Magnetostrictive Fe-Ga alloys have captivated substantial focus in biomedical applications because of their exceptional transition efficiency and favorable cytocompatibility.Nevertheless,Fe-Ga alloys always exhibit fr...Magnetostrictive Fe-Ga alloys have captivated substantial focus in biomedical applications because of their exceptional transition efficiency and favorable cytocompatibility.Nevertheless,Fe-Ga alloys always exhibit frustrating magnetostriction coefficients when presented in bulk dimensions.It is well-established that the magnetostrictive performance of Fe-Ga alloys is intimately linked to their phase and crystal structures.In this study,various concentrations of boron(B)were doped into Fe_(81)Ga_(19) alloys via the laser-beam powder bed fusion(LPBF)technique to tailor the crystal and phase structures,thereby improving the magnetostrictive performance.The results revealed the capacity for quick solidification of the LPBF process in expediting the solid solution of B element,which increased both lattice distortion and dislocations within the Fe-Ga matrix.These factors contributed to an elevation in the density of the modified-D0_(3) phase structure.Moreover,the prepared Fe-Ga-B alloys also exhibited a(001)preferred grain orientation caused by the high thermal gradients during the LPBF process.As a result,a maximum magnetostriction coefficient of 105 ppm was achieved in the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy.In alternating magnetic fields,all the LPBF-prepared alloys showed good dynamic magnetostriction response without visible hysteresis,while the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy presented a notable enhancement of~30%in magnetostriction coefficient when compared with the Fe_(81)Ga_(19) alloy.Moreover.the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy exhibited favorable biocompatibility and osteogenesis,as confirmed by increased alkaline phosphatase(ALP)activity and the formation of mineralized nodules.These findings suggest that the B-doped Fe-Ga alloys combined with the LPBF technique hold promise for the development of bulk magnetostrictive alloys that are applicable for bone repair applications.展开更多
Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.Howe...Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.展开更多
The DLBSW（ dual laser-beam bilateral synchronous welding） technology of T-type joint has been widely used for the connection of skins and stringers in airplane industry. To understand the thermodynamic and mechanica...The DLBSW（ dual laser-beam bilateral synchronous welding） technology of T-type joint has been widely used for the connection of skins and stringers in airplane industry. To understand the thermodynamic and mechanical behavior of this process, it is necessary to establish a reasonable heat source model. Two different surface-body combination heat source models are adopted in this paper. Both models use the Gaussian surface heat source model and one is combined with the cone body heat source model and the other is combined with Gaussian rotator body heat source model. The simulation results of these two different models are investigated. And the temperature field results of DLBSW process for T-joint with two different heat sources are discussed. It is indicated that the combination heat source model is effective to simulate the DLBSW process and the current study is useful for more profound research in this field.展开更多
Magnetostrictive Fe-Ga alloys have been demonstrated potentialities for numerous applications,whereas,suffering a tradeoff between large magnetostrictive strain and high sensitivity.Herein,bulk polycrystalline Fe81Ga1...Magnetostrictive Fe-Ga alloys have been demonstrated potentialities for numerous applications,whereas,suffering a tradeoff between large magnetostrictive strain and high sensitivity.Herein,bulk polycrystalline Fe81Ga19 alloys were prepared by laser-beam powder bed fusion(LPBF)and then annealed in magnetic field for manipulating the comprehensive magnetostrictive properties.Results indicate that<001>oriented grains are developed in the LPBF-prepared Fe81Ga19 alloys due to high temperature gradient.After magnetic field annealing(MFA),the magnetic domains within the alloys gradually transformed into well-arranged stripe domains,especially,flat and smooth 90°domains were established in the alloys annealed at 2600 Oe.As a result,the induced<001>orientation grains and 90°domains contributed to an improved effective magnetic anisotropy constant(57.053 kJ/m^(3)),leading to an enhanced magnetostrictive strain of 92 ppm.Moreover,the MFA-treated alloys also displayed enhanced magnetostrictive sensitivity(0.097 ppm/Oe)owing to the smooth domain structures and low dislocation densities,demonstrating a fruitful strain-sensitivity synergy.In addition,good magnetostrictive dynamic response and enhanced compressive yield strength were also observed for the prepared alloys.This work demonstrates that LPBF and MFA might be an attractive strategy to resolve the tradeoff between strain and sensitivity,providing a basis for the preparation of high-performance magnetostrictive materials.展开更多
