针对目前矿石检测技术准确性不高、效率低、实时性差以及环境适应性弱等问题,提出了一种基于香橙派的矿石识别系统。该系统利用高清摄像头实时捕获矿石图像,并通过香橙派Orange Pi 5B开发板搭载YOLOv4-tiny-tf2模型处理图像数据,实现矿...针对目前矿石检测技术准确性不高、效率低、实时性差以及环境适应性弱等问题,提出了一种基于香橙派的矿石识别系统。该系统利用高清摄像头实时捕获矿石图像,并通过香橙派Orange Pi 5B开发板搭载YOLOv4-tiny-tf2模型处理图像数据,实现矿石种类的高效准确识别。结果表明:轻量化的YOLOv4-tiny-tf2模型在不牺牲模型精度的情况下简化了其结构,更适合在配置较低的设备上部署,具备了较高的便携性;相较于传统的人工视觉检测和化学分析方法,基于香橙派Orange Pi 5B的矿石识别系统能够实时识别矿石,识别准确率达到93.75%,具有较高的可靠性和稳定性。展开更多
Traumatic brain injury(TBI)is a public health problem with an undue economic burden that impacts nearly every age,ethnic,and gender group across the globe(Capizzi et al.,2020).TBIs are often sustained during a dynamic...Traumatic brain injury(TBI)is a public health problem with an undue economic burden that impacts nearly every age,ethnic,and gender group across the globe(Capizzi et al.,2020).TBIs are often sustained during a dynamic range of exposures to energetic environmental forces and as such outcomes are typically heterogeneous regarding severity and pathology(Capizzi et al.,2020).展开更多
Zirconia nanotube array films(ZNAF)prepared by anodic oxidation method were used as immobilization materials for acridine orange(AO),rhodamine B(RB)and AO-RB systems.A comparative study on their fluorescence emission ...Zirconia nanotube array films(ZNAF)prepared by anodic oxidation method were used as immobilization materials for acridine orange(AO),rhodamine B(RB)and AO-RB systems.A comparative study on their fluorescence emission intensity,fluorescence resonance energy transfer(FRET)and fluorescence detection of nitrite in aqueous solutions and on immobilization films with ZNAF as carriers was carried out.Results demonstrate that the solution pH values and immobilization on ZNAF have a great influence on the per-formance of these fluorescent molecules.Compared with aqueous solutions,the fluorescence emission in-tensity of AO and RB is considerably increased by immobilization,which is 8.0 and 4.2 times higher than the original,respectively.The energy transfer efficiency(E)of the AO-RB system increases from 40.9%to 84.8%by loading it on ZNAF.Moreover,after immobilization onto ZNAF,the fluorescence detection performance of nitrite is also significantly improved.The limit of detection decreases from 0.95 ng/mL to 0.22 ng/mL and the sensitivity increases from 939.18 to 15,031.68 mL/μg through loading AO onto ZNAF.展开更多
Pectin is a natural polysaccharide with a complex structure consisting of linear and branched regions rich in galacturonic acid.The growing interest in orange peel pectin can be attributed to its abundant supply.Accor...Pectin is a natural polysaccharide with a complex structure consisting of linear and branched regions rich in galacturonic acid.The growing interest in orange peel pectin can be attributed to its abundant supply.According to statistics,about 10 million tons of orange peel waste are produced worldwide each year.Traditionally,the extraction and utilization of pectin have focused on its gelling,thickening,and stabilizing properties in food.However,as more and more research teams have found that pectin has good biocompatibility,biodegradability and easy chemical modification,its potential in drug delivery systems,tissue engineering,and wound healing is gradually being explored.This review focuses on orange peel pectin polysaccharides and discusses its traditional and modern extraction techniques,especially the advanced method of subcritical water extraction.This study also outlines the structural modifications of pectin such as methylation and acetylation,and introduces its antioxidant and anticancer biological activities and their emerging roles in the development of advanced biomaterials such as bone tissue engineering and fibre pad dressings.展开更多
Gannan sweet orange essential oil has garnered significant attention due to its diverse chemical composition and pharmacological activities.The main active ingredients include sabinene,limonene,and linalool,which exhi...Gannan sweet orange essential oil has garnered significant attention due to its diverse chemical composition and pharmacological activities.The main active ingredients include sabinene,limonene,and linalool,which exhibit antioxidant,anti-inflammatory,antibacterial,and analgesic properties.This essential oil has potential applications in the development of medicinal products.This paper reviews the primary chemical composition and pharmacological effects of Jiangxi orange flower essential oil,highlighting the need for future research to focus on its biological activity and clinical application potential.Additionally,it emphasizes the importance of optimizing extraction and detection technologies to enhance its application value in medicine and other industries,thereby promoting the development of Gannan’s sweet orange industry.展开更多
