Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and appl...Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and applications.However,most new materials are obtained in polycrystalline form or even as mixtures with multiple phases when first synthesized,presenting significant challenges in their structure determination and phase elucidation.Fortunately,the developed three-dimensional electron diffraction(3DED/MicroED)has provided a promising solution to overcome these challenges.In this study,we have constructed a state-of-the-art 3DED/MicroED data acquisition equipment by integrating a hybrid-pixel detector with a script developed for Serial EM,and thus successfully developed an automated 3DED/MicroED method for the high-throughput structure determination.To demonstrate its effectiveness,a multiphase sample with complex porous structures is employed,showcasing that individual phases and their structures can be identified and determined,respectively.One remarkable finding is the identification of an impurity metal-organic framework(MOF)that is completely invisible to traditional powder X-ray diffraction in a supposedly“pure”commercial MOF sample.Additionally,our method also enables the atomic-resolution structure determination of flexible covalent organic framework materials,which are highly sensitive to electron beams.Moreover,a new microporous aluminoborate is discovered using this rapid structure determination method.These experimental results highlight the enormous potential of our 3DED/MicroED method in the field of new materials discovery,offering a powerful tool for the structure determination of polycrystalline functional materials.展开更多
Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crysta...Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crystal X-ray diffraction(SCXRD)has traditionally been the primary method for elucidating such structures,but it demands large,high-quality crystals,often exceeding 5μm in size.The growth of these crystals can be a time-consuming process,especially for one-and two-dimensional materials.To explore structures at the nanoscale,MicroED(microcrystal electron diffraction(ED))offers unprecedented insights into the realm of nanomaterials.This revolutionary technique enables researchers to uncover intricate details within nanoscale structures,promising to reshape our fundamental understanding of materials.In this review,we delve into the applications of MicroED in the study of various porous materials,including zeolites,metal-organic frameworks(MOFs),and covalent organic frameworks(COFs).We emphasize the pivotal role of MicroED in nanomaterial characterization,enabling precise crystallographic analysis and phase identification.展开更多
Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematic...Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.展开更多
In the realm of secure information storage,optical encryption has emerged as a vital technique,particularly with the miniaturization of encryption devices.However,many existing systems lack the necessary reconfigurabi...In the realm of secure information storage,optical encryption has emerged as a vital technique,particularly with the miniaturization of encryption devices.However,many existing systems lack the necessary reconfigurability and dynamic functionality.This study presents a novel approach through the development of dynamic optical-to-chemical energy conversion metamaterials,which enable enhanced steganography and multilevel information storage.We introduce a micro-dynamic multiple encryption device that leverages programmable optical properties in coumarin-based metamaterials,achieved through a direct laser writing grayscale gradient strategy.This methodology allows for the dynamic regulation of photoluminescent characteristics and cross-linking networks,facilitating innovative steganographic techniques under varying light conditions.The integration of a multi-optical field control system enables real-time adjustments to the material’s properties,enhancing the device’s reconfigurability and storage capabilities.Our findings underscore the potential of these metamaterials in advancing the field of microscale optical encryption,paving the way for future applications in dynamic storage and information security.展开更多
Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always...Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.展开更多
The deployment of flexible zinc-ion batteries is impeded by dendrite growth from random anode defects.Conventional defect-elimination strategies often compromise flexibility and fail to achieve uniform interfaces.We p...The deployment of flexible zinc-ion batteries is impeded by dendrite growth from random anode defects.Conventional defect-elimination strategies often compromise flexibility and fail to achieve uniform interfaces.We propose a paradigm shift:reconfiguring random defects into engineered,monodisperse artificial micro-curves to homogenize electric fields and guide aligned zinc(Zn)deposition.Using moisture-assisted flash heating,we transform zincophilic silver(Ag)coatings on carbon fibers into uniformly dispersed micro-curved particles(Ag Particles@CC),creating identical nucleation sites with optimal zinc ion(Zn^(2+))adsorption energetics.Theoretical simulations confirm these structures eliminate localized field concentrations,enabling homogeneous plating/stripping.This design demonstrates remarkable performance,with ultrastable 1500 cycles at 10 mA cm^(-2)(98.6%avg.Coulombic efficiency)and symmetric cell operation>650 h(57.7 mV hysteresis).Crucially,interparticle discontinuities preserve intrinsic flexibility,enabling flexible pouch cells(Ag Particles@CC-Zn//NaV_(3)O_(8)·1,5H_(2)O)to successfully power wearable devices such as smartwatches and smartphones.This work establishes defect reconfiguration via artificial micro-curvature engineering as a universal strategy toward dendritesuppressed,flexible energy storage.展开更多
Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic condu...Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.展开更多
Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2)...Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.展开更多
The performance degradation of micro light-emitting diodes(micro-LEDs)is closely associated with the deterioration of sidewall passivation layers under prolonged electrical bias.We investigate reliability improvements...The performance degradation of micro light-emitting diodes(micro-LEDs)is closely associated with the deterioration of sidewall passivation layers under prolonged electrical bias.We investigate reliability improvements in 20μm×20μm InGaN/GaN blue micro-LEDs by suppressing the formation of an unstable interfacial layer during sidewall passivation.SiO_(2)is deposited on the etched mesa sidewalls using either Sputtering or plasma-enhanced chemical vapor deposition(PECVD).Comparative analysis reveals that PECVD-passivated devices experience more severe performance degradation,primarily due to the increased leakage current.After 100 h of accelerated aging,external quantum efficiency decreases by 44%in PECVD-passivated samples,whereas Sputter-passivated devices exhibit only an11%reduction.This discrepancy is attributed to the formation of a thicker and chemically unstable gallium oxynitride(Ga-O_(X)-N_(1-X))interfacial layer at the SiO_(2)∕GaN-based interface,which facilitates the generation of sidewall defects.Suppressing the formation of this interlayer enhances the crystallinity and structural stability of the passivation layer,thereby mitigating the activation of point defects.Notably,Sputter deposition is more effective in minimizing the formation of Ga-O-N interlayer.These findings emphasize the critical role of achieving low-defect-density sidewall passivation to improve the reliability of micro-LEDs for next-generation high-resolution display applications.展开更多
Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.Th...Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.The published version showed“Hongzhen Chen”,whereas the correct spelling should be“Hongzheng Chen”.The correct author name has been provided in this Correction,and the original article[1]has been corrected.展开更多
Aluminum scandium nitride(AlScN),an emergingⅢ-nitride semiconductor material,has attracted significant atten-tion in recent years due to its exceptional piezoelectric properties,high thermal stability,tunable bandgap...Aluminum scandium nitride(AlScN),an emergingⅢ-nitride semiconductor material,has attracted significant atten-tion in recent years due to its exceptional piezoelectric properties,high thermal stability,tunable bandgap,and excellent com-patibility with micro/nano fabrication.This paper systematically reviews the crystal structure,fundamental properties,and prop-erty modulation mechanisms of AlScN.It also summarizes recent progress in micro/nano fabrication technologies,including deposition,etching,and device integration.Furthermore,the applications of AlScN in diverse fields such as micro-electrome-chanical systems(MEMS),RF communications,energy conversion,optoelectronics and sensors are discussed.Finally,current challenges and promising future research directions for AlScN are outlined.展开更多
In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the...In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the grout-limestone interface induced by rock stress disturbances during mining.In this study,graphene oxide(GO)was integrated into cement-polyacrylate composite grout to improve its interfacial bonding.First,four-point bending tests were conducted,and the Monte Carlo method combined with the simplex search algorithm was employed to determine the variations in shear cohesion and static friction parameters.The results reveal that GO can significantly increase both the tensile and shear cohesion of the grout-limestone interface,but minimally affects the interfacial friction coefficient.Second,nuclear magnetic resonance(NMR)and scanning electron microscopy(SEM)tests were performed.The results indicate that GO nanosheets result in a squamaceous microstructure of the grout consolidation mass,increasing the adhesion of the grout-limestone interface.Moreover,spiny Aft(ettringite)clusters can be induced in limestone fracture surfaces by GO,which could serve as anchors for limestone and grout consolidation mass.展开更多
Micro/nano devices(MNDs)are characterized by miniaturization,high precision,and multifunctional integration,making them highly suitable for use in areas such as microrobotics,biomedical devices and electronic sensors....Micro/nano devices(MNDs)are characterized by miniaturization,high precision,and multifunctional integration,making them highly suitable for use in areas such as microrobotics,biomedical devices and electronic sensors.Their fabrication requires exceptional precision in structural integrity,material control,and functional integration.Traditional micro/nano fabrication techniques face inherent limitations in constructing complex three-dimensional(3D)architectures and integrating multiple materials.While additive manufacturing(AM)provides flexibility,challenges remain in material alignment control,microstructural organization,and multifunctional integration.To overcome these limitations,field-assisted additive