,this review provides a systematic overview of emerging"rocking chair"type ZIBs with zinc metal-free anodes.Firstly,the basic fundamen-tals,advantages,and challenges of“rocking chair”type ZIBs are introduced.Subsequently,an overview of the design principles and recent progress of"rocking chair"type ZIBs with zinc metal-free anodes are presented.Finally,the key challenges and perspectives for future advancement of"rocking chair"type ZiBs with zinc metal-free anodes are proposed.This review is anticipated to attracted increased focus to metal-free anodes"rocking chair"type metal-ion battery and provide new inspirations for the develop-ment of high-energy metal-ion batteries.展开更多
The Oligo-Miocene Asmari Formation is one of the most important hydrocarbon reservoirs in the Middle East.The oilfield under study is one of the largest oilfields in the Zagros basin with the Asmari Formation being th...The Oligo-Miocene Asmari Formation is one of the most important hydrocarbon reservoirs in the Middle East.The oilfield under study is one of the largest oilfields in the Zagros basin with the Asmari Formation being the major reservoir rock.In this study,petrographic analyses,petrophysical data and neural network clustering techniques were used for identifying rock types in the Asmari reservoir.Facies analysis of the Asmari Formation in the study area has resulted in the definition of 1 clastic lithofacies and 14 carbonate microfacies types.Using petrophysical logs from 43 wells and their correlation with capillary pressure(Pc)curves,led to the recognition of 7 electrofacies(EF1-EF7).Microscopic evidence of Electrofacies group C1 and S1 show that the sedimentary facies of these electrofacies are most commonly found in restricted and shoal facies belts zone.Also,petrographic studies show that the sedimentary facies of C2,C3,C4,S2 and S3 were formed in the open marine,Lagoon,and Tidal flat facies belt zone of homoclinal ramp sedimentary environment during the Oligo-Miocene based on relative sea level changes respectively.The link between electrofacies and geological data indicated that both sedimentary and diagenetic processes controlled the reservoir quality of the Asmari Formation.Porosity,permeability and water saturation were used to estimate the reservoir quality of each electrofacies.EFs 1 and 2 with high porosity and permeability,low water saturation is considered as the best reservoir with regard to sedimentary textures(dolowackestone and dolograinstone)and the effect of diagenetic processes such as dolomitization processes.Vuggy,growth framework and interparticle porosities are major in EF-2,while the intercrystalline porosity is the major type in EF-1.EFs 3 and 4 show low values of porosity,permeability and high percentage of water saturations,which characterizes them as poor reservoir rocks.Finally,EF-5 is the only electrofacies in the siliciclastic parts of the Asmari reservoir,which is composed of rounded and well-sorted quartz grains that are slightly cemented.In sandstone electrofacies,electrofacies EF-5(S1),is the best type of sandstone reservoir rock and to move towards electrofacies EF-7(S3),will reduce reservoir quality.In carbonate electrofacies,also,electrofacies no 1,the best type of carbonate reservoir rock can be observed and move towards electrofacie number 4,lower quality of reservoir rocks is seen.展开更多
The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate ...The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate that the deposit is characterized by the enrichment of some platinum group elements in principal metallic minerals such as chalcopyrite, galena, sphalerite and pyrite, and the presence of millerite. Stable isotope studies show that carbon, sulfur and most of the metallogenic elements were probably derived largely from the host Xiaozhangjiakou ultrabasic rocks and that it is possible that the ore\|forming fluid was predominated by meteoric water.展开更多
Metallogenic models of gold deposits of quartz vein type and altered rock type will be dis-cussed in this note. They are considered to be closely related to granite spatially andgenetically.
