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Interacting Mathieu equation,synchronization dynamics and collision-induced velocity exchange in trapped ions
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作者 Asma Benbouza Xiaoshui Lin +1 位作者 Jin Ming Cui Ming Gong 《Communications in Theoretical Physics》 2025年第8期67-81,共15页
Recently,large-scale trapped ion systems have been realized in experiments for quantum simulation and quantum computation.They are the simplest systems for dynamical stability and parametric resonance.In this model,th... Recently,large-scale trapped ion systems have been realized in experiments for quantum simulation and quantum computation.They are the simplest systems for dynamical stability and parametric resonance.In this model,the Mathieu equation plays the most fundamental role for us to understand the stability and instability of a single ion.In this work,we investigate the dynamics of trapped ions with the Coulomb interaction based on the Hamiltonian equation.We show that the many-body interaction will not influence the phase diagram for instability.Then,the dynamics of this model in the large damping limit will also be analytically calculated using few trapped ions.Furthermore,we find that in the presence of modulation,synchronization dynamics can be observed,showing an exchange of velocities between distant ions on the left side and on the right side of the trap.These dynamics resemble that of the exchange of velocities in Newton's cradle for the collision of balls at the same time.These dynamics are independent of their initial conditions and the number of ions.As a unique feature of the interacting Mathieu equation,we hope this behavior,which leads to a quasi-periodic solution,can be measured in current experimental systems.Finally,we have also discussed the effect of anharmonic trapping potential,showing the desynchronization during the collision process.It is hoped that the dynamics in this many-body Mathieu equation with damping may find applications in quantum simulations.This model may also find interesting applications in dynamics systems as a pure mathematical problem,which may be beyond the results in the Floquet theorem. 展开更多
关键词 trapped ions Mathieu equation Floquet theory SYNCHRONIZATION many-body interactions
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Temporal and Spatial Variations in the Concentration of Negative Ions and Its Influencing Factors in Xinfeng County
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作者 Yiping LIN Xuanying XIE +1 位作者 Liqing ZHOU Liwen YE 《Meteorological and Environmental Research》 2025年第1期41-43,48,共4页
Based on the data of meteorological elements and concentration of negative ions in the county town station,Luguhe station and Yunjishan station during 2020-2024,the temporal and spatial variations in the concentration... Based on the data of meteorological elements and concentration of negative ions in the county town station,Luguhe station and Yunjishan station during 2020-2024,the temporal and spatial variations in the concentration of negative ions and their influencing factors in Xinfeng County were analyzed.The results show that the concentration of negative ions was the highest in summer,followed by spring;it was lower in autumn and the lowest in winter.In terms of diurnal variations,it was higher in the early morning and night,and lower in the noon and afternoon,which was closely related to the diurnal variations of human activities and meteorological conditions.The factors that affect the concentration of negative ions in the air are more complex.Besides meteorological factors,vegetation,altitude,human activities and other factors should be considered. 展开更多
关键词 Concentration of negative ions Temporal and spatial variations Influencing factors Xinfeng County
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Failure mechanisms of AlGaN/GaN HEMTs irradiated by high-energy heavy ions with and without bias 被引量:1
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作者 Pei-Pei Hu Li-Jun Xu +9 位作者 Sheng-Xia Zhang Peng-Fei Zhai Ling Lv Xiao-Yu Yan Zong-Zhen Li Yan-Rong Cao Xue-Feng Zheng Jian Zeng Yuan He Jie Liu 《Nuclear Science and Techniques》 2025年第1期49-58,共10页
Gallium nitride(GaN)-based devices have significant potential for space applications.However,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains unknown.This study inve... Gallium nitride(GaN)-based devices have significant potential for space applications.However,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains unknown.This study investigates the effects of radiation on p-gate AlGaN/GaN high-electron-mobility transistors(HEMTs).Under a high voltage,the HEMT leakage current increased sharply and was accompanied by a rapid increase in power density that caused"thermal burnout"of the devices.In addition,a burnout signature appeared on the surface of the burned devices,proving that a single-event burnout effect occurred.Additionally,degradation,including an increase in the on-resistance and a decrease in the breakdown voltage,was observed in devices irradiated with high-energy heavy ions and without bias.The latent tracks induced by heavy ions penetrated the heterojunction interface and extended into the GaN layer.Moreover,a new type of N_(2)bubble defect was discovered inside the tracks using Fresnel analysis.The accumulation of N_(2)bubbles in the heterojunction and buffer layers is more likely to cause leakage and failure.This study indicates that electrical stress accelerates the failure rate and that improving heat dissipation is an effective reinforcement method for GaN-based devices. 展开更多