Fe-Ga-based alloys are considered promising magnetostrictive candidates because of their high permeability and favorable mechanical properties.However,currently developed Fe-Ga-based alloys often suffer from a limited...Fe-Ga-based alloys are considered promising magnetostrictive candidates because of their high permeability and favorable mechanical properties.However,currently developed Fe-Ga-based alloys often suffer from a limited capability for microstructure manipulation,which restricts their magnetostrictive performance.To address this limitation,this study proposes a novel strategy combining laser-beam powder bed fusion(LPBF)and aging treatment to modulate the microstructure and enhance magnetostrictive properties of Fe-Ga-B alloys.Considering the positive influence of B element on magnetostrictive property and ductility,B-doped magnetostrictive Fe-Ga alloys were prepared via the LPBF process and then aged at 600℃for varying times(1,2,and 3 h,respectively).The LPBF process,characterized by high thermal gradients and rapid solidification,produced a microstructure featuring<001>oriented grains and sparse m-D0_(3)nanoprecipitates embedded in an A2 matrix.After the aging treatment,sufficient nucleation and growth of nanoprecipitates were enhanced.Specifically,the sample aged for 2 h developed a high density of larger m-D0_(3)nanoprecipitates.This optimized microstructure yielded a high magnetostrictive strain of(109±12)ppm and a substantially reduced saturation field—decreased by~49.1%compared to the as-fabricated state—primarily due to the synergistic effect of the<001>texture and the dense nanoprecipitates.Moreover,all the prepared alloys exhibited good soft-magnetic characteristics and comparable mechanical properties.Therefore,the combination of LPBF and aging treatment offers a promising route for tailoring the macro/microstructure and performance of magnetostrictive Fe-Ga alloys for diverse applications.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52275395,51935014,and 82072084)the Science and Technology Innovation Program of Hunan Province(No.2023RC3046)+4 种基金the Young Elite Scientists Sponsorship Program byCAST(No.2020QNRC002)the NationalKeyResearchand Development Program of China(No.2023YFB4605800)the Central South University Innovation-Driven Research Programme(No.2023CXQD023)the Jiangxi Provincial Natural Science Foundation of China(No.20224ACB204013)the Project of State Key Laboratory of Precision Manufacturing for Extreme Service Performance,Central South University.
文摘Magnetostrictive Fe-Ga alloys have captivated substantial focus in biomedical applications because of their exceptional transition efficiency and favorable cytocompatibility.Nevertheless,Fe-Ga alloys always exhibit frustrating magnetostriction coefficients when presented in bulk dimensions.It is well-established that the magnetostrictive performance of Fe-Ga alloys is intimately linked to their phase and crystal structures.In this study,various concentrations of boron(B)were doped into Fe_(81)Ga_(19) alloys via the laser-beam powder bed fusion(LPBF)technique to tailor the crystal and phase structures,thereby improving the magnetostrictive performance.The results revealed the capacity for quick solidification of the LPBF process in expediting the solid solution of B element,which increased both lattice distortion and dislocations within the Fe-Ga matrix.These factors contributed to an elevation in the density of the modified-D0_(3) phase structure.Moreover,the prepared Fe-Ga-B alloys also exhibited a(001)preferred grain orientation caused by the high thermal gradients during the LPBF process.As a result,a maximum magnetostriction coefficient of 105 ppm was achieved in the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy.In alternating magnetic fields,all the LPBF-prepared alloys showed good dynamic magnetostriction response without visible hysteresis,while the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy presented a notable enhancement of~30%in magnetostriction coefficient when compared with the Fe_(81)Ga_(19) alloy.Moreover.the(Fe_(81)Ga_(19))_(98.5)B_(1.5) alloy exhibited favorable biocompatibility and osteogenesis,as confirmed by increased alkaline phosphatase(ALP)activity and the formation of mineralized nodules.These findings suggest that the B-doped Fe-Ga alloys combined with the LPBF technique hold promise for the development of bulk magnetostrictive alloys that are applicable for bone repair applications.
基金supported by the following funds:National Natural Science Foundation of China(51935014,52165043)Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects(20225BCJ23008)+1 种基金Jiangxi Provincial Natural Science Foundation(20224ACB204013,20224ACB214008)Scientific Research Project of Anhui Universities(KJ2021A1106)。
文摘Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.
基金The research is sponsored by the Shanghai STCSM Project of the Postdoctoral Science Research Assistant Plan （10R21421200）, the National Natural Science Foundation of China （50904038） and the China Postdoctoral Science Foundation （20100470064）.
文摘The DLBSW（ dual laser-beam bilateral synchronous welding） technology of T-type joint has been widely used for the connection of skins and stringers in airplane industry. To understand the thermodynamic and mechanical behavior of this process, it is necessary to establish a reasonable heat source model. Two different surface-body combination heat source models are adopted in this paper. Both models use the Gaussian surface heat source model and one is combined with the cone body heat source model and the other is combined with Gaussian rotator body heat source model. The simulation results of these two different models are investigated. And the temperature field results of DLBSW process for T-joint with two different heat sources are discussed. It is indicated that the combination heat source model is effective to simulate the DLBSW process and the current study is useful for more profound research in this field.
