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Low Frequency Dispersion Mechanism of Dielectric Response for Oil-paper Insulation Diagnosis 被引量:14
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作者 ZHOU Lijun LI Xianlang WU Guangning 《高电压技术》 EI CAS CSCD 北大核心 2013年第8期1873-1880,共8页
Both the real part and imaginary part of complex permittivity approximately have a log-linear frequency dependency at low fre- quencies, especially at ultra-low frequencies under conditions of different moisture conce... Both the real part and imaginary part of complex permittivity approximately have a log-linear frequency dependency at low fre- quencies, especially at ultra-low frequencies under conditions of different moisture concentrations and temperatures, which is recognized as the low frequency dispersion (LFD). In order to explain this dispersion, a new mechanism of dielectric response of LFD of oil-paper insula- tion is proposed. A simplified one-dimensional mathematical model of concentration polarization carrier caused by slow migration is developed and solved, which indicates that ion mobility is closely related to the size of gap and the adsorption capacity of cellulose molecu- lar chains to ions. A stochastic statistical model of the carrier mobility induced LFD is also developed. Moreover, actual tests under 50 °C and 2% moisture content were put forward, as well as simulations with according current waveforms. The simulation results agreed well with the experimental data in that concentration polarization of carriers caused by slow migration is the probable cause of low frequency dispersion of dielectric response for oil-paper insulation diagnosis. 展开更多
关键词 分散介质 油纸绝缘 绝缘诊断 低频率 机制 离子迁移率 一维数学模型 载流子迁移率
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Surface Partial Discharge Characteristics of Oil-paper Insulation Under Combined AC-DC Voltage 被引量:5
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作者 SHA Yanchao ZHOU Yuanxiang +3 位作者 NIE Dexin WU Zhirong DENG Jiangang LU Licheng 《高电压技术》 EI CAS CSCD 北大核心 2013年第8期1902-1910,共9页
The valve side windings of converter transformers bear AC, DC, impulse, and reversal-polarity voltages during operation, which could result in serious insulation problems of the equipment. By performing experiments wi... The valve side windings of converter transformers bear AC, DC, impulse, and reversal-polarity voltages during operation, which could result in serious insulation problems of the equipment. By performing experiments with surface discharge model of oil-paper insula- tion at 80 ℃ under combined AC-DC voltage for 200 h, we studied the spectrums and statistical parameters of partial discharges at different discharge stages. Furthermore, some fingerprint parameters were calculated in order to estimate the development situation of par- tial discharge, while the characteristic gases dissolved in the transformer oil were measured by gas chromatography. The surface discharges in the experiments were observed using a high speed camera, and a full discharge process could be marked off into four stages as follows. ①The elementary stage. When a partial discharge occurs near electrodes, electrical charges are injected into the region near electrodes and causing bubble generation. ②Due to their high resistivity and low dielectric constant, the bubbles would bare the major part of the voltage applied to samples. Therefore, discharge happens inside the small bubbles, and it emits a lot of light. ③Micromolecules of gas are produced in discharge, and further ionization in the transformer oil takes place simultaneously when high-energy electrons collide with oil molecules. ④The carrier charge moves forward to electrodes driven by the applied electric field, till they neutralize with the charge from electrodes, and hence discharge channels are formed subsequently. 