Software application is still a heavy dependence for most of the business operation today.Whenever software application encounters error that causes downtime in the production environment,the root cause of the error c...Software application is still a heavy dependence for most of the business operation today.Whenever software application encounters error that causes downtime in the production environment,the root cause of the error can be either within the software application layer or any other factor outside the software application layer.To accurately identify the root cause is difficult whenever more than one log file is required for the root cause analysis activity.Due to such complexity,it leads to the entire duration on the root cause analysis activity became prolong.This will increase the total time taken on restoring the software application service back to the users.In order to identify the root cause of software application error in a more accurate manner,and shorten the duration of root cause analysis activity conducting on software application error,a Prescriptive Analytical Logic Model incorporates with Analytic Hierarchy Process(AHP)is proposed.The proposed Logic Model along with the algorithm will contribute a new knowledge in the area of log file analysis to shorten the total time spent on root cause analysis activity.展开更多
Treating plant dynamics as an ideal integrator chain disturbed by the total disturbance is the hallmark of active disturbance rejection control(ADRC).To interpret its effectiveness and success,to explain why so many v...Treating plant dynamics as an ideal integrator chain disturbed by the total disturbance is the hallmark of active disturbance rejection control(ADRC).To interpret its effectiveness and success,to explain why so many vastly different dynamic systems can be treated in this manner,and to answer why a detailed,accurate,and global mathematical model is unnecessary,is the target of this paper.Driven by a motivating example,the notions of normality and locality are introduced.Normality shows that,in ADRC,the plant is normalized to an integrator chain,which is called local nominal model and locally describes the plant’s frequency response in the neighborhood of the expected gain crossover frequency.Locality interprets why ADRC can design the controller only with the local information of the plant.With normality and locality,ADRC can be effective and robust,and obtain operational stability discussed by T.S.Tsien.Then viewing proportional-integral-derivative(PID)control as a low-frequency approximation of second-order linear ADRC,the above results are extended to PID control.A controller design framework is proposed to obtain the controller in three steps:(1)choose an integrator chain as the local nominal model of the plant;(2)select a controller family corresponding to the local nominal model;and(3)tune the controller to guarantee the gain crossover frequency specification.The second-order linear ADRC and the PID control are two special cases of the framework.展开更多
The use of additive is an effective approach to optimize the active layer morphology and improve the power conversion efficiency(PCE)of organic solar cells(OSCs).However,residual solvent additives always lead to undes...The use of additive is an effective approach to optimize the active layer morphology and improve the power conversion efficiency(PCE)of organic solar cells(OSCs).However,residual solvent additives always lead to undesirably compromise the stability of OSCs.In this work,an organic small molecule BBT-Cl was designed and used as a novel solid additive to partly replace solvent additive to fabricate highperformance OSCs.The synergistic effect of the dual additives on the optical property,morphology and photovoltaic characteristics of the PM6:Y6 based non-fullerene OSCs have been systematically characterized.The introduction of BBT-Cl could effectively enhance the crystallinity of the blend and promote charge extraction and transport.Consequently,the OSCs processed by the dual additives exhibit a high PCE of 17.73%,which is obviously higher than OSCs with CN additive(16.48%).Meanwhile,BBT-Cl based dual additives treatment has also been successfully introduced into another two non-fullerene OSCs to verify its general applicability.Furthermore,20%PCE aging is significantly prolonged from 720 min to 2880 min for the devices proceeded with the dual additives.This work highlights the great potential of solid additive in the fabrication of efficient OSCs with excellent stability.展开更多
Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and t...Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of PSCs.In this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting material.The GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.展开更多
The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium he...The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium hexafluorophosphate)(PTA),and introduce it into the buried interface of PSCs.The quaternary ammonium cation(N(-CH_(3))^(3+))in PTA can fill the vacancies of organic cations within the perovskite structure and reduce shallow energy level defects.Additionally,the hexafluorophosphate(PF6−)in PTA forms a Lewis acid-base interaction with Pb^(2+)in the perovskite layer,effectively passivating deep en-ergy level defects.Furthermore,hydrogen bonding can be established between organic cations and the PF6−anion,preventing the formation of shallow energy level defects.Through this synergistic mecha-nism,the deep and shallow energy level defects are effectively mitigated,resulting in improved device performance.As a result,the resulting treated inverted PSC exhibits an impressive power conversion ef-ficiency(PCE)of 24.72%.Notably,the PTA-treated PSCs exhibit remarkable stability,with 88.5%of the original PCE retained after undergoing heat aging at 85℃ for 1078 h,and 89.1%of the initial PCE main-tained following continuous exposure to light for 1100 h at the maximum power point.Synergistically suppressing multiple defects at the buried interface through the use of polyionic liquids is a promising way to improve the commercial viability of PSCs.展开更多