The information from sparsely logged wellbores is currently under-utilized in reservoir simulation models and their proxies using deep and machine learning (DL/ML).This is particularly problematic for large heterogene...The information from sparsely logged wellbores is currently under-utilized in reservoir simulation models and their proxies using deep and machine learning (DL/ML).This is particularly problematic for large heterogeneous gas/oil reservoirs being considered for repurposing as gas storage reservoirs for CH_(4),CO_(2) or H_(2) and/or enhanced oil recovery technologies.Lack of well-log data leads to inadequate spatial definition of complex models due to the large uncertainties associated with the extrapolation of petrophysical rock types (PRT) calibrated with limited core data across heterogeneous and/or anisotropic reservoirs.Extracting well-log attributes from the few well logs available in many wells and tying PRT predictions based on them to seismic data has the potential to substantially improve the confidence in PRT 3D-mapping across such reservoirs.That process becomes more efficient when coupled with DL/ML models incorporating feature importance and optimized,dual-objective feature selection techniques.展开更多
Engineering geomechanics characteristics of roadways in deep soft rock at Hegang Xing'an Coal Mine were studied and the nature of clay minerals of roadway surrounding rock was analyzed. This paper is to solve the ...Engineering geomechanics characteristics of roadways in deep soft rock at Hegang Xing'an Coal Mine were studied and the nature of clay minerals of roadway surrounding rock was analyzed. This paper is to solve the technical problems of high stress and the difficulty in supporting the coal mine, and provide a rule for the support design. Results show that mechanical deformation mechanisms of deep soft rock roadway at Xing'an Coal Mine is of ⅠABⅡABCⅢABCD type, consisting of molecular water absorption (the ⅠAB -type), the tectonic stress type + gravity deformation type + hydraulic type (the ⅡABC -type), and the ⅢABCD -type with fault, weak intercalation and bedding formation. According to the compound mechanical deformation mechanisms, the corresponding mechanical control measures and conversion technologies were proposed, and these technologies have been successfully applied in roadway supporting practice in deep soft rock at Xing'an Coal Mine with good effect. Xing'an Coal Mine has the deepest burial depth in China, with its overburden ranging from Mesozoic Jurassic coal-forming to now. The results of the research can be used as guidance in the design of roadway support in soft rock.展开更多
The late Jurassic Arab Formation, a significant carbonate-evaporite reservoir rock in the Persian Gulf, is characterized by frequent grainstone facies. For rock type identification and reservoir characterization, core...The late Jurassic Arab Formation, a significant carbonate-evaporite reservoir rock in the Persian Gulf, is characterized by frequent grainstone facies. For rock type identification and reservoir characterization, core description, petrographic studies and pore system evaluation are integrated for Balal oil field in the Persian Gulf. The grainstone facies are developed into three shoal subenvironments on a carbonate ramp platform： leeward, central and seaward. Compaction, dissolution, cementation, anhydrite mineralization and dolomitization are the main diagenetic processes affecting the depositional pore system. Considering depositional and diagenetic features and pore types, the grainstones are classified into six rock types （RT 1 to RT6）. Rock types 1, 2 and 5 have large pore throat sizes with inter- granular and touching vug pore types. In rock type 3, moldic pores lead to high porosity and low permeability. Rock types 4 and 6 are cemented by anhydrite, calcite and dolomite. Generally, RTs 1, 2, 3 and 5 are related to late Transgressive systems tract （TST） and early Highstand systems tracts （HST） and show fair to good reservoir quality. In contrast, RTs 4 and 6 of late HST system tract show lower poroperm values, due to evaporite mineralization. Characterization of the grainstone facies provides a comprehensive understanding of the reservoir zones of the Arab Formation.展开更多
We used the geological map and published rock density measurements to compile the digital rock density model for the Hong Kong territories.We then estimated the average density for the whole territory.According to our...We used the geological map and published rock density measurements to compile the digital rock density model for the Hong Kong territories.We then estimated the average density for the whole territory.According to our result,the rock density values in Hong Kong vary from 2101 to 2681 kg·m^(-3).These density values are typically smaller than the average density of 2670 kg·m^(-3),often adopted to represent the average density of the upper continental crust in physical geodesy and gravimetric geophysics applications.This finding reflects that the geological configuration in Hong Kong is mainly formed by light volcanic formations and lava flows with overlying sedimentary deposits at many locations,while the percentage of heavier metamorphic rocks is very low(less than 1%).This product will improve the accuracy of a detailed geoid model and orthometric heights.展开更多
