The solubilities of the quinary system Na^＋ ,K^＋ ,Mg^2＋ //Cl ,NO 3 ^-H2O and its two quaternary subsystems, Na^＋ ,K^＋ ,Mg^2＋ //NO 3 -H2O and K^ ＋ ,Mg ^2＋ //Cl ,NO 3 ^-H2O,were studied by isothermal method at 2...The solubilities of the quinary system Na^＋ ,K^＋ ,Mg^2＋ //Cl ,NO 3 ^-H2O and its two quaternary subsystems, Na^＋ ,K^＋ ,Mg^2＋ //NO 3 -H2O and K^ ＋ ,Mg ^2＋ //Cl ,NO 3 ^-H2O,were studied by isothermal method at 25°C and their phase diagrams were plotted.In the equilibrium phase diagram of quaternary system Na^ ＋ ,K^ ＋ ,Mg ^2＋ //NO 3 ^-H2O, there are one invariant point,three univariant curves and three regions of crystallization with one salt：NaNO3, KNO3 and Mg（NO3）2·6H2O.In the equilibrium phase diagram of quaternary system K ^＋ ,Mg ^2＋ //Cl ,NO 3 ^-H2O,there are three invariant points,seven univariant curves and five regions of crystallization with one salt：KNO3,KCl, Mg（NO3）2·6H2O,MgCl2·6H2O and KCl·MgCl2·6H2O.In the equilibrium phase diagram of the quinary system Na ^＋ , K^ ＋ ,Mg ^2＋ //Cl ,NO 3^ -H2O,there are four invariant points,and seven regions of crystallization with one salt：NaCl, KCl,NaNO3,KCl·MgCl2·6H2O,KNO3,MgCl2·6H2O and Mg（NO3）2·6H2O.展开更多
In this paper, we construct some continuous but non-differentiable functions defined by quinary dec-imal, that are Kiesswetter-like functions. We discuss their properties, then investigate the Hausdorff dimensions of ...In this paper, we construct some continuous but non-differentiable functions defined by quinary dec-imal, that are Kiesswetter-like functions. We discuss their properties, then investigate the Hausdorff dimensions of graphs of these functions and give a detailed proof.展开更多
Two quinary high-entropy alloys （HEAs） with equiatomic concentrations formed by doping either Cu or A1 elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques. Their entr...Two quinary high-entropy alloys （HEAs） with equiatomic concentrations formed by doping either Cu or A1 elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques. Their entropy of fusion, thermal expansion coefficient and thermal diffusivity are experimentally investigated with differential scanning cMorimetry, dilatometry and laser flash methods. The NiFeCoCrCu HEAs contain a face- centered cubic high-entropy phase plus a minor interdendritic （Cu） phase and display a lower entropy of fasion and the Vickers hardness. The NiFeCoCrAl HEAs consist of two body-centered cubie high-entropy phases with coarse dendritic structures and show higher entropy of fusion and the Vickers hardness. Both the thermal expansion coefficient and the thermal diffusivity of the former Cu-doped alloy are signitieantly larger than those of the latter At-doped M1oy. Although the temperature dependence of thermal diffusivity is similar for both HEAs, it is peculiar that the thermal expansion curve of the NiFeCoCrAl alloy exhibits an inflexion at temperatures of 860-912 K.展开更多
Nuclear magnetic resonance(NMR)serves as a powerful tool for studying both the structure and dynamics of proteins.The NOE method,alongside residual dipolar;coupling,paramagnetic effects,J-coupling,and other related te...Nuclear magnetic resonance(NMR)serves as a powerful tool for studying both the structure and dynamics of proteins.The NOE method,alongside residual dipolar;coupling,paramagnetic effects,J-coupling,and other related techniques,has reached a level of maturity that allows for the determination of protein structures.Furthermore,NMR relaxation methods prove to be highly effective in characterizing protein dynamics across various timescales.The properties of protein systems are dictated by intra-and intermo-lecular interactions among atoms,which involve covalent bonds,hydrogen bonds(H-bonds),electrostatic interactions,and van der Waals forces.Multiple NMR approaches have been developed to measure noncovalent interactions,and this paper offers a concise overview of noncovalent interaction measurements using NMR,with a specific emphasis on the advancements accomplished in our laboratory.展开更多
