Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and appl...Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and applications.However,most new materials are obtained in polycrystalline form or even as mixtures with multiple phases when first synthesized,presenting significant challenges in their structure determination and phase elucidation.Fortunately,the developed three-dimensional electron diffraction(3DED/MicroED)has provided a promising solution to overcome these challenges.In this study,we have constructed a state-of-the-art 3DED/MicroED data acquisition equipment by integrating a hybrid-pixel detector with a script developed for Serial EM,and thus successfully developed an automated 3DED/MicroED method for the high-throughput structure determination.To demonstrate its effectiveness,a multiphase sample with complex porous structures is employed,showcasing that individual phases and their structures can be identified and determined,respectively.One remarkable finding is the identification of an impurity metal-organic framework(MOF)that is completely invisible to traditional powder X-ray diffraction in a supposedly“pure”commercial MOF sample.Additionally,our method also enables the atomic-resolution structure determination of flexible covalent organic framework materials,which are highly sensitive to electron beams.Moreover,a new microporous aluminoborate is discovered using this rapid structure determination method.These experimental results highlight the enormous potential of our 3DED/MicroED method in the field of new materials discovery,offering a powerful tool for the structure determination of polycrystalline functional materials.展开更多
Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crysta...Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crystal X-ray diffraction(SCXRD)has traditionally been the primary method for elucidating such structures,but it demands large,high-quality crystals,often exceeding 5μm in size.The growth of these crystals can be a time-consuming process,especially for one-and two-dimensional materials.To explore structures at the nanoscale,MicroED(microcrystal electron diffraction(ED))offers unprecedented insights into the realm of nanomaterials.This revolutionary technique enables researchers to uncover intricate details within nanoscale structures,promising to reshape our fundamental understanding of materials.In this review,we delve into the applications of MicroED in the study of various porous materials,including zeolites,metal-organic frameworks(MOFs),and covalent organic frameworks(COFs).We emphasize the pivotal role of MicroED in nanomaterial characterization,enabling precise crystallographic analysis and phase identification.展开更多
[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereoche...[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereochemistry,presents a significant challenge.Plumerubradins A-C(1-3),three novel iridoid glycoside[2+2]dimers featuring a highly functionalized cyclobutane core and multiple stereogenic centers,were isolated from the flowers of Plumeria rubra.Through biomimetic semisynthesis and chemical degradation of compounds 1-3,synthesis of phenylpropanoid-derived[2+2]dimers 7-10,combined with extensive spectroscopic analysis,single-crystal X-ray crystallography,and microcrystal electron diffraction experiments,the structures with absolute configurations of 1-3 were unequivocally elucidated.Furthermore,quantum mechanics-based^(1)H NMR iterative full spin analysis successfully established the correlations between the signal patterns of cyclobutane protons and the structural information of the cyclobutane ring in phenylpropanoid-derived[2+2]dimers,providing a diagnostic tool for the rapid structural elucidation of[2+2]-type cyclobutane derivatives.展开更多
The poor surface conditions and osseointegration capacity of 3D printed Ti6Al4V implants(3DPT)significantly influence their performance as orthopedic and dental implants.In this work,we creatively introduce a one-step...The poor surface conditions and osseointegration capacity of 3D printed Ti6Al4V implants(3DPT)significantly influence their performance as orthopedic and dental implants.In this work,we creatively introduce a one-step femtosecond laser treatment to improve the surface conditions and osteointegration.The surface characterization,mechanical properties,corrosion resistance,and biological responses were investigated.These results found that femtosecond laser eliminated defects like embedded powders and superficial cracks while forming the nano cones-like structures surface on 3DPT,leading to enhanced osseointegration,anti-corrosion,and anti-fatigue performance.Molecular dynamics simulations revealed the ablation removal mechanism and the formation of nano cone-like structures.These findings were further supported by the in vivo studies,showing that the FS-treated implants had superior bone-implant contact and osseointegration.Hence,the one-step femtosecond laser method is regarded as a promising surface modification method for improving the functional performance of Ti-based orthopedic implants.展开更多