关键词 GaN HEMTs Heavy ions Single-event burnout Latent tracks Degradation
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Enhanced Ion Sampling Techniques for In-situ Neutral Gas and Low-energy Ions Exploration of Main-belt Comet
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作者 WANG Xinyue ZHANG Aibing +4 位作者 SU Bin DU Dan KONG Linggao TIAN Zheng ZHENG Xiangzhi 《空间科学学报》 北大核心 2025年第3期749-760,共12页
One of the detection objectives of the Chinese Asteroid Exploration mission is to investigate the space environment near the Main-belt Comet(MBC,Active Asteroid)311P/PANSTARRS.This paper outlines the scientific object... One of the detection objectives of the Chinese Asteroid Exploration mission is to investigate the space environment near the Main-belt Comet(MBC,Active Asteroid)311P/PANSTARRS.This paper outlines the scientific objectives,measurement targets,and measurement requirements for the proposed Gas and Ion Analyzer(GIA).The GIA is designed for in-situ mass spectrometry of neutral gases and low-energy ions,such as hydrogen,carbon,and oxygen,in the vicinity of 311P.Ion sampling techniques are essential for the GIA's Time-of-Flight(TOF)mass analysis capabilities.In this paper,we present an enhanced ion sampling technique through the development of an ion attraction model and an ion source model.The ion attraction model demonstrates that adjusting attraction grid voltage can enhance the detection efficiency of low-energy ions and mitigate the repulsive force of ions during sampling,which is influenced by the satellite's surface positive charging.The ion source model simulates the processes of gas ionization and ion multiplication.Simulation results indicate that the GIA can achieve a lower pressure limit below 10-13Pa and possess a dynamic range exceeding 10~9.These performances ensure the generation of ions with stable and consistent current,which is crucial for high-resolution and broad dynamic range mass spectrometer analysis.Preliminary testing experiments have verified GIA's capability to detect gas compositions such as H2O and N2.In-situ measurements near 311P using GIA are expected to significantly contribute to our understanding of asteroid activity mechanisms,the evolution of the atmospheric and ionized environments of main-belt comets,the interactions with solar wind,and the origin of Earth's water. 展开更多
关键词 neutral gas low energy ions sampling techniques ion sampling techniques investigate space environment main belt comet gas ion analyzer gia situ measurement
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A highly-integrated fiber fluid sensing system of metal ion concentrations with resistance to temperature crosstalk
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作者 GUO Junqi XU Qianwen +3 位作者 GUO Binwei Andrei KULIKOV ZHENG Wenyue CUI Jiwen 《Optoelectronics Letters》 2025年第4期193-198,共6页
To address the temperature cross-talk issue in detecting heavy metal ions in natural waters, a highly-integrated and fully fiber-optic metal ion sensing system capable of temperature-concentration decoupling measureme... To address the temperature cross-talk issue in detecting heavy metal ions in natural waters, a highly-integrated and fully fiber-optic metal ion sensing system capable of temperature-concentration decoupling measurement has been designed. This system integrates a fluidic detection structure assisted by side-polished fibers(SPFs) with a Sagnac interferometer. 展开更多
关键词 refractive index ranges natural watersa fiber optic sensing fluidic detection structure heavy metal ions metal ion sensing contaminated water sources temperature crosstalk
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Synergistic mechanism of metal ions and sodium N-oleoylsarcosinate on flotation separation of lepidolite from feldspar
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作者 Guo-yuan XIANG Rui-hua FAN +3 位作者 Wen-tao ZHU Wei SUN Ren-ji ZHENG Zhi-yong GAO 《Transactions of Nonferrous Metals Society of China》 2025年第1期296-312,共17页
