A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acid...A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased.展开更多
A SiC/ZrSiO4？SiO2 （SZS） coating was successfully fabricated on the carbon/carbon （C/C） composites by pack cementation, slurry painting and sintering to improve the anti-oxidation property and thermal shock r...A SiC/ZrSiO4？SiO2 （SZS） coating was successfully fabricated on the carbon/carbon （C/C） composites by pack cementation, slurry painting and sintering to improve the anti-oxidation property and thermal shock resistance. The anti-oxidation properties under different oxygen partial pressures （OPP） and thermal shock resistance of the SZS coating were investigated. The results show that the SZS coated sample under low OPP, corresponding to the ambient air, during isothermal oxidation was 0.54% in mass gain after 111 h oxidation at 1500 ° C and less than 0.03% in mass loss after 50 h oxidation in high OPP, corresponding to the air flow rate of 36 L/h. Additionally, the residual compressive strengths （RCS） of the SZS coated samples after oxidation for 50 h in high OPP and 80 h in low OPP remain about 70% and 72.5% of those of original C/C samples, respectively. Moreover, the mass loss of SZS coated samples subjected to the thermal cycle from 1500 ° C in high OPP to boiling water for 30 times was merely 1.61%.展开更多
Ultra fine SO 2- 4/TiO 2-SiO 2 complex catalysts were synthesized by the one-step calcination method,which used titania sulfate and white carbon as raw materials and polyvinyl alcohol as dispersing agent. Catalysts ar...Ultra fine SO 2- 4/TiO 2-SiO 2 complex catalysts were synthesized by the one-step calcination method,which used titania sulfate and white carbon as raw materials and polyvinyl alcohol as dispersing agent. Catalysts are characterized by XRDIRTDA and BET. Different preparation factors were discussed.The catalysts consisting of SO 2- 43.4% and TiO 2∶SiO 2=1∶6 showed excellent reaction activity and stability for the photocatalytic degradation of phenol.Controlling calcination temperature and time (450℃,2h) could avoid or diminish the formation of Ti-O-Si bond and obtain higher V g and better dispersivity of TiO 2 on the surface of SiO 2.The kinetic study on photocatalytic degradation of phenol with the complex catalysts in a suspension system under 40W UV-lamp showed that apparent rate constant k conformed to a zero-order kinetic model at initial concentration <100mg·L -1 and increased with increasing pH value of phenol solution up to pH=12.When pH=10,k=3.32×10 -1 mg·L -1 ·min -1 . Solar photocatalytic experiment also gave good results.展开更多
文摘A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased.
基金Supported by the Natural Science Foundation of Hunan Province(0 0 JJY2 0 1 1 0 ) and Scientific Re-search Fund of Hunan Provincial Education Department(0 1 C0 2 2
基金Project supported by the Nonferrous Metal Oriented Advanced Structural Materials and Manufacturing Cooperative Innovation Center,ChinaProject(51205417)supported by the National Natural Science Foundation of China
文摘A SiC/ZrSiO4？SiO2 （SZS） coating was successfully fabricated on the carbon/carbon （C/C） composites by pack cementation, slurry painting and sintering to improve the anti-oxidation property and thermal shock resistance. The anti-oxidation properties under different oxygen partial pressures （OPP） and thermal shock resistance of the SZS coating were investigated. The results show that the SZS coated sample under low OPP, corresponding to the ambient air, during isothermal oxidation was 0.54% in mass gain after 111 h oxidation at 1500 ° C and less than 0.03% in mass loss after 50 h oxidation in high OPP, corresponding to the air flow rate of 36 L/h. Additionally, the residual compressive strengths （RCS） of the SZS coated samples after oxidation for 50 h in high OPP and 80 h in low OPP remain about 70% and 72.5% of those of original C/C samples, respectively. Moreover, the mass loss of SZS coated samples subjected to the thermal cycle from 1500 ° C in high OPP to boiling water for 30 times was merely 1.61%.
文摘Ultra fine SO 2- 4/TiO 2-SiO 2 complex catalysts were synthesized by the one-step calcination method,which used titania sulfate and white carbon as raw materials and polyvinyl alcohol as dispersing agent. Catalysts are characterized by XRDIRTDA and BET. Different preparation factors were discussed.The catalysts consisting of SO 2- 43.4% and TiO 2∶SiO 2=1∶6 showed excellent reaction activity and stability for the photocatalytic degradation of phenol.Controlling calcination temperature and time (450℃,2h) could avoid or diminish the formation of Ti-O-Si bond and obtain higher V g and better dispersivity of TiO 2 on the surface of SiO 2.The kinetic study on photocatalytic degradation of phenol with the complex catalysts in a suspension system under 40W UV-lamp showed that apparent rate constant k conformed to a zero-order kinetic model at initial concentration <100mg·L -1 and increased with increasing pH value of phenol solution up to pH=12.When pH=10,k=3.32×10 -1 mg·L -1 ·min -1 . Solar photocatalytic experiment also gave good results.
