Nobel metallic Pt/ZSM-22 and Pt/ZSM-23 catalysts were prepared for hydroisomerization of normal dodecane and hydrodewaxing of heavy waxy lube base oil.The hydroisomerization performance of n-dodecane indicated that th...Nobel metallic Pt/ZSM-22 and Pt/ZSM-23 catalysts were prepared for hydroisomerization of normal dodecane and hydrodewaxing of heavy waxy lube base oil.The hydroisomerization performance of n-dodecane indicated that the Pt/ZSM-23 catalyst preferred to crack the C-C bond near the middle of n-dodecane chain,while the Pt/ZSM-22 catalyst was favorable for breaking the carbon chain near the end of n-dodecane.As a result,more than 2%of light products(gas plus naphtha)and3%more of heavy lube base oil with low-pour point and high viscosity index were produced on Pt/ZSM-22 than those on Pt/ZSM-23 while using the heavy waxy vacuum distillate oil as feedstock.展开更多
This article illustrates the application of the ICR series lube oil isodewaxing catalysts in commercial scale and proposes the strategy on long cycle operation and optimization of catalysts. The results of commercial ...This article illustrates the application of the ICR series lube oil isodewaxing catalysts in commercial scale and proposes the strategy on long cycle operation and optimization of catalysts. The results of commercial application of the catalyst have revealed that the catalyst after pretreatment including drying, sulfidation and reduction can process VGO into base oils meeting the HVI II and HVI II+ standards, and can manufacture base oils meeting the HVI III standard after incorporating the filtrate oil or gatch from acetone-benzene solvent dewaxing unit. The nitrogen content of the feed oil to the IDW reactor should be controlled at 1.0—1.5 ppm, while the CO and CO2 contents in fresh hydrogen is strictly controlled to avoid poisoning of the IDW-HDF catalysts.展开更多
A laboratory study was performed to assess the biodegradation of lube oil in bio-reactor with 304#stainless steel as a biofilm carrier.Among 164 oil degrading bacterial cultures isolated from oil contaminated soil sam...A laboratory study was performed to assess the biodegradation of lube oil in bio-reactor with 304#stainless steel as a biofilm carrier.Among 164 oil degrading bacterial cultures isolated from oil contaminated soil samples,Commaonas acidovorans Px1,Bacillus sp.Px2,Pseudomonas sp.Px3 were selected to prepare a mixed consortium for the study based on the efficiency of lube oil utilization.The percentage of oil degraded by the mixed bacterial consortium decreased slightly from 99%to 97.2%as the concentration of lube oil was increased from 2000 to 10,000 mg/L.The degradation of TDOC(total dissolved organic carbon)showed a similar tendency compared with lube oil removal,which indicated that the intermediates in degradation process hardly accumulated.Selected mixed bacterial consortium showed their edge compared to activated sludge.Scanning electron microscopy(SEM)photos showed that biofilms on stainless steel were robust and with a dimensional framework constructed by EPS(extracellular polymeric substances),which could promote the biodegradation of hydrocarbons.The increase of biofilm followed first-order kinetics with rate of 0.216μg glucose/(cm2·day)in logarithm phase.With analysis of Fourier transform infrared spectroscopy(FT-IR)and gas chromatography-mass spectrometry(GC-MS)combined with removal of lube oil and TDOC,mixed bacterial consortium could degrade benzene and its derivatives,aromatic ring organic matters with a percentage over 97%.展开更多
A new type of boron-nitrogen modified fatty acid as water base lube additive was prepared and the chemical structure characterized by infrared spectrum.The tribological properties of the additive in water were evaluat...A new type of boron-nitrogen modified fatty acid as water base lube additive was prepared and the chemical structure characterized by infrared spectrum.The tribological properties of the additive in water were evaluated by friction testers.The morphographies and tribochemical species of the worn surfaces were analyzed by means of X-ray Photoelectron Spectroscope(XPS).The results showed that the additive is excellent in increasing load-carrying capacity,anti-wear and friction-reducing abilities of water.The lubrication mechanism is inferred that a high strength adsorption film and a tribochemical reaction film are formed on the rubbing surfaces due to the carrier effect of the long chain fatty acid molecules,high reaction activities of nitrogen,electron-deficient orbit of boron and their synergisms.展开更多
In a gas turbine power plant,the lubrication oil must be hot enough for the turbine start-up where the unit is in standstill mode.Currently,the strategy to heat the lubrication oil of ANSALDO V94.2 gas turbine power p...In a gas turbine power plant,the lubrication oil must be hot enough for the turbine start-up where the unit is in standstill mode.Currently,the strategy to heat the lubrication oil of ANSALDO V94.2 gas turbine power plant is operating the units in turning gear mode or interval mode.However,these strategies cause to suffering the power plant from high power consumption rate and aging.In this study,an auxiliary portable heating system was added to the unit 5 of the MAPNA built MGT-70(an Iranian version of V94.2)Aliabad Katoul-Iran power plant for increasing the lube oil temperature.Irreversibility,cost-effectiveness,and availability of the proposed heating system are studied by the concepts of exergy,economy,and reliability analyses,respectively.The result of the exergy analysis shows that by using the auxiliary portable lube oil heating system the exergy destruction decreases about 94.7%and 92.6%in comparison with turning gear mode and interval mode,respectively.The result of the economic analysis shows that the auxiliary portable heating system consumes less power rather than turning gear mode.Moreover,it is a cost-effective system which has no penalty and no non-profit production.Finally,the reliability analysis shows that the auxiliary portable lube oil heating system is a reliable tool during its lifetime.展开更多
基金financial supports by National Key R&D Program of China(Grant No.2017YFB0306702)are gratefully acknowledged。
文摘Nobel metallic Pt/ZSM-22 and Pt/ZSM-23 catalysts were prepared for hydroisomerization of normal dodecane and hydrodewaxing of heavy waxy lube base oil.The hydroisomerization performance of n-dodecane indicated that the Pt/ZSM-23 catalyst preferred to crack the C-C bond near the middle of n-dodecane chain,while the Pt/ZSM-22 catalyst was favorable for breaking the carbon chain near the end of n-dodecane.As a result,more than 2%of light products(gas plus naphtha)and3%more of heavy lube base oil with low-pour point and high viscosity index were produced on Pt/ZSM-22 than those on Pt/ZSM-23 while using the heavy waxy vacuum distillate oil as feedstock.
