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Coordination Thermodynamic Control of Magnetic Domain Configuration Evolution toward Low‑Frequency Electromagnetic Attenuation
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作者 Tong Huang Dan Wang +9 位作者 Xue He Zhaobo Feng Zhiqiang Xiong Yuqi Luo Yuhui Peng Guangsheng Luo Xuliang Nie Mingyue Yuan Chongbo Liu Renchao Che 《Nano-Micro Letters》 2026年第3期860-875,共16页
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at... The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials. 展开更多
关键词 Thermodynamically controlled coordination strategy magnetic domain configuration Low-frequency electromagnetic wave absorption Electrical/magnetic coupling MULTIFUNCTION
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The fitting of a dipolar magnetic field by a dipole model
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作者 ZhaoJin Rong Yong Wei +8 位作者 Fei He Lucy Klinger YanYan Yang JiaWei Gao Zhen Shi HuaPei Wang ShuHui Cai HuaFeng Qin RiXiang Zhu 《Earth and Planetary Physics》 2025年第6期1125-1134,共10页
Many planets,including the Earth,possess a global dipolar magnetic field.To diagnose the interior source of the dipolar field,researchers usually adopt a dipole model consisting of six parameters to fit the observed d... Many planets,including the Earth,possess a global dipolar magnetic field.To diagnose the interior source of the dipolar field,researchers usually adopt a dipole model consisting of six parameters to fit the observed dataset of the magnetic field.However,the simultaneous fitting of these parameters often leads to multiple local optimal parameter sets.To address this fitting dilemma,Rong ZJ et al.(2021)recently developed a current loop model.This technique can successively separate and invert the loop parameters.Here,we further show how this technique can be reduced and modified to fit a dipole model.Applications of this reduced technique to the International Geomagnetic Reference Field model and the Martian crustal field model highlight its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly,a capability that sets it apart from existing methods.The potential impact of this technique on geomagnetism and planetary magnetism is significant,given its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly. 展开更多
关键词 geomagnetic field magnetic dipole INVERSION dipolar magnetic field magnetic anomaly crustal magnetic field magnetic sources eccentic dipole
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SLM-3D Printed Soft Magnetic Alloys:Process,Performance,and Prospects
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作者 Liu Bingxu You Caiyin +4 位作者 Wang Fenghui Tian Na Liu Heguang Zhang Jing Zhu Xiaopei 《稀有金属材料与工程》 北大核心 2026年第2期365-388,共24页
Soft magnetic alloys are extensively used in various power electronic devices due to their advantageous properties,including high saturation magnetic induction,low coercivity,and high permeability.In certain applicati... Soft magnetic alloys are extensively used in various power electronic devices due to their advantageous properties,including high saturation magnetic induction,low coercivity,and high permeability.In certain applications,complex-shaped components are increasingly required for performance enhancement.Additive manufacturing technique,particularly selective laser melting(SLM),has emerged as an effective method for fabricating such complex-shaped soft magnetic components.SLM,a laserbased additive manufacturing technique,employs high-power-density lasers to melt and fuse metal powders within a powder bed selectively.This approach enables rapid prototyping,precise geometrical control,and the integration of multi-material designs.This review highlights recent advancements in the application of SLM technique for the production of soft magnetic alloys,focusing on Fe-Si,Fe-Ni,Fe-Co,and amorphous alloy systems.Moreover,it explores the implementation of SLM in manufacturing processes and evaluates both the opportunities and challenges associated with SLM-based production of soft magnetic alloys. 展开更多
关键词 additive manufacturing selective laser melting soft magnetic alloys magnetic properties
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Lithospheric magnetic variations on the Tibetan Plateau based on a 3D surface spline model,compared with strong earthquake occurrences
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作者 PengTao Zhang Jun Yang +3 位作者 LiLi Feng Xia Li YuHong Zhao YingFeng Ji 《Earth and Planetary Physics》 2026年第1期30-43,共14页