The past two years have witnessed remarkable progress in perovskite solar cells(PSCs),marked by breakthroughs in power conversion efficiency and strides in addressing long-term operational stability.At present,the cer...The past two years have witnessed remarkable progress in perovskite solar cells(PSCs),marked by breakthroughs in power conversion efficiency and strides in addressing long-term operational stability.At present,the certified power conversion efficiencies of singlejunction PSCs and silicon/perovskite tandem cells have surpassed 27%and 34%,respectively.Regarding stability,researchers begun to focus their attention on the challenges faced by PSCs when operated in outdoor environments.Furthermore,breakthroughs in the utilization of green solvents,fabrication in ambient air conditions,aqueous-phase synthesis of perovskite raw materials at kilogram scale,vacuum flash evaporation,and machine learning-assisted design are accelerating the commercialization of PSCs.The review summarizes the key advancements of PSCs during 2024-2025.It identifies a critical performance discrepancy between small-area devices and perovskite solar modules and delves into strategies aimed at bridging this gap.Finally,perspectives on the future directions of PSCs are presented,with a particular emphasis on improving photocurrent and environmental sustainability.展开更多
The hygroscopic nature and severe ions diffusion of conventional dopant Li-TFSI,along with interfacial ionic defects,limiting the efficiency and stability of n-i-p perovskite solar cells(PSCs).To address this,we propo...The hygroscopic nature and severe ions diffusion of conventional dopant Li-TFSI,along with interfacial ionic defects,limiting the efficiency and stability of n-i-p perovskite solar cells(PSCs).To address this,we propose a single-dopant strategy employing a multifunctional,star-shaped dopant 2,4,6-tris(3,4,5-tri fluorophenyl)boroxine(TBRX)with a Lewis acidic boroxine core and highly electronegative fluorinated aryl groups,incorporated into Spiro-OMeTAD.Theoretical and experimental results indicate that TBRX significantly enhances hole mobility,conductivity and the flatness of hole-transporting layer(HTL)while passivating interfacial defects(Pb^(2+),V_(I)),leading to a reinforced perovskite/HTL interface.Additionally,the corresponding p-dopant effectively reduces the energy barrier between the perovskite and the HTL,promoting efficient hole extraction.Consequently,Spiro-OMeTAD:TBRX-based devices deliver a high PCE of25.57%(certified at 25.01%)with excellent long-term operational stability obtained for over 1000 h,retaining~94%of its initial efficiency after 1000 h according to ISOS-L-2 protocols,highlighting the significance of utilizing multifunctional single-dopant framework.展开更多
While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor ...While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.展开更多
It is of vital importance to improve the long-term and photostability of organic photovoltaics,including organic solar cells(OSCs)and organic photodetectors(OPDs),for their ultimate industrialization.Herein,two series...It is of vital importance to improve the long-term and photostability of organic photovoltaics,including organic solar cells(OSCs)and organic photodetectors(OPDs),for their ultimate industrialization.Herein,two series of terpolymers featuring with an antioxidant butylated hydroxytoluene(BHT)-terminated side chain,PTzBI-EHp-BTBHTx and N2200-BTBHTx(x=0.05,0.1,0.2),are designed and synthesized.It was found that incorporating appropriate ratio of benzothiadiazole(BT)with BHT side chains on the conjugated backbone would induce negligible effect on the molecular weight,absorption spectra and energy levels of polymers,however,which would obviously enhance the photostability of these polymers.Consequently,all-polymer solar cells(all-PSCs)and photodetectors were fabricated,and the all-PSC based on PTzBI-EHp-BTBHT0.05:N2200 realized an optimal power conversion efficiency(PCE)approaching~10%,outperforming the device based on pristine PTzBI-EHp:N2200.Impressively,the all-PSCs based on BHT-featuring terpolymers displayed alleviated PCEs degradation under continuous irradiation for 300 h due to the improved morphological and photostability of active layers.The OPDs based on BHT-featuring terpolymers achieved a lower dark current at−0.1 bias,which could be stabilized even after irradiation over 400 h.This study provides a feasible approach to develop terpolymers with antioxidant efficacy for improving the lifetime of OSCs and OPDs.展开更多
Jacket cutting operation is one of the most complicated and highest risk operations in the process of decommissioning offshore piled platform, the security and stability of which must be assured. In this paper, the cu...Jacket cutting operation is one of the most complicated and highest risk operations in the process of decommissioning offshore piled platform, the security and stability of which must be assured. In this paper, the current research on offshore structure removal and jacket cutting is introduced, on the basis of which the types of load along with the load calculation method are determined. The main influences on the stability of a jacket in cutting are analyzed. The experiment test plan is drawn by using orthogonal testing method, and the formula of critical load during the cutting procedure is deduced by differential evolution algorithm. To verify the method and results of this paper, an offshore piled platform to be decommissioned in the South China Sea is taken for an example, and the detailed schedule for jacket cutting is made with the three-dimensional finite element model of the jacket established. The natural frequency, stress, strain and stability of the jacket during cutting process are calculated, which indicates that the results of finite element analysis agree well with that of the deduced formula. The result provides the scientific reference for guaranteeing the safety of jacket in cutting operation.展开更多
With the exponential growth of the internet of things,artificial intelligence,and energy-efficient high-volume data digital communications,there is an urgent demand to develop new information technologies with high st...With the exponential growth of the internet of things,artificial intelligence,and energy-efficient high-volume data digital communications,there is an urgent demand to develop new information technologies with high storage capacity.This needs to address the looming challenge of conventional Von Neumann architecture and Moore's law bottleneck for future data-intensive computing applications.A promising remedy lies in memristors,which offer distinct advantages of scalability,rapid access times,stable data retention,low power consumption,multistate storage capability and fast operation.Among the various materials used for active layers in memristors,low dimensional perovskite semiconductors with structural diversity and superior stability exhibit great potential for next generation memristor applications,leveraging hysteresis characteristics caused by ion migration and defects.In this review the progress of low-dimensional perovskite memory devices is comprehensively summarized.The working mechanism and fundamental processes,including ion migration dynamics,charge carrier transport and electronic resistance that underlies the switching behavior of memristors are discussed.Additionally,the device parameters are analyzed with special focus on the effective methods to improve electrical performance and operational stability.Finally,the challenges and perspective on major hurdles of low-dimensional perovskite memristors in the expansive application domains are provided.展开更多