As one of the most widely distributed and highly conserved transcription factors in eukaryotes,basic leucine zipper proteins(bZIPs)are involved in a variety of biological processes in plants,but they are largely unkno...As one of the most widely distributed and highly conserved transcription factors in eukaryotes,basic leucine zipper proteins(bZIPs)are involved in a variety of biological processes in plants,but they are largely unknown in citrus.In this study,56 bZIP family members were identified genome-wide from an important citrus rootstock,namely trifoliate orange(Poncirus trifoliata L.Raf.),and these putative bZIPs were named PtbZIP1—PtbZIP56.All PtbZIPs were classified into 13 subgroups by phylogenetic comparison with Arabidopsis thaliana bZIPs(AtbZIPs),and they were randomly distributed on nine known(50 genes)chromosomes and one unknown(6 genes)chromosome.Sequence analysis revealed the detailed characteristics of PtPZIPs,including their amino acid length,isoelectric point(pI),molecular weight(MW),predicted subcellular localization,gene structure,and conserved motifs.Prediction of promoter elements suggested the presence of drought,low-temperature,wound,and defense and stress responsive elements,as well as multiple hormone-responsive cis-acting elements.Spatiotemporal expression analysis showed the transcriptional patterns of PtbZIPs in different tissues and under dehydration,high salt,ABA,and IAA treatments.In addition,21 PtbZIPs were predicted to have direct or indirect protein—protein interactions.Among these,PtbZIP49 was experimentally proven to interact with PtbZIP1 or PtbZIP11 by using a yeast two-hybrid assay and bimolecular fluorescence complementation(BiFC).Subcellular localization analysis further revealed that PtbZIP1,PtbZIP11,and PtbZIP49 were localized in the nucleus.Moreover,PtbZIP49 was functionally identified as having an important role in salt stress via ectopic expression in A.thaliana and silenced in trifoliate orange using virus-induced gene silencing(VIGS).This study provided comprehensive information on PtbZIP transcription factors in citrus and highlights their potential functions in abiotic stress.展开更多
Dye pollution is a common pollutant in wastewater that poses a serious threat to human health.Layered double hydroxide(LDH)is a commonly used adsorbent for dye removal.However,its adsorption efficiency is significantl...Dye pollution is a common pollutant in wastewater that poses a serious threat to human health.Layered double hydroxide(LDH)is a commonly used adsorbent for dye removal.However,its adsorption efficiency is significantly limited by the limited adsorption active sites of the adsorbent.In this paper,a defects-rich MgFe LDH adsorbent for anionic dye wastewater was synthesized by a simple hydrothermal method and alkaline etching.Different analytical techniques,such as XRD,FT-IR,SEM,TEM,XPS,and N2 adsorption-desorption isotherm,were used to verify the chemical composition and surface characteristics of the materials,and the effects of pH,temperature,and contact time on the adsorption effect of methyl orange and the adsorption mechanism were analyzed.Alkaline etching of Al and Zn in the laminate generated defects that expose unsaturated coordination centers and create abundant adsorption sites,which can electrostatically attract and coordinate with dye ions.At 25℃,the adsorption capacity of MgFe LDH with Al etched and MgFe LDH with Zn etched for methyl orange dye reached 1722 mg·g^(-1 ) and 1685 mg·g^(-1 ),respectively,much higher than that of MgFe LDH(544 mg·g^(-1 )).This work provides a promising method for the removal of dye wastewater by adsorption and a new idea for the design and development of high-performance dye wastewater adsorbents.展开更多
The exploration and research of low-cost,environmentally friendly,and sustainable organic semiconductor materials are of immense significance in various fields,including electronics,optoelectronics,and energy conversi...The exploration and research of low-cost,environmentally friendly,and sustainable organic semiconductor materials are of immense significance in various fields,including electronics,optoelectronics,and energy conversion.Unfortunately,these semiconductors have almost poor charge transport properties,which range from∼10^(−4) cm^(2)·V^(−1)·s^(−1) to∼10^(−2) cm^(2)·V^(−1)·s^(−1).Vat orange 3,as one of these organic semiconductors,has great potential due to its highly conjugated structure.We obtain high-quality multilayered Vat orange 3 crystals with two-dimensional(2D)growth on h-BN surfaces with thickness of 10–100 nm using physical vapor transport.Raman’s results confirm the stability of the chemical structure of Vat orange 3 during growth.Furthermore,by leveraging the structural advantages of 2D materials,an organic field-effect transistor with a 2D vdW vertical heterostructure is further realized with h-BN encapsulation and multilayered graphene contact electrodes,resulting in an excellent transistor performance with On/Off ratio of 104 and high field-effect mobility of 0.14 cm^(2)·V^(−1)·s^(−1).Our results show the great potential of Vat orange 3 with 2D structures in future nano-electronic applications.Furthermore,we showcase an approach that integrates organic semiconductors with 2D materials,aiming to offer new insights into the study of organic semiconductors.展开更多