manufacturing(FAM)has emerged as a promising approach that combines magnetic,acoustic,or electric fields to regulate material alignment,microstructural organization,and spatial alignment.This capability improves fabrication precision,enhances material anisotropy and facilitates functional integration.This review systematically explores the mechanisms,fabrication process,and functional integration of FAM in the framework of nozzle-based and vat photopolymerization-based,while further exploring their applications in microrobotics,biomedical devices,and electronic sensors.Moreover,this review provides a comparative overview of different FAM approaches,highlighting their respective characteristics,typical applications,and unique advantages.In addition,the major challenges facing FAM research are comprehensively assessed and future directions are explored,including advances in spatial precision control capability,intelligent control for process integration,and multi-field coupling optimization.This review establishes a foundational theoretical framework that can serve as a systematic reference for micro/nano manufacturing researchers to promote the development of FAM for high-performance micro/nano device fabrication.展开更多
Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and intro...Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.展开更多
Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency devia...Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency deviations,voltage fluctuations,and poor reactive power coordination,posing serious challenges to grid stability.Conventional Interconnection FlowControllers(IFCs)primarily regulate active power flowand fail to effectively handle dynamic frequency variations or reactive power sharing in multi-microgrid networks.To overcome these limitations,this study proposes an enhanced Interconnection Flow Controller(e-IFC)that integrates frequency response balancing and an Interconnection Reactive Power Flow Controller(IRFC)within a unified adaptive control structure.The proposed e-IFC is implemented and analyzed in DIgSILENT PowerFactory to evaluate its performance under various grid disturbances,including frequency drops,load changes,and reactive power fluctuations.Simulation results reveal that the e-IFC achieves 27.4% higher active power sharing accuracy,19.6% lower reactive power deviation,and 18.2% improved frequency stability compared to the conventional IFC.The adaptive controller ensures seamless transitions between grid-connected and islanded modes and maintains stable operation even under communication delays and data noise.Overall,the proposed e-IFCsignificantly enhances active-reactive power coordination and dynamic stability in renewable-integrated multi-microgrid systems.Future research will focus on coupling the e-IFC with tertiary-level optimization frameworks and conducting hardware-in-the-loop validation to enable its application in large-scale smart microgrid environments.展开更多
On January 19,2026,China's first structural interest rate cut of the year took effect.The People's Bank of China announced a 0.25 percentage point reduction in relending and rediscount rates,targeting key sect...On January 19,2026,China's first structural interest rate cut of the year took effect.The People's Bank of China announced a 0.25 percentage point reduction in relending and rediscount rates,targeting key sectors like small and micro enterprises(SMEs),technological innovation,and green transition.For the textile industry,where small and medium-sized enterprises account for over 90%of traditional manufacturing,the policy benefits will inject strong momentum into the high-quality development from multiple dimensions,including reduced financing costs,support for transformation funds,and expansion of foreign trade markets.展开更多
基金supported by the National Natural Science Foundation of China(22371121)the Natural Science Foundation of Jiangsu Province(BK20230772)the Fundamental Research Funds for Central Universities of China(020514380306)。
文摘Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and applications.However,most new materials are obtained in polycrystalline form or even as mixtures with multiple phases when first synthesized,presenting significant challenges in their structure determination and phase elucidation.Fortunately,the developed three-dimensional electron diffraction(3DED/MicroED)has provided a promising solution to overcome these challenges.In this study,we have constructed a state-of-the-art 3DED/MicroED data acquisition equipment by integrating a hybrid-pixel detector with a script developed for Serial EM,and thus successfully developed an automated 3DED/MicroED method for the high-throughput structure determination.To demonstrate its effectiveness,a multiphase sample with complex porous structures is employed,showcasing that individual phases and their structures can be identified and determined,respectively.One remarkable finding is the identification of an impurity metal-organic framework(MOF)that is completely invisible to traditional powder X-ray diffraction in a supposedly“pure”commercial MOF sample.Additionally,our method also enables the atomic-resolution structure determination of flexible covalent organic framework materials,which are highly sensitive to electron beams.Moreover,a new microporous aluminoborate is discovered using this rapid structure determination method.These experimental results highlight the enormous potential of our 3DED/MicroED method in the field of new materials discovery,offering a powerful tool for the structure determination of polycrystalline functional materials.