The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-bas... The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau. 展开更多
关键词 Tibetan Plateau magnetic variation SEISMICITY surface spline model enhanced magnetic model
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Magnetic field enhanced electrocatalytic oxygen evolution of CoFe_(2)O_(4) with tunable oxygen vacancy concentrations
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作者 Xiangyang Zou Ping Guo +2 位作者 Yuanyuan Zhang Feng Gao Ping Xu 《Chinese Chemical Letters》 2026年第1期671-677,共7页
Magnetic field-driven spin polarization modulation has emerged as an effective way to boost the electrocatalytic oxygen evolution reaction(OER).However,the correlation among catalyst structure,magnetic property,and ma... Magnetic field-driven spin polarization modulation has emerged as an effective way to boost the electrocatalytic oxygen evolution reaction(OER).However,the correlation among catalyst structure,magnetic property,and magnetic field enhanced-electrochemical activity remains to be fully elucidated.Herein,single-domain CoFe_(2)O_(4) catalysts with tunable oxygen vacancies(CFO-V_(O)) were synthesized to probe how V_(O) mediates magnetism and OER activity under magnetic field.The introduction of V_(O) can simultaneously modulate saturation magnetization(M_(s)) and coercivity(H_(c)),where the increased M_(s) dominates the magnetic field-enhanced OER activity.Under a 14,000 G magnetic field,the optimized CFO-V_(O) exhibits up to 16.1 % reduction in overpotential and 365 % enhancement in magnetocurrent(MC).Electrochemical analyses and post-OER characterization reveal that the magnetic field synergistically improves OER kinetics through lattice distortion induction,magnetohydrodynamic effect,and spin charge transfer effect.Importantly,the magnetic field promotes additional Co^(3+) generation to compensate for charge imbalance caused by V_(O) filling,maintaining dynamic equilibrium of V_(O) and effective reactant adsorption-conversion processes.This work unveils the synergistic mechanism of V_(O) and magnetic parameters for enhancing OER performance under the magnetic field,providing new insights into the design of high-efficiency spinregulated OER catalysts. 展开更多
关键词 Spinel oxide Oxygen vacancy magnetic field magnetic property Oxygen evolution reaction
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The Magnetism of Monolayer FeSe in Multiple Environments
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作者 Bangjie Cao Can Huang +5 位作者 Lingzi Jiang Yanfei Pan Daning Shi Jiyu Fan Chunlan Ma Yan Zhu 《Chinese Physics Letters》 2025年第7期401-409,共9页
FeSe is an Fe-based paramagnetic superconductor with the simplest structure.The competition between the Néel and stripe magnetic orders is believed to be one of the reasons for the absence of magnetic orders in F... FeSe is an Fe-based paramagnetic superconductor with the simplest structure.The competition between the Néel and stripe magnetic orders is believed to be one of the reasons for the absence of magnetic orders in FeSe.FeSe is recognized as a prototypical platform for competing magnetic interactions,including Néel,stripe,and staggered antiferromagnetic coupling.However,the correlations between these magnetic orders and how they change with varying environmental conditions require further study.Here,we calculated the magnetic order of monolayer FeSe in three diferent environments:pure one,with slight lattice distortion,and on SrTiO_(3) substrate,by frst principles calculations.We fnd that in the calculated dispersion relation E(q)between the spin spiral energy E and spin spiral vector q of the monolayer FeSe structure,the stripe magnetic order M(π/2,π/2)has the lowest energy,and there is a fat E(q)between the wave vector X(π/2,0)and Néel magnetic order 2X(π,0),which are the degenerate E(q)states.The ground state of M and the highest density of states around 2X may be the reason for the competition of two magnetic orders.The slight lattice distortion does not alter the magnetic properties of monolayer FeSe.When monolayer FeSe is attached to the SrTiO_(3)substrate,the degenerate E(q)is still retained;meanwhile,the energy of the 2X(π,0)state is closer to the M state,which may be one of the reasons for the increase of superconducting temperature in FeSe/SrTiO_(3). 展开更多
关键词 magnetic orders n el magnetic order n el stripe magnetic orders monolayer Fese stripe magnetic order SrTiO substrate lattice distortion staggered antiferromagnetic couplinghoweverthe