The combined reagents of sodium N-oleoylsarcosinate(SNOS)with metal ions(Ca(Ⅱ),Mg(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ))was employed to facilitate the separation of lepidolite from feldspar.The synergistic interaction mechanism of t... The combined reagents of sodium N-oleoylsarcosinate(SNOS)with metal ions(Ca(Ⅱ),Mg(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ))was employed to facilitate the separation of lepidolite from feldspar.The synergistic interaction mechanism of this combined reagent was systematically investigated via contact angle measurements,AFM,FTIR,species distribution calculations,and DFT calculations.The results suggested that Ca(Ⅱ)exhibited the best selectivity for activating lepidolite flotation.SNOS was chemically adsorbed on the Ca(Ⅱ)-activated lepidolite surface with an adsorption energy of−1248.91 kJ/mol while a lower adsorption energy of−598.84 kJ/mol of SNOS on Ca(Ⅱ)-activated feldspar was calculated.Therefore,this combination of SNOS and Ca(Ⅱ)is a promising reagent scheme for the efficient recovery of lithium from aluminosilicate ore. 展开更多
关键词 FLOTATION LEPIDOLITE FELDSPAR sodium N-oleoylsarcosinate metal ions
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Recovering Ag^(+)with nano-MOF-303 to form Ag/AgCl/MOF-303 photocatalyst:The role of stored Cl^(-)ions
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作者 Ming-Yi Sun Lu Zhang +4 位作者 Ya Li Chong-Chen Wang Peng Wang Xueying Ren Xiao-Hong Yi 《Chinese Chemical Letters》 2025年第2期460-464,共5页
The nano-MOF-303 synthesized by microwave method exhibited efficient adsorption capacity(232 mg/g)toward Ag^(+),in which the adsorption behaviors were fitted by the pseudo-second-order kinetic and the Freundlich isoth... The nano-MOF-303 synthesized by microwave method exhibited efficient adsorption capacity(232 mg/g)toward Ag^(+),in which the adsorption behaviors were fitted by the pseudo-second-order kinetic and the Freundlich isotherm model.The outstanding Ag^(+)sorption ability of nano-MOF-303 could be contributed to electrostatic interactions,weak coordination interaction of Ag-N,and Ag Cl precipitates originating from the stored Cl^(-)in nano-MOF-303.Besides the adsorbent regeneration,the formed Ag/Ag Cl onto nano-MOF-303 could produce Ag/Ag Cl/MOF-303 as a photocatalyst for sulfamethoxazole degradation under visible light.In this work,both the adsorption and photocatalysis mechanisms were clarified,which might provide insight to develop more effective adsorbents for mining the critical resource from the wastewater. 展开更多
关键词 MOF-303 Silver ions Resource recovery PHOTOCATALYST Mechanism
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Corrosion behavior of an ultrafine-grained Ti6Al4V-5Cu alloy in artificial saliva containing fluoride ions
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作者 Hui Liu Lizhen Shi +4 位作者 Susu Li Shuyuan Zhang Hai Wang Ling Ren Ke Yang 《Journal of Materials Science & Technology》 2025年第9期259-271,共13页
Ti6Al4V alloy has been widely used in dental applications,such as orthodontic mini-implants.However,it has been reported that fluoride ions could obviously accelerate the corrosion of implant materials and affect thei... Ti6Al4V alloy has been widely used in dental applications,such as orthodontic mini-implants.However,it has been reported that fluoride ions could obviously accelerate the corrosion of implant materials and affect their performance.This work aimed to improve the F^(−)erosion resistance of Ti6Al4V alloy through the strategy of both Cu addition and grain refinement.As contrasted with Ti6Al4V alloy,both the coarse-and ultrafine-grained Ti6Al4V-5Cu alloys effectively mitigated the acceleration of the fluoride ions to the anode process,because Cu substituents blocked the continuous damage of F·_(O) doped in the passive film.Furthermore,grain refinement enhanced the protective ability of the passive film,more oxides and less adsorption amount of fluorides presented in the passive film of ultrafine-grained Ti6Al4V-5Cu alloy than those of coarse-grained Ti6Al4V-5Cu alloy.Under the combination of Cu alloying and grain refinement,the ultrafine-grained Ti6Al4V-5Cu alloy is greatly appropriate for the fabrication of orthodontic devices. 展开更多
关键词 Cu-containing titasknium alloy Grain refinement Fluoride ions Corrosion Dental application
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Impact of local amorphous environment on the diffusion of sodium ions at the solid electrolyte interface in sodium-ion batteries
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作者 Yao Wang Jun Ouyang +5 位作者 Huadong Yuan Jianmin Luo Shihui Zou Jianwei Nai Xinyong Tao Yujing Liu 《Chinese Chemical Letters》 2025年第10期647-653,共7页