展开更多
关键词 AC-DC 放电特性 绝缘表面 电压 油纸 油中溶解气体 换流变压器 合作
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Influence of Vegetable Oil on the Thermal Aging Rate of Kraft Paper and its Mechanism 被引量:4
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作者 YANG Lijun DENG Bangfei +2 位作者 LIAO Ruijin SUN Caixin ZHU Mengzhao 《高电压技术》 EI CAS CSCD 北大核心 2012年第8期2059-2067,共9页
关键词 局部放电 射频信号 放电量 高电压技术
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Characteristic Analysis of Partial Discharges and Dissolved Gases Generated Cavityin Oil-paper Insulation Under AC-DC Combined Voltages 被引量:2
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作者 HE Zhiman LI Jian +2 位作者 BAO Lianwei JIANG Tianyan WANG Youyuan 《高电压技术》 EI CAS CSCD 北大核心 2012年第8期2091-2096,共6页
关键词 局部放电 射频信号 放电量 高电压技术
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Space Charge Characteristics of Oil-paper Insulation with New Paper and Aged Oil 被引量:1
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作者 MU Haibao WANG Da +4 位作者 WANG Shiqiang TIAN Jie LI Yuan WEI Yanhui ZHANG Guanjun 《高电压技术》 EI CAS CSCD 北大核心 2013年第8期1865-1872,共8页
Oil-paper compound insulation has been widely used in power transformers for quite a long time because of its good performances. The insulation gradually degrades under combined thermal, electrical and chemical stress... Oil-paper compound insulation has been widely used in power transformers for quite a long time because of its good performances. The insulation gradually degrades under combined thermal, electrical and chemical stresses during routine operations, mainly because of space charges inside. This work investigated the space charge characteristics in oil-paper insulation under oil aging circumstance. New trans- former oil samples are thermally aged to obtain different aging states, and their physical and chemical properties are analyzed. New Kraft papers are dried in vacuum and fully immersed in these different aged oil samples, and three kinds of oil-paper samples are obtained. We use the pulsed electro-acoustic (PEA) method to measure space charge under both DC voltage-on and voltage-off conditions at room temperature. The effect of oil aging state on characteristics of space charge injection, accumulation, and decay is analyzed and discussed. The results show that comparing with the DC voltage-off condition, more charges are injected into samples at the interface of electrode and dielectric when DC voltage is on. When the oil-aged state gets worse, more charges are induced at both cathode and anode, more space charges are accumulated in the bulk, the area of negative charges is larger, and local electric field is distorted more seriously. Moreover, for the voltage-off condition, aged oil is good for space charge decay, and trapped positive space charges decay faster than trapped negative charges. 展开更多