The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable po...The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable pollutants such as methyl orange which make their degradation difficult. It is therefore necessary to find new, more effective techniques for the treatment of these discharges. Among the different solutions proposed to deal with this problem, we find advanced oxidation processes (POAs) which are clean and promising technologies in the field of wastewater depollution. In this regard, heterogeneous photocatalysis was used in an aqueous suspension of titanium oxide (TiO2) using a ultraviolet (UV) lamp as artificial radiation. The objective of this work is to study the influence of some operating parameters such as: the catalyst mass, the initial pollutant concentration, the volume of the solution and the pH of the solution, were examined. The results obtained showed that this photocatalyst made it possible to degrade 99.85% of the initial concentration of methyl orange (10 ppm), after 240 min of irradiation with an optimal mass of 0.50 g of TiO2 for a volume of 200 mL of methyl orange solution at pH = 3.0.展开更多
Green synthesis of silver nanoparticles (AgNPs) using aqueous extracts of orange and lemon peels, as a reducing agent, and silver nitrate salts as a source of silver ions is a promising field of research due to the ve...Green synthesis of silver nanoparticles (AgNPs) using aqueous extracts of orange and lemon peels, as a reducing agent, and silver nitrate salts as a source of silver ions is a promising field of research due to the versatility of biomedical applications of metal nanoparticles. In this paper, AgNPs were synthetized at different reaction parameters such as the type and concentration of the extracts, metal salt concentration, temperature, speed stirring, and pH. The antibacterial properties of the obtained silver nanoparticles against E. coli, as well as the physical and chemical characteristics of the synthesized silver nanoparticles, were investigated. UV-Vis spectroscopy was used to confirm the formation of AgNPs. In addition to green biogenic synthesis, chemical synthesis of silver nanoparticles was also carried out. The optimal temperature for extraction was 65˚C, while for the synthesis of AgNPs was 35˚C. The synthesis is carried out in an acidic environment (pH = 4.7 orange and pH = 3.8 lemon), neutral (pH = 7) and alkaline (pH = 10), then for different concentrations of silver nitrate solution (0.5 mM - 1 mM), optimal time duration of the reaction was 60 min and optimal stirring speed rotation was 250 rpm on the magnetic stirrer. The physical properties of the synthesized silver nanoparticles (conductivity, density and refractive index) were also studied, and the passage of laser light through the obtained solution and distilled water was compared. Positive inhibitory effect on the growth of new Escherichia coli colonies have shown AgNPs synthesized at a basic pH value and at a 0.1 mM AgNO<sub>3</sub> using orange or lemon peel extract, while for a 0.5 mM AgNO<sub>3 </sub>using lemon peel extract.展开更多
With the arrival of the 4G and 5G,the telecommunications networks have experienced a large expansion of these networks.That enabled the integration of many services and adequate flow,thus enabling the operators to res...With the arrival of the 4G and 5G,the telecommunications networks have experienced a large expansion of these networks.That enabled the integration of many services and adequate flow,thus enabling the operators to respond to the growing demand of users.This rapid evolution has given the operators to adapt,their methods to the new technologies that increase.This complexity becomes more important,when these networks include several technologies to access different from the heterogeneous network like in the 4G network.The dimensional new challenges tell the application and the considerable increase in demand for services and the compatibility with existing networks,the management of mobility intercellular of users and it offers a better quality of services.Thus,the proposed solution to meet these new requirements is the sizing of the EPC(Evolved Packet Core)core network to support the 5G access network.For the case of Orange Guinea,this involves setting up an architecture for interconnecting the core networks of Sonfonia and Camayenne.The objectives of our work are of two orders:(1)to propose these solutions and recommendations for the heart network EPC sizing and the deployment to be adopted;(2)supply and architectural interconnection in the heart network EPC and an existing heart network.In our work,the model of traffic in communication that we use to calculate the traffic generated with each technology has link in the network of the heart.展开更多
