摘要
摘要Me_4FeLi_2不同于烷基铜、烷基锰试剂,与α,β-不饱和酮的反应不是优先进行1,4-加成。
Me_4FeLi_2 prepared in situ is used to alkylate α,β-unsaturated ketone, unlike those of alkyl derivatives of the 4d metals, the behavior of Me_4FeLi_2 is noexclusive in β-poaition to the keto group.
关键词
有机铁试剂
炔基酮
加成反应
α, β-acetylenic ketone, organoiron reagents