The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold g...The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold grades of 1.0–19.5 g/t set within a larger, lower-grade(0.2–1.0 g/t) zone. According to the fluid inclusions study, the homogenization temperature ranges from 70–350℃, and concentrates between 140–220℃. The laser Rama results show that the CO2 and CH4 exist in mineralized fluid. In addition, the major and trace element and REE geochemical data show that the genesis of the siliceous rocks is hydrothermal genesis, formed by mineralized fluid bearing SiO2 transmitted along faults to the surface, and replace the carbonate rocks to begin deposition. Primary gold mineralization is attributed to hydrothermal activity that followed the main period of tectonic deformation of the Indosinian orogeny, which caused the regional detachment regime in southeast Hubei. The reversed fold and the fault system formed the fluid migration channel in the Shewushan area. EPMA results show that Au exists in arsenopyrite(850×10-6–1550×10-6 Au) and pyrite(470×10-6–1340×10-6 Au). Therefore, based on the above results and combined with the field observation, we suggest that the genesis of primary orebody in Shewushan deposit is carlin type, while not weathered residual type.展开更多
Terrestrial faulted lacustrine basin is considered as a favorable place for the development of source rocks,especially the fault basins in eastern China.Based on molecular composition study of saturated and aromatic h...Terrestrial faulted lacustrine basin is considered as a favorable place for the development of source rocks,especially the fault basins in eastern China.Based on molecular composition study of saturated and aromatic hydrocarbons in the extracts of source rocks of the Yingcheng and Shahezi formations in the Lishu Fault Depression,it is revealed that the extracts of source rocks are provided with low ratio of Pr/Ph,low content of C24 tetracyclic terpanes,high content of tricyclic terpanes and gammacerane,relatively high content of C27 steranes in the sag belt and its periphery;relatively high ratio of Pr/Ph,relatively high content of tetracyclic terpanes and gammacerane,low content of C27 steranes and obvious advantages of C29 steranes in its gentle slope belt;with high ratio of Pr/Ph,high content of C19,C20 tricyclic and C24 tetracyclic terpanes,very low content of gammacerane and C27 steranes,and high content of C29 steranes in the edge of fault depression.According to the organic matter input and sedimentary environment,three types of source rocks have been established,which,respectively,are the mode of mixing organic matter input in deep and semi-deep lake,the advantage of terrigenous input in shallow lake and terrigenous input in shore-shallow lacustrine.The first mode is supposed to generate oil and gas,while the second one tends to generate oil.The distribution characteristics of oil and gas in the Lishu Fault Depression are very likely to be controlled by hydrocarbon generating characteristic of different source rock types.展开更多
The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrati...The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrating there is a great potential for natural gas exploration in oil-type basins.The ethane isotope of the Bozhong 19-6 condensate gas is heavy,showing the characteristics of partial humic gas.In this paper,aimed at the source rocks of the Bozhong 19-6 gas field in the Bohai Bay Basin,the characteristics of the source rocks in the Bozhong 19-6 structural belt were clarified and the reason are explained from impact of microorganism degradation on hydrocarbon generation of source rocks why the condensate oil and gas had heavy carbon isotope and why it showed partial humic characteristics was explored based on the research of parent materials.The following conclusions were obtained:The paleontology of the Bozhong 19-6 structural belt and its surrounding sub-sags is dominated by higher plants,such as angiosperm and gymnosperm.During the formation of source rocks,under the intensive transformation of microorganism,the original sedimentary organic matter such as higher plants was degraded and transformed by defunctionalization.Especially,the transformation of anaerobic microorganisms on source rocks causes the degradation and defunctionalization of a large number of humic products such as higher plants and the increase of hydrogen content.The degradation and transformation of microorganism don't transform the terrestrial humic organic matter into newly formed“sapropel”hydrocarbons,the source rocks are mixed partial humic source rocks.As a result,hydrogen content incrased and the quality of source rocks was improved,forming the partial humic source rocks dominated by humic amorphous bodies.The partial humic source rocks are the main source rocks in the Bozhong 19-6 gas field,and it is also the internal reason why the isotope of natural gas is heavy.展开更多
基金supported financially by the National Natural Scientific Foundation of China (Grants No. 40872069 and 41173059)the National Basic Research Program of China (973 Program) (Grants No. 2015CB453000)+1 种基金China Geological Survey (Grants No. 12120113095500)the Foundation of China Nuclear Geology (Grants No. 201148)
文摘The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained：64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories：the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous（about 90 Ma）, while the latter, closely related to the granite porphyry, formed at early Paleogene（about 60 Ma）. And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.