The flavonoid content in orange peels of different Brazilian citrus varieties such as bahia, lima, lima-of-persian, morcote, pera, ponkan, seleta, cravo, kinkan and pomelo was assessed. Industry processing juice waste...The flavonoid content in orange peels of different Brazilian citrus varieties such as bahia, lima, lima-of-persian, morcote, pera, ponkan, seleta, cravo, kinkan and pomelo was assessed. Industry processing juice wastes such as bagasse, bagasse residues, animal feeding bagasse, pulp WEUE and CORE-wash were also analyzed. The HPLC analysis indicates that the most abundant flavonoids found in these Brazilian citrus peels are hesperidin and naringin. The solvents used are selective for flavonoid extraction, and depending on their polarity, glycoside or aglycone flavonoids are extracted. The use of multivariate analysis shows that DMSO is the best solvent to extract glycosides flavanones while hexane displays high selectivity in the extraction of polymethoxylated flavones. The flavonoids present in the orange wastes, obtained at different stages of the industrial processing, are qualitative and quantitatively different. The identification and quantification of the flavonoid composition in each Brazilian citrus variety were evaluated and allowed the selection of the best solvent for the extraction of each specific class of flavonoids. These compounds were found to be more abundant in the fruit peels than in their juices, revealing their great industrial potential. The residual portion of the processing juices is also rich in flavonoids, depending on the processing step.展开更多
A novel adsorbent was prepared by modifying orange peel with sodium hydroxide and calcium chloride. The morphological and characteristics of the adsorbent were evaluated by infrared spectroscopy （IR）, scanning elect...A novel adsorbent was prepared by modifying orange peel with sodium hydroxide and calcium chloride. The morphological and characteristics of the adsorbent were evaluated by infrared spectroscopy （IR）, scanning electron microscopy （SEM） and N2-adsorption techniques. The adsorption behavior of Cu^2＋, Pb^2＋ and Zn^2＋ on modified orange peel （SCOP） was studied by varying parameters like pH, initial concentration of metal ions. Equilibrium was well described by Langmuir equation with the maximum adsorption capacities for Cu^2＋, Pb^2＋ and Zn^2＋ of 70.73, 209.8 and 56.18 mg/g, respectively. Based on the results obtained in batch experiments, breakthrough profiles were examined using a column packed with SCOP for the separation of small concentration of Pb^2＋ from an excess of Zn^2＋ followed by elution tests. Ion exchange with Ca^2＋ neutralizing the carboxyl groups of the pectin was found to be the predominant mechanism.展开更多
Viscose activated carbon fibers （ACFs） were characterized using specific surface area, scanning electron modified with chemical vapor deposition （CVD）. The samples were microscopy （SEM）, pore size distribution a...Viscose activated carbon fibers （ACFs） were characterized using specific surface area, scanning electron modified with chemical vapor deposition （CVD）. The samples were microscopy （SEM）, pore size distribution and Fourier transform infrared spectroscopy （FTIR）. Batch adsorption experiments were carried out to investigate the adsorption behavior of modified ACFs for methyl orange（MO） from its aqueous solutions. The results show that the adsorption isotherms of MO onto modified ACFs well follows the Langmuir isotherm equation. The adsorption kinetics of MO can be well described by the pseudo second-order kinetic model. The adsorption process involves the intra-particle diffusion, but is not the only rate-controlling step. Thermodynamic parameters including AG, AH and AS were calculated, suggesting that the adsorption of MO onto modified ACFs is a spontaneous, exothermic and physisorption process. FTIR result indicates that the major adsorption mechanism of modified ACFs for MO is hydrogen bond.展开更多
The dynamic concentrations of glucose, fructose, sucrose and total sugar were determined through exogenous ABA and GA3 treatments during young period of fruit and before fruit coloring in pulp of ‘Cara cara’ navel o...The dynamic concentrations of glucose, fructose, sucrose and total sugar were determined through exogenous ABA and GA3 treatments during young period of fruit and before fruit coloring in pulp of ‘Cara cara’ navel orange. The results are as fol ows： 10 mg/L ABA increased glucose, fructose and total sugar concen-tration significantly or very significantly, ABA treatment of 50 mg/L increased sucrose concentration very significantly, but ABA treatment of 100 mg/L decreased glucose concentration very significantly. GA3 treatment of lower and middle concentrations（10, 50 and 250 mg/L） increased sucrose concentration very significantly, GA3 treatment of 10 mg/L had no remarkable effect on glucose and fructose concentration but in-creased total sugar concentration very significantly, GA3 treatment of 50, 250 and 500 mg/L decreased glucose, fructose and total sugar concentration very significant-ly. Therefore, ABA treatment of lower concentration could increase one or several kinds of sugar concentration, but GA3 treatment of higher concentration （250 and 500 mg/L） restrained sugar concentration in pulp of ‘Cara cara’ navel orange seri-ously.展开更多