关键词 空间电荷 油纸绝缘 电荷特性 老年 老化状态 直流电压 衰减特性 电荷积累
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Improvement on Condition Assessment Model for Oil-paper Insulation 被引量:1
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作者 LA Yuan SHI Xuetao +4 位作者 CAO Wen HE Baosheng KE Chunjun WU Kai LONG Hongyu 《高电压技术》 EI CAS CSCD 北大核心 2013年第8期1974-1980,共7页
Identification of the aging condition and the failure probability of oil-paper insulation in transformer is important for improving the reliability of electric power transmission system and applying life cycle cost (L... Identification of the aging condition and the failure probability of oil-paper insulation in transformer is important for improving the reliability of electric power transmission system and applying life cycle cost (LCC) management to electrical equipment. Based on data obtained in a series of multi-accelerated-aging experiments, two approaches for calculating failure probability of oil-paper insulation were compared in aspects of degree of polymerization (DP) and condition ranking. In the experiments, mineral oil and cellulose paper are sub- jected to electrical and thermal stresses, and several parameters, including dissolved gases’ volume fraction, furfural content, moisture content, and degree of polymerization, are measured after the aging process. Results show that weight of carbon oxide, which has a close relationship with cellulose paper degradation, is much higher in DP model than in condition ranking model. Moreover, it is concluded that DP model is more practically accurate than condition ranking model, because aging of cellulose paper rather than mineral oil is the key and critical factor of oil-paper insulation aging. 展开更多
关键词 油纸绝缘 评估模型 绝缘状态 老化实验 寿命周期成本 电力传输系统 失效概率 纤维素
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Statistical Distributions of Partial Discharges in Oil-paper Insulation Under AC-DC Combined Voltages 被引量:5
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作者 LI Jian JIANG Tianyan +2 位作者 HE Zhiman CHENG Changkui BAO Lianwei 《高电压技术》 EI CAS CSCD 北大核心 2012年第8期1856-1862,共7页
关键词 局部放电 射频信号 放电量 高电压技术
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Copper Release Kinetics and Ageing of Insulation Paper in Oil-Immersed Transformers 被引量:3
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作者 Olena Sevastyanova Bogdan Pasalskiy Boris Zhmud 《Engineering(科研)》 2015年第8期514-529,共16页
The paper provides a general overview of chemical processes leading to the degradation of oil-paper insulation in oil-immersed electrical current transformers. Previous knowledge available in literature is complemente... The paper provides a general overview of chemical processes leading to the degradation of oil-paper insulation in oil-immersed electrical current transformers. Previous knowledge available in literature is complemented by new results placing a specific emphasis on the physicochemical factors which affect the copper release in the insulation oil and the oil oxidation kinetics. It is demonstrated that various ageing processes interact with each other, with one or another process dominating under specific conditions. Comprehensive but disjoint studies focusing on separate sub-processes may produce rather misleading results, and occasionally, lie behind rather irrelevant quality demands imposed on the insulating liquids. 展开更多