The in-depth study of the transport properties of the solid electrolyte interface(SEI)is crucial for the development of ultra-high-rate,and long lifespan sodium-ion batteries(SIBs).However,there remains a lack of theo... The in-depth study of the transport properties of the solid electrolyte interface(SEI)is crucial for the development of ultra-high-rate,and long lifespan sodium-ion batteries(SIBs).However,there remains a lack of theoretical investigation into the transport mechanisms of the main inorganic components of the SEI,namely Na F,Na_(2)O,and Na_(2)CO_(3).To address this research gap,we performed classical molecular dynamics simulations in this work to study the diffusion mechanisms of sodium ions in these inorganic components of the SEI,with special emphasis on the impact of the amorphous SEI environment on the diffusion behavior of sodium ions.The results have shown that amorphous SEI components significantly enhance the diffusion rate of sodium ions at room temperature compared to crystalline components.Within these amorphous SEI components,we reveal that the diffusion coefficients of sodium ions in amorphous Na_(2)O and Na_(2)CO_(3)are more than an order of magnitude higher than that of Na F,suggesting that amorphous Na_(2)O and Na_(2)CO_(3)are more effective in facilitating the Na ion diffusion.Analysis of the local atomic structure indicates that the amorphous local structures are dominant in Na_(2)O and Na_(2)CO_(3)at room temperature,maintaining a disordered amorphous phase.In contrast,amorphous Na F undergoes a spontaneously transformation into an ordered structure,exhibiting crystalline characteristics that restrict the diffusion of sodium ions.In summary,our work provides atomic insights into the impact of local amorphous environments on Na ion diffusion in SEI and suggests that amorphous SEI components play a critical role in improving battery performance. 展开更多
关键词 Sodium ions diffusion Solid electrolyte interphase AMORPHOUS Molecular dynamics Sodium-ion batteries
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Saturation effect study and ion recombination correction on ionization chamber for ultra‑high dose rate (FLASH) of carbon ions
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作者 Xin-Le Lang Zheng-Guo Hu +10 位作者 Zhi-Guo Xu Juan Li Kai Zhou Fa-Ming Luo Yu-Cong Chen Rui-Shi Mao Chuan Huang Zu-Long Zhao Jia-Li Fu Li-Bin Zhou Guo-Qing Xiao 《Nuclear Science and Techniques》 2025年第10期35-46,共12页
The ionization chamber produces significant space-charge and ion recombination effects at ultra-high dose rates,posing achallenge for dose monitoring.In addition,there is no generally accepted ion correction model for... The ionization chamber produces significant space-charge and ion recombination effects at ultra-high dose rates,posing achallenge for dose monitoring.In addition,there is no generally accepted ion correction model for dosimetry in FLASHradiotherapy,making it crucial to monitor the dose at ultra-high dose rates accurately and in real time.In this study,the airpressure of the ionization chamber was reduced to perform real-time beam monitoring,and a Faraday cup was used for calibrationfor active dosimetry.To study the saturation effect of the ionization chamber,the drift,attachment,recombination,anddiffusion processes of the electron-ion pairs were modeled using finite-element analysis based on physical phenomenologicalprinciples,and the correction factor was calculated.The experimental results showed that the FLASH ionization chambermeasures good dose linearity at a dose rate of approximately 0.2 Gy/s.When the air pressure of the chamber was adjustedto 10 mbar,the response of the FLASH ionization chamber was linear at a dose rate of approximately 50 Gy/s,with theresiduals within 2%.Furthermore,by using physical phenomenology to resolve the process of electron-ion pair motion inthe sensitive volume of the ionization chamber,the analytical model better describes the saturation effect of carbon ions atultra-high dose rates.The maximum deviation in the calculated correction factor is less than 10%.We studied the saturationeffect in dose measurement,achieving accurate and fast dose and profile position measurement across different dose ratesin a wide range based on the Heavy Ion Research Facility in Lanzhou. 展开更多
关键词 FLASH radiotherapy Ultra-high dose rate Carbon ions·Dosimetry Saturation effect Correction factor
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From natural medicines to metal weapons:therapeutic potential of flavonoid metabolites in regulating host-Mycobacterium tuberculosis metal interactions
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作者 Tianyi Zhao Qingxuan Wu +4 位作者 Yihao Fan Ru Li Zifei Yang Wenxin Li Xiaoyun Zhao 《Asian Journal of Traditional Medicines》 2025年第3期140-155,共16页
Tuberculosis,an infectious disease,causes considerable morbidity and mortality.Within the host immune system,transition metals play vital roles in combating Mycobacterium tuberculosis(MTB),acting as catalytic cofactor... Tuberculosis,an infectious disease,causes considerable morbidity and mortality.Within the host immune system,transition metals play vital roles in combating Mycobacterium tuberculosis(MTB),acting as catalytic cofactors,mediating electron transport,and catalyzing antimicrobial radical formation.Both the host and MTB have developed mechanisms to maintain metal homeostasis.Flavonoids,important herbal materials with potent iron-chelating ability,have gained attention for their antitubercular and anti-inflammatory effects,making them a promising treatment option.This review explores how trace metals restrict MTB and the dynamic balance between pathogen and host,revealing innovative perspectives for therapeutic interventions. 展开更多