The optimal process for orange vinegar was investigated in order to explore the effect of process parameters and obtain the superior process parameters.The process for orange vinegar was optimized using single-factor ...The optimal process for orange vinegar was investigated in order to explore the effect of process parameters and obtain the superior process parameters.The process for orange vinegar was optimized using single-factor methodology and Box-behnken methodology, and the effect of process parameters was analyzed in the light of response surface plots. Results were as follows. The optimal process of alcohol fermentation was as follows： original sugar degree of 16%, yeast inoculum size of 5% and p H value of 3.5 through single-factor experiment. The optimal fermentation process of acetic acid optimized by response surface methodology was as follows： inoculum size of 8.52%, original alcohol content of 6.0% and p H value of 3.3, in the optimal condition the yield of acetic acid was 53.11 g/L. Single factor action and the interaction of two factors were presented on the yield of acetic acid.The effects of inoculum size and p H were extremely significant, and that of original alcohol content significant. The interaction of inoculum size and original alcohol content was non-significant, that of inoculum size and p H also non-significant. On contrast, original alcohol content and p H had significant interaction.展开更多
文摘针对目前矿石检测技术准确性不高、效率低、实时性差以及环境适应性弱等问题,提出了一种基于香橙派的矿石识别系统。该系统利用高清摄像头实时捕获矿石图像,并通过香橙派Orange Pi 5B开发板搭载YOLOv4-tiny-tf2模型处理图像数据,实现矿石种类的高效准确识别。结果表明:轻量化的YOLOv4-tiny-tf2模型在不牺牲模型精度的情况下简化了其结构,更适合在配置较低的设备上部署,具备了较高的便携性;相较于传统的人工视觉检测和化学分析方法,基于香橙派Orange Pi 5B的矿石识别系统能够实时识别矿石,识别准确率达到93.75%,具有较高的可靠性和稳定性。
文摘Traumatic brain injury(TBI)is a public health problem with an undue economic burden that impacts nearly every age,ethnic,and gender group across the globe(Capizzi et al.,2020).TBIs are often sustained during a dynamic range of exposures to energetic environmental forces and as such outcomes are typically heterogeneous regarding severity and pathology(Capizzi et al.,2020).
基金supported by the National Natural Science Foundation of China(No.51972095).
文摘Zirconia nanotube array films(ZNAF)prepared by anodic oxidation method were used as immobilization materials for acridine orange(AO),rhodamine B(RB)and AO-RB systems.A comparative study on their fluorescence emission intensity,fluorescence resonance energy transfer(FRET)and fluorescence detection of nitrite in aqueous solutions and on immobilization films with ZNAF as carriers was carried out.Results demonstrate that the solution pH values and immobilization on ZNAF have a great influence on the per-formance of these fluorescent molecules.Compared with aqueous solutions,the fluorescence emission in-tensity of AO and RB is considerably increased by immobilization,which is 8.0 and 4.2 times higher than the original,respectively.The energy transfer efficiency(E)of the AO-RB system increases from 40.9%to 84.8%by loading it on ZNAF.Moreover,after immobilization onto ZNAF,the fluorescence detection performance of nitrite is also significantly improved.The limit of detection decreases from 0.95 ng/mL to 0.22 ng/mL and the sensitivity increases from 939.18 to 15,031.68 mL/μg through loading AO onto ZNAF.
文摘Pectin is a natural polysaccharide with a complex structure consisting of linear and branched regions rich in galacturonic acid.The growing interest in orange peel pectin can be attributed to its abundant supply.According to statistics,about 10 million tons of orange peel waste are produced worldwide each year.Traditionally,the extraction and utilization of pectin have focused on its gelling,thickening,and stabilizing properties in food.However,as more and more research teams have found that pectin has good biocompatibility,biodegradability and easy chemical modification,its potential in drug delivery systems,tissue engineering,and wound healing is gradually being explored.This review focuses on orange peel pectin polysaccharides and discusses its traditional and modern extraction techniques,especially the advanced method of subcritical water extraction.This study also outlines the structural modifications of pectin such as methylation and acetylation,and introduces its antioxidant and anticancer biological activities and their emerging roles in the development of advanced biomaterials such as bone tissue engineering and fibre pad dressings.
基金Jiangxi University of Chinese Medicine Project(Project No.2024BSZR011)。
文摘Gannan sweet orange essential oil has garnered significant attention due to its diverse chemical composition and pharmacological activities.The main active ingredients include sabinene,limonene,and linalool,which exhibit antioxidant,anti-inflammatory,antibacterial,and analgesic properties.This essential oil has potential applications in the development of medicinal products.This paper reviews the primary chemical composition and pharmacological effects of Jiangxi orange flower essential oil,highlighting the need for future research to focus on its biological activity and clinical application potential.Additionally,it emphasizes the importance of optimizing extraction and detection technologies to enhance its application value in medicine and other industries,thereby promoting the development of Gannan’s sweet orange industry.