基金supported by the National Natural Science Foundation of China(No.22371121)the Fundamental Research Funds for the Central Universities(No.0205-14380306).
文摘Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crystal X-ray diffraction(SCXRD)has traditionally been the primary method for elucidating such structures,but it demands large,high-quality crystals,often exceeding 5μm in size.The growth of these crystals can be a time-consuming process,especially for one-and two-dimensional materials.To explore structures at the nanoscale,MicroED(microcrystal electron diffraction(ED))offers unprecedented insights into the realm of nanomaterials.This revolutionary technique enables researchers to uncover intricate details within nanoscale structures,promising to reshape our fundamental understanding of materials.In this review,we delve into the applications of MicroED in the study of various porous materials,including zeolites,metal-organic frameworks(MOFs),and covalent organic frameworks(COFs).We emphasize the pivotal role of MicroED in nanomaterial characterization,enabling precise crystallographic analysis and phase identification.
基金Supported by the Guangdong Provincial Natural Science Foundation(No.2114050001527).
文摘Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.
基金the National Key R&D Program of China(Project No.2022YFB4700100)National Natural Science Foundation of China(Grant Nos.61973298)+2 种基金Hong Kong Research Grants Council(GRF Project Number 11216120)the CAS-RGC Joint Laboratory Funding Scheme(Project Number JLFS/E-104/18)the Innovation Promotion Research Association of the Chinese Academy of Sciences(NO.2022199)。
文摘In the realm of secure information storage,optical encryption has emerged as a vital technique,particularly with the miniaturization of encryption devices.However,many existing systems lack the necessary reconfigurability and dynamic functionality.This study presents a novel approach through the development of dynamic optical-to-chemical energy conversion metamaterials,which enable enhanced steganography and multilevel information storage.We introduce a micro-dynamic multiple encryption device that leverages programmable optical properties in coumarin-based metamaterials,achieved through a direct laser writing grayscale gradient strategy.This methodology allows for the dynamic regulation of photoluminescent characteristics and cross-linking networks,facilitating innovative steganographic techniques under varying light conditions.The integration of a multi-optical field control system enables real-time adjustments to the material’s properties,enhancing the device’s reconfigurability and storage capabilities.Our findings underscore the potential of these metamaterials in advancing the field of microscale optical encryption,paving the way for future applications in dynamic storage and information security.
基金supported by Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2022QNRC001)the National Natural Science Foundation of China(No.52273053)the Chenguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA41)。
文摘Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.
基金supported by the National Natural Science Foundation of China(52202218)the Fundamental Research Funds for the Central Universities(CUSF-DH-T-2023044)。
文摘The deployment of flexible zinc-ion batteries is impeded by dendrite growth from random anode defects.Conventional defect-elimination strategies often compromise flexibility and fail to achieve uniform interfaces.We propose a paradigm shift:reconfiguring random defects into engineered,monodisperse artificial micro-curves to homogenize electric fields and guide aligned zinc(Zn)deposition.Using moisture-assisted flash heating,we transform zincophilic silver(Ag)coatings on carbon fibers into uniformly dispersed micro-curved particles(Ag Particles@CC),creating identical nucleation sites with optimal zinc ion(Zn^(2+))adsorption energetics.Theoretical simulations confirm these structures eliminate localized field concentrations,enabling homogeneous plating/stripping.This design demonstrates remarkable performance,with ultrastable 1500 cycles at 10 mA cm^(-2)(98.6%avg.Coulombic efficiency)and symmetric cell operation>650 h(57.7 mV hysteresis).Crucially,interparticle discontinuities preserve intrinsic flexibility,enabling flexible pouch cells(Ag Particles@CC-Zn//NaV_(3)O_(8)·1,5H_(2)O)to successfully power wearable devices such as smartwatches and smartphones.This work establishes defect reconfiguration via artificial micro-curvature engineering as a universal strategy toward dendritesuppressed,flexible energy storage.
