This paper discusses the findings of the first car MAX-DOAS（multi-axis differential optical absorption spectroscopy） field campaign（300 km long） along the National Highway-05（N5-Highway） of Pakistan conducted on...This paper discusses the findings of the first car MAX-DOAS（multi-axis differential optical absorption spectroscopy） field campaign（300 km long） along the National Highway-05（N5-Highway） of Pakistan conducted on 13 and 14 November, 2012. The main objective of the field campaign was to assess the spatial distribution of tropospheric nitrogen dioxide（NO_2）columns and corresponding concentrations along the N5-Highway from Islamabad to Lahore.Source identification of NO_2 revealed that the concentrations were higher within major cities along the highway. The highest NO_2 vertical column densities（NO_2VCDs） were found around two major cities of Rawalpindi and Lahore. This study also presents a comparison of NO_2 VCDs measured by the ozone monitoring instrument（OMI） and car MAX-DOAS observations. The comparison revealed similar spatial distribution of the NO_2 columns with both car MAX-DOAS and satellite observations, but the car MAX-DOAS observations show much more spatial details. Maximum NO_2 VCD retrieved from car MAX-DOAS observations was up to an order of magnitude larger than the OMI observations in urban areas.展开更多
The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when th...The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when the cations are the same and the anions are different,in complex 1,Na^(+)closes one port of CyB5Q[5]through Na—O seven coordination bonds to form a molecular bowl;in complex 3,Na^(+)completely closes the two ports of CyB5Q[5]to form a molecular capsule with six Na—O coordination bonds;in complexes 2 and 4,the two ports of CyB5Q[5]are completely closed to form K—O coordinated molecular capsules,but the K^(+)of complex 2 is six-coordinated and that of complex 4 is eight-/nine-coordinated.and complex 4 are connected by three oxygen bridges to form a 1D molecular chain.CCDC:2457122,1;2457121,2;2457400,3;2457120,4.展开更多
基金financial support as Master thesis research fund to conduct this study
文摘This paper discusses the findings of the first car MAX-DOAS（multi-axis differential optical absorption spectroscopy） field campaign（300 km long） along the National Highway-05（N5-Highway） of Pakistan conducted on 13 and 14 November, 2012. The main objective of the field campaign was to assess the spatial distribution of tropospheric nitrogen dioxide（NO_2）columns and corresponding concentrations along the N5-Highway from Islamabad to Lahore.Source identification of NO_2 revealed that the concentrations were higher within major cities along the highway. The highest NO_2 vertical column densities（NO_2VCDs） were found around two major cities of Rawalpindi and Lahore. This study also presents a comparison of NO_2 VCDs measured by the ozone monitoring instrument（OMI） and car MAX-DOAS observations. The comparison revealed similar spatial distribution of the NO_2 columns with both car MAX-DOAS and satellite observations, but the car MAX-DOAS observations show much more spatial details. Maximum NO_2 VCD retrieved from car MAX-DOAS observations was up to an order of magnitude larger than the OMI observations in urban areas.
文摘The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when the cations are the same and the anions are different,in complex 1,Na^(+)closes one port of CyB5Q[5]through Na—O seven coordination bonds to form a molecular bowl;in complex 3,Na^(+)completely closes the two ports of CyB5Q[5]to form a molecular capsule with six Na—O coordination bonds;in complexes 2 and 4,the two ports of CyB5Q[5]are completely closed to form K—O coordinated molecular capsules,but the K^(+)of complex 2 is six-coordinated and that of complex 4 is eight-/nine-coordinated.and complex 4 are connected by three oxygen bridges to form a 1D molecular chain.CCDC:2457122,1;2457121,2;2457400,3;2457120,4.