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Printable magnetoresistive sensors: A crucial step toward unconventional magnetoelectronics
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作者 Lin Guo Rui Xu Denys Makarov 《Chinese Journal of Structural Chemistry》 2025年第2期14-16,共3页
In the modern technological landscape,magnetic field sensors play a crucial role and are indispensable across a range of high-tech applications[1].In conjunction with magnets,magnetic field sensors can accurately dete... In the modern technological landscape,magnetic field sensors play a crucial role and are indispensable across a range of high-tech applications[1].In conjunction with magnets,magnetic field sensors can accurately detect any form of relative movement of objects without physical contact.For instance,in the precise control of robotic arms or machine tools,a permanent magnet is used as a reference.The magnetic sensor detects the relative movement of magnet by sensing changes in the magnetic field strength.These changes are converted into electrical signals,which are fed back to the control system,enabling accurate positioning and control of the device.This advanced detection technology not only greatly enhances measurement precision but also significantly extends the lifespan of equipment.Among various types of magnetic field sensors,magnetoresistive(MR)sensors stand out for their exceptional performance[1].The high sensitivity allows them to detect minimal changes of magnetic fields in high-precision measurements.Today,MR sensors are widely used across numerous fields,including automobile industries,information processing and storage,navigation systems,biomedical applications,etc[1,2].With their outstanding performance and wide-ranging applications,MR sensors are at the forefront of sensor technology. 展开更多
关键词 permanent magnet field sensors magnetic field sensors magnetic sensor machine toolsa magnetOELECTRONICS magnetoresistive sensors precise control robotic arms
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Unconventional Compensated Magnetic Material LaMn_(2)SbO_(6)
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作者 Xiao-Yao Hou Ze-Feng Gao +2 位作者 Huan-Cheng Yang Peng-Jie Guo Zhong-Yi Lu 《Chinese Physics Letters》 2025年第7期388-392,共5页
Unconventional magnetism,including altermagnetism and unconventional compensated magnetism,characterized by its duality of real-space antiferromagnetic alignment and momentum-space spin splitting,has garnered widespre... Unconventional magnetism,including altermagnetism and unconventional compensated magnetism,characterized by its duality of real-space antiferromagnetic alignment and momentum-space spin splitting,has garnered widespread attention.While altermagnetism has been extensively studied,research on unconventional compensated magnetism remains very rare.In particular,unconventional compensated magnetic materials are only theoretically predicted and have not yet been synthesized experimentally.In this study,based on symmetry analysis and frst-principles electronic structure calculations,we predict that LaMn_(2)SbO_(6)is an unconventional compensated magnetic semiconductor.Given that the Mn ions at opposite spin lattice cannot be connected by any symmetry,the spin splitting in LaMn_(2)SbO_(6)is isotropic.More importantly,LaMn_(2)SbO_(6)has already been synthesized experimentally,and its magnetic structure has been confrmed by neutron scattering experiments.Therefore,LaMn_(2)SbO_(6)serves as an excellent material platform for investigating the novel physical properties of unconventional compensated magnetic materials. 展开更多
关键词 unconventional compensated magnetismcharacterized lamn sbo spin splitting symmetry analysis unconventional compensated magnetism unconventional magnetismincluding compensated magnetic materials altermagnetism
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Realization of Large Magnetocaloric Effect in the Kagome Antiferromagnet Gd_(3)BWO_(9) for Sub-Kelvin Cryogenic Refrigeration
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作者 Fangyuan Song Xinyang Liu +10 位作者 Chao Dong Jin Zhou Xinlong Shi Yuyan Han Langsheng Ling Huifen Ren Songliu Yuan Shun Wang Junsen Xiang Peijie Sun Zhaoming Tian 《Chinese Physics Letters》 2025年第12期253-268,共16页