基金supported by the National Basic Research Program of China(973 Program)(No.2014CB239001).
文摘Due to the complicated lithology in the ES3 Member of the Shahejie Formation in the Shulu sag,Jizhong depression,it is difficult to classify the rock types and characterize the reservoirs at the marl intervals.In this paper,a four-element classification method has been proposed,and seven rock types have been identified by analyzing the mineral composition.The primary rock types are medium-high organic carbonate rocks and medium-high organic shaly-siliceous carbonate rocks.With the methods of field emission scanning electron microscopy,high-pressure mercury intrusion,nitrogen adsorption,and nano-CT,four types of reservoir spaces have been identified,including intra-granular pores,intergranular pores(inter-crystalline pores),organic pores,and micro-fractures.By combining the method of high-pressure mercury intrusion with the method of the nitrogen adsorption,the porosity of the marl has been measured,ranging from 0.73%to 5.39%.The distribution of the pore sizes is bimodal,and the pore types are dominated by micron pores.Through this study,it has been concluded that the sag area to the east of Well ST1H is the favorable area for the development of self-sourced and self-reservoired shale oil.According to the results of geochemical and reservoir analysis,the III Oil Group may have sweet spot layers.
文摘Rock typing is an important tool in evaluation and performance prediction of reservoirs.Different techniques such as flow zone indicator(FZI),FZI~*and Winland methods are used to categorize reservoir rocks into distinct rock types.Generally,these methods are applied to petrophysical data that are measured at a pressure other than reservoir pressure.Since the pressure changes the pore structure of rock,the effect of overburden pressure on rock typing should be considered.In this study,porosity and permeability of 113 core samples were measured at five different pressures.To investigate the effect of pressure on determination of rock types,FZI,FZI~*and Winland methods were applied.Results indicated that although most of the samples remain in the same rock type when pressure changes,some of them show different trends.These are related to the mineralogy and changes in pore system of the samples due to pressure change.Additionally,the number of rock types increases with increasing pressure.Furthermore,the effect of overburden pressure on determination of rock types is more clearly observed in the Winland and FZI~*methods.Also,results revealed that a more precise reservoir dynamic simulation can be obtained by considering the reservoir rock typing process at reservoir conditions.
文摘Dariyan (Shuaiba) Formation is one of the main reservoir units in the Persian Gulf and South Western Iran. The microfacies and depositional environment of this formation is been investigated in the current study and influencing factors in reservoir characteristics have been discussed for Dariyan reservoir in the Soroush oil field. Facies analysis conducted on core and cutting samples indicated that Dariyan Formation is mainly deposited on a carbonate ramp setting with a shallow intra shelf basin. In addition, it has been demonstrated that facies changes reflect the main controls of the tectonic and climate (sea level fluctuations) during the deposition of these sediments. To determine the reservoir unites in this formation, 5 electrofacies were determined by neural network method that it is using different petrophysical logs (i.e. GR, PHIE and SWE). Using rock typing as the best way to establish an association between the various collected data (e.g. logs and cores) and geological descriptions 4 hydraulic flow units or rock types, determined on the basis of the Flow Zone Indicator (FZI) method in the Dariyan Formation of the Soroush field. Establishing a correlation between microfacies and rock types, the carbonate zones with moderate to good reservoir properties and also the intervals with the highest reservoir quality were determined.
基金supported the National Natural Science Foundation of China(No.62101296)the Natural Science Foundation of Shaanxi Province(Nos.2021JQ-760 and 2021JQ-756).