3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have...3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have been limited. This study explores the impact of poly(vinylidene fluoride) and polydopamine-coated aluminum particles on the thermal and combustion properties of 3D printed hybrid rocket fuels. Physical self-assembly and anti-solvent methods were employed for constructing composite μAl particles. Characterization using SEM, XRD, XPS, FTIR, and μCT revealed a core-shell structure and homogeneous elemental distribution. Thermal analysis showed that PVDF coatings significantly increased the heat of combustion for aluminum particles, with maximum enhancement observed in μAl@PDA@PVDF(denoted as μAl@PF) at 6.20 k J/g. Subsequently, 3D printed fuels with varying pure and composite μAl particle contents were prepared using 3D printing. Combustion tests indicated higher regression rates for Al@PF/Resin composites compared to pure resin, positively correlating with particle content. The fluorocarbon-alumina reaction during the combustion stage intensified Al particle combustion, reducing residue size. A comprehensive model based on experiments provides insights into the combustion process of PDA and PVDF-coated droplets. This study advances the design of 3D-printed hybrid rocket fuels, offering strategies to improve regression rates and energy release, crucial for enhancing solid fuel performance for hybrid propulsion.展开更多
The micro-drama No Trivial Matters in Xicheng was awarded the title of Outstanding Online Micro-drama for 2024 by the National Radio and Television Administration.By depicting how community workers address people'...The micro-drama No Trivial Matters in Xicheng was awarded the title of Outstanding Online Micro-drama for 2024 by the National Radio and Television Administration.By depicting how community workers address people's livelihood concerns such as housing,transportation,and elderly care,the drama vividly showcases the warmth and responsibility in urban grassroots governance.展开更多
Micro/nano hierarchical structures could endow materials with various surface functions.However,the multilayer and multiscale characteristics of micro/nano hierarchical structures bring difficulties for their one step...Micro/nano hierarchical structures could endow materials with various surface functions.However,the multilayer and multiscale characteristics of micro/nano hierarchical structures bring difficulties for their one step and controllable fabrication.Accordingly,based on tip-based fabrication techniques,this study proposed a micro-amplitude vibration-assisted scratching method by introducing a periodic backward displacement into the conventional scratching process,which enabled the synchronous creation of the microscale V-groove and nanoscale ripples,i.e.a typical micro/nano hierarchical structure.The experiments and finite element modeling were employed to explore the formation process and mechanism of the micro/nano hierarchical structures.Being different from conventional cutting,this method was mainly based on the plow mechanism,and it could accurately replicate the shape of the indenter on the material surface.The microscale V-groove was formed due to the scratching action,and the nanoscale ripple was formed due to the extrusion action of the indenter on the microscale V-groove’s surface.Furthermore,the relationships between the processing parameters and the dimensions of the micro/nano hierarchical structures were established through experiments,and optimized processing parameters were determined to achieve regular micro/nano hierarchical structures.By this method,complex patterns constructed by various micro/nano hierarchical structures were fabricated on both flat and curved surfaces,achieving diverse surface structural colors.展开更多
Enzyme-powered micro/nanomotors(MNMs)(EMNMs)use natural enzymes to facilitate the decomposition of fuels,including hydrogen peroxide(H2O2),glucose,triglycerides,and urea to provide power.EMNMs can achieve self-propuls...Enzyme-powered micro/nanomotors(MNMs)(EMNMs)use natural enzymes to facilitate the decomposition of fuels,including hydrogen peroxide(H2O2),glucose,triglycerides,and urea to provide power.EMNMs can achieve self-propulsion through the in situ utilization of biofuels without additional fuels,exhibiting excellent biocompatibility and significant potential for application in the biomedical field.Compared with H_(2)O_(2),which may cause oxidative damage to the body,urea exhibits superior biosafety characteristics.Presently,urease-powered MNMs(UMNMs)have made notable progress in their applications in the biomedical field and have garnered considerable attention from researchers.In this review,we present the latest advancements in the biomedical field of UMNMs,primarily focusing on:1)diverse materials used for constructing the fundamental framework of motors;2)control of motor movement through the regulation of enzymatic reaction rates;and 3)research directions for the clinical application of motors,including in vivo imaging,biomarker detection,cancer treatment,optical therapy,overcoming biological barriers,antibacterial interventions,antithrombotic strategies,and gastric disease management.Despite showing immense potential in biomedical applications,there are still several challenges impeding its practical implementation,such as maintaining activity in the in vivo environment while accurately targeting specific sites to achieve the desired clinical therapeutic effects.展开更多
Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(F...Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(FWMRs)have garnered widespread attention among scientists due to their superior miniaturized aerodynamic theory,reduced noise,and enhanced resistance to disturbances in complex and diverse environments.Flying insects,it not only has remarkable flapping flight ability(wings),but also takeoff and landing habitat ability(legs).If the various functions of flying insects can be imitated,efficient biomimetic FWMRs can be produced.This paper provides a review of the flight kinematics,aerodynamics,and wing structural parameters of insects.Then,the traditional wings and folding wings of insect-inspired FWMRs were compared.The research progress in takeoff and landing of FWMRs was also summarized,and the future developments and challenges for insect-inspired FWMRs were discussed.展开更多
Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges...Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges in self-takeoff,which refers to taking off without both external device and energy input.In this study,a cliff-drop method is implemented for an independent takeoff of a heavy FWAV,relying solely on gravity.In the takeoff process using the cliff-drop method,the FWAV moves on the ground to a cliff edge using a wheel-driving motor and then descends from the cliff to achieve the necessary speed for flight.To demonstrate the cliff-drop method,the KAIST Robotic Hawk(KRoHawk)with a mass of 740 g and a wingspan of 120 cm is developed.The takeoff tests demonstrate that the KRoHawk,significantly heavier than the vertical-takeoff capable FWAVs,can successfully take off using the gravity-assisted takeoff method.The scalability of cliff-drop method is analyzed through simulations.When drop constraints are absent,the wheel-driving motor mass fraction for cliff-drop method remains negligible even as the vehicle's weight increases.When drop constraints are set to 4 m,FWAVs heavier than KRoHawk,weighing up to 4.4 kg,can perform the cliff-drop takeoffs with a wheel-driving motor mass fraction of less than 8%.展开更多
The prioritization of financial infrastructure construction serves as a crucial guarantee for the high-quality development of small and micro enterprises.However,resolving the financing challenges of small and micro e...The prioritization of financial infrastructure construction serves as a crucial guarantee for the high-quality development of small and micro enterprises.However,resolving the financing challenges of small and micro enterprises is not a task to be accomplished overnight.It necessitates the establishment of a long-term mechanism,the acceleration of financial innovation,the gradual enhancement of the vitality of micro-entities,and the creation of a stable and healthy economic development environment.Therefore,the author first analyzes the current financing situation of small and micro enterprises,as well as the problems they face during the process of financial innovation enabling small and micro enterprises to access financing and solve their financing difficulties,such as insufficient technical support,an imperfect risk control system,incomplete information disclosure,and a lack of credit data.Subsequently,targeted paths for financial innovation are proposed,aiming to offer suggestions for solving the financing problems of small and micro enterprises.展开更多
The wing of a butterfly consists of partially overlapping forewing and hindwing,and forewing sweeping can dynamically change the shape of the whole wing.In this work,the effect of forewing sweeping on aerodynamic perf...The wing of a butterfly consists of partially overlapping forewing and hindwing,and forewing sweeping can dynamically change the shape of the whole wing.In this work,the effect of forewing sweeping on aerodynamic performance of a butterfly like model is studied using a solver based on immersed boundary method and adaptive mesh.For aerodynamic performance,adding a"forward-backward-forward"sweeping motion to the forewing makes it more suitable for fast cruising flight,and compared to the situation without forewing sweeping,the drag is reduced by 46%and the lift to drag ratio is increased by 45%.On the contrary,adding a"backward-for ward-backward"sweeping motion to the forewing increases lift and makes it more suitable for climb flight.For downstroke and middle to late upstroke,the forewing sweeping affects the Leading-Edge Vortex(LEV)through two factors:sweeping velocity and forward sweeping angle,and their effects are coupled.A large forward sweeping velocity can enhance the strength of LEV,while a large forward sweeping angle can weaken it.For early upstroke,the forewing sweeping can affect the wake capture mechanism,sweeping backward can enhance it while sweeping forward can weaken it.The findings in this work provide insight into the design of butterfly like Micro AirVehicles(MAVs).展开更多