关键词 TRANSFORMER oil Insulating oil COPPER CORROSION paper DEGRADATION Ageing
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Chaotic Characteristic of Time Series of Partial Discharge in Oil-Paper Insulation
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作者 罗勇芬 纪海英 +1 位作者 黄平 李彦明 《Plasma Science and Technology》 SCIE EI CAS CSCD 2011年第6期740-746,共7页
The chaotic characteristics of time series of five partial discharge (PD) patterns in oil-paper insulation are studied. The results verify obvious chaotic characteristic of the time series of discharge signals and t... The chaotic characteristics of time series of five partial discharge (PD) patterns in oil-paper insulation are studied. The results verify obvious chaotic characteristic of the time series of discharge signals and the fact that PD is a chaotic process. These time series have distinctive features, and the chaotic attractors obtained from time series differed greatly from each other by shapes in the phase space, so they could be used to qualitatively identify the PD patterns. The phase space parameters are selected, then the chaotic characteristic quantities can be extracted. These quantities could quantificationally characterize the PD patterns. The effects on pattern recognition of PRPD and CAPD are compared by using the neural network of radial basis function. The results show that both of the two recognition methods work well and have their respective advantages. Then, both the statistical operators under PRPD mode and the chaotic characteristic quantities under CAPD mode are selected comprehensively as the input vectors of neural network, and the PD pattern recognition accuracy is thereby greatly improved. 展开更多
关键词 oil-paper insulation partial discharge time series CHAOS pattern recognition
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The Research of Connection between Degree of Polymerization and Frequency Domain Dielectric Spectroscopy Characteristics during Oil-Paper Insulation Aging
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作者 Danyu Jiang Guangning Wu +1 位作者 Xian Yang Qingkai Hao 《Energy and Power Engineering》 2017年第4期667-674,共8页
In order to study the linkage effects between degree of polymerization and frequency domain dielectric spectroscopy characteristics of oil-paper insulation, the frequency domain dielectric response test platform of oi... In order to study the linkage effects between degree of polymerization and frequency domain dielectric spectroscopy characteristics of oil-paper insulation, the frequency domain dielectric response test platform of oil-paper insulation is set up. Complex permittivity of oil-paper insulation respectively composed by new or aged oil and insulation paper with different DP are tested, and complex permittivity of oil-paper insulation respectively composed by insulation respectively composed by new oil and insulation paper with different DP and low or high moisture content are tested. The test results are analyzed, and the analysis results show that the degree of polymerization of insulation paper has an influence on complex permittivity of oil-paper insulation though influencing the distribution of moisture and acids between oil and paper. 展开更多
关键词 DEGREE of POLYMERIZATION oil-paper INSULATION Frequency Domain DIELECTRIC Spectroscopy MOISTURE