文摘"Rocking chair"type lithium-ion batteries with lithium metal-free anodes have been successfully com-mercialized over the past few decades.Zinc-ion batteries(zIBs)have gained increasing attention in recent years given their safety,greenness,ease of manufacture,and cost-efficiency.Nevertheless,the practical application of ZIBs is largely hindered by the dendritic growth of the Zn metal anode,low Coulombic eficiency,great harm,and existence of various side reactions.Herein,this review provides a systematic overview of emerging"rocking chair"type ZIBs with zinc metal-free anodes.Firstly,the basic fundamen-tals,advantages,and challenges of“rocking chair”type ZIBs are introduced.Subsequently,an overview of the design principles and recent progress of"rocking chair"type ZIBs with zinc metal-free anodes are presented.Finally,the key challenges and perspectives for future advancement of"rocking chair"type ZiBs with zinc metal-free anodes are proposed.This review is anticipated to attracted increased focus to metal-free anodes"rocking chair"type metal-ion battery and provide new inspirations for the develop-ment of high-energy metal-ion batteries.
文摘The Oligo-Miocene Asmari Formation is one of the most important hydrocarbon reservoirs in the Middle East.The oilfield under study is one of the largest oilfields in the Zagros basin with the Asmari Formation being the major reservoir rock.In this study,petrographic analyses,petrophysical data and neural network clustering techniques were used for identifying rock types in the Asmari reservoir.Facies analysis of the Asmari Formation in the study area has resulted in the definition of 1 clastic lithofacies and 14 carbonate microfacies types.Using petrophysical logs from 43 wells and their correlation with capillary pressure(Pc)curves,led to the recognition of 7 electrofacies(EF1-EF7).Microscopic evidence of Electrofacies group C1 and S1 show that the sedimentary facies of these electrofacies are most commonly found in restricted and shoal facies belts zone.Also,petrographic studies show that the sedimentary facies of C2,C3,C4,S2 and S3 were formed in the open marine,Lagoon,and Tidal flat facies belt zone of homoclinal ramp sedimentary environment during the Oligo-Miocene based on relative sea level changes respectively.The link between electrofacies and geological data indicated that both sedimentary and diagenetic processes controlled the reservoir quality of the Asmari Formation.Porosity,permeability and water saturation were used to estimate the reservoir quality of each electrofacies.EFs 1 and 2 with high porosity and permeability,low water saturation is considered as the best reservoir with regard to sedimentary textures(dolowackestone and dolograinstone)and the effect of diagenetic processes such as dolomitization processes.Vuggy,growth framework and interparticle porosities are major in EF-2,while the intercrystalline porosity is the major type in EF-1.EFs 3 and 4 show low values of porosity,permeability and high percentage of water saturations,which characterizes them as poor reservoir rocks.Finally,EF-5 is the only electrofacies in the siliciclastic parts of the Asmari reservoir,which is composed of rounded and well-sorted quartz grains that are slightly cemented.In sandstone electrofacies,electrofacies EF-5(S1),is the best type of sandstone reservoir rock and to move towards electrofacies EF-7(S3),will reduce reservoir quality.In carbonate electrofacies,also,electrofacies no 1,the best type of carbonate reservoir rock can be observed and move towards electrofacie number 4,lower quality of reservoir rocks is seen.
文摘The Jinjiazhuang gold deposit occurs in the Zhangjiakou gold field, Northwest Hebei. The ore bodies are mostly hosted in Xiaozhangjiakou ultrabasic rocks dominated by diopsidite. Electron microprobe analyses indicate that the deposit is characterized by the enrichment of some platinum group elements in principal metallic minerals such as chalcopyrite, galena, sphalerite and pyrite, and the presence of millerite. Stable isotope studies show that carbon, sulfur and most of the metallogenic elements were probably derived largely from the host Xiaozhangjiakou ultrabasic rocks and that it is possible that the ore\|forming fluid was predominated by meteoric water.
基金Project supported by Doctorate Foundation of the State Education Commission of China.
文摘Metallogenic models of gold deposits of quartz vein type and altered rock type will be dis-cussed in this note. They are considered to be closely related to granite spatially andgenetically.
文摘The information from sparsely logged wellbores is currently under-utilized in reservoir simulation models and their proxies using deep and machine learning (DL/ML).This is particularly problematic for large heterogeneous gas/oil reservoirs being considered for repurposing as gas storage reservoirs for CH_(4),CO_(2) or H_(2) and/or enhanced oil recovery technologies.Lack of well-log data leads to inadequate spatial definition of complex models due to the large uncertainties associated with the extrapolation of petrophysical rock types (PRT) calibrated with limited core data across heterogeneous and/or anisotropic reservoirs.Extracting well-log attributes from the few well logs available in many wells and tying PRT predictions based on them to seismic data has the potential to substantially improve the confidence in PRT 3D-mapping across such reservoirs.That process becomes more efficient when coupled with DL/ML models incorporating feature importance and optimized,dual-objective feature selection techniques.