基金financially supported by the National Key Research and Development Program(2022YFE0127400)the National Natural Science Foundation of China(52172040,52202041,and U23B2077)+1 种基金Taishan Scholar Project of Shandong Province(tsqn202211086,ts202208832,tsqnz20221118)the Fundamental Research Funds for the Central Universities(23CX06055A).
文摘Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.
基金supported by the National Natural Science Foundation of China(22168008,22378085)the Guangxi Natural Science Foundation(2024GXNSFDA010053)+1 种基金the Technology Development Project of Guangxi Bossco Environmental Protection Technology Co.,Ltd(202100039)Innovation Project of Guangxi Graduate Education(YCBZ2024065).
文摘Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.
基金supported by the Samsung Research Funding&Incubation Center of Samsung Electronics under Project No.SRFC-MA2402-05supported by the KENTECH Center for Shared Research Facilities。
文摘The performance degradation of micro light-emitting diodes(micro-LEDs)is closely associated with the deterioration of sidewall passivation layers under prolonged electrical bias.We investigate reliability improvements in 20μm×20μm InGaN/GaN blue micro-LEDs by suppressing the formation of an unstable interfacial layer during sidewall passivation.SiO_(2)is deposited on the etched mesa sidewalls using either Sputtering or plasma-enhanced chemical vapor deposition(PECVD).Comparative analysis reveals that PECVD-passivated devices experience more severe performance degradation,primarily due to the increased leakage current.After 100 h of accelerated aging,external quantum efficiency decreases by 44%in PECVD-passivated samples,whereas Sputter-passivated devices exhibit only an11%reduction.This discrepancy is attributed to the formation of a thicker and chemically unstable gallium oxynitride(Ga-O_(X)-N_(1-X))interfacial layer at the SiO_(2)∕GaN-based interface,which facilitates the generation of sidewall defects.Suppressing the formation of this interlayer enhances the crystallinity and structural stability of the passivation layer,thereby mitigating the activation of point defects.Notably,Sputter deposition is more effective in minimizing the formation of Ga-O-N interlayer.These findings emphasize the critical role of achieving low-defect-density sidewall passivation to improve the reliability of micro-LEDs for next-generation high-resolution display applications.
文摘Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.The published version showed“Hongzhen Chen”,whereas the correct spelling should be“Hongzheng Chen”.The correct author name has been provided in this Correction,and the original article[1]has been corrected.
基金supported by the National Natural Science Foundation of China(General Program,No.52473331).
文摘Aluminum scandium nitride(AlScN),an emergingⅢ-nitride semiconductor material,has attracted significant atten-tion in recent years due to its exceptional piezoelectric properties,high thermal stability,tunable bandgap,and excellent com-patibility with micro/nano fabrication.This paper systematically reviews the crystal structure,fundamental properties,and prop-erty modulation mechanisms of AlScN.It also summarizes recent progress in micro/nano fabrication technologies,including deposition,etching,and device integration.Furthermore,the applications of AlScN in diverse fields such as micro-electrome-chanical systems(MEMS),RF communications,energy conversion,optoelectronics and sensors are discussed.Finally,current challenges and promising future research directions for AlScN are outlined.
基金supported by the National Key R&D Program of China(Grant Nos.U25A20810 and 2024YFF0508201)the National Natural Science Foundation of China(Grant No.12302504).
文摘In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the grout-limestone interface induced by rock stress disturbances during mining.In this study,graphene oxide(GO)was integrated into cement-polyacrylate composite grout to improve its interfacial bonding.First,four-point bending tests were conducted,and the Monte Carlo method combined with the simplex search algorithm was employed to determine the variations in shear cohesion and static friction parameters.The results reveal that GO can significantly increase both the tensile and shear cohesion of the grout-limestone interface,but minimally affects the interfacial friction coefficient.Second,nuclear magnetic resonance(NMR)and scanning electron microscopy(SEM)tests were performed.The results indicate that GO nanosheets result in a squamaceous microstructure of the grout consolidation mass,increasing the adhesion of the grout-limestone interface.Moreover,spiny Aft(ettringite)clusters can be induced in limestone fracture surfaces by GO,which could serve as anchors for limestone and grout consolidation mass.