文摘This article illustrates the application of the ICR series lube oil isodewaxing catalysts in commercial scale and proposes the strategy on long cycle operation and optimization of catalysts. The results of commercial application of the catalyst have revealed that the catalyst after pretreatment including drying, sulfidation and reduction can process VGO into base oils meeting the HVI II and HVI II+ standards, and can manufacture base oils meeting the HVI III standard after incorporating the filtrate oil or gatch from acetone-benzene solvent dewaxing unit. The nitrogen content of the feed oil to the IDW reactor should be controlled at 1.0—1.5 ppm, while the CO and CO2 contents in fresh hydrogen is strictly controlled to avoid poisoning of the IDW-HDF catalysts.
基金supported by the Foundation of Science and Technology Commission of Shanghai Municipality(No.08230707100)the State Education Ministry(No.200802471044)+2 种基金the National Major Project of Science&Technology Ministry of China(No.2008ZX07421-002)the International S&T Cooperation Projects from Ministry of Science and Technology of China(No.2009DFA90740)the State Key Laboratory of Pollution Control and Resource Reuse,China(No.PCR-RY08001)
文摘A laboratory study was performed to assess the biodegradation of lube oil in bio-reactor with 304#stainless steel as a biofilm carrier.Among 164 oil degrading bacterial cultures isolated from oil contaminated soil samples,Commaonas acidovorans Px1,Bacillus sp.Px2,Pseudomonas sp.Px3 were selected to prepare a mixed consortium for the study based on the efficiency of lube oil utilization.The percentage of oil degraded by the mixed bacterial consortium decreased slightly from 99%to 97.2%as the concentration of lube oil was increased from 2000 to 10,000 mg/L.The degradation of TDOC(total dissolved organic carbon)showed a similar tendency compared with lube oil removal,which indicated that the intermediates in degradation process hardly accumulated.Selected mixed bacterial consortium showed their edge compared to activated sludge.Scanning electron microscopy(SEM)photos showed that biofilms on stainless steel were robust and with a dimensional framework constructed by EPS(extracellular polymeric substances),which could promote the biodegradation of hydrocarbons.The increase of biofilm followed first-order kinetics with rate of 0.216μg glucose/(cm2·day)in logarithm phase.With analysis of Fourier transform infrared spectroscopy(FT-IR)and gas chromatography-mass spectrometry(GC-MS)combined with removal of lube oil and TDOC,mixed bacterial consortium could degrade benzene and its derivatives,aromatic ring organic matters with a percentage over 97%.
基金National Natural Science Fund(50275147)Chongqing City Tackle Key Problem Sustentation Item(CSTC,2008AC4080)+2 种基金Chongqing City Natural Science FundMinistry of Education"New Century Excellent Person with Ability Sustain Project"Institute Youth Fund.
文摘A new type of boron-nitrogen modified fatty acid as water base lube additive was prepared and the chemical structure characterized by infrared spectrum.The tribological properties of the additive in water were evaluated by friction testers.The morphographies and tribochemical species of the worn surfaces were analyzed by means of X-ray Photoelectron Spectroscope(XPS).The results showed that the additive is excellent in increasing load-carrying capacity,anti-wear and friction-reducing abilities of water.The lubrication mechanism is inferred that a high strength adsorption film and a tribochemical reaction film are formed on the rubbing surfaces due to the carrier effect of the long chain fatty acid molecules,high reaction activities of nitrogen,electron-deficient orbit of boron and their synergisms.
文摘In a gas turbine power plant,the lubrication oil must be hot enough for the turbine start-up where the unit is in standstill mode.Currently,the strategy to heat the lubrication oil of ANSALDO V94.2 gas turbine power plant is operating the units in turning gear mode or interval mode.However,these strategies cause to suffering the power plant from high power consumption rate and aging.In this study,an auxiliary portable heating system was added to the unit 5 of the MAPNA built MGT-70(an Iranian version of V94.2)Aliabad Katoul-Iran power plant for increasing the lube oil temperature.Irreversibility,cost-effectiveness,and availability of the proposed heating system are studied by the concepts of exergy,economy,and reliability analyses,respectively.The result of the exergy analysis shows that by using the auxiliary portable lube oil heating system the exergy destruction decreases about 94.7%and 92.6%in comparison with turning gear mode and interval mode,respectively.The result of the economic analysis shows that the auxiliary portable heating system consumes less power rather than turning gear mode.Moreover,it is a cost-effective system which has no penalty and no non-profit production.Finally,the reliability analysis shows that the auxiliary portable lube oil heating system is a reliable tool during its lifetime.