基金partially supported by program for the New Century Excellent Talents in University (No. NCET-08-0833)the National Natural Science Foundation of China (No. 41040027)the Special Fund of Basic Research and Operating Expenses of China University of Mining and Technology, Beijing
文摘Engineering geomechanics characteristics of roadways in deep soft rock at Hegang Xing'an Coal Mine were studied and the nature of clay minerals of roadway surrounding rock was analyzed. This paper is to solve the technical problems of high stress and the difficulty in supporting the coal mine, and provide a rule for the support design. Results show that mechanical deformation mechanisms of deep soft rock roadway at Xing'an Coal Mine is of ⅠABⅡABCⅢABCD type, consisting of molecular water absorption (the ⅠAB -type), the tectonic stress type + gravity deformation type + hydraulic type (the ⅡABC -type), and the ⅢABCD -type with fault, weak intercalation and bedding formation. According to the compound mechanical deformation mechanisms, the corresponding mechanical control measures and conversion technologies were proposed, and these technologies have been successfully applied in roadway supporting practice in deep soft rock at Xing'an Coal Mine with good effect. Xing'an Coal Mine has the deepest burial depth in China, with its overburden ranging from Mesozoic Jurassic coal-forming to now. The results of the research can be used as guidance in the design of roadway support in soft rock.
基金the Research Institute of Petroleum Industry (RIPI),Tehran,for sponsorship
文摘The late Jurassic Arab Formation, a significant carbonate-evaporite reservoir rock in the Persian Gulf, is characterized by frequent grainstone facies. For rock type identification and reservoir characterization, core description, petrographic studies and pore system evaluation are integrated for Balal oil field in the Persian Gulf. The grainstone facies are developed into three shoal subenvironments on a carbonate ramp platform： leeward, central and seaward. Compaction, dissolution, cementation, anhydrite mineralization and dolomitization are the main diagenetic processes affecting the depositional pore system. Considering depositional and diagenetic features and pore types, the grainstones are classified into six rock types （RT 1 to RT6）. Rock types 1, 2 and 5 have large pore throat sizes with inter- granular and touching vug pore types. In rock type 3, moldic pores lead to high porosity and low permeability. Rock types 4 and 6 are cemented by anhydrite, calcite and dolomite. Generally, RTs 1, 2, 3 and 5 are related to late Transgressive systems tract （TST） and early Highstand systems tracts （HST） and show fair to good reservoir quality. In contrast, RTs 4 and 6 of late HST system tract show lower poroperm values, due to evaporite mineralization. Characterization of the grainstone facies provides a comprehensive understanding of the reservoir zones of the Arab Formation.
基金supported by the Hong Kong GRF RGC project 15217222:“Modernization of the leveling network in the Hong Kong territories.”。
文摘We used the geological map and published rock density measurements to compile the digital rock density model for the Hong Kong territories.We then estimated the average density for the whole territory.According to our result,the rock density values in Hong Kong vary from 2101 to 2681 kg·m^(-3).These density values are typically smaller than the average density of 2670 kg·m^(-3),often adopted to represent the average density of the upper continental crust in physical geodesy and gravimetric geophysics applications.This finding reflects that the geological configuration in Hong Kong is mainly formed by light volcanic formations and lava flows with overlying sedimentary deposits at many locations,while the percentage of heavier metamorphic rocks is very low(less than 1%).This product will improve the accuracy of a detailed geoid model and orthometric heights.
