开发从工业废气流中回收氢气的高效分离技术,对于满足日益增长的氢气需求起着重要作用。坎塔布里亚大学化学与生物分子工程系Inmaculada Ortiz教授在《分离纯化技术》(Separation and Purification Technology)期刊发表文章表明:通过将...开发从工业废气流中回收氢气的高效分离技术,对于满足日益增长的氢气需求起着重要作用。坎塔布里亚大学化学与生物分子工程系Inmaculada Ortiz教授在《分离纯化技术》(Separation and Purification Technology)期刊发表文章表明:通过将具有分子筛特性的无机填料(ZIF-8)掺入Matrimid聚合物基体中,合成了混合基质中空纤维膜。展开更多
In this work, the zeolite-Y was ion-exchanged by introducing silver cations into the framework of microsized nano-porous sodium zeolite-Y using a liquid-phase ion exchanged method. The Ag+ion-exchanged zeolite, was th...In this work, the zeolite-Y was ion-exchanged by introducing silver cations into the framework of microsized nano-porous sodium zeolite-Y using a liquid-phase ion exchanged method. The Ag+ion-exchanged zeolite, was then embedded into the Matrimid5218 matrix to form novel mixed matrix membranes(MMMs). The particles and MMMs were characterized by ultraviolet-visible diffuse reflectance spectroscopy(UV–vis DRS), N2adsorption–desorption isotherm, X-ray diffraction(XRD), Fourier transform infrared(FTIR) and scanning electron microscopy(SEM). Furthermore, the effects of filler content(0–20wt%) on pure and mixed gas experiments, feed pressure(2–20 bar) and operating temperature(35–75 oC)on CO2/CH4transport properties of Matrimid/Ag Y MMMs were considered. Characterization results confirmed an appropriate ion-exchange treatment of the zeolites. The SEM results confirmed the superior interfacial adhesion between polymer and zeolites, particularly in the case of Matrimid/Ag Y membranes.This is due to the proper silverous zeolite/Matrimid functional groups’ interactions. The gas permeation results showed that the CO2permeability increased about 123%, from 8.34 Barrer for pure Matrimid to18.62 Barrer for Matrimid/Ag Y(15 wt%). The CO2/CH4selectivity was improved about 66%, from 36.3 for Matrimid to 60.1 for Matrimid/Ag Y(15 wt%). The privileged gas separation performance of Matrimid/Ag Y(15 wt%) was the result of a combined effect of facilitated transport mechanism of Ag+ions as well as the intrinsic surface diffusion mechanism of Y-type zeolite. In order to survey the possibility of using the developed MMMs in industry, the CO2-induced plasticization effect and mixed gas experiment were accomplished. It was deduced that the fabricated MMMs could maintain the superior performance in actual operating conditions.展开更多
Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeabili...Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeability and small in layer thickness.These impermeable inte rlayers act as baffles and barriers between flow units and are crucial in hydrocarbon development.Donghe Sandstone in the Hade Oilfield of Tarim Basin,NW China,belongs to coastal clastic reservoirs of high oil productivity.Following nearly 30 years of development,the distribution of remaining hydrocarbon resources is affected by the muddy,calcareous,and marlaceous interlayers.Taking the Donghe Sandstone as an example,a quantitative recognition method of interlayers in coastal sandstone reservoirs is proposed in this paper.Based on cores from 26 wells,the sensitive conventional log curves of different interlayers,namely the natural gamma-ray(GR),density(DEN),compensated neutron(CNL),and acoustic(AC),are extracted by the Extreme Gradient Boosting(XGBoost).Multi-mineral model(MMM)is used to calculate continuous curves for muddy,sandy,and calcareous contents by the mentioned sensitive logs.A set of quantitative standard system is established for identifying muddy,calcareous,and marlaceous interlayers based on their respective contents.The types of inte rlayers are identified across all vertical wells.The interlayers exhibit lateral continuity at the top of each bed-set.Interlayers are currently more developed in the slope region than in the coastal region.Muddy and marlaceous interlayers are more developed at high relative sea-level,while calcareous interlayers are more developed at low relative sea-level.The extended interlayers at the top of BS6 lead to two different oil-water contacts in the Donghe Sandstone.The proposed quantitative recognition method for interlayers provides valuable insights into the exploitation potential of petroleum systems in the Donghe Sandstone of the Hade Oilfield.The flexible and easy-to-use method can be applied to other marine sandstone reservoirs or similar formations.展开更多