A promising way to realize controlled nuclear fusion involves the use of magnetic fields to control and confine the hot plasma configuration.This approach requires superconductor magnets operating above 15 T for the n...A promising way to realize controlled nuclear fusion involves the use of magnetic fields to control and confine the hot plasma configuration.This approach requires superconductor magnets operating above 15 T for the next generation of fusion devices.Due to their high in-field transport current capacity,rare-Earth barium copper oxide(REBCO)coated conductors are promising materials for manufacturing of cable-in-conduit conductors(CICCs)for fusion.However,the high-aspect-ratio geometry makes it difficult to find a multi-tape CICC configuration that fulfills the high engineering current density requirements while retaining enough flexibility for winding large-scale magnets.Moreover,the multilayer structure and inherent brittleness make the REBCO tapes susceptible to degradation during CICC manufacturing and operation.For more than a decade,the development of a reliable REBCO-based CICC that can sustain the huge combined mechanical,thermal,and Lorentz loads without degradation has been ongoing,albeit with limited progress.In this paper,we report on a prototype REBCO CICC that can withstand an applied cyclic Lorentz load of at least 830 kN·m^(-1),corresponding to a transport current of 80 kA at 10.85 T and 4.5 K.To our knowledge,this is the highest load achieved to date.The CICC uses 288 tapes wound into six strengthened sub-cables,making it capable of having a current sharing temperature,Tcs,of around 39 and 20 K when operated under 10.85 T with a current of 40 and 80 kA,respectively.Scaled to a 20-T peak field and 46.5-kA transport current,this provides a temperature margin of over 10 K with respect to an operating temperature of 4.5 K.In addition,no perceptible transport current performance degradation was observed after cyclic Lorentz loading,cyclic warm-up/cool-down(WUCD),and quench campaigns.The proposed REBCO CICC is a milestone in the development of high-temperature superconductors for large-scale and high-field magnet applications.展开更多
Although three-dimensional metal halide perovskites are promising candidates for direct X-ray detection,the ion migration of perovskites seriously affects the detector stability.Herein,face-/edge-shared 3D heterometal...Although three-dimensional metal halide perovskites are promising candidates for direct X-ray detection,the ion migration of perovskites seriously affects the detector stability.Herein,face-/edge-shared 3D heterometallic glycinate hybrid perovskitoid Pb_(2)CuGly_(2)X_(4)(Gly=-O_(2)C-CH_(2)-NH_(2);X=Cl,Br)single crystals(SCs),in which the adjacent lead halide layers are linked by large-sized Cu(Gly)_(2)pillars,are synthesized in water.The Cu(Gly)_(2)pillars in combination with face-/edge-shared inorganic skeleton are found able to synergistically suppress the ion migration,delivering a high ion migration activation energy(Ea)of 1.06 eV.The Pb_(2)CuGly_(2)Cl_(4)SC X-ray detector displays extremely low dark current drift of 1.20×10^(-9)nA mm^(-1)s^(-1)V^(-1)under high electric field(120 V mm^(-1))and continuous X-ray irradiation(2.86 Gy),and a high sensitivity of 9,250μC Gy^(-1)cm^(-2)is also achieved.More excitingly,the Pb_(2)CuGly_(2)Cl_(4)nanocrystal can be easily dispersed in water and directly blade-coated on thin-film transistor(TFT)array substrate,and the obtained Pb_(2)CuGly_(2)Cl_(4)-based TFT array detector offers an X-ray imaging capability with spatial resolution of 2.2 lp mm^(-1).展开更多
Recent advances in all-inorganic perovskite semiconductors have garnered significant research interest due to their potential for high-performance optoelectronic devices and enhanced stability under harsh environmenta...Recent advances in all-inorganic perovskite semiconductors have garnered significant research interest due to their potential for high-performance optoelectronic devices and enhanced stability under harsh environmental conditions.A deeper understanding of their structural,chemical,and physical properties has driven notable progress in addressing challenges related to electrical characteristics,reproducibility,and long-term operational stability in perovskite-based memristors.These advancements have been realized through composition engineering,dimensionality modulation,thin-film processing,and device optimization.This review concisely summarizes recent developments in all-inorganic perovskite memristors,highlighting their diverse material properties,device performance,and applications in artificial synapses and logic operations.We discuss key resistance-switching mechanisms,optimization strategies,and operational capabilities while outlining remaining challenges and future directions for perovskitebased memory technologies.展开更多
Ba0.5Sr0.5Co0.8Fe0.2O3-δ （BSCF） is one of the most active cathode materials and shows significant hydration effect suggesting possible proton conductivity. In this study, the performance of BSCF cathode on a proto...Ba0.5Sr0.5Co0.8Fe0.2O3-δ （BSCF） is one of the most active cathode materials and shows significant hydration effect suggesting possible proton conductivity. In this study, the performance of BSCF cathode on a protonconducting BaZr0.1Ce0.7Y0.2O3-δ（BZCY） electrolyte with silver and gold current collectors was determined. The electrochemical characteristics of the symmetrical and anode-supported cell with diluted silver electrode, silver current collector or gold current collector on BSCF electrode were compared. The significant result is that, although the diluted silver electrode itself shows poor operation stability, the silver current collector has strong electrocatalytic contribution to the BSCF cathode performance on the proton-conducting electrolyte, leading to higher cell performance than that with the gold current collector.展开更多