Rare-earth based frustrated magnets have attracted great attention as excellent candidates for magnetic refrigeration at sub-Kelvin temperatures,while the experimental identification of systems exhibiting both large v... Rare-earth based frustrated magnets have attracted great attention as excellent candidates for magnetic refrigeration at sub-Kelvin temperatures,while the experimental identification of systems exhibiting both large volumetric cooling capacity and reduced working temperatures far below 1K remains a challenge.Here,through ultra-low temperature magnetism and thermodynamic characterizations,we unveil the large magnetocaloric effect(MCE)realized at sub-Kelvin temperatures in the frustrated Kagome antiferromagnet Gd_(3)BWO_(9) with T_(N)∼1.0 K.The isothermal magnetization curves indicate the existence of field(B)induced anisotropic magnetic phase diagrams,where four distinct magnetic phases for B‖c-axis and five magnetic phases for B‖ab-plane are identified at T<T_(N).The analysis of magnetic entropy S(B,T)data and direct adiabatic demagnetization tests reveal remarkable cooling performance at sub-Kelvin temperatures featured by a large volumetric entropy density of 502.2 mJ/K/cm^(3)and a low attainable minimal temperature T_(min)∼168mK from the initial cooling condition of 2K and 6 T,surpassing most Gd-based refrigerants previously documented in temperature ranges of 0.25–4 K.The realized T_(min)∼168mK far below T_(N)∼1.0K in Gd_(3)BWO_(9) is related to the combined effects of magnetic frustration and criticality-enhanced MCE,which together leave substantial magnetic entropy at reduced temperatures by enhancing spin fluctuations. 展开更多
关键词 magnetic refrigeration GD BWO magnetocaloric effect kagome antiferromagnet thermodynamic characterizationswe magnetocaloric effect mce realized frustrated magnets sub kelvin refrigeration
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Tunneling Magnetoresistance Effect in Altermagnetic Tunnel Junctions with g-Wave Splitting
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作者 Xinlu Li Meng Zhu +3 位作者 Jianting Dong Kun Wu Fanxing Zheng Jia Zhang 《Chinese Physics Letters》 2025年第10期144-165,共22页
Altermagnets,a class of unconventional antiferromagnets with non-relativistic spin-splitting,offer promising potential for antiferromagnetic spintronic devices.While many altermagnets are limited by either low magneti... Altermagnets,a class of unconventional antiferromagnets with non-relativistic spin-splitting,offer promising potential for antiferromagnetic spintronic devices.While many altermagnets are limited by either low magnetic transition temperatures or weak spin splitting,the recently discovered metal CrSb,with high N′eel temperature(T_(N)=710 K)and significant spin-splitting due to its unique spin space group,provides a robust platform for remarkable tunneling magnetoresistance(TMR)in collinear all-antiferromagnetic tunnel junctions(AATJs).This study systematically investigates the spin-polarized Fermi surface of CrSb and spin-dependent electron transport in CrSb-based AATJs.The CrSb/β-InSe/CrSb junction with a three-monolayer InSe barrier exhibits a TMR ratio of approximately 290%,with energy-dependent analysis revealing TMR ratios that may exceed 850%when considering the shift of the Fermi energy.We also demonstrate the angle-dependent TMR of CrSb-based AATJs by adjusting N′eel vector orientations.Our findings might provide strong theoretical support for CrSb as a versatile building block for all-antiferromagnetic memory devices. 展开更多
关键词 G wave splitting antiferromagnetic spintronic deviceswhile tunneling magnetoresistance tmr Alt magnets low magnetic transition temperatures spin splittingthe tunneling magnetoresistance Crsb
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Microstructure and Properties of Mg/Fe Dissimilar Metal Joints Fabricated by Magnetic Pulse Welding
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作者 Xie Jilin Li Shimeng +3 位作者 Wang Yaping Liu Dongya Liu Xiaofang Chen Yuhua 《稀有金属材料与工程》 北大核心 2026年第1期67-77,共11页
Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively invest... Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively investigated.Macroscopic morphology,microstructure,and interfacial structure of the joints were analyzed using scanning electron microscope,energy dispersive spectrometer,and X-ray diffractometer(XRD).The results show that magnetic pulse welding of dissimilar Mg/Fe metals is achieved using an Al interlayer,which acts as a bridge for deformation and diffusion.Specifically,the AZ31B/AA1060 interface exhibits a typical wavy morphology,and a transition zone exists at the joint interface,which may result in an extremely complex microstructure.The microstructure of this transition zone differs from that of AZ31B magnesium and 1060 Al alloys,and it is