By taking Chongqing Nan Hot Spring Park as the research object,eight functional zones of the park has been selected as sampling spots,covering landscape facility zone at main entrance,garden zone at main entrance,lawn...By taking Chongqing Nan Hot Spring Park as the research object,eight functional zones of the park has been selected as sampling spots,covering landscape facility zone at main entrance,garden zone at main entrance,lawn garden zone,river walking facility zone,activity landscape facility zone,natural garden zone,VILLA facility zone,and trees preservation zone which are recorded as LG1,LG2,LG3,LG4,LG5,LG6,LG7 and LG8,respectively.It has investigated soil pH,the content of B,Cu,Zn and Fe in soils of the eight sampling spots.The results show that soil pH of each spot is equal to or larger than 7.5,indicating that the soils are neutral and alkaline;available Cu,Zn and Fe are abundant while available B is insuff icient.In view of the actual situation of each spot,it has proposed ecological restoration based on soil improvement,so as to provide a reference for plants disposition,later maintenance and soil restoration in the park in the future.展开更多
On the basis of sampling and testing for coal and its ash in power-plant, the changes of separation of minor elements from coal in burning process and the distribution and enrichment of minor elements in ashes were an...On the basis of sampling and testing for coal and its ash in power-plant, the changes of separation of minor elements from coal in burning process and the distribution and enrichment of minor elements in ashes were analyzed. The coal combustion tests were carried out at five different temperatures. The concentration of minor elements separated and the separation ratio were studied. Separation characteristic of minor elements from coal and coal gangue in the process of spontaneous combustion was also analyzed.展开更多
Geochemical characteristics of trace and minor elements in some strata of geosynclinal tectonic layer, platform tectonic layer, in granite of Diwa stage, altered rocks and wolframite in the Xiangdong Tungsten Mine are...Geochemical characteristics of trace and minor elements in some strata of geosynclinal tectonic layer, platform tectonic layer, in granite of Diwa stage, altered rocks and wolframite in the Xiangdong Tungsten Mine are systematically studied. Enrichment of W, Sn and Cu in geosynclinal tectonic layer could be one part of mineralization. Different types of alteration might result in variance of distribution of the same trace or minor element. mNb/mTa and mMn/mFe ratios, contents of Nb and Ta in wolframite vary with vein groups′ location.展开更多
In this paper, we developed a portable laser-induced breakdown spectroscopy(LIBS) using an optical fiber to deliver laser energy and used it to quantitatively analyze minor elements in steel.The R^2 factors of calibra...In this paper, we developed a portable laser-induced breakdown spectroscopy(LIBS) using an optical fiber to deliver laser energy and used it to quantitatively analyze minor elements in steel.The R^2 factors of calibration curves of elements Mn, Ti, V, and Cr in pig iron were 0.9965,0.9983, 0.9963, and 0.991, respectively, and their root mean square errors of cross-validation were 0.0501, 0.0054, 0.0205, and 0.0245 wt%, respectively. Six test samples were used for the validation of the performance of the calibration curves established by the portable LIBS. The average relative errors of elements Mn, Ti, V, and Cr were 2.5%, 11.7%, 13.0%, and 5.6%,respectively. These results were comparable with most results reported in traditional LIBS in steel or other matrices. However, the portable LIBS is flexible, compact, and robust, providing a promising prospect in industrial application.展开更多
An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is stud...An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.展开更多
基金Supported by Scientif ic Research Project of Chongqing Education Commission (KJ100704)~~
文摘By taking Chongqing Nan Hot Spring Park as the research object,eight functional zones of the park has been selected as sampling spots,covering landscape facility zone at main entrance,garden zone at main entrance,lawn garden zone,river walking facility zone,activity landscape facility zone,natural garden zone,VILLA facility zone,and trees preservation zone which are recorded as LG1,LG2,LG3,LG4,LG5,LG6,LG7 and LG8,respectively.It has investigated soil pH,the content of B,Cu,Zn and Fe in soils of the eight sampling spots.The results show that soil pH of each spot is equal to or larger than 7.5,indicating that the soils are neutral and alkaline;available Cu,Zn and Fe are abundant while available B is insuff icient.In view of the actual situation of each spot,it has proposed ecological restoration based on soil improvement,so as to provide a reference for plants disposition,later maintenance and soil restoration in the park in the future.
文摘On the basis of sampling and testing for coal and its ash in power-plant, the changes of separation of minor elements from coal in burning process and the distribution and enrichment of minor elements in ashes were analyzed. The coal combustion tests were carried out at five different temperatures. The concentration of minor elements separated and the separation ratio were studied. Separation characteristic of minor elements from coal and coal gangue in the process of spontaneous combustion was also analyzed.
文摘Geochemical characteristics of trace and minor elements in some strata of geosynclinal tectonic layer, platform tectonic layer, in granite of Diwa stage, altered rocks and wolframite in the Xiangdong Tungsten Mine are systematically studied. Enrichment of W, Sn and Cu in geosynclinal tectonic layer could be one part of mineralization. Different types of alteration might result in variance of distribution of the same trace or minor element. mNb/mTa and mMn/mFe ratios, contents of Nb and Ta in wolframite vary with vein groups′ location.
基金supported by National Natural Science Foundation of China (Grant Nos. 61705064 & 11647122)the Natural Science Foundation of Hubei Province (Grant Nos. 2018CFB773 & 2018CFB672)the Project of the Hubei Provincial Department of Education (Grant No. T201617)
文摘In this paper, we developed a portable laser-induced breakdown spectroscopy(LIBS) using an optical fiber to deliver laser energy and used it to quantitatively analyze minor elements in steel.The R^2 factors of calibration curves of elements Mn, Ti, V, and Cr in pig iron were 0.9965,0.9983, 0.9963, and 0.991, respectively, and their root mean square errors of cross-validation were 0.0501, 0.0054, 0.0205, and 0.0245 wt%, respectively. Six test samples were used for the validation of the performance of the calibration curves established by the portable LIBS. The average relative errors of elements Mn, Ti, V, and Cr were 2.5%, 11.7%, 13.0%, and 5.6%,respectively. These results were comparable with most results reported in traditional LIBS in steel or other matrices. However, the portable LIBS is flexible, compact, and robust, providing a promising prospect in industrial application.
基金The China Ocean Mineral Resources Research and Development Association Research Program of the State Oceanic Administration of China under contract No.DY125-13-R-07the National Natural Science Foundation of China under contract Nos 41322036 and 41230960+1 种基金the Shandong Provincial Natural Science Foundation of China under contract No.ZR2014DP009the Special Basic Research Funds for Central Public Research Institutes for The First Institute of Oceanography,State Oceanic Administration of China under contract Nos GY0213G06 and GY02-2012G35
文摘An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.