基金supported by the following funds:The Natural Science Foundation of China(52275395,51935014,82072084)The Science and Technology Innovation Program of Hunan Province(2023RC3046)+5 种基金Young Elite Scientists Sponsorship Program by CAST(2020QNRC002)National Key Research and Development Program of China(2023YFB4605800)Central South University Innovation-Driven Research Programme(2023CXQD023)JiangXi Provincial Natural Science Foundation of China(20224ACB204013)The Project of State Key Laboratory of Precision Manufacturing for Extreme Service Performance,Central South UniversityThe Fundamental Research Funds for the Central Universities of Central South University(1053320230182).
文摘Magnetostrictive Fe-Ga alloys have been demonstrated potentialities for numerous applications,whereas,suffering a tradeoff between large magnetostrictive strain and high sensitivity.Herein,bulk polycrystalline Fe81Ga19 alloys were prepared by laser-beam powder bed fusion(LPBF)and then annealed in magnetic field for manipulating the comprehensive magnetostrictive properties.Results indicate that<001>oriented grains are developed in the LPBF-prepared Fe81Ga19 alloys due to high temperature gradient.After magnetic field annealing(MFA),the magnetic domains within the alloys gradually transformed into well-arranged stripe domains,especially,flat and smooth 90°domains were established in the alloys annealed at 2600 Oe.As a result,the induced<001>orientation grains and 90°domains contributed to an improved effective magnetic anisotropy constant(57.053 kJ/m^(3)),leading to an enhanced magnetostrictive strain of 92 ppm.Moreover,the MFA-treated alloys also displayed enhanced magnetostrictive sensitivity(0.097 ppm/Oe)owing to the smooth domain structures and low dislocation densities,demonstrating a fruitful strain-sensitivity synergy.In addition,good magnetostrictive dynamic response and enhanced compressive yield strength were also observed for the prepared alloys.This work demonstrates that LPBF and MFA might be an attractive strategy to resolve the tradeoff between strain and sensitivity,providing a basis for the preparation of high-performance magnetostrictive materials.
基金supported by the Hunan Provincial Natural Science Foundation of China(Grant No.2025JJ30015)the National Natural Science Foundation of China(Grant Nos.52571276,52275395,U24A20120,52475362)+4 种基金the Science and Technology Innovation Program of Hunan Province(Grant No.2023RC3046)the National Key Research and Development Program of China(Grant No.2023YFB4605800)the Central South University Innovation-driven Research Programme(Grant No.2023CXQD023)the Jiangxi Provincial Natural Science Foundation of China(Grant No.20224ACB204013)the Project of State Key Laboratory of Precision Manufacturing for Extreme Service Performance of Central South University and the Fundamental Research Funds for the Central Universities of Central South University(Grant No.1053320230182)。
文摘Fe-Ga-based alloys are considered promising magnetostrictive candidates because of their high permeability and favorable mechanical properties.However,currently developed Fe-Ga-based alloys often suffer from a limited capability for microstructure manipulation,which restricts their magnetostrictive performance.To address this limitation,this study proposes a novel strategy combining laser-beam powder bed fusion(LPBF)and aging treatment to modulate the microstructure and enhance magnetostrictive properties of Fe-Ga-B alloys.Considering the positive influence of B element on magnetostrictive property and ductility,B-doped magnetostrictive Fe-Ga alloys were prepared via the LPBF process and then aged at 600℃for varying times(1,2,and 3 h,respectively).The LPBF process,characterized by high thermal gradients and rapid solidification,produced a microstructure featuring<001>oriented grains and sparse m-D0_(3)nanoprecipitates embedded in an A2 matrix.After the aging treatment,sufficient nucleation and growth of nanoprecipitates were enhanced.Specifically,the sample aged for 2 h developed a high density of larger m-D0_(3)nanoprecipitates.This optimized microstructure yielded a high magnetostrictive strain of(109±12)ppm and a substantially reduced saturation field—decreased by~49.1%compared to the as-fabricated state—primarily due to the synergistic effect of the<001>texture and the dense nanoprecipitates.Moreover,all the prepared alloys exhibited good soft-magnetic characteristics and comparable mechanical properties.Therefore,the combination of LPBF and aging treatment offers a promising route for tailoring the macro/microstructure and performance of magnetostrictive Fe-Ga alloys for diverse applications.