The crisis of excessive increase in CO_(2)emissions has quickly become a serious issue and requires low-cost and bio-compatible solutions.The employee of membrane technology for CO_(2)gas separation has garnered signi...The crisis of excessive increase in CO_(2)emissions has quickly become a serious issue and requires low-cost and bio-compatible solutions.The employee of membrane technology for CO_(2)gas separation has garnered significant interest among researchers.However,this method encounters challenges related to selectivity and permeability.Therefore,modifying and reinforcing the polymer membranes to improve gas separation performance seems essential.Among the various methods for polymer membrane modification,modification with magnesium-based fillers to prepare a mixed matrix membrane(MMM)is considered an efficient method.Owing to magnesium metal's low weight,low density,high strength,and good selectivity,magnesium-based materials(Mg-based materials)have more porosity,higher available surface area,more adsorption sites,lighter weight,and more gas absorption tendency than other fillers,which makes them an attractive choice for the preparation of gas separation MMMs.This research deals with the introduction of Mg-based materials,various methods of synthesis of Mg-based materials,different methods of introducing Mg-based materials into the membrane matrix,and their effect on the performance of MMMs in CO_(2)gas separation applications.Therefore,this review can provide researchers with light horizons in using the high potential of Mg-based materials as efficient fillers in MMMs to achieve excellent permeability and selectivity and generally improve their performance in CO_(2)gas separation applications.展开更多
In this study,Pebax■2533 polymer was used as the continuous phase and UiO-67 was employed as the filler to prepare mixed matrix membranes.UiO-67 is usually synthesized using two ligands:biphenyl-4,4'-dicarboxylat...In this study,Pebax■2533 polymer was used as the continuous phase and UiO-67 was employed as the filler to prepare mixed matrix membranes.UiO-67 is usually synthesized using two ligands:biphenyl-4,4'-dicarboxylate(bpdc)and 2,2'-bipyridine-5,5'-dicarboxylic acid(bpy).In this research,UiO-67 was synthesized not only with these two ligands but also using a mixed ligand approach(50% bpdc and 50% bpy).The synthesized UiOs were incorporated into the polymer matrix at mass percentages ranging from 0% to 2% to form the mixed matrix membranes(MMMs).Membranes containing UiO-67 with mixed ligands exhibited a greater affinity for CO_(2) compared to other membranes.Various analytical techniques,including X-ray diffraction,thermogravimetric analyzer,Fourier transform infrared spectroscope(FTIR),field emission scanning electron micro scope(FESEM),and differential scanning calorimetry,were used to analyze the properties of the prepared membranes.The FTIR spectrum confirmed all desired bands of Pebax?2533 and UiO-67 in the MMMs.The FESEM images showed that the pure Pebax membrane has a uniform structure,and the developed membranes are uniformly incorporated with the synthesized UiO-67 nanoparticles.Gas permeation measurements indicated that CO_(2) permeability and CO_(2)/CH_4 selectivity increased from 402.7 Barrer(1 Barrer=1.33×10^(-14)m^(3)(STP)·m·m^(-2)·s^(-1)·kPa^(-1))and 9.32 for the pure Pebax membrane at 1.0 MPa to 770.1 Barrer and 16.96 in the modified membrane.Additionally,the gas permeation test results demonstrated that adding functionalized porous nanofillers increases the CO_(2)separation performance.Permeability tests at different temperatures revealed that as temperature was raised,at constant pressure,CO_(2) permeability for the membrane containing the mixed ligand increased from 682.2 Barrer to 733.5 Barrer,While CO_(2)/CH_(4) selectivity decreased from 15.46 to 13.43.展开更多
文摘开发从工业废气流中回收氢气的高效分离技术,对于满足日益增长的氢气需求起着重要作用。坎塔布里亚大学化学与生物分子工程系Inmaculada Ortiz教授在《分离纯化技术》(Separation and Purification Technology)期刊发表文章表明:通过将具有分子筛特性的无机填料(ZIF-8)掺入Matrimid聚合物基体中,合成了混合基质中空纤维膜。
文摘In this work, the zeolite-Y was ion-exchanged by introducing silver cations into the framework of microsized nano-porous sodium zeolite-Y using a liquid-phase ion exchanged method. The Ag+ion-exchanged zeolite, was then embedded into the Matrimid5218 matrix to form novel mixed matrix membranes(MMMs). The particles and MMMs were characterized by ultraviolet-visible diffuse reflectance spectroscopy(UV–vis DRS), N2adsorption–desorption isotherm, X-ray diffraction(XRD), Fourier transform infrared(FTIR) and scanning electron microscopy(SEM). Furthermore, the effects of filler content(0–20wt%) on pure and mixed gas experiments, feed pressure(2–20 bar) and operating temperature(35–75 oC)on CO2/CH4transport properties of Matrimid/Ag Y MMMs were considered. Characterization results confirmed an appropriate ion-exchange treatment of the zeolites. The SEM results confirmed the superior interfacial adhesion between polymer and zeolites, particularly in the case of Matrimid/Ag Y membranes.This is due to the proper silverous zeolite/Matrimid functional groups’ interactions. The gas permeation results showed that the CO2permeability increased about 123%, from 8.34 Barrer for pure Matrimid to18.62 Barrer for Matrimid/Ag Y(15 wt%). The CO2/CH4selectivity was improved about 66%, from 36.3 for Matrimid to 60.1 for Matrimid/Ag Y(15 wt%). The privileged gas separation performance of Matrimid/Ag Y(15 wt%) was the result of a combined effect of facilitated transport mechanism of Ag+ions as well as the intrinsic surface diffusion mechanism of Y-type zeolite. In order to survey the possibility of using the developed MMMs in industry, the CO2-induced plasticization effect and mixed gas experiment were accomplished. It was deduced that the fabricated MMMs could maintain the superior performance in actual operating conditions.
