Sediment is recognized as the largest reservoir and source of methane(CH_(4))in the ocean,especially in the shallow coastal areas.To date,few data of CH_(4)concentration in sediment have been reported in the China she...Sediment is recognized as the largest reservoir and source of methane(CH_(4))in the ocean,especially in the shallow coastal areas.To date,few data of CH_(4)concentration in sediment have been reported in the China shelf seas.In this study,we measured CH_(4)concentration in sediment and overlying seawater columns,and conducted an incubation experiment in the Bohai Sea in May 2017.CH_(4)concentration was found to be ranged from 3.075 to 1.795μmol/L in sediment,which was 2 to 3 orders of magnitude higher than that in overlying seawater columns.The surface sediment was an important source of CH_(4),while bottom seawater acted as its sink.Furthermore,the net emission rate via sediment water interface(SWI)was calculated as 2.45μmol/(m^(2)·day)based on the incubation experiment at station73,and the earthquake may enhance CH_(4)release from sediment to seawater column in the eastern Bohai Sea.展开更多
Although to date some technologies producing bio-based phosphorus(P) fertilizers have been proposed and implemented, the efficient use of the recovered products is still limited due to legislative constraints and lack...Although to date some technologies producing bio-based phosphorus(P) fertilizers have been proposed and implemented, the efficient use of the recovered products is still limited due to legislative constraints and lack of insights in the P release with time and in the corresponding mechanisms. The aim of this work was to evaluate the fertilizer performance in terms of P release and use efficiency of recovered struvite, FePO_4-sludge, digestate, and animal manure as compared to fossil reserve-based mineral triple superphosphate(TSP). First, product physicochemical characteristics and P fractions in the context of European fertilizer legislation were assessed. Next, a controlled greenhouse experiment was set up to evaluate plant reactions as well as changes of P availability in a sandy soil with high P status and a Rheinsand soil with low P status. Soil P fractions were determined in the extracts with water, ammonium lactate and CaCl_2, and in soil solution sampled with Rhizon soil moisture samplers. Based on all results, it is worth conducting long-term field trials to evaluate the P release effect of struvite and digestate as compared to animal manure and TSP on different soil types with varying P status. These products showed promise as sustainable substitutes for conventional P fertilizers and could contribute to a more efficient use of P in agriculture. A refined classification of P application standards/recommendations in terms of soil P status, soil texture, and fertilizer characteristics, next to the crop P demand, is recommended. Moreover, the additional use of Rhizon samplers for determination of direct available P, including dissolved organic P, is proposed for better understanding and categorization of different P fertilizers in environmental and fertilizer legislations.展开更多
基金supported by the National Key Research and Development Program of China(No.2020YFA0607500)the National Natural Science Foundation of China(Nos.41775127 and 42075112)+3 种基金Key Laboratory of Global Change and Marine Atmospheric Chemistry,Ministry of Natural Resources(No.GCMAC2001)the Basic Research Fund of Chinese Academy of Meteorological Sciences(No.2020Z002)Key Laboratory of Atmospheric Chemistry,China Meteorological Administration(No.2019B07)Key Laboratory on Marine Hazards Forcasting,Ministry of Natural Resources(No.LOMF1803)
文摘Sediment is recognized as the largest reservoir and source of methane(CH_(4))in the ocean,especially in the shallow coastal areas.To date,few data of CH_(4)concentration in sediment have been reported in the China shelf seas.In this study,we measured CH_(4)concentration in sediment and overlying seawater columns,and conducted an incubation experiment in the Bohai Sea in May 2017.CH_(4)concentration was found to be ranged from 3.075 to 1.795μmol/L in sediment,which was 2 to 3 orders of magnitude higher than that in overlying seawater columns.The surface sediment was an important source of CH_(4),while bottom seawater acted as its sink.Furthermore,the net emission rate via sediment water interface(SWI)was calculated as 2.45μmol/(m^(2)·day)based on the incubation experiment at station73,and the earthquake may enhance CH_(4)release from sediment to seawater column in the eastern Bohai Sea.
基金supported by the European Commission under the Interreg IVb NWE Project Arbor(No.Interreg IVB 223G)the Environmental&Energy Technology Innovation Platform(MIP),Belgium+2 种基金the Natural Science and Engineering Research Council of Canada(NSERC)the Fonds de Recherche de Québec sur la Nature et les Technologies(FRQNT),CanadaPrimodal Inc.,Hamilton,Canada
文摘Although to date some technologies producing bio-based phosphorus(P) fertilizers have been proposed and implemented, the efficient use of the recovered products is still limited due to legislative constraints and lack of insights in the P release with time and in the corresponding mechanisms. The aim of this work was to evaluate the fertilizer performance in terms of P release and use efficiency of recovered struvite, FePO_4-sludge, digestate, and animal manure as compared to fossil reserve-based mineral triple superphosphate(TSP). First, product physicochemical characteristics and P fractions in the context of European fertilizer legislation were assessed. Next, a controlled greenhouse experiment was set up to evaluate plant reactions as well as changes of P availability in a sandy soil with high P status and a Rheinsand soil with low P status. Soil P fractions were determined in the extracts with water, ammonium lactate and CaCl_2, and in soil solution sampled with Rhizon soil moisture samplers. Based on all results, it is worth conducting long-term field trials to evaluate the P release effect of struvite and digestate as compared to animal manure and TSP on different soil types with varying P status. These products showed promise as sustainable substitutes for conventional P fertilizers and could contribute to a more efficient use of P in agriculture. A refined classification of P application standards/recommendations in terms of soil P status, soil texture, and fertilizer characteristics, next to the crop P demand, is recommended. Moreover, the additional use of Rhizon samplers for determination of direct available P, including dissolved organic P, is proposed for better understanding and categorization of different P fertilizers in environmental and fertilizer legislations.