基金supported by grants from the National Natural Science Foundation of China(Grant Nos.32072550,31902084)the National Key Research and Development Program of China(Grant No.2018YFD1000300)。
文摘As one of the most widely distributed and highly conserved transcription factors in eukaryotes,basic leucine zipper proteins(bZIPs)are involved in a variety of biological processes in plants,but they are largely unknown in citrus.In this study,56 bZIP family members were identified genome-wide from an important citrus rootstock,namely trifoliate orange(Poncirus trifoliata L.Raf.),and these putative bZIPs were named PtbZIP1—PtbZIP56.All PtbZIPs were classified into 13 subgroups by phylogenetic comparison with Arabidopsis thaliana bZIPs(AtbZIPs),and they were randomly distributed on nine known(50 genes)chromosomes and one unknown(6 genes)chromosome.Sequence analysis revealed the detailed characteristics of PtPZIPs,including their amino acid length,isoelectric point(pI),molecular weight(MW),predicted subcellular localization,gene structure,and conserved motifs.Prediction of promoter elements suggested the presence of drought,low-temperature,wound,and defense and stress responsive elements,as well as multiple hormone-responsive cis-acting elements.Spatiotemporal expression analysis showed the transcriptional patterns of PtbZIPs in different tissues and under dehydration,high salt,ABA,and IAA treatments.In addition,21 PtbZIPs were predicted to have direct or indirect protein—protein interactions.Among these,PtbZIP49 was experimentally proven to interact with PtbZIP1 or PtbZIP11 by using a yeast two-hybrid assay and bimolecular fluorescence complementation(BiFC).Subcellular localization analysis further revealed that PtbZIP1,PtbZIP11,and PtbZIP49 were localized in the nucleus.Moreover,PtbZIP49 was functionally identified as having an important role in salt stress via ectopic expression in A.thaliana and silenced in trifoliate orange using virus-induced gene silencing(VIGS).This study provided comprehensive information on PtbZIP transcription factors in citrus and highlights their potential functions in abiotic stress.
基金the National Natural Science Foundation of China(21908012)the Natural Science Foundation of Chongqing,China(cstc2020jcyj-msxmX0875 and CSTB2022BSXM-JSX0021)+2 种基金Chongqing Postdoctoral Research Project Special Funding(2023CQBSHTB3110)Postgraduate Research and Innovation Project of Chongqing University of Science and Technology(YKJCX2220541)Major Enterprise Demand Projects with Open Bidding for Selecting the Best Candidates in Yichun City,China(2023JBGSXM05)for the financial support to this work.
文摘Dye pollution is a common pollutant in wastewater that poses a serious threat to human health.Layered double hydroxide(LDH)is a commonly used adsorbent for dye removal.However,its adsorption efficiency is significantly limited by the limited adsorption active sites of the adsorbent.In this paper,a defects-rich MgFe LDH adsorbent for anionic dye wastewater was synthesized by a simple hydrothermal method and alkaline etching.Different analytical techniques,such as XRD,FT-IR,SEM,TEM,XPS,and N2 adsorption-desorption isotherm,were used to verify the chemical composition and surface characteristics of the materials,and the effects of pH,temperature,and contact time on the adsorption effect of methyl orange and the adsorption mechanism were analyzed.Alkaline etching of Al and Zn in the laminate generated defects that expose unsaturated coordination centers and create abundant adsorption sites,which can electrostatically attract and coordinate with dye ions.At 25℃,the adsorption capacity of MgFe LDH with Al etched and MgFe LDH with Zn etched for methyl orange dye reached 1722 mg·g^(-1 ) and 1685 mg·g^(-1 ),respectively,much higher than that of MgFe LDH(544 mg·g^(-1 )).This work provides a promising method for the removal of dye wastewater by adsorption and a new idea for the design and development of high-performance dye wastewater adsorbents.
基金supported by the National Natural Science Foundation of China(Grant Nos.U21A6004,62375160,62274180,and 12004389).
文摘The exploration and research of low-cost,environmentally friendly,and sustainable organic semiconductor materials are of immense significance in various fields,including electronics,optoelectronics,and energy conversion.Unfortunately,these semiconductors have almost poor charge transport properties,which range from∼10^(−4) cm^(2)·V^(−1)·s^(−1) to∼10^(−2) cm^(2)·V^(−1)·s^(−1).Vat orange 3,as one of these organic semiconductors,has great potential due to its highly conjugated structure.We obtain high-quality multilayered Vat orange 3 crystals with two-dimensional(2D)growth on h-BN surfaces with thickness of 10–100 nm using physical vapor transport.Raman’s results confirm the stability of the chemical structure of Vat orange 3 during growth.Furthermore,by leveraging the structural advantages of 2D materials,an organic field-effect transistor with a 2D vdW vertical heterostructure is further realized with h-BN encapsulation and multilayered graphene contact electrodes,resulting in an excellent transistor performance with On/Off ratio of 104 and high field-effect mobility of 0.14 cm^(2)·V^(−1)·s^(−1).Our results show the great potential of Vat orange 3 with 2D structures in future nano-electronic applications.Furthermore,we showcase an approach that integrates organic semiconductors with 2D materials,aiming to offer new insights into the study of organic semiconductors.