Microwave sensing technology has become increasingly widely applied in the biomedical field,playing a significant role in medical diagnosis,biological monitoring,and environmental warning.In recent years,the introduct...Microwave sensing technology has become increasingly widely applied in the biomedical field,playing a significant role in medical diagnosis,biological monitoring,and environmental warning.In recent years,the introduction of metamaterials has brought new possibilities and opportunities to microwave biosensors.This paper aims to explore the applications of microwave sensors in biosensing,with a particular emphasis on analyzing the crucial role of metamaterials in enhancing sensor performance and sensitivity.It provides a thorough examination of the fundamental principles,design strategies,fabrication techniques,and applications of microwave biosensors leveraging metamaterial enhancement.Moreover,it meticulously explores the latest applications spanning biomedical diagnostics,environmental monitoring,and food safety,shedding light on their transformative potential in healthcare,environmental sustainability,and food quality assurance.By delving into future research directions and confronting present challenges such as standardization and validation protocols,cost-effectiveness and scalability considerations and exploration of emerging applications,the paper provides a roadmap for advancing microwave biosensors with metamaterial enhancement,promising breakthroughs in multifaceted bioanalytical realms.展开更多
基金supported by the National Natural Science Foundation of China(22371121)the Natural Science Foundation of Jiangsu Province(BK20230772)the Fundamental Research Funds for Central Universities of China(020514380306)。
文摘Structure determination plays the most crucial role in the discovery of novel functional materials,because only by knowing the intrinsic structures can we accurately and completely understand their properties and applications.However,most new materials are obtained in polycrystalline form or even as mixtures with multiple phases when first synthesized,presenting significant challenges in their structure determination and phase elucidation.Fortunately,the developed three-dimensional electron diffraction(3DED/MicroED)has provided a promising solution to overcome these challenges.In this study,we have constructed a state-of-the-art 3DED/MicroED data acquisition equipment by integrating a hybrid-pixel detector with a script developed for Serial EM,and thus successfully developed an automated 3DED/MicroED method for the high-throughput structure determination.To demonstrate its effectiveness,a multiphase sample with complex porous structures is employed,showcasing that individual phases and their structures can be identified and determined,respectively.One remarkable finding is the identification of an impurity metal-organic framework(MOF)that is completely invisible to traditional powder X-ray diffraction in a supposedly“pure”commercial MOF sample.Additionally,our method also enables the atomic-resolution structure determination of flexible covalent organic framework materials,which are highly sensitive to electron beams.Moreover,a new microporous aluminoborate is discovered using this rapid structure determination method.These experimental results highlight the enormous potential of our 3DED/MicroED method in the field of new materials discovery,offering a powerful tool for the structure determination of polycrystalline functional materials.
基金supported by the National Natural Science Foundation of China(No.22371121)the Fundamental Research Funds for the Central Universities(No.0205-14380306).
文摘Porous materials have garnered significant attention in recent years.Understanding the intrinsic relationship between their structures and properties requires precise knowledge of their atomic structures.Single-crystal X-ray diffraction(SCXRD)has traditionally been the primary method for elucidating such structures,but it demands large,high-quality crystals,often exceeding 5μm in size.The growth of these crystals can be a time-consuming process,especially for one-and two-dimensional materials.To explore structures at the nanoscale,MicroED(microcrystal electron diffraction(ED))offers unprecedented insights into the realm of nanomaterials.This revolutionary technique enables researchers to uncover intricate details within nanoscale structures,promising to reshape our fundamental understanding of materials.In this review,we delve into the applications of MicroED in the study of various porous materials,including zeolites,metal-organic frameworks(MOFs),and covalent organic frameworks(COFs).We emphasize the pivotal role of MicroED in nanomaterial characterization,enabling precise crystallographic analysis and phase identification.
