Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendli...Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendliness.In this paper,we reported the dopant compensation effect in the component-dependent self-doped(111)-oriented Cs_(2)SnI_(6)thin films grown with pulsed laser deposition(PLD)at room temperature.The films were grown on(100)-SrTiO_(3)(STO)substrates at room temperature by PLD.Hall results of the Cs_(2)SnI_(6)films with different components realizing by controlling the ratio of SnI_(4)/CsI in the targets demonstrate a clear change of conductivity type from N-type to P-type,while the carrier concentration decreases from 1018 to 1013 and accordingly the film resistivity increases significantly from 3.8 to 2506Ωcm.The defect-relatedopticalfingerprints of Cs_(2)SnI_(6)films werealsoinvestigated withtemperature-dependent photoluminescence spectroscopy.At low temperatures of 10 K,the Cs_(2)SnI_(6)films exhibit donor-bound(D^(0)X)and donor-acceptor pair(DAP)emission,respectively,due to the self-doping effect.These re-sults indicate that controlling the composition of the PLD target is a powerful way to tune the electrical properties of Cs_(2)SnI_(6)films for possible applications in solar cells or X-ray detectors.展开更多
The wide band gap characteristics of gallium oxide make it very suitable for the preparation of solar-blind ultra-violet photodetectors.The responsivity of ultraviolet photodetectors based on thin films is often low.H...The wide band gap characteristics of gallium oxide make it very suitable for the preparation of solar-blind ultra-violet photodetectors.The responsivity of ultraviolet photodetectors based on thin films is often low.However,nanomaterials have excellent photoelectric properties in device applications due to the high stability brought by high specific surface area and high crystal quality.Here,we successfully depositedβ-Ga_(2)O_(3) nanopores on the double-pass ordered porous AAO tem-plate by PLD.The porous AAO template is used as the growth space of nanomaterials,and the gallium oxide material is filled into the pores of the template to form a nanotube structure.By optimizing the preparation process,the relationship be-tween the performance of gallium oxide nanopores and the growth time was studied in depth.With the increase of growth time,the responsivity of the detector was improved.The rise timeτr=0.7 s,the decay timeτ_(d)=1.3 s,and the responsivity reached 4.63 mA·W^(-1),which was higher than 2.24 mA·W^(-1)of the responsivity of silicon-based gallium oxide nanorods.展开更多
2025年9月10日,浙江大学良渚实验室、东部战区总医院国家肾脏疾病临床医学研究中心刘志红教授、俞晓敏研究员、周青教授团队在《自然》(Nature)杂志发表了题为“Loss-of-function mutations in PLD4 lead to systemic lupus erythemato...2025年9月10日,浙江大学良渚实验室、东部战区总医院国家肾脏疾病临床医学研究中心刘志红教授、俞晓敏研究员、周青教授团队在《自然》(Nature)杂志发表了题为“Loss-of-function mutations in PLD4 lead to systemic lupus erythematosus”论文(DOI:10.1038/s41586-025-09513-x),证实人类PLD4缺陷可导致系统性红斑狼疮(SLE)并阐明了其致病机制,为SLE的精准诊疗提供了重要的理论依据。展开更多
The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD ...The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD properties, searching for patterns that might reveal periodic characteristics of the planet's climate history. Although much progress has been made in our understanding of orbital periodicities reflected in the PLD, questions remain regarding how Martian orbital changes have affected the formation of the PLD and regarding the extent of climate information that is recorded in the PLD. Future studies of PLD should be carried out via integrated research that targets multi-profiles throughout the entire Martian polar regions that would clarify their general features at the hemisphere scale. Numerical modeling, coupled with modern observations of dust and water vapor transportation, should greatly advance our understanding of planetary climate evolution. Furthermore, future landing missions may help to clarify the paleoclimatic characteristics reflected in the PLD by drilling into these layered deposits and measuring mineralogical and geochemical compositions of the drilled samples.展开更多
基金financially supported by the National Key Re-search and Development Program of China(No.2022YFC3700801)the Key R&D Program of Shandong Province,China(No.2024SFGC0102),the Jinan Bureau of Education(No.JNSX2023015)the Jinan Bureau of Science and Technology(No.202333042).