The main technical problems that should be considered in the design of hydro-turbine generating units of Three Gorges Project (TGP) are analyzed;the key technical researches performed are summarized,and the parameters...The main technical problems that should be considered in the design of hydro-turbine generating units of Three Gorges Project (TGP) are analyzed;the key technical researches performed are summarized,and the parameters of hydro-turbine generating units are optimized through the study on key technical problems.The unit operation indicates that the performance of the hydro-turbine generating units is excellent,and the units can operate in a safe,stable and highly efficient mode for a long term.Therefore,it is verified effectively that the general technical design of units is scientific and rational.展开更多
Biocompatible devices are widely employed in modernized lives and medical fields in the forms of wearable and implantable devices,raising higher requirements on the battery biocompatibility,high safety,low cost,and ex...Biocompatible devices are widely employed in modernized lives and medical fields in the forms of wearable and implantable devices,raising higher requirements on the battery biocompatibility,high safety,low cost,and excellent electrochemical performance,which become the evaluation criteria toward developing feasible biocompatible batteries.Herein,through conducting the battery implantation tests and leakage scene simulations on New Zealand rabbits,zinc sulfate electrolyte is proved to exhibit higher biosecurity and turns out to be one of the ideal zinc salts for biocompatible zinc-ion batteries(ZIBs).Furthermore,in order to mitigate the notorious dendrite growth and hydrogen evolution in mildly acidic electrolyte as well as improve their operating stability,Sn hetero nucleus is introduced to stabilize the zinc anode,which not only facilitates the planar zinc deposition,but also contributes to higher hydrogen evolution overpotential.Finally,a long lifetime of 1500 h for the symmetrical cell,the specific capacity of 150 mAh g^(-1)under 0.5 A g^(-1)for the Zn-MnO_(2)battery and 212 mAh g^(-1)under 5 A g^(-1)for the Zn—NH4V4O10 battery are obtained.This work may provide unique perspectives on biocompatible ZIBs toward the biosecurity of their cell components.展开更多
Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirabl...Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirable thickness and a low defect density in perovskite solar mod-ules(PSMs)is still challenging.Here,we report preparation of high-quality large-area SnO_(2) films by chemical bath depo-sition(CBD)with the addition of KMnO_(4).The strong oxidiz-ing nature of KMnO_(4) promotes the conversion from Sn(II)to Sn(VI),leading to reduced trap defects and a higher carrier mobility of SnO_(2).In addition,K ions diffuse into the per-ovskite film resulting in larger grain sizes,passivated grain boundaries,and reduced hysteresis of PSCs.Furthermore,Mn ion doping improves both the crystallinity and the phase stability of the perovskite film.Such a multifunctional interface engineering strategy enabled us to achieve a power conversion efficiency(PCE)of 21.70% with less hysteresis for lab-scale PSCs.Using this method,we also fabricated 5×5 and 10×10 cm^(2) PSMs,which showed PCEs of 15.62% and 11.80%(active area PCEs are 17.26%and 13.72%),respectively.For the encapsulated 5×5 cm^(2) PSM,we obtained a T80 operation lifetime(the lifespan during which the solar module PCE drops to 80%of its initial value)exceeding 1000 h in ambient condition.展开更多
Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the ex...Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal electric field.We propose a heterojunction route to help suppress ion migration,thus improving the operational stability of the cell from the perspective of eliminating the electric field response in the perovskite absorber.A heavily doped p-type(p^(+))thin layer semiconductor is introduced between the electron transporting layer(ETL)and perovskite absorber.The heterojunction charge depletion and electric field are limited to the ETL and p^(+)layers,while the perovskite absorber and hole transporting layer remain neutral.The p^(+)layer has a variety of candidate materials and is tolerant of defect density and carrier mobility,which makes this heterojunction route highly feasible and promising for use in practical applications.展开更多
文摘Software application is still a heavy dependence for most of the business operation today.Whenever software application encounters error that causes downtime in the production environment,the root cause of the error can be either within the software application layer or any other factor outside the software application layer.To accurately identify the root cause is difficult whenever more than one log file is required for the root cause analysis activity.Due to such complexity,it leads to the entire duration on the root cause analysis activity became prolong.This will increase the total time taken on restoring the software application service back to the users.In order to identify the root cause of software application error in a more accurate manner,and shorten the duration of root cause analysis activity conducting on software application error,a Prescriptive Analytical Logic Model incorporates with Analytic Hierarchy Process(AHP)is proposed.The proposed Logic Model along with the algorithm will contribute a new knowledge in the area of log file analysis to shorten the total time spent on root cause analysis activity.
基金This work was supported by the National Nature Science Foundation of China(Grant No.61733017).
文摘Treating plant dynamics as an ideal integrator chain disturbed by the total disturbance is the hallmark of active disturbance rejection control(ADRC).To interpret its effectiveness and success,to explain why so many vastly different dynamic systems can be treated in this manner,and to answer why a detailed,accurate,and global mathematical model is unnecessary,is the target of this paper.Driven by a motivating example,the notions of normality and locality are introduced.Normality shows that,in ADRC,the plant is normalized to an integrator chain,which is called local nominal model and locally describes the plant’s frequency response in the neighborhood of the expected gain crossover frequency.Locality interprets why ADRC can design the controller only with the local information of the plant.With normality and locality,ADRC can be effective and robust,and obtain operational stability discussed by T.S.Tsien.Then viewing proportional-integral-derivative(PID)control as a low-frequency approximation of second-order linear ADRC,the above results are extended to PID control.A controller design framework is proposed to obtain the controller in three steps:(1)choose an integrator chain as the local nominal model of the plant;(2)select a controller family corresponding to the local nominal model;and(3)tune the controller to guarantee the gain crossover frequency specification.The second-order linear ADRC and the PID control are two special cases of the framework.