文摘The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable pollutants such as methyl orange which make their degradation difficult. It is therefore necessary to find new, more effective techniques for the treatment of these discharges. Among the different solutions proposed to deal with this problem, we find advanced oxidation processes (POAs) which are clean and promising technologies in the field of wastewater depollution. In this regard, heterogeneous photocatalysis was used in an aqueous suspension of titanium oxide (TiO2) using a ultraviolet (UV) lamp as artificial radiation. The objective of this work is to study the influence of some operating parameters such as: the catalyst mass, the initial pollutant concentration, the volume of the solution and the pH of the solution, were examined. The results obtained showed that this photocatalyst made it possible to degrade 99.85% of the initial concentration of methyl orange (10 ppm), after 240 min of irradiation with an optimal mass of 0.50 g of TiO2 for a volume of 200 mL of methyl orange solution at pH = 3.0.
文摘Green synthesis of silver nanoparticles (AgNPs) using aqueous extracts of orange and lemon peels, as a reducing agent, and silver nitrate salts as a source of silver ions is a promising field of research due to the versatility of biomedical applications of metal nanoparticles. In this paper, AgNPs were synthetized at different reaction parameters such as the type and concentration of the extracts, metal salt concentration, temperature, speed stirring, and pH. The antibacterial properties of the obtained silver nanoparticles against E. coli, as well as the physical and chemical characteristics of the synthesized silver nanoparticles, were investigated. UV-Vis spectroscopy was used to confirm the formation of AgNPs. In addition to green biogenic synthesis, chemical synthesis of silver nanoparticles was also carried out. The optimal temperature for extraction was 65˚C, while for the synthesis of AgNPs was 35˚C. The synthesis is carried out in an acidic environment (pH = 4.7 orange and pH = 3.8 lemon), neutral (pH = 7) and alkaline (pH = 10), then for different concentrations of silver nitrate solution (0.5 mM - 1 mM), optimal time duration of the reaction was 60 min and optimal stirring speed rotation was 250 rpm on the magnetic stirrer. The physical properties of the synthesized silver nanoparticles (conductivity, density and refractive index) were also studied, and the passage of laser light through the obtained solution and distilled water was compared. Positive inhibitory effect on the growth of new Escherichia coli colonies have shown AgNPs synthesized at a basic pH value and at a 0.1 mM AgNO<sub>3</sub> using orange or lemon peel extract, while for a 0.5 mM AgNO<sub>3 </sub>using lemon peel extract.
文摘With the arrival of the 4G and 5G,the telecommunications networks have experienced a large expansion of these networks.That enabled the integration of many services and adequate flow,thus enabling the operators to respond to the growing demand of users.This rapid evolution has given the operators to adapt,their methods to the new technologies that increase.This complexity becomes more important,when these networks include several technologies to access different from the heterogeneous network like in the 4G network.The dimensional new challenges tell the application and the considerable increase in demand for services and the compatibility with existing networks,the management of mobility intercellular of users and it offers a better quality of services.Thus,the proposed solution to meet these new requirements is the sizing of the EPC(Evolved Packet Core)core network to support the 5G access network.For the case of Orange Guinea,this involves setting up an architecture for interconnecting the core networks of Sonfonia and Camayenne.The objectives of our work are of two orders:(1)to propose these solutions and recommendations for the heart network EPC sizing and the deployment to be adopted;(2)supply and architectural interconnection in the heart network EPC and an existing heart network.In our work,the model of traffic in communication that we use to calculate the traffic generated with each technology has link in the network of the heart.
文摘The flavonoid content in orange peels of different Brazilian citrus varieties such as bahia, lima, lima-of-persian, morcote, pera, ponkan, seleta, cravo, kinkan and pomelo was assessed. Industry processing juice wastes such as bagasse, bagasse residues, animal feeding bagasse, pulp WEUE and CORE-wash were also analyzed. The HPLC analysis indicates that the most abundant flavonoids found in these Brazilian citrus peels are hesperidin and naringin. The solvents used are selective for flavonoid extraction, and depending on their polarity, glycoside or aglycone flavonoids are extracted. The use of multivariate analysis shows that DMSO is the best solvent to extract glycosides flavanones while hexane displays high selectivity in the extraction of polymethoxylated flavones. The flavonoids present in the orange wastes, obtained at different stages of the industrial processing, are qualitative and quantitatively different. The identification and quantification of the flavonoid composition in each Brazilian citrus variety were evaluated and allowed the selection of the best solvent for the extraction of each specific class of flavonoids. These compounds were found to be more abundant in the fruit peels than in their juices, revealing their great industrial potential. The residual portion of the processing juices is also rich in flavonoids, depending on the processing step.
