A concise approach to the synthesis of organoiron intermediate from organoboron and Fe(III)has been developed,and the reactivity of the intermediate with a series of electrophiles has been investigated.The results rev...A concise approach to the synthesis of organoiron intermediate from organoboron and Fe(III)has been developed,and the reactivity of the intermediate with a series of electrophiles has been investigated.The results revealed that pinacol substituent of organoboron is crucial for C—B cleavage.The resulted organoiron intermediate is not stable,with weak nucleophicility.The coupling reactions of organoiron intermediate with acyl chlorides,anhydrides,isocyanates have been performed.展开更多
文摘A concise approach to the synthesis of organoiron intermediate from organoboron and Fe(III)has been developed,and the reactivity of the intermediate with a series of electrophiles has been investigated.The results revealed that pinacol substituent of organoboron is crucial for C—B cleavage.The resulted organoiron intermediate is not stable,with weak nucleophicility.The coupling reactions of organoiron intermediate with acyl chlorides,anhydrides,isocyanates have been performed.