基金the National Natural Science Foundation of China(Nos.21975012 and 51825301).
文摘The use of additive is an effective approach to optimize the active layer morphology and improve the power conversion efficiency(PCE)of organic solar cells(OSCs).However,residual solvent additives always lead to undesirably compromise the stability of OSCs.In this work,an organic small molecule BBT-Cl was designed and used as a novel solid additive to partly replace solvent additive to fabricate highperformance OSCs.The synergistic effect of the dual additives on the optical property,morphology and photovoltaic characteristics of the PM6:Y6 based non-fullerene OSCs have been systematically characterized.The introduction of BBT-Cl could effectively enhance the crystallinity of the blend and promote charge extraction and transport.Consequently,the OSCs processed by the dual additives exhibit a high PCE of 17.73%,which is obviously higher than OSCs with CN additive(16.48%).Meanwhile,BBT-Cl based dual additives treatment has also been successfully introduced into another two non-fullerene OSCs to verify its general applicability.Furthermore,20%PCE aging is significantly prolonged from 720 min to 2880 min for the devices proceeded with the dual additives.This work highlights the great potential of solid additive in the fabrication of efficient OSCs with excellent stability.
基金King Abdulaziz City for Science and Technology (KACST) for the fellowshipfunding from the European Union’s Horizon 2020 research and innovation program GRAPHENE Flagship Core 3 under agreement No.: 881603+2 种基金funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sk?odowska-Curie grant agreement No. 945363funding from the Shanghai Pujiang Program (22PJ1401200)the National Natural Science Foundation of China (No. 52302229)
文摘Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their commercialization.The interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of PSCs.In this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting material.The GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.
基金supported by the Science,Technology,and Innovation Commission of Shenzhen Municipality(No.GJHZ20220913143204008)the Shccig-Qinling Program(No.SMYJY202300294C)+3 种基金National Natural Science Foundation of China(Nos.22261142666,52372225,52172237,22305191)the Shaanxi Science Fund for Distinguished Young Scholars(No.2022JC-21)the Research Fund of the State Key Laboratory of Solidification Processing(NPU)China(No.2021-QZ-02).
文摘The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium hexafluorophosphate)(PTA),and introduce it into the buried interface of PSCs.The quaternary ammonium cation(N(-CH_(3))^(3+))in PTA can fill the vacancies of organic cations within the perovskite structure and reduce shallow energy level defects.Additionally,the hexafluorophosphate(PF6−)in PTA forms a Lewis acid-base interaction with Pb^(2+)in the perovskite layer,effectively passivating deep en-ergy level defects.Furthermore,hydrogen bonding can be established between organic cations and the PF6−anion,preventing the formation of shallow energy level defects.Through this synergistic mecha-nism,the deep and shallow energy level defects are effectively mitigated,resulting in improved device performance.As a result,the resulting treated inverted PSC exhibits an impressive power conversion ef-ficiency(PCE)of 24.72%.Notably,the PTA-treated PSCs exhibit remarkable stability,with 88.5%of the original PCE retained after undergoing heat aging at 85℃ for 1078 h,and 89.1%of the initial PCE main-tained following continuous exposure to light for 1100 h at the maximum power point.Synergistically suppressing multiple defects at the buried interface through the use of polyionic liquids is a promising way to improve the commercial viability of PSCs.
基金the financial support of the National Natural Science Foundation of China(Nos.U21A20171,12074245,52102281)National Key R&D Program of China(Nos.2021YFB3800068 and 2020YFB1506400)+1 种基金Shanghai Sailing Program(No.21YF1421600)Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2021QNRC001)。
文摘The past two years have witnessed remarkable progress in perovskite solar cells(PSCs),marked by breakthroughs in power conversion efficiency and strides in addressing long-term operational stability.At present,the certified power conversion efficiencies of singlejunction PSCs and silicon/perovskite tandem cells have surpassed 27%and 34%,respectively.Regarding stability,researchers begun to focus their attention on the challenges faced by PSCs when operated in outdoor environments.Furthermore,breakthroughs in the utilization of green solvents,fabrication in ambient air conditions,aqueous-phase synthesis of perovskite raw materials at kilogram scale,vacuum flash evaporation,and machine learning-assisted design are accelerating the commercialization of PSCs.The review summarizes the key advancements of PSCs during 2024-2025.It identifies a critical performance discrepancy between small-area devices and perovskite solar modules and delves into strategies aimed at bridging this gap.Finally,perspectives on the future directions of PSCs are presented,with a particular emphasis on improving photocurrent and environmental sustainability.