identified as brittle intermetallic compounds(IMCs)Al_(3)Mg_(2) and Al_(12)Mg_(17).The transition zone is mainly distributed on the Al side,with the maximum thickness of Al-side transition layer reaching approximately 13.53μm.Incomplete melting layers with varying thicknesses are observed at the primary weld interface,while micron-sized hole defects appear in the transition zone of the secondary weld interface.The AA1060/DC56D interface is mainly straight,with only a small number of discontinuous transition zones distributed intermittently along the interface.These transition zones are characterized by the presence of the brittle IMC FeAl_(3),with a maximum thickness of about 4μm. 展开更多
关键词 magnetic pulse welding mechanical properties MICROSTRUCTURE fracture morphology primary and secondary welding
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Detection of the Oscillation Marks on Casting Slabs Using Magnetic Flux Variation and the Nonexcitation Method
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作者 FENG Kaibin LIU Runcong +3 位作者 LI Silong WU Yunfei NA Xianzhao WANG Xiaodong 《材料导报》 北大核心 2026年第1期149-158,共10页
T he residual stray magnetic fields present in ferromagnetic casting slabs were investigated in this work,which result from the magnetic fields generated during the steel casting process.Existing optical detection met... T he residual stray magnetic fields present in ferromagnetic casting slabs were investigated in this work,which result from the magnetic fields generated during the steel casting process.Existing optical detection methods face challenges owing to surface oxide scales,and conventional high-precision magnetic sensors are ineffective at high temperatures.To overcome these limitations,a small coil sensor was employed to measure the residual magnetism strength in oscillation traces,using metal magnetic memory and electromagnetic induction methods,which can carry out detection without an external excitation source.Using this technology,the proposed scheme successfully detects defects at high tempe-ratures(up to 670℃)without a cooling device.The key findings include the ability to detect both surface and near-surface defects,such as cracks and oscillation marks,with an enhanced signal-to-noise ratio(SNR)of 7.2 dB after signal processing.The method’s practicality was validated in a steel mill environment,where testing on casting slabs effectively detected defects,providing a foundation for improving industrial quality control.The proposed detection scheme offers a significant advancement in nondestructive testing(NDT)for high-temperature applications,contributing to more efficient and accurate monitoring of ferromagnetic material integrity. 展开更多
关键词 oscillation marks REMANENCE metal magnetic memory near surface defects nondestructive testing(NDT)
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Ligand-directed construction of cobalt-oxo cluster-based organic frameworks:Structural modulation,semiconductor,and antiferromagnetic properties
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作者 SHI Jinlian LIU Xiaoru XU Zhongxuan 《无机化学学报》 北大核心 2026年第1期45-54,共10页
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct... Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24. 展开更多
关键词 semi-rigid carboxylic acid ligands three-dimensional framework tetranuclear cobalt-oxo cluster semiconductor material antiferromagnetic magnetism
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Effects of Mn doping on the reactivity,elastic,and magnetic properties ofα-Fe_(2)O_(3)based on DFT calculation
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作者 WANG Peng DONG Changqing +4 位作者 XUE Junjie GAO Qi HU Xiaoying ZHANG Junjiao ZHAO Jie 《燃料化学学报(中英文)》 北大核心 2026年第2期140-152,共13页
Oxygen carriers play a fundamental role in chemical looping combustion(CLC).Iron-based carriers have been extensively investigated owing to their abundance and environmentally friendly.However,the reactivity and separ... Oxygen carriers play a fundamental role in chemical looping combustion(CLC).Iron-based carriers have been extensively investigated owing to their abundance and environmentally friendly.However,the reactivity and separability of iron-based carriers require further enhancement.This study investigates the effect of the concentration of Mn doping on reactivity,elastic properties and magnetic properties based on density functional theory(DFT)calculations.Theoretical results demonstrate that Mn doping effectively enhances reactivity by reducing the oxygen vacancy formation energy(E_(vac))from 2.33 to 0.87 eV.However,Mn doping introduces HV/EV Ms lattice distortions that deteriorate elastic properties,thereby reducing wear resistance,as evidenced by a 54.54%decrease in the hardness-to-Young's modulus ratio(H_(v)/E_(v))forα-Fe_(2)O_(3)and an 83.33%reduction for Fe_(3)O_(4).Furthermore,Mn doping also modifies magnetic properties.The maximum of saturation magnetization(M_(s))of Fe_(3)O_(4)reaches 121.02 emu/g at 33.33%Mn doping concentration.Finally,systematic evaluation identifies 33.33%as the optimal Mn doping concentration,achieving a balance in enhanced reactivity,superior magnetic performance,and retained elastic stability. 展开更多