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抗氧化剂对变压器油纸绝缘系统钝化剂防护性能影响
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作者 李冠男 戴景琪 +3 位作者 董明 焦在滨 郑璐 刘鑫荣 《科学技术与工程》 北大核心 2026年第2期655-662,共8页
目前对抗氧化剂对变压器油纸绝缘系统和钝化剂的防护效果是否有影响研究较少,为此选取了应用较为广泛的抗氧化剂DBPC、钝化剂Irgamet 39和两种典型硫化物二苄基二硫醚(dibenzyl disulfide,DBDS)和十二硫醇(dodecylmercaptan,DDM),采用... 目前对抗氧化剂对变压器油纸绝缘系统和钝化剂的防护效果是否有影响研究较少,为此选取了应用较为广泛的抗氧化剂DBPC、钝化剂Irgamet 39和两种典型硫化物二苄基二硫醚(dibenzyl disulfide,DBDS)和十二硫醇(dodecylmercaptan,DDM),采用反应分子动力学仿真模拟,通过测量范德华能、均方位移、弹性模量和氢键数目等参数,研究不同含量的抗氧化剂DBPC分子加入后,对油纸绝缘性能和对钝化剂的防护效果的影响。结果表明:DBPC添加量应按照标准添加,即变压器中抗氧化剂含量在0.15%~0.3%。若大于或小于这个范围,均会在不同程度上加速油纸绝缘的老化,降低其绝缘性能。DBPC产生的DBPC-Cu复合物溶于绝缘油,进而使硫化亚铜沉积于绝缘纸上,即使按标准含量添加,仍会对绝缘纸的绝缘性能造成微量影响。但是若DBPC按照0.15%~0.3%的标准添加,对变压器油纸绝缘系统的绝缘性能影响很小,对钝化剂的防护效果几乎没有影响。 展开更多
关键词 变压器 油纸绝缘系统 抗氧化剂 分子动力学 防护效果
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计及谐波电流影响的变压器绕组温度分布及油纸绝缘热老化寿命分析研究
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作者 钱国超 吴洁 +3 位作者 许晶 郝建 代维菊 洪志湖 《电工电能新技术》 北大核心 2026年第2期99-110,共12页
谐波电流会显著增加变压器绕组的谐波损耗和温升,因此量化分析谐波电流对变压器温度分布和热老化寿命的影响对于准确构建变压器寿命计算模型至关重要。本文开展了计及谐波电流影响的变压器绕组温度分布及油纸绝缘热老化寿命分析研究。首... 谐波电流会显著增加变压器绕组的谐波损耗和温升,因此量化分析谐波电流对变压器温度分布和热老化寿命的影响对于准确构建变压器寿命计算模型至关重要。本文开展了计及谐波电流影响的变压器绕组温度分布及油纸绝缘热老化寿命分析研究。首先,构建110 kV交流油浸式变压器电-磁-热-流场仿真模型,仿真分析变压器绕组在不同负载电流和谐波电流作用下的温度分布特性;其次,研究构建计及谐波电流影响的绕组热点温度量化计算模型,并开展试验验证;最后,研究提出计及谐波电流影响的油纸绝缘热老化寿命改进模型,量化分析谐波电流对油纸绝缘热老化寿命的影响程度。结果表明:绕组热点温度随负载率增大呈指数规律上升,随入口流速增大呈指数规律下降;工频电流作用下绕组温度仿真计算值与实测值误差百分比最大为1.06%,谐波电流作用下的热点温度仿真值与模型计算值最大相对误差为0.855%;绕组热老化寿命随着谐波电流频率和含量的增大呈指数形式下降,当250 Hz谐波电流含量从5%增大到30%时,绕组油纸绝缘热老化寿命减少百分比增至97.02%。本文为解决谐波影响下变压器温升检测和老化寿命评估提供科学依据。 展开更多
关键词 变压器 谐波电流 油纸绝缘 温度分布 热老化寿命
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YD联结换流变压器阀侧绕组饼间等效电压下的局部放电特性
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作者 杨宇翔 李斯盟 +1 位作者 卜泽伟 汲胜昌 《变压器》 2026年第2期14-23,共10页
换流变压器阀侧绕组长期承受含高比例谐波的复杂电应力,其绝缘问题更加突出。缺陷局部放电是诱发绝缘事故的主要原因之一,同时也是绝缘状态的有效表征手段之一,因此有必要研究换流变纵绝缘电应力下的局放特性。本文作者以插入屏连续式绕... 换流变压器阀侧绕组长期承受含高比例谐波的复杂电应力,其绝缘问题更加突出。缺陷局部放电是诱发绝缘事故的主要原因之一,同时也是绝缘状态的有效表征手段之一,因此有必要研究换流变纵绝缘电应力下的局放特性。本文作者以插入屏连续式绕组YD联结换流变为研究对象,首先搭建换流变阀侧绕组等效电路模型,仿真得到阀侧绕组饼间电压波形;然后在此基础上提出一种饼间电压波形的等效方法,搭建局部放电试验平台,以尖端缺陷为例,研究等效饼间电应力下油纸绝缘的放电特性及机理。 展开更多
关键词 换流变压器 油纸绝缘 饼间电压 局部放电
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Comparative Evaluation of the Thermal Aging of Solid Insulation in Mineral Oil and Methyl Ester of Palm Kernel Oil
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作者 Gerard Ombick Boyekong Ghislain Mengata Mengounou Adolphe Moukengue Imano 《Journal of Power and Energy Engineering》 2021年第5期166-183,共18页
The purpose of this work is to determine the impact of thermal aging on the dielectric and physicochemical properties of the oil/paper mixed insulation. We performed a comparative analysis of dielectric paper dipped i... The purpose of this work is to determine the impact of thermal aging on the dielectric and physicochemical properties of the oil/paper mixed insulation. We performed a comparative analysis of dielectric paper dipped in two cooling fluids: palm kernel oil methyl ester (MEPKO) and mineral oil (MO). Two types of dielectric paper were used: Thermally Upgraded Kraft paper (TUK) and Nomex-910 paper (NP-910). An accelerated aging test was realized at 110<span style="white-space:nowrap;">°</span>C during a total of 96 hours. Samples of oil and paper were collected after 0, 48, 72 and 96 hours for analyses