基金the National Natural Science Foundation of China(Nos.22175029,62474033,62374029 and W2433038)the Sichuan Science and Technology Program(No.2024NSFSC0250)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2025A1515010313)the Fundamental Research Funds for the Central Universities of China(No.ZYGX2022J032)the Foundation of China Petroleum&Chemical Corporation(Nos.30000000-23ZC0607-0127 and 36850000-23-ZC0607-0045)for financial support。
文摘The hygroscopic nature and severe ions diffusion of conventional dopant Li-TFSI,along with interfacial ionic defects,limiting the efficiency and stability of n-i-p perovskite solar cells(PSCs).To address this,we propose a single-dopant strategy employing a multifunctional,star-shaped dopant 2,4,6-tris(3,4,5-tri fluorophenyl)boroxine(TBRX)with a Lewis acidic boroxine core and highly electronegative fluorinated aryl groups,incorporated into Spiro-OMeTAD.Theoretical and experimental results indicate that TBRX significantly enhances hole mobility,conductivity and the flatness of hole-transporting layer(HTL)while passivating interfacial defects(Pb^(2+),V_(I)),leading to a reinforced perovskite/HTL interface.Additionally,the corresponding p-dopant effectively reduces the energy barrier between the perovskite and the HTL,promoting efficient hole extraction.Consequently,Spiro-OMeTAD:TBRX-based devices deliver a high PCE of25.57%(certified at 25.01%)with excellent long-term operational stability obtained for over 1000 h,retaining~94%of its initial efficiency after 1000 h according to ISOS-L-2 protocols,highlighting the significance of utilizing multifunctional single-dopant framework.
基金funding supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB1140000)National Natural Science Foundation of China(22379156,U23A20141)+1 种基金Qingdao New Energy Shandong Laboratory(QIBEBT/SEI/QNESL S202305)Key R&D Program of Shandong Province,China(2024SFGC0102)。
文摘While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.
基金The work was financially supported by National Key Research and Development Program of China(2019YFA0705900,2022YFB4200400)funded by MOSTthe Basic and Applied Basic Research Major Program of Guangdong Province(No.2019B030302007)+2 种基金the National Natural Science Foundation of China(No.U21A6002)Guangdong-Hong Kong-Macao joint laboratory of optoelectronic and magnetic functional materials(No.2019B121205002)C.Z.acknowledges the financial support by Basic and Applied Basic Research Major Program of Guangdong Province(No.202201010270).
文摘It is of vital importance to improve the long-term and photostability of organic photovoltaics,including organic solar cells(OSCs)and organic photodetectors(OPDs),for their ultimate industrialization.Herein,two series of terpolymers featuring with an antioxidant butylated hydroxytoluene(BHT)-terminated side chain,PTzBI-EHp-BTBHTx and N2200-BTBHTx(x=0.05,0.1,0.2),are designed and synthesized.It was found that incorporating appropriate ratio of benzothiadiazole(BT)with BHT side chains on the conjugated backbone would induce negligible effect on the molecular weight,absorption spectra and energy levels of polymers,however,which would obviously enhance the photostability of these polymers.Consequently,all-polymer solar cells(all-PSCs)and photodetectors were fabricated,and the all-PSC based on PTzBI-EHp-BTBHT0.05:N2200 realized an optimal power conversion efficiency(PCE)approaching~10%,outperforming the device based on pristine PTzBI-EHp:N2200.Impressively,the all-PSCs based on BHT-featuring terpolymers displayed alleviated PCEs degradation under continuous irradiation for 300 h due to the improved morphological and photostability of active layers.The OPDs based on BHT-featuring terpolymers achieved a lower dark current at−0.1 bias,which could be stabilized even after irradiation over 400 h.This study provides a feasible approach to develop terpolymers with antioxidant efficacy for improving the lifetime of OSCs and OPDs.
基金financially supported by the National Basic Research Program of China(973 Program,Grant No.2011CB013702)the National Natural Science Foundation of China(Grant No.51379214)the National High Technology Research and Development Program of China(863 Program,Grant No.2008AA092701-3)
文摘Jacket cutting operation is one of the most complicated and highest risk operations in the process of decommissioning offshore piled platform, the security and stability of which must be assured. In this paper, the current research on offshore structure removal and jacket cutting is introduced, on the basis of which the types of load along with the load calculation method are determined. The main influences on the stability of a jacket in cutting are analyzed. The experiment test plan is drawn by using orthogonal testing method, and the formula of critical load during the cutting procedure is deduced by differential evolution algorithm. To verify the method and results of this paper, an offshore piled platform to be decommissioned in the South China Sea is taken for an example, and the detailed schedule for jacket cutting is made with the three-dimensional finite element model of the jacket established. The natural frequency, stress, strain and stability of the jacket during cutting process are calculated, which indicates that the results of finite element analysis agree well with that of the deduced formula. The result provides the scientific reference for guaranteeing the safety of jacket in cutting operation.
基金supported by funding from the Deutsche Forschungsgemeinschaft(DFG,German Research Foundation)under Germany's Excellence Strategy-EXC 2089/1-390776260(e-conversion)via the International Research Training Group 2022 Alberta/Technical University of Munich International Graduate School for Environmentally Responsible Functional Hybrid Materials(ATUMS).
文摘With the exponential growth of the internet of things,artificial intelligence,and energy-efficient high-volume data digital communications,there is an urgent demand to develop new information technologies with high storage capacity.This needs to address the looming challenge of conventional Von Neumann architecture and Moore's law bottleneck for future data-intensive computing applications.A promising remedy lies in memristors,which offer distinct advantages of scalability,rapid access times,stable data retention,low power consumption,multistate storage capability and fast operation.Among the various materials used for active layers in memristors,low dimensional perovskite semiconductors with structural diversity and superior stability exhibit great potential for next generation memristor applications,leveraging hysteresis characteristics caused by ion migration and defects.In this review the progress of low-dimensional perovskite memory devices is comprehensively summarized.The working mechanism and fundamental processes,including ion migration dynamics,charge carrier transport and electronic resistance that underlies the switching behavior of memristors are discussed.Additionally,the device parameters are analyzed with special focus on the effective methods to improve electrical performance and operational stability.Finally,the challenges and perspective on major hurdles of low-dimensional perovskite memristors in the expansive application domains are provided.