关键词 oxygen carrier Mn-dopedα-Fe_(2)O_(3) REACTIVITY elastic properties magnetic properties
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Optimizing Magnetic Performance and Microstructure of CoPt Nanoparticles by Sol-Gel Synthesis
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作者 WANG Xinchi WANG Wei +2 位作者 LIU Shuai WANG Yun LI Baohe 《Journal of Wuhan University of Technology(Materials Science)》 2026年第1期8-14,共7页
We prepared Co_(x)Pt_(100-x)(x=40,45,50,55,60)nanoparticles by the sol-gel method.The phase composition and crystal structure,morphology and microstructure,and magnetic properties of the samples were characterized and... We prepared Co_(x)Pt_(100-x)(x=40,45,50,55,60)nanoparticles by the sol-gel method.The phase composition and crystal structure,morphology and microstructure,and magnetic properties of the samples were characterized and tested using X-ray diffraction(XRD),transmission electron microscopy(TEM),and vibrating sample magnetometer(VSM),respectively.The results demonstrate that the coercivity of CoPt nanoparticles can be effectively controlled by adjusting the atomic ratio of Co and Pt in the samples.Among the compositions studied,the Co_(45)Pt_(55)sample synthesized by the sol-gel method exhibits smaller grain size and a coercivity as high as 6.65×10^(5) A/m is achieved.The morphology and microstructure of the nanoparticles were analyzed by TEM images,indicating that a slight excess of Pt can effectively enhance the coercivity of CoPt nanoparticles. 展开更多
关键词 COPT sol-gel method atomic ratio magnetic nanoparticles COERCIVITY
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Ultrasound/magnetic field dual-responsive Fe_(3)O_(4)/glucose oxidase catalytic microbubbles for enhanced bacterial biofilm elimination
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作者 Chi Zhang Dou Wang +6 位作者 Liang Lu Feng-Jiao Xu Fan-Sen Xu Xuan Wu Xiao-Xiao Xu Xiao Li Li-Hui Yuwen 《Biomedical Engineering Communications》 2026年第1期4-12,共9页
Background:The bacterial biofilm poses a significant challenge to traditional antibiotic therapy.There is a great need to develop novel antibiofilm agents combined with biofilm disrupting and bacteria-killing without ... Background:The bacterial biofilm poses a significant challenge to traditional antibiotic therapy.There is a great need to develop novel antibiofilm agents combined with biofilm disrupting and bacteria-killing without the dependence of antibiotic.Methods:Herein,we prepared ultrasound/magnetic field-responsive ferroferric oxide nanoparticles(Fe_(3)O_(4))/glucose oxidase microbubbles(FGMB)to form a cascade catalytic system for effective removing methicillin-resistant Staphylococcus aureus biofilms.FGMB were prepared through interfacial self-assembly of Fe_(3)O_(4) nanoparticles(NPs)and glucose oxidase(GOx)at the gas-liquid interface stabilized by surfactants.Under ultrasound/magnetic field stimulation,FGMB disrupted biofilm architecture through microbubble collapse-induced microjets and magnetically driven displacement.Simultaneously,ultrasound-triggered rupture of FGMB released GOx and Fe_(3)O_(4) NPs.Glucose can be oxidized by GOx to generate gluconic acid and hydrogen peroxide which was subsequently catalyzed into hydroxyl radicals by Fe_(3)O_(4) NPs,enabling chemical eradication of biofilm-embedded bacteria.Results:Optical microscopy images demonstrated that FGMB have spherical structure with average size of approximately 17μm.FGMB showed a 65.4%decrease in methicillin-resistant Staphylococcus aureus biofilm biomass and 1.1 log bacterial inactivation efficiency(91.2%),suggesting effective biofilm elimination.In vitro experimental results also indicate that FGMB have good biocompatibility.Conclusion:This antibiofilm strategy integrated dual modes of physical biofilm disruption with chemical bacteria-killing shows great potential as a versatile,non-resistant strategy for bacterial biofilm elimination. 展开更多