基金funded by the National Natural Science Foundation of China(No.42202113)。
文摘Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeability and small in layer thickness.These impermeable inte rlayers act as baffles and barriers between flow units and are crucial in hydrocarbon development.Donghe Sandstone in the Hade Oilfield of Tarim Basin,NW China,belongs to coastal clastic reservoirs of high oil productivity.Following nearly 30 years of development,the distribution of remaining hydrocarbon resources is affected by the muddy,calcareous,and marlaceous interlayers.Taking the Donghe Sandstone as an example,a quantitative recognition method of interlayers in coastal sandstone reservoirs is proposed in this paper.Based on cores from 26 wells,the sensitive conventional log curves of different interlayers,namely the natural gamma-ray(GR),density(DEN),compensated neutron(CNL),and acoustic(AC),are extracted by the Extreme Gradient Boosting(XGBoost).Multi-mineral model(MMM)is used to calculate continuous curves for muddy,sandy,and calcareous contents by the mentioned sensitive logs.A set of quantitative standard system is established for identifying muddy,calcareous,and marlaceous interlayers based on their respective contents.The types of inte rlayers are identified across all vertical wells.The interlayers exhibit lateral continuity at the top of each bed-set.Interlayers are currently more developed in the slope region than in the coastal region.Muddy and marlaceous interlayers are more developed at high relative sea-level,while calcareous interlayers are more developed at low relative sea-level.The extended interlayers at the top of BS6 lead to two different oil-water contacts in the Donghe Sandstone.The proposed quantitative recognition method for interlayers provides valuable insights into the exploitation potential of petroleum systems in the Donghe Sandstone of the Hade Oilfield.The flexible and easy-to-use method can be applied to other marine sandstone reservoirs or similar formations.
文摘The crisis of excessive increase in CO_(2)emissions has quickly become a serious issue and requires low-cost and bio-compatible solutions.The employee of membrane technology for CO_(2)gas separation has garnered significant interest among researchers.However,this method encounters challenges related to selectivity and permeability.Therefore,modifying and reinforcing the polymer membranes to improve gas separation performance seems essential.Among the various methods for polymer membrane modification,modification with magnesium-based fillers to prepare a mixed matrix membrane(MMM)is considered an efficient method.Owing to magnesium metal's low weight,low density,high strength,and good selectivity,magnesium-based materials(Mg-based materials)have more porosity,higher available surface area,more adsorption sites,lighter weight,and more gas absorption tendency than other fillers,which makes them an attractive choice for the preparation of gas separation MMMs.This research deals with the introduction of Mg-based materials,various methods of synthesis of Mg-based materials,different methods of introducing Mg-based materials into the membrane matrix,and their effect on the performance of MMMs in CO_(2)gas separation applications.Therefore,this review can provide researchers with light horizons in using the high potential of Mg-based materials as efficient fillers in MMMs to achieve excellent permeability and selectivity and generally improve their performance in CO_(2)gas separation applications.
基金Babol Noshirvani University of Technology for financially support of this project(BNUT/393054/2023)。
文摘In this study,Pebax■2533 polymer was used as the continuous phase and UiO-67 was employed as the filler to prepare mixed matrix membranes.UiO-67 is usually synthesized using two ligands:biphenyl-4,4'-dicarboxylate(bpdc)and 2,2'-bipyridine-5,5'-dicarboxylic acid(bpy).In this research,UiO-67 was synthesized not only with these two ligands but also using a mixed ligand approach(50% bpdc and 50% bpy).The synthesized UiOs were incorporated into the polymer matrix at mass percentages ranging from 0% to 2% to form the mixed matrix membranes(MMMs).Membranes containing UiO-67 with mixed ligands exhibited a greater affinity for CO_(2) compared to other membranes.Various analytical techniques,including X-ray diffraction,thermogravimetric analyzer,Fourier transform infrared spectroscope(FTIR),field emission scanning electron micro scope(FESEM),and differential scanning calorimetry,were used to analyze the properties of the prepared membranes.The FTIR spectrum confirmed all desired bands of Pebax?2533 and UiO-67 in the MMMs.The FESEM images showed that the pure Pebax membrane has a uniform structure,and the developed membranes are uniformly incorporated with the synthesized UiO-67 nanoparticles.Gas permeation measurements indicated that CO_(2) permeability and CO_(2)/CH_4 selectivity increased from 402.7 Barrer(1 Barrer=1.33×10^(-14)m^(3)(STP)·m·m^(-2)·s^(-1)·kPa^(-1))and 9.32 for the pure Pebax membrane at 1.0 MPa to 770.1 Barrer and 16.96 in the modified membrane.Additionally,the gas permeation test results demonstrated that adding functionalized porous nanofillers increases the CO_(2)separation performance.Permeability tests at different temperatures revealed that as temperature was raised,at constant pressure,CO_(2) permeability for the membrane containing the mixed ligand increased from 682.2 Barrer to 733.5 Barrer,While CO_(2)/CH_(4) selectivity decreased from 15.46 to 13.43.