基金supported by the Comprehensive Research Facility for the Fusion Technology Program of China(2018-000052-73-01-001228)the National Key Research and Development Program of China(2022YFE03150200)+3 种基金the Institute of Energy,Hefei Comprehensive National Science Center(21KZS207)the National Natural Science Foundation of China(52077212)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2021444)the European–China collaboration program on the FUSION magnet.
文摘A promising way to realize controlled nuclear fusion involves the use of magnetic fields to control and confine the hot plasma configuration.This approach requires superconductor magnets operating above 15 T for the next generation of fusion devices.Due to their high in-field transport current capacity,rare-Earth barium copper oxide(REBCO)coated conductors are promising materials for manufacturing of cable-in-conduit conductors(CICCs)for fusion.However,the high-aspect-ratio geometry makes it difficult to find a multi-tape CICC configuration that fulfills the high engineering current density requirements while retaining enough flexibility for winding large-scale magnets.Moreover,the multilayer structure and inherent brittleness make the REBCO tapes susceptible to degradation during CICC manufacturing and operation.For more than a decade,the development of a reliable REBCO-based CICC that can sustain the huge combined mechanical,thermal,and Lorentz loads without degradation has been ongoing,albeit with limited progress.In this paper,we report on a prototype REBCO CICC that can withstand an applied cyclic Lorentz load of at least 830 kN·m^(-1),corresponding to a transport current of 80 kA at 10.85 T and 4.5 K.To our knowledge,this is the highest load achieved to date.The CICC uses 288 tapes wound into six strengthened sub-cables,making it capable of having a current sharing temperature,Tcs,of around 39 and 20 K when operated under 10.85 T with a current of 40 and 80 kA,respectively.Scaled to a 20-T peak field and 46.5-kA transport current,this provides a temperature margin of over 10 K with respect to an operating temperature of 4.5 K.In addition,no perceptible transport current performance degradation was observed after cyclic Lorentz loading,cyclic warm-up/cool-down(WUCD),and quench campaigns.The proposed REBCO CICC is a milestone in the development of high-temperature superconductors for large-scale and high-field magnet applications.
基金financially supported by the National Natural Science Foundation of China (62004089,62374053, 62474187 and 12235006)the Special Zone Support Program for Outstanding Talents of Henan University+4 种基金the Shenzhen Basic Research Program (JCYJ20220818101612027)the Guangdong Basic and Applied Basic Research Foundation (2024A1515012494)the Henan Province Postdoctoral Science Foundation (J23029Y)the Natural Science Foundation of Henan Province (232300420412)the Science and Technology Tackling Project of Henan Province (242102210160)
文摘Although three-dimensional metal halide perovskites are promising candidates for direct X-ray detection,the ion migration of perovskites seriously affects the detector stability.Herein,face-/edge-shared 3D heterometallic glycinate hybrid perovskitoid Pb_(2)CuGly_(2)X_(4)(Gly=-O_(2)C-CH_(2)-NH_(2);X=Cl,Br)single crystals(SCs),in which the adjacent lead halide layers are linked by large-sized Cu(Gly)_(2)pillars,are synthesized in water.The Cu(Gly)_(2)pillars in combination with face-/edge-shared inorganic skeleton are found able to synergistically suppress the ion migration,delivering a high ion migration activation energy(Ea)of 1.06 eV.The Pb_(2)CuGly_(2)Cl_(4)SC X-ray detector displays extremely low dark current drift of 1.20×10^(-9)nA mm^(-1)s^(-1)V^(-1)under high electric field(120 V mm^(-1))and continuous X-ray irradiation(2.86 Gy),and a high sensitivity of 9,250μC Gy^(-1)cm^(-2)is also achieved.More excitingly,the Pb_(2)CuGly_(2)Cl_(4)nanocrystal can be easily dispersed in water and directly blade-coated on thin-film transistor(TFT)array substrate,and the obtained Pb_(2)CuGly_(2)Cl_(4)-based TFT array detector offers an X-ray imaging capability with spatial resolution of 2.2 lp mm^(-1).
基金supported by the JST SPRING Grant number JPMJSP2131funded by the Research Fellow Scheme from The Chinese University of Hong KongUniversiti Teknologi Malaysia AJ090000.6700.09453-Tabung Pembayaran Lantikan Skim Prominent Visiting Researcher Scheme JTNCPI。
文摘Recent advances in all-inorganic perovskite semiconductors have garnered significant research interest due to their potential for high-performance optoelectronic devices and enhanced stability under harsh environmental conditions.A deeper understanding of their structural,chemical,and physical properties has driven notable progress in addressing challenges related to electrical characteristics,reproducibility,and long-term operational stability in perovskite-based memristors.These advancements have been realized through composition engineering,dimensionality modulation,thin-film processing,and device optimization.This review concisely summarizes recent developments in all-inorganic perovskite memristors,highlighting their diverse material properties,device performance,and applications in artificial synapses and logic operations.We discuss key resistance-switching mechanisms,optimization strategies,and operational capabilities while outlining remaining challenges and future directions for perovskitebased memory technologies.
