Medium-entropy state quinary keplerate clusters as a remarkable electrocatalyst for small molecule electrooxidation
摘要
The synthesis of discrete polyoxometalate clusters composed of more than 3 metallic elements has always been attractive but seldom successful.For the first time,we have developed a de novo synthetic route to quinary Cu-Ni-Co-Mn-Zn Keplerate clusters with a nuclearity of 20.Seven single-crystalline quinary Keplerates in a medium-entropy state with various compositions have been obtained.
基金
supported by the National Natural Science Foundation of China(Grant No.21301057 and 22075073)
Fundamental Research Funds for the Central Universities(531107051077).