关键词 bacterial biofilm ULTRASOUND magnetic field catalytic microbubbles mechanical disruption chemical degradation
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Spatiotemporal heterogeneity of magnetic enhancement mechanisms in aeolian deposits on the southern Tibetan Plateau:Implications for paleoclimatic reconstruction in mountainbasin systems
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作者 WANG Haoyu YANG Junhuai +9 位作者 QU Wenxi WANG Linkai ZHANG Canyi LIU Xin TANG Jinmeng GAO Fuyuan CHEN Zixuan WANG Shuyuan FAN Yijiao WU Duo 《Journal of Geographical Sciences》 2026年第1期177-198,共22页
Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear resp... Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear responses to climate forcing,complicating the interpretation of its high-altitude environmental dynamics.Investigating the magnetic enhancement mechanism of aeolian deposits offers an opportunity to decipher climate signals.Our analysis of three aeolian sections from the basin indicates that magnetic minerals are predominantly low-coercivity ferrimagnetic minerals,and grain sizes fine from upper to lower reaches due to climate shifts from arid to humid.Magnetic enhancement in the upper reaches primarily originates from dust input,while dust input and pedogenesis contribute variably over time in the middle and lower reaches.Similar complex patterns occur in the Ili basin,a mountain-basin system in northwestern China.They differ from the Chinese Loess Plateau,where long-distance-transported dust is well-mixed and the pedogenic enhancement model is applied,and desert peripheries where short-distance dust is transported and the dust input model is applied.We summarize the magnetic enhancement mechanisms in various settings and offer a new framework for applying magnetic techniques in paleoclimate reconstruction within global mountain-basin systems,which highlights the need for caution in interpreting their magnetic susceptibility records. 展开更多
关键词 HOLOCENE aeolian deposits magnetic properties climate change Yarlung Zangbo River Basin
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Magnetic fabric of the late Miocene extrusive rocks of the Combia Volcanic Province:Tectonic implications for the northern Andes
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作者 Victor A.Piedrahita Martin Chadima +3 位作者 Jackeline Ramírez Alejandra Tabares Maria I.Marín-Cerón JinHua Li 《Earth and Planetary Physics》 2026年第1期44-56,共13页
The accretion of the Panama-ChocóBlock to the South American Plate partially drove the geological setting of the northern Andes.This event occurred in different collisional stages that are recorded in Oligocene-m... The accretion of the Panama-ChocóBlock to the South American Plate partially drove the geological setting of the northern Andes.This event occurred in different collisional stages that are recorded in Oligocene-middle Miocene deformed rocks of the inter-Andean valley between the Western and Central Cordilleras of Colombia.However,uncertainty remains about the age of the latest accretionary phases of the Panama-ChocóBlock.Poorly studied late Miocene volcanic rocks within the northern inter-Andean valley may provide key information to constrain the temporality of that final collision.Here,we study the deformational features of the~12-6 Ma extrusive rocks of the Combia Volcanic Province located in the northwestern Andes(Colombia).We present anisotropy of magnetic susceptibility(AMS)data for pyroclastic and volcanic rocks within the AmagáBasin,an inter-Andean depression with Oligocene-middle Miocene sedimentary rocks that recorded NW-SE compression and NE-SW simple shear caused by the Panama-ChocóBlock collision.We identified that the magnetic fabrics of the extrusive rocks of the Combia Volcanic Province reveal flow directions that indicate the occurrence of ancient volcanoes in the central axis of the AmagáBasin.Some of these fabrics do not contain any deformational features,whereas others record the same structural regime as the Oligocene-middle Miocene sedimentary rocks.We infer that variations in the intensity of the deformation promoted late Miocene local fault reactivations that,in contrast to the Oligocene-middle Miocene deformational events,did not affect the entire AmagáBasin.Age differences among the studied sections can also explain the different deformational patterns identified in the basin.Both interpretations suggest that the most significant collisional events of the Panama-ChocóBlock occurred in the Oligocene-middle Miocene,whereas the formation of the Combia Volcanic Province may have either followed or coincided with the latest stages of the accretion. 展开更多