基金supported by the National Key R&D Program of China(No.2023YFC3503902)the National Natural Science Foundation of China(Nos.82293681(82293680)and 82321004)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(Nos.2022B1515120015 and 2021A1515111021)the Guangdong Major Project of Basic and Applied Basic Research(No.2023B0303000026)the Science and Technology Projects in Guangzhou(No.202102070001).
文摘[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereochemistry,presents a significant challenge.Plumerubradins A-C(1-3),three novel iridoid glycoside[2+2]dimers featuring a highly functionalized cyclobutane core and multiple stereogenic centers,were isolated from the flowers of Plumeria rubra.Through biomimetic semisynthesis and chemical degradation of compounds 1-3,synthesis of phenylpropanoid-derived[2+2]dimers 7-10,combined with extensive spectroscopic analysis,single-crystal X-ray crystallography,and microcrystal electron diffraction experiments,the structures with absolute configurations of 1-3 were unequivocally elucidated.Furthermore,quantum mechanics-based^(1)H NMR iterative full spin analysis successfully established the correlations between the signal patterns of cyclobutane protons and the structural information of the cyclobutane ring in phenylpropanoid-derived[2+2]dimers,providing a diagnostic tool for the rapid structural elucidation of[2+2]-type cyclobutane derivatives.
基金supported by the National Natural Science Foundation of China(No.U21A2055),Natural Science Foundation of Tianjin of China(No.21JCQNJC01280)Tianjin Key R&D Program Beijing-Tianjin-Hebei Collaborative Innovation Project(No.22YFXTHZ00120).
文摘The poor surface conditions and osseointegration capacity of 3D printed Ti6Al4V implants(3DPT)significantly influence their performance as orthopedic and dental implants.In this work,we creatively introduce a one-step femtosecond laser treatment to improve the surface conditions and osteointegration.The surface characterization,mechanical properties,corrosion resistance,and biological responses were investigated.These results found that femtosecond laser eliminated defects like embedded powders and superficial cracks while forming the nano cones-like structures surface on 3DPT,leading to enhanced osseointegration,anti-corrosion,and anti-fatigue performance.Molecular dynamics simulations revealed the ablation removal mechanism and the formation of nano cone-like structures.These findings were further supported by the in vivo studies,showing that the FS-treated implants had superior bone-implant contact and osseointegration.Hence,the one-step femtosecond laser method is regarded as a promising surface modification method for improving the functional performance of Ti-based orthopedic implants.
基金funded by the National Natural Science Foundation of China(Grant No.06101213)the National Natural Science Foundation of China(Grant No.22105160).
文摘3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have been limited. This study explores the impact of poly(vinylidene fluoride) and polydopamine-coated aluminum particles on the thermal and combustion properties of 3D printed hybrid rocket fuels. Physical self-assembly and anti-solvent methods were employed for constructing composite μAl particles. Characterization using SEM, XRD, XPS, FTIR, and μCT revealed a core-shell structure and homogeneous elemental distribution. Thermal analysis showed that PVDF coatings significantly increased the heat of combustion for aluminum particles, with maximum enhancement observed in μAl@PDA@PVDF(denoted as μAl@PF) at 6.20 k J/g. Subsequently, 3D printed fuels with varying pure and composite μAl particle contents were prepared using 3D printing. Combustion tests indicated higher regression rates for Al@PF/Resin composites compared to pure resin, positively correlating with particle content. The fluorocarbon-alumina reaction during the combustion stage intensified Al particle combustion, reducing residue size. A comprehensive model based on experiments provides insights into the combustion process of PDA and PVDF-coated droplets. This study advances the design of 3D-printed hybrid rocket fuels, offering strategies to improve regression rates and energy release, crucial for enhancing solid fuel performance for hybrid propulsion.
文摘The micro-drama No Trivial Matters in Xicheng was awarded the title of Outstanding Online Micro-drama for 2024 by the National Radio and Television Administration.By depicting how community workers address people's livelihood concerns such as housing,transportation,and elderly care,the drama vividly showcases the warmth and responsibility in urban grassroots governance.