文摘Tetravalent tin(Sn^(4+))-based inorganic perovskite semiconductors like Cs_(2)SnI_(6)are expected to replace lead-based perovskite counterparts due to advantages such as structural stability and environmental friendliness.In this paper,we reported the dopant compensation effect in the component-dependent self-doped(111)-oriented Cs_(2)SnI_(6)thin films grown with pulsed laser deposition(PLD)at room temperature.The films were grown on(100)-SrTiO_(3)(STO)substrates at room temperature by PLD.Hall results of the Cs_(2)SnI_(6)films with different components realizing by controlling the ratio of SnI_(4)/CsI in the targets demonstrate a clear change of conductivity type from N-type to P-type,while the carrier concentration decreases from 1018 to 1013 and accordingly the film resistivity increases significantly from 3.8 to 2506Ωcm.The defect-relatedopticalfingerprints of Cs_(2)SnI_(6)films werealsoinvestigated withtemperature-dependent photoluminescence spectroscopy.At low temperatures of 10 K,the Cs_(2)SnI_(6)films exhibit donor-bound(D^(0)X)and donor-acceptor pair(DAP)emission,respectively,due to the self-doping effect.These re-sults indicate that controlling the composition of the PLD target is a powerful way to tune the electrical properties of Cs_(2)SnI_(6)films for possible applications in solar cells or X-ray detectors.
文摘The wide band gap characteristics of gallium oxide make it very suitable for the preparation of solar-blind ultra-violet photodetectors.The responsivity of ultraviolet photodetectors based on thin films is often low.However,nanomaterials have excellent photoelectric properties in device applications due to the high stability brought by high specific surface area and high crystal quality.Here,we successfully depositedβ-Ga_(2)O_(3) nanopores on the double-pass ordered porous AAO tem-plate by PLD.The porous AAO template is used as the growth space of nanomaterials,and the gallium oxide material is filled into the pores of the template to form a nanotube structure.By optimizing the preparation process,the relationship be-tween the performance of gallium oxide nanopores and the growth time was studied in depth.With the increase of growth time,the responsivity of the detector was improved.The rise timeτr=0.7 s,the decay timeτ_(d)=1.3 s,and the responsivity reached 4.63 mA·W^(-1),which was higher than 2.24 mA·W^(-1)of the responsivity of silicon-based gallium oxide nanorods.
文摘2025年9月10日,浙江大学良渚实验室、东部战区总医院国家肾脏疾病临床医学研究中心刘志红教授、俞晓敏研究员、周青教授团队在《自然》(Nature)杂志发表了题为“Loss-of-function mutations in PLD4 lead to systemic lupus erythematosus”论文(DOI:10.1038/s41586-025-09513-x),证实人类PLD4缺陷可导致系统性红斑狼疮(SLE)并阐明了其致病机制,为SLE的精准诊疗提供了重要的理论依据。
基金supported financially by the Key Research Program of the Institute of Geology and Geophysics, CAS (Grant No. IGGCAS-202102 and IGGCAS-201905)。
文摘The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD properties, searching for patterns that might reveal periodic characteristics of the planet's climate history. Although much progress has been made in our understanding of orbital periodicities reflected in the PLD, questions remain regarding how Martian orbital changes have affected the formation of the PLD and regarding the extent of climate information that is recorded in the PLD. Future studies of PLD should be carried out via integrated research that targets multi-profiles throughout the entire Martian polar regions that would clarify their general features at the hemisphere scale. Numerical modeling, coupled with modern observations of dust and water vapor transportation, should greatly advance our understanding of planetary climate evolution. Furthermore, future landing missions may help to clarify the paleoclimatic characteristics reflected in the PLD by drilling into these layered deposits and measuring mineralogical and geochemical compositions of the drilled samples.