purposes. The analyses performed included the measurement of the Breakdown voltage (BDV) of the dielectric papers, the Total Acid Number (TAN) and the Decay Dissolved Products (DDP) of the liquid dielectrics. The BDV of NP-910 is greater than the BDV of TUK. Concerning the type of oil, the BDV of dielectric papers impregnated with MEPKO is greater than the BDV of similar papers impregnated with MO, indicating a better preservation of paper when dipped in methyl esters. The analyses of TAN and DDP revealed that Nomex-910 improves the oxidation stability of MO, but reduces the oxidation stability of MEPKO. These results prove that methyl esters can be used as a substitute to replace mineral oils in power transformers. Furthermore, they show that NP can be used mainly in areas of transformer where solid insulation is subjected to high thermal and electrical stress, and TUK other places where solid insulation is required. Such combination could assure money savings and a better preservation of the oil viscosity. 展开更多
关键词 oil/paper Mixed Insulation Methyl Ester Thermal Aging Breakdown Voltage Oxidation Stability
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基于分子动力学模拟探究不同交联剂对变压器纤维素绝缘纸性能的影响 被引量:1
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作者 侯微 杨占刚 +5 位作者 谢梁 杨馥豪 汪昌霜 吴勇军 颜巍 任毅 《绝缘材料》 北大核心 2026年第1期102-109,共8页
纤维素绝缘纸作为油浸式电力变压器的重要绝缘组成部分,其绝缘性能直接影响变压器的安全稳定运行。本文提出以交联剂为“桥梁”连接相邻两条纤维素分子链的三维网状分子结构方案,并通过分子动力学模拟探究了3种交联剂(1,2,3,4-丁烷四羧... 纤维素绝缘纸作为油浸式电力变压器的重要绝缘组成部分,其绝缘性能直接影响变压器的安全稳定运行。本文提出以交联剂为“桥梁”连接相邻两条纤维素分子链的三维网状分子结构方案,并通过分子动力学模拟探究了3种交联剂(1,2,3,4-丁烷四羧酸(BTCA)、柠檬酸(CA)和马来酸(MA))对纤维素绝缘纸性能的影响,选取出合适的交联剂作为“桥梁”用于研制具有三维网状结构的绝缘纸,从而提高纤维素绝缘纸的性能。结果表明:MA改性虽然提升了纤维素体系的拉伸性能和韧性,但导致纤维素体系的热稳定性降低,极化率和介电常数增加;BTCA改性不仅导致纤维素体系的热稳定性降低,而且BTCA存在成本高、合成复杂,污染环境的缺点;CA改性使纤维素体系具有更低介电常数、介质损耗的同时保持了优良的热稳定性和力学性能,因此优选CA作为交联剂改性纤维素绝缘纸。 展开更多
关键词 油浸式变压器 交联剂 纤维素绝缘纸 三维网状结构 分子动力学
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Properties of Electrical Discharges Developing in Transformer Oil Under Lightning Impulse in the Setup of Insulated Electrodes
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作者 Pawel Rozga 《高电压技术》 EI CAS CSCD 北大核心 2013年第8期1805-1812,共8页
Looking at the problem of electrical discharge development in mineral oil, it is easy to see that most studies in this area focused on the setups of bare high voltage electrodes having a point-plane electrode arrangem... Looking at the problem of electrical discharge development in mineral oil, it is easy to see that most studies in this area focused on the setups of bare high voltage electrodes having a point-plane electrode arrangement. The setups with insulated electrodes are the mar- gin of these studies but it seems to be important to find the dependences between the paper insulation on high voltage electrode and parameters of the discharges initiated in the vicinity of this electrode. Hence, in this paper the results of researches intended to reveal the role of insulation wrapping on a HV electrode in the mechanism of electrical discharges in transformer oil under lightning impulse of both polar- ities are presented. This role is determined by analysis of the parameters characterizing the discharges (onset voltage, propagation velocity, time to initiation, rise-time of light impulses) and also by observation of their spatio-temporal development and oscillograms of the light emitted