基金Supported by the National Natural Science Foundation of China（20466003 20866008）
文摘The solubilities of the quinary system Na^＋ ,K^＋ ,Mg^2＋ //Cl ,NO 3 ^-H2O and its two quaternary subsystems, Na^＋ ,K^＋ ,Mg^2＋ //NO 3 -H2O and K^ ＋ ,Mg ^2＋ //Cl ,NO 3 ^-H2O,were studied by isothermal method at 25°C and their phase diagrams were plotted.In the equilibrium phase diagram of quaternary system Na^ ＋ ,K^ ＋ ,Mg ^2＋ //NO 3 ^-H2O, there are one invariant point,three univariant curves and three regions of crystallization with one salt：NaNO3, KNO3 and Mg（NO3）2·6H2O.In the equilibrium phase diagram of quaternary system K ^＋ ,Mg ^2＋ //Cl ,NO 3 ^-H2O,there are three invariant points,seven univariant curves and five regions of crystallization with one salt：KNO3,KCl, Mg（NO3）2·6H2O,MgCl2·6H2O and KCl·MgCl2·6H2O.In the equilibrium phase diagram of the quinary system Na ^＋ , K^ ＋ ,Mg ^2＋ //Cl ,NO 3^ -H2O,there are four invariant points,and seven regions of crystallization with one salt：NaCl, KCl,NaNO3,KCl·MgCl2·6H2O,KNO3,MgCl2·6H2O and Mg（NO3）2·6H2O.
文摘In this paper, we construct some continuous but non-differentiable functions defined by quinary dec-imal, that are Kiesswetter-like functions. We discuss their properties, then investigate the Hausdorff dimensions of graphs of these functions and give a detailed proof.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51571163,51371150,51271150 and 51327901
文摘Two quinary high-entropy alloys （HEAs） with equiatomic concentrations formed by doping either Cu or A1 elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques. Their entropy of fusion, thermal expansion coefficient and thermal diffusivity are experimentally investigated with differential scanning cMorimetry, dilatometry and laser flash methods. The NiFeCoCrCu HEAs contain a face- centered cubic high-entropy phase plus a minor interdendritic （Cu） phase and display a lower entropy of fasion and the Vickers hardness. The NiFeCoCrAl HEAs consist of two body-centered cubie high-entropy phases with coarse dendritic structures and show higher entropy of fusion and the Vickers hardness. Both the thermal expansion coefficient and the thermal diffusivity of the former Cu-doped alloy are signitieantly larger than those of the latter At-doped M1oy. Although the temperature dependence of thermal diffusivity is similar for both HEAs, it is peculiar that the thermal expansion curve of the NiFeCoCrAl alloy exhibits an inflexion at temperatures of 860-912 K.
文摘Nuclear magnetic resonance(NMR)serves as a powerful tool for studying both the structure and dynamics of proteins.The NOE method,alongside residual dipolar;coupling,paramagnetic effects,J-coupling,and other related techniques,has reached a level of maturity that allows for the determination of protein structures.Furthermore,NMR relaxation methods prove to be highly effective in characterizing protein dynamics across various timescales.The properties of protein systems are dictated by intra-and intermo-lecular interactions among atoms,which involve covalent bonds,hydrogen bonds(H-bonds),electrostatic interactions,and van der Waals forces.Multiple NMR approaches have been developed to measure noncovalent interactions,and this paper offers a concise overview of noncovalent interaction measurements using NMR,with a specific emphasis on the advancements accomplished in our laboratory.