基金financially supported jointly by the National Natural Science Foundation of China (No. 40902026 No 41272097)+4 种基金the State Key Laboratory of Geological Processes and Mineral Resources (No. GPMR 201006)the Special Fund for Basic Scientific Research of Central Colleges China University of Geosciences (Wuhan) (No. CUG120702)the Shewushan Gold Mine Co. Ltd and No. 4 Geological PartyHubei Bureau of Geology and Mineral Resources for the field support
文摘The Shewushan gold deposit is located 16 km southwest of Jiayu County, Hubei Province, eastern China, which is the largest lateritic gold deposit in Asia, consisting of a series of mineralized faults containing gold grades of 1.0–19.5 g/t set within a larger, lower-grade(0.2–1.0 g/t) zone. According to the fluid inclusions study, the homogenization temperature ranges from 70–350℃, and concentrates between 140–220℃. The laser Rama results show that the CO2 and CH4 exist in mineralized fluid. In addition, the major and trace element and REE geochemical data show that the genesis of the siliceous rocks is hydrothermal genesis, formed by mineralized fluid bearing SiO2 transmitted along faults to the surface, and replace the carbonate rocks to begin deposition. Primary gold mineralization is attributed to hydrothermal activity that followed the main period of tectonic deformation of the Indosinian orogeny, which caused the regional detachment regime in southeast Hubei. The reversed fold and the fault system formed the fluid migration channel in the Shewushan area. EPMA results show that Au exists in arsenopyrite(850×10-6–1550×10-6 Au) and pyrite(470×10-6–1340×10-6 Au). Therefore, based on the above results and combined with the field observation, we suggest that the genesis of primary orebody in Shewushan deposit is carlin type, while not weathered residual type.
文摘Terrestrial faulted lacustrine basin is considered as a favorable place for the development of source rocks,especially the fault basins in eastern China.Based on molecular composition study of saturated and aromatic hydrocarbons in the extracts of source rocks of the Yingcheng and Shahezi formations in the Lishu Fault Depression,it is revealed that the extracts of source rocks are provided with low ratio of Pr/Ph,low content of C24 tetracyclic terpanes,high content of tricyclic terpanes and gammacerane,relatively high content of C27 steranes in the sag belt and its periphery;relatively high ratio of Pr/Ph,relatively high content of tetracyclic terpanes and gammacerane,low content of C27 steranes and obvious advantages of C29 steranes in its gentle slope belt;with high ratio of Pr/Ph,high content of C19,C20 tricyclic and C24 tetracyclic terpanes,very low content of gammacerane and C27 steranes,and high content of C29 steranes in the edge of fault depression.According to the organic matter input and sedimentary environment,three types of source rocks have been established,which,respectively,are the mode of mixing organic matter input in deep and semi-deep lake,the advantage of terrigenous input in shallow lake and terrigenous input in shore-shallow lacustrine.The first mode is supposed to generate oil and gas,while the second one tends to generate oil.The distribution characteristics of oil and gas in the Lishu Fault Depression are very likely to be controlled by hydrocarbon generating characteristic of different source rock types.
文摘The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrating there is a great potential for natural gas exploration in oil-type basins.The ethane isotope of the Bozhong 19-6 condensate gas is heavy,showing the characteristics of partial humic gas.In this paper,aimed at the source rocks of the Bozhong 19-6 gas field in the Bohai Bay Basin,the characteristics of the source rocks in the Bozhong 19-6 structural belt were clarified and the reason are explained from impact of microorganism degradation on hydrocarbon generation of source rocks why the condensate oil and gas had heavy carbon isotope and why it showed partial humic characteristics was explored based on the research of parent materials.The following conclusions were obtained:The paleontology of the Bozhong 19-6 structural belt and its surrounding sub-sags is dominated by higher plants,such as angiosperm and gymnosperm.During the formation of source rocks,under the intensive transformation of microorganism,the original sedimentary organic matter such as higher plants was degraded and transformed by defunctionalization.Especially,the transformation of anaerobic microorganisms on source rocks causes the degradation and defunctionalization of a large number of humic products such as higher plants and the increase of hydrogen content.The degradation and transformation of microorganism don't transform the terrestrial humic organic matter into newly formed“sapropel”hydrocarbons,the source rocks are mixed partial humic source rocks.As a result,hydrogen content incrased and the quality of source rocks was improved,forming the partial humic source rocks dominated by humic amorphous bodies.The partial humic source rocks are the main source rocks in the Bozhong 19-6 gas field,and it is also the internal reason why the isotope of natural gas is heavy.