基金supported by the Jilin Province Key Research and Development Plan Project(20240302066GX)the National Natural Science Foundation of China(Grant No.52075221)the Fundamental Research Funds for the Central Universities(2023-JCXK-02)。
文摘Micro/nano hierarchical structures could endow materials with various surface functions.However,the multilayer and multiscale characteristics of micro/nano hierarchical structures bring difficulties for their one step and controllable fabrication.Accordingly,based on tip-based fabrication techniques,this study proposed a micro-amplitude vibration-assisted scratching method by introducing a periodic backward displacement into the conventional scratching process,which enabled the synchronous creation of the microscale V-groove and nanoscale ripples,i.e.a typical micro/nano hierarchical structure.The experiments and finite element modeling were employed to explore the formation process and mechanism of the micro/nano hierarchical structures.Being different from conventional cutting,this method was mainly based on the plow mechanism,and it could accurately replicate the shape of the indenter on the material surface.The microscale V-groove was formed due to the scratching action,and the nanoscale ripple was formed due to the extrusion action of the indenter on the microscale V-groove’s surface.Furthermore,the relationships between the processing parameters and the dimensions of the micro/nano hierarchical structures were established through experiments,and optimized processing parameters were determined to achieve regular micro/nano hierarchical structures.By this method,complex patterns constructed by various micro/nano hierarchical structures were fabricated on both flat and curved surfaces,achieving diverse surface structural colors.
基金supported by the National Natural Science Foundation of China(Grant No.:82372102).
文摘Enzyme-powered micro/nanomotors(MNMs)(EMNMs)use natural enzymes to facilitate the decomposition of fuels,including hydrogen peroxide(H2O2),glucose,triglycerides,and urea to provide power.EMNMs can achieve self-propulsion through the in situ utilization of biofuels without additional fuels,exhibiting excellent biocompatibility and significant potential for application in the biomedical field.Compared with H_(2)O_(2),which may cause oxidative damage to the body,urea exhibits superior biosafety characteristics.Presently,urease-powered MNMs(UMNMs)have made notable progress in their applications in the biomedical field and have garnered considerable attention from researchers.In this review,we present the latest advancements in the biomedical field of UMNMs,primarily focusing on:1)diverse materials used for constructing the fundamental framework of motors;2)control of motor movement through the regulation of enzymatic reaction rates;and 3)research directions for the clinical application of motors,including in vivo imaging,biomarker detection,cancer treatment,optical therapy,overcoming biological barriers,antibacterial interventions,antithrombotic strategies,and gastric disease management.Despite showing immense potential in biomedical applications,there are still several challenges impeding its practical implementation,such as maintaining activity in the in vivo environment while accurately targeting specific sites to achieve the desired clinical therapeutic effects.
基金supported by the National Natural Science Foundation of China(grant numbers 52305321 and 62273246)The Natural Science Foundation of Jiangsu Province(BK20230496)+3 种基金China Postdoctoral Science Foundation Funded Project(2023M732536 and 2024T170630)Jiangsu Province Excellence Postdoctoral Program(2023ZB218)The National Key R&D Program of China(2022YFB4702202)The Jiangsu Provincial Key Technology R&D Program(BE2021009-02).
文摘Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(FWMRs)have garnered widespread attention among scientists due to their superior miniaturized aerodynamic theory,reduced noise,and enhanced resistance to disturbances in complex and diverse environments.Flying insects,it not only has remarkable flapping flight ability(wings),but also takeoff and landing habitat ability(legs).If the various functions of flying insects can be imitated,efficient biomimetic FWMRs can be produced.This paper provides a review of the flight kinematics,aerodynamics,and wing structural parameters of insects.Then,the traditional wings and folding wings of insect-inspired FWMRs were compared.The research progress in takeoff and landing of FWMRs was also summarized,and the future developments and challenges for insect-inspired FWMRs were discussed.
基金supported by Unmanned Vehicles Core Technology Research and Development Program through the National Research Foundation of Korea(NRF)Unmanned Vehicle Advanced Research Center(UVARC)funded by the Ministry of Science and ICT,the Republic of Korea(2020M3C1C1A01083415).