基金financially supported by the National Natural Science Foundation of China(No.51502001)the Natural Science Fund of Anhui Province (No.1608085MB31)+2 种基金the Provincial Natural Science Research Program of Higher Education Institutions of Anhui Province (No.KJ2015A0501)Anhui University Personnel Recruiting Project of Academic and Technical Leaders (No.J10117700069)the State Key Laboratory of MaterialsOriented Chemical Engineering (No.KL15-01)
文摘Ba0.5Sr0.5Co0.8Fe0.2O3-δ （BSCF） is one of the most active cathode materials and shows significant hydration effect suggesting possible proton conductivity. In this study, the performance of BSCF cathode on a protonconducting BaZr0.1Ce0.7Y0.2O3-δ（BZCY） electrolyte with silver and gold current collectors was determined. The electrochemical characteristics of the symmetrical and anode-supported cell with diluted silver electrode, silver current collector or gold current collector on BSCF electrode were compared. The significant result is that, although the diluted silver electrode itself shows poor operation stability, the silver current collector has strong electrocatalytic contribution to the BSCF cathode performance on the proton-conducting electrolyte, leading to higher cell performance than that with the gold current collector.
文摘The main technical problems that should be considered in the design of hydro-turbine generating units of Three Gorges Project (TGP) are analyzed;the key technical researches performed are summarized,and the parameters of hydro-turbine generating units are optimized through the study on key technical problems.The unit operation indicates that the performance of the hydro-turbine generating units is excellent,and the units can operate in a safe,stable and highly efficient mode for a long term.Therefore,it is verified effectively that the general technical design of units is scientific and rational.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.82103472,82202480,and 52372252)the Hunan Natural Science Fund for Distinguished Young Scholar(2021JJ10064)the Program of Youth Talent Support for Hunan Province(2020RC3011).
文摘Biocompatible devices are widely employed in modernized lives and medical fields in the forms of wearable and implantable devices,raising higher requirements on the battery biocompatibility,high safety,low cost,and excellent electrochemical performance,which become the evaluation criteria toward developing feasible biocompatible batteries.Herein,through conducting the battery implantation tests and leakage scene simulations on New Zealand rabbits,zinc sulfate electrolyte is proved to exhibit higher biosecurity and turns out to be one of the ideal zinc salts for biocompatible zinc-ion batteries(ZIBs).Furthermore,in order to mitigate the notorious dendrite growth and hydrogen evolution in mildly acidic electrolyte as well as improve their operating stability,Sn hetero nucleus is introduced to stabilize the zinc anode,which not only facilitates the planar zinc deposition,but also contributes to higher hydrogen evolution overpotential.Finally,a long lifetime of 1500 h for the symmetrical cell,the specific capacity of 150 mAh g^(-1)under 0.5 A g^(-1)for the Zn-MnO_(2)battery and 212 mAh g^(-1)under 5 A g^(-1)for the Zn—NH4V4O10 battery are obtained.This work may provide unique perspectives on biocompatible ZIBs toward the biosecurity of their cell components.
基金supported by funding from the Energy Materials and Surface Sciences Unit of the Okinawa Institute of Science and Technology Graduate Universitythe OIST R&D Cluster Research Program,the OIST Proof of Concept(POC)ProgramJST A-STEP Grant Number JPMJTM20HS,Japan。
文摘Tin dioxide(SnO_(2))has been demonstrated as one of the promising electron transport layers for high-efficiency perovskite solar cells(PSCs).However,scalable fabrication of SnO_(2) films with uniform coverage,desirable thickness and a low defect density in perovskite solar mod-ules(PSMs)is still challenging.Here,we report preparation of high-quality large-area SnO_(2) films by chemical bath depo-sition(CBD)with the addition of KMnO_(4).The strong oxidiz-ing nature of KMnO_(4) promotes the conversion from Sn(II)to Sn(VI),leading to reduced trap defects and a higher carrier mobility of SnO_(2).In addition,K ions diffuse into the per-ovskite film resulting in larger grain sizes,passivated grain boundaries,and reduced hysteresis of PSCs.Furthermore,Mn ion doping improves both the crystallinity and the phase stability of the perovskite film.Such a multifunctional interface engineering strategy enabled us to achieve a power conversion efficiency(PCE)of 21.70% with less hysteresis for lab-scale PSCs.Using this method,we also fabricated 5×5 and 10×10 cm^(2) PSMs,which showed PCEs of 15.62% and 11.80%(active area PCEs are 17.26%and 13.72%),respectively.For the encapsulated 5×5 cm^(2) PSM,we obtained a T80 operation lifetime(the lifespan during which the solar module PCE drops to 80%of its initial value)exceeding 1000 h in ambient condition.
基金supported by the National Natural Science Foundation of China(52072402,11874402,51627803,51421002,91733301,51761145042,and 51872321)the International Partnership Program of Chinese Academy of Sciences(112111KYSB20170089)。
文摘Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal electric field.We propose a heterojunction route to help suppress ion migration,thus improving the operational stability of the cell from the perspective of eliminating the electric field response in the perovskite absorber.A heavily doped p-type(p^(+))thin layer semiconductor is introduced between the electron transporting layer(ETL)and perovskite absorber.The heterojunction charge depletion and electric field are limited to the ETL and p^(+)layers,while the perovskite absorber and hole transporting layer remain neutral.The p^(+)layer has a variety of candidate materials and is tolerant of defect density and carrier mobility,which makes this heterojunction route highly feasible and promising for use in practical applications.