基金financial support from the National Natural Science Foundation of China(Nos.52205590,52575652,52322502,52175009)State Key Laboratory of Robotics and Systems(HIT)(No.SKLRS-2024-KF11)+3 种基金the Natural Science Foundation of Jiangsu Province(No.BK20220834)the Taihu Lake Innovation Fund for the School of Future Technology of Southeast University,the Start-up Research Fund of Southeast University(No.RF1028623098)the National Heilongjiang Providence Nature Science Foundation of China(YQ2022E022)the European Research Council(ERC)under the European Union’s Horizon Europe research and innovation programme(I-BOT Project,Grant Agreement No.101162939)。
文摘Micro/nano devices(MNDs)are characterized by miniaturization,high precision,and multifunctional integration,making them highly suitable for use in areas such as microrobotics,biomedical devices and electronic sensors.Their fabrication requires exceptional precision in structural integrity,material control,and functional integration.Traditional micro/nano fabrication techniques face inherent limitations in constructing complex three-dimensional(3D)architectures and integrating multiple materials.While additive manufacturing(AM)provides flexibility,challenges remain in material alignment control,microstructural organization,and multifunctional integration.To overcome these limitations,field-assisted additive manufacturing(FAM)has emerged as a promising approach that combines magnetic,acoustic,or electric fields to regulate material alignment,microstructural organization,and spatial alignment.This capability improves fabrication precision,enhances material anisotropy and facilitates functional integration.This review systematically explores the mechanisms,fabrication process,and functional integration of FAM in the framework of nozzle-based and vat photopolymerization-based,while further exploring their applications in microrobotics,biomedical devices,and electronic sensors.Moreover,this review provides a comparative overview of different FAM approaches,highlighting their respective characteristics,typical applications,and unique advantages.In addition,the major challenges facing FAM research are comprehensively assessed and future directions are explored,including advances in spatial precision control capability,intelligent control for process integration,and multi-field coupling optimization.This review establishes a foundational theoretical framework that can serve as a systematic reference for micro/nano manufacturing researchers to promote the development of FAM for high-performance micro/nano device fabrication.
基金financially supported by the China Scholarship Council(CSC)。
文摘Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.
基金the Deanship of Scientific Research at Northern Border University,Arar,Saudi Arabia,for funding this research work through the project number“NBU-FFR-2025-3623-11”.
文摘Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency deviations,voltage fluctuations,and poor reactive power coordination,posing serious challenges to grid stability.Conventional Interconnection FlowControllers(IFCs)primarily regulate active power flowand fail to effectively handle dynamic frequency variations or reactive power sharing in multi-microgrid networks.To overcome these limitations,this study proposes an enhanced Interconnection Flow Controller(e-IFC)that integrates frequency response balancing and an Interconnection Reactive Power Flow Controller(IRFC)within a unified adaptive control structure.The proposed e-IFC is implemented and analyzed in DIgSILENT PowerFactory to evaluate its performance under various grid disturbances,including frequency drops,load changes,and reactive power fluctuations.Simulation results reveal that the e-IFC achieves 27.4% higher active power sharing accuracy,19.6% lower reactive power deviation,and 18.2% improved frequency stability compared to the conventional IFC.The adaptive controller ensures seamless transitions between grid-connected and islanded modes and maintains stable operation even under communication delays and data noise.Overall,the proposed e-IFCsignificantly enhances active-reactive power coordination and dynamic stability in renewable-integrated multi-microgrid systems.Future research will focus on coupling the e-IFC with tertiary-level optimization frameworks and conducting hardware-in-the-loop validation to enable its application in large-scale smart microgrid environments.
文摘On January 19,2026,China's first structural interest rate cut of the year took effect.The People's Bank of China announced a 0.25 percentage point reduction in relending and rediscount rates,targeting key sectors like small and micro enterprises(SMEs),technological innovation,and green transition.For the textile industry,where small and medium-sized enterprises account for over 90%of traditional manufacturing,the policy benefits will inject strong momentum into the high-quality development from multiple dimensions,including reduced financing costs,support for transformation funds,and expansion of foreign trade markets.