文摘Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges in self-takeoff,which refers to taking off without both external device and energy input.In this study,a cliff-drop method is implemented for an independent takeoff of a heavy FWAV,relying solely on gravity.In the takeoff process using the cliff-drop method,the FWAV moves on the ground to a cliff edge using a wheel-driving motor and then descends from the cliff to achieve the necessary speed for flight.To demonstrate the cliff-drop method,the KAIST Robotic Hawk(KRoHawk)with a mass of 740 g and a wingspan of 120 cm is developed.The takeoff tests demonstrate that the KRoHawk,significantly heavier than the vertical-takeoff capable FWAVs,can successfully take off using the gravity-assisted takeoff method.The scalability of cliff-drop method is analyzed through simulations.When drop constraints are absent,the wheel-driving motor mass fraction for cliff-drop method remains negligible even as the vehicle's weight increases.When drop constraints are set to 4 m,FWAVs heavier than KRoHawk,weighing up to 4.4 kg,can perform the cliff-drop takeoffs with a wheel-driving motor mass fraction of less than 8%.
文摘The prioritization of financial infrastructure construction serves as a crucial guarantee for the high-quality development of small and micro enterprises.However,resolving the financing challenges of small and micro enterprises is not a task to be accomplished overnight.It necessitates the establishment of a long-term mechanism,the acceleration of financial innovation,the gradual enhancement of the vitality of micro-entities,and the creation of a stable and healthy economic development environment.Therefore,the author first analyzes the current financing situation of small and micro enterprises,as well as the problems they face during the process of financial innovation enabling small and micro enterprises to access financing and solve their financing difficulties,such as insufficient technical support,an imperfect risk control system,incomplete information disclosure,and a lack of credit data.Subsequently,targeted paths for financial innovation are proposed,aiming to offer suggestions for solving the financing problems of small and micro enterprises.
基金supported by the National Natural Science Foundation of China(No.52175277)The computations were conducted in Computing Center in Xi'an.The authors thankfully acknowledge these institutions.
文摘The wing of a butterfly consists of partially overlapping forewing and hindwing,and forewing sweeping can dynamically change the shape of the whole wing.In this work,the effect of forewing sweeping on aerodynamic performance of a butterfly like model is studied using a solver based on immersed boundary method and adaptive mesh.For aerodynamic performance,adding a"forward-backward-forward"sweeping motion to the forewing makes it more suitable for fast cruising flight,and compared to the situation without forewing sweeping,the drag is reduced by 46%and the lift to drag ratio is increased by 45%.On the contrary,adding a"backward-for ward-backward"sweeping motion to the forewing increases lift and makes it more suitable for climb flight.For downstroke and middle to late upstroke,the forewing sweeping affects the Leading-Edge Vortex(LEV)through two factors:sweeping velocity and forward sweeping angle,and their effects are coupled.A large forward sweeping velocity can enhance the strength of LEV,while a large forward sweeping angle can weaken it.For early upstroke,the forewing sweeping can affect the wake capture mechanism,sweeping backward can enhance it while sweeping forward can weaken it.The findings in this work provide insight into the design of butterfly like Micro AirVehicles(MAVs).
基金support from the National Key R&D Program of China(Grant No.2021YFC3002204)the National Natural Science Foundation of China(Grant No.U2233206)。
文摘Microwave sensing technology has become increasingly widely applied in the biomedical field,playing a significant role in medical diagnosis,biological monitoring,and environmental warning.In recent years,the introduction of metamaterials has brought new possibilities and opportunities to microwave biosensors.This paper aims to explore the applications of microwave sensors in biosensing,with a particular emphasis on analyzing the crucial role of metamaterials in enhancing sensor performance and sensitivity.It provides a thorough examination of the fundamental principles,design strategies,fabrication techniques,and applications of microwave biosensors leveraging metamaterial enhancement.Moreover,it meticulously explores the latest applications spanning biomedical diagnostics,environmental monitoring,and food safety,shedding light on their transformative potential in healthcare,environmental sustainability,and food quality assurance.By delving into future research directions and confronting present challenges such as standardization and validation protocols,cost-effectiveness and scalability considerations and exploration of emerging applications,the paper provides a roadmap for advancing microwave biosensors with metamaterial enhancement,promising breakthroughs in multifaceted bioanalytical realms.