by their channels. The research was performed for two model electrode configurations: an electrode with paper insulation and a bare electrode which had the same outer dimensions as the insulated one. The most essential conclusion from performed experiment is related to times to initiation. These times, equal in the case of insulated electrodes and model bare electrode, indicate that the source of "weak points" of the paper-oil insulation system is the oil, not the surface of insulation wrapping or the metal. 展开更多
关键词 高压电极 放电特性 雷电冲击 变压器油 绝缘纸 上升时间 安装 开发
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基于微分解谱的油纸绝缘多弛豫频温机理与归一化研究 被引量:1
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作者 邹阳 黄煜 +2 位作者 方梦泓 姚雨佳 金涛 《电工技术学报》 北大核心 2025年第5期1575-1586,共12页
为研究温度对油纸绝缘频域介电谱的影响,并探索高效的频温归一化策略以消除不同环境因素带来的测试温度误差,该文提出了基于极化复电容实部一阶微分解谱的多弛豫分解方法。首先,利用微分图谱特征划分出低频弛豫、中低频多弛豫、高频弛... 为研究温度对油纸绝缘频域介电谱的影响,并探索高效的频温归一化策略以消除不同环境因素带来的测试温度误差,该文提出了基于极化复电容实部一阶微分解谱的多弛豫分解方法。首先,利用微分图谱特征划分出低频弛豫、中低频多弛豫、高频弛豫三类不同弛豫区间进行频温介电机理推演,发现各弛豫过程温度特性差异显著;其次,以Arrhenius衍生方程计算不同弛豫的活化能,基于该频温特性参量提取介质中多类贡献分量的频温频移因子,还原标准温度下的介电图谱;最后,利用不同温度及不同老化程度的试样验证该方法。实验分析表明,该方法很好地解决了传统频温归一法所存在的偏差,且对于不同老化程度的介质具有较好的适用性,可为现场测试提供可靠的理论支撑。 展开更多
关键词 油纸绝缘 微分解谱 弛豫活化能 频域介电法 频温归一化
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基于介质响应原理的变压器油纸绝缘测试实验平台设计 被引量:2
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作者 邹阳 黄煜 +3 位作者 方梦泓 石松浩 姚雨佳 高伟 《实验技术与管理》 北大核心 2025年第1期176-183,共8页
油纸绝缘作为电力变压器中的主绝缘设备,在工业生产和电力传输应用中尤为重要,为验证油纸绝缘的性能状态,该文研制了基于介质响应原理的现场可编程电力电子控制实验平台。平台以LabVIEW编程环境和三电极测试装置作为载体,采用状态机框... 油纸绝缘作为电力变压器中的主绝缘设备,在工业生产和电力传输应用中尤为重要,为验证油纸绝缘的性能状态,该文研制了基于介质响应原理的现场可编程电力电子控制实验平台。平台以LabVIEW编程环境和三电极测试装置作为载体,采用状态机框架设计了回复电压谱与极化谱测量流程,并嵌入聚类云模型算法实现油纸绝缘状态精准分类。该实验平台可促进理论知识与实践经验相结合的教学模式革新,满足实验探索、科学研究等多层次需求。 展开更多
关键词 油纸绝缘 实验平台设计 回复电压测试 数字编程控制
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离子影响油纸绝缘结合性能的分子动力学模拟研究 被引量:1
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作者 李亚莎 晏欣悦 +3 位作者 王佳敏 郭玉杰 陈俊璋 张永蘅 《材料导报》 北大核心 2025年第14期272-279,共8页
油纸绝缘材料在电力设备中广泛应用,其在老化过程中产生的离子可能对油纸绝缘结合性能产生潜在影响。为此采用分子动力学方法模拟了H_(3)O^(+)、OH^(-)、Cl^(-)、Cu^(2+)四种离子在油纸复合系统中的微观行为,并构建无离子的纯油纸复合... 油纸绝缘材料在电力设备中广泛应用,其在老化过程中产生的离子可能对油纸绝缘结合性能产生潜在影响。为此采用分子动力学方法模拟了H_(3)O^(+)、OH^(-)、Cl^(-)、Cu^(2+)四种离子在油纸复合系统中的微观行为,并构建无离子的纯油纸复合模型进行对比,深入分析离子介入对油纸复合系统的结合能、氢键作用和均方位移的影响。结果表明,离子的存在使油纸间的结合能减弱,该效应随温度的升高而加剧,并导致油纸绝缘性能下降。另一方面,离子的介入会促进氢键的形成,进而减弱油纸复合体系的结合性能,但也将离子与油之间的强结合能引入到了复合体系中,再加上不同分子间氢键的作用,使得油纸体系的整体稳定性得以维持且有所提升。本工作可为理解离子在油纸绝缘体系中的作用机理提供新视角,并为油纸绝缘材料的性能优化提供理论支撑。 展开更多
关键词 油纸绝缘 离子 分子动力学 相互作用机理 氢键
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烟草精油微胶囊的制备及其在卷烟纸中的应用 被引量:1
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作者 薛云 吴艺虹 +6 位作者 刘远上 黄家乐 周鹏飞 白家峰 贾学伟 代玉祥 许春平 《河南农业科学》 北大核心 2025年第2期154-162,共9页
为探究烟草精油微胶囊在卷烟纸加香的效果,首先通过水中蒸馏法制备烟草精油,采用复凝聚法,以烟草精油为芯材、壳聚糖为壁材、司班-80为乳化剂,制备烟草精油微胶囊并测定包埋产率,然后采用扫描电子显微镜、激光粒度仪和红外光谱分析仪等... 为探究烟草精油微胶囊在卷烟纸加香的效果,首先通过水中蒸馏法制备烟草精油,采用复凝聚法,以烟草精油为芯材、壳聚糖为壁材、司班-80为乳化剂,制备烟草精油微胶囊并测定包埋产率,然后采用扫描电子显微镜、激光粒度仪和红外光谱分析仪等对微胶囊的物理化学性质进行表征,最后将微胶囊进行卷烟纸加香并对加香后的卷烟进行感官评价和烟气成分分析。结果表明,以壳聚糖为壁材、烟草精油为芯材制备烟草精油微胶囊的平均粒径为221.1 nm,包埋产率为75.3%。通过扫描电子显微镜对制备的烟草精油微胶囊观察发现,其呈现表面光滑饱满的球状。对烟草精油、壳聚糖和烟草精油微胶囊进行红外光谱分析,通过对比三者的特征吸收峰可以证明烟草精油被包埋在壳聚糖中。感官评吸结果表明,加香后的卷烟感官质量均有明显改善。烟草精油微胶囊与烟草精油按体积比1∶2复配后加香效果更为显著,感官评吸得分可达86.6。与未加香空白组卷烟相比,添加复配溶液的卷烟烟气成分中烟碱、醇类、醛类、酸类、酯类、酮类成分的含量均有提高,卷烟香味、吃味和劲头均得到改善。 展开更多
关键词 烟草精油 微胶囊 卷烟纸加香 感官评价 烟气
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