基金Project (50774100) supported by the National Natural Science Foundation of China
文摘A novel adsorbent was prepared by modifying orange peel with sodium hydroxide and calcium chloride. The morphological and characteristics of the adsorbent were evaluated by infrared spectroscopy （IR）, scanning electron microscopy （SEM） and N2-adsorption techniques. The adsorption behavior of Cu^2＋, Pb^2＋ and Zn^2＋ on modified orange peel （SCOP） was studied by varying parameters like pH, initial concentration of metal ions. Equilibrium was well described by Langmuir equation with the maximum adsorption capacities for Cu^2＋, Pb^2＋ and Zn^2＋ of 70.73, 209.8 and 56.18 mg/g, respectively. Based on the results obtained in batch experiments, breakthrough profiles were examined using a column packed with SCOP for the separation of small concentration of Pb^2＋ from an excess of Zn^2＋ followed by elution tests. Ion exchange with Ca^2＋ neutralizing the carboxyl groups of the pectin was found to be the predominant mechanism.
基金Project (50802115) supported by the National Natural Science Foundation of ChinaProject (2010FJ4075) supported by Science and Technology Planning Project of Hunan Province, China+1 种基金Project (CDJJ-10010205) supported by the Science Foundation of Changsha University, ChinaProject supported by the Construct Program of the Key Discipline in Hunan Province, China
文摘Viscose activated carbon fibers （ACFs） were characterized using specific surface area, scanning electron modified with chemical vapor deposition （CVD）. The samples were microscopy （SEM）, pore size distribution and Fourier transform infrared spectroscopy （FTIR）. Batch adsorption experiments were carried out to investigate the adsorption behavior of modified ACFs for methyl orange（MO） from its aqueous solutions. The results show that the adsorption isotherms of MO onto modified ACFs well follows the Langmuir isotherm equation. The adsorption kinetics of MO can be well described by the pseudo second-order kinetic model. The adsorption process involves the intra-particle diffusion, but is not the only rate-controlling step. Thermodynamic parameters including AG, AH and AS were calculated, suggesting that the adsorption of MO onto modified ACFs is a spontaneous, exothermic and physisorption process. FTIR result indicates that the major adsorption mechanism of modified ACFs for MO is hydrogen bond.
基金Supported by Startup Foundation for Doctors of Yangtze University~~
文摘The dynamic concentrations of glucose, fructose, sucrose and total sugar were determined through exogenous ABA and GA3 treatments during young period of fruit and before fruit coloring in pulp of ‘Cara cara’ navel orange. The results are as fol ows： 10 mg/L ABA increased glucose, fructose and total sugar concen-tration significantly or very significantly, ABA treatment of 50 mg/L increased sucrose concentration very significantly, but ABA treatment of 100 mg/L decreased glucose concentration very significantly. GA3 treatment of lower and middle concentrations（10, 50 and 250 mg/L） increased sucrose concentration very significantly, GA3 treatment of 10 mg/L had no remarkable effect on glucose and fructose concentration but in-creased total sugar concentration very significantly, GA3 treatment of 50, 250 and 500 mg/L decreased glucose, fructose and total sugar concentration very significant-ly. Therefore, ABA treatment of lower concentration could increase one or several kinds of sugar concentration, but GA3 treatment of higher concentration （250 and 500 mg/L） restrained sugar concentration in pulp of ‘Cara cara’ navel orange seri-ously.
基金financially supported in part by Guangdong Province Ministry of industry university research project (No. 2013B090600032)Science and Technology Project Program of Guangdong Province (No. 2014B040404027)
文摘The optimal process for orange vinegar was investigated in order to explore the effect of process parameters and obtain the superior process parameters.The process for orange vinegar was optimized using single-factor methodology and Box-behnken methodology, and the effect of process parameters was analyzed in the light of response surface plots. Results were as follows. The optimal process of alcohol fermentation was as follows： original sugar degree of 16%, yeast inoculum size of 5% and p H value of 3.5 through single-factor experiment. The optimal fermentation process of acetic acid optimized by response surface methodology was as follows： inoculum size of 8.52%, original alcohol content of 6.0% and p H value of 3.3, in the optimal condition the yield of acetic acid was 53.11 g/L. Single factor action and the interaction of two factors were presented on the yield of acetic acid.The effects of inoculum size and p H were extremely significant, and that of original alcohol content significant. The interaction of inoculum size and original alcohol content was non-significant, that of inoculum size and p H also non-significant. On contrast, original alcohol content and p H had significant interaction.