关键词 Combia Volcanic Province Panama-ChocóBlock magnetic fabric deformation flow direction
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Magnetic pulse welding of Al-5754 with Al-7075 and MARS 380:Weldability windows and ballistic testing
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作者 Benoit Lagain Thomas Heuzé +1 位作者 Guillaume Racineux Michel Arrigoni 《Defence Technology(防务技术)》 2026年第1期64-79,共16页
Joining dissimilar materials encounters significant engineering challenges due to the contrast in material properties that makes conventional welding not feasible.Magnetic Pulse Welding(MPW)offers a solidstate joining... Joining dissimilar materials encounters significant engineering challenges due to the contrast in material properties that makes conventional welding not feasible.Magnetic Pulse Welding(MPW)offers a solidstate joining technique that overcomes these issues by using impact to create strong bonds without melting the substrate materials.This study investigates the weldability of aluminum alloy Al-5754 with Al-7075 and MARS 380 steel,used in armouring solutions of defense systems,by the use of MPW.In this work,weldability windows are investigated by varying standoff distances between the coating material and its substrate(0.25-4.5 mm)and discharge energies(5-13 kJ)with both O-shape and U-shape inductors.Mechanical strength of the welded joints were assessed through single lap shear tests,identifying optimal welding parameters.Then,the velocity profiles of the flyer plates were measured using heterodyne velocimetry to understand the dynamics of the impact.Then,substructures assembled with the optimal welding conditions were subjected to ballistic testing using 7.62 mm×51 mm NATO and 9 mm×19 mm Parabellum munitions to evaluate the resilience of the welds under ballistic impact.The outcomes demonstrate that MPW effectively joins Al-5754 with both Al-7075 and MARS 380,producing robust welds capable of withstanding ballistic impacts under certain conditions.This research advances the application of MPW in lightweight ballistic protection of defense systems,contributing to the development of more resilient and lighter protective structures. 展开更多
关键词 magnetic pulse welding(MPW) Dissimilar material joining Weldability windows Impact welding Ballistic testing
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Pulsed octupole magnet for beam instability mitigation in rapid cycling synchrotron
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作者 Liang‑Sheng Huang Shou‑Yan Xu +7 位作者 Yun‑Tao Liu Yi‑Qin Liu Jian‑Liang Chen Chang‑Dong Deng Ming‑Yang Huang Li Rao Han‑Yang Liu Xin Qi 《Nuclear Science and Techniques》 2026年第1期107-118,共12页
The rapid cycling synchrotron(RCS)at the China spallation neutron source operates as a high-intensity proton accelerator.The coupled bunch instability was observed during RCS beam commissioning,which significantly lim... The rapid cycling synchrotron(RCS)at the China spallation neutron source operates as a high-intensity proton accelerator.The coupled bunch instability was observed during RCS beam commissioning,which significantly limited the beam power.To investigate the dynamics of instability under an increased beam power,a pulsed octupole magnet with a gradient of 900 T/m^(3) was developed.The magnet system integrated an octupole magnet with a pulsed power supply.The field was carefully measured to examine the performance before its installation into the tunnel.After the installation of the magnets,beam measurements were performed to confirm the effectiveness of the instability mitigation on an actual proton beam.The measurement results show that the instability can be suppressed using the pulsed octupole magnet,particularly at the highenergy stage in an acceleration cycle,meeting the requirements for stable operation of the accelerator.Additionally,when the instability is completely suppressed through chromaticity optimization,octupole magnets can significantly enhance the RCS transmission efficiency,which is crucial for controlling beam loss.The pulsed octupole magnet offers significant progress in beam stability in the RCS,providing valuable experience for further beam power enhancement. 展开更多
关键词 China spallation neutron source Rapid cycling synchrotron Coupled bunch instability Octupole magnet
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