关键词 Mycobacterium tuberculosis flavonoid metal ions homeostasis zinc oxide nanoparticles
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Weakening Mechanism of Sulfate Ions on Grouting Composites in the Strong Weathering Rock of Submarine Tunnels in a Dynamic Seawater Environment
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作者 LI Peng WANG Cheng-qian +3 位作者 LIU Yong SHENG Yu-ming SUN Yue HE Ling-yao 《China Ocean Engineering》 2025年第3期518-528,共11页
Grouting represents a reliable method for strengthening fractured rock masses and preventing seawater infiltration in subsea tunnel engineering. However, grouting composites are continuously subjected to harsh marine ... Grouting represents a reliable method for strengthening fractured rock masses and preventing seawater infiltration in subsea tunnel engineering. However, grouting composites are continuously subjected to harsh marine environments,experiencing both chemical and physical effects from high-concentration erosive seawater ions, elevated water pressure, and complex flow fields. This multi-factor erosion deterioration diminishes the waterproofing capabilities of grouting composites and threatens the service life of subsea tunnel linings. To investigate the erosion deteriortion mechanism induced by sulfate, erosion weakening experiments were conducted using a seawater flow simulation device. The research examined the compressive strength and permeability coefficient of grouting composites under different erosion durations, water-cement ratios, and grouting pressures. In the later stages of the experiment, the strength of grouting composites in the static water erosion control group(SEG) and dynamic water erosion group(DEG) decreased by 31.2% and 18.8%, respectively, compared to the freshwater control group(FG). Futhermore, the permeability coefficient exhibited significant increases. Subsequent microscopic analyses of the eroded grouting composites were performed. This research elucidated the erosion-weakening mechanism of grouting composites subjected to sulfate-induced degradation in complex marine environments. The study emphasizes the critical role of erosion resistance and durability in design and implementation. From practical perspective, this work establishes a foundation for developing enhanced strategies to improve the long-term performance and integrity of grouting composites in subsea tunnel applications. 展开更多
关键词 subsea tunnel grouting composite erosion of sulfate ions dynamic water environment
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A stable scandium(III) metal-organic framework with introduced nitrate ions for enhancing C_(2)H_(6)/C_(2)H_(4) selectivity in the separation of MTO products
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作者 Yajun Gao Xinyu Yang +1 位作者 Jian Su Zhizhong Li 《Chinese Journal of Structural Chemistry》 2025年第6期18-25,共8页
Based upon the thiophene-2,5-dicarboxylic acid(H_(2)Tdc),a novel[Sc_(3)(μ_(2)-OH)_(3)(CO_(2))_(4)O_(6)]n inorganic chain-based Sc-MOF with decorated nitrate ions,{[Sc_(3)(OH)_(2)(Tdc)_(3)(NO_(3))]⋅H_(2)O}_(∞)(AEU-1;... Based upon the thiophene-2,5-dicarboxylic acid(H_(2)Tdc),a novel[Sc_(3)(μ_(2)-OH)_(3)(CO_(2))_(4)O_(6)]n inorganic chain-based Sc-MOF with decorated nitrate ions,{[Sc_(3)(OH)_(2)(Tdc)_(3)(NO_(3))]⋅H_(2)O}_(∞)(AEU-1;AEU for Army Engineering University of PLA),was synthesized,which shows good water and chemical stabilities.Significantly,due to channel constriction accompanied by the polar window caused by introducing nitrate ions,AEU-1 exhibits high C_(2)H_(6)/C_(2)H_(4)adsorption selectivity comparable to many famous C_(2)H_(6)-selective MOFs,making it a promising candidate for the purification of methanol-to-olefin(MTO)products.Furthermore,theoretical investigations reveal that the introduced nitrate ions in AEU-1 as the main adsorption sites could provide strong interactions between the framework and C2H6/C3H6 in the full-contacting mode,leading to an increase in the adsorption enthalpies(Qst)of C_(2)H_(6)and C_(3)H_(6),and thus further improving the C_(2)H_(6)/C_(2)H_(4)and C_(3)H_(6)/C_(2)H_(4)adsorption selectivity.Our work could open up a new avenue for constructing MOFs with inorganic polar moieties as adsorption sites for one-step C_(2)H_(4)purification and C3H6 recovery from MTO mixtures with high selectivity. 展开更多
关键词 Scandium(III)metal-organic framework Nitrate ions SELECTIVITY MTO product separation
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State-selective single-and double-electron capture in collisions of low-energy S^(5+) ions with helium
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作者 Yixin Fan Dadi Xing +10 位作者 Shucheng Cui Xiaoxia Wang Junxia Ran Kaizhao Lin Xubin Zhu Dongmei Zhao Dalong Guo Yong Gao Shaofeng Zhang Xiaolong Zhu Xinwen Ma 《Chinese Physics B》 2025年第7期53-58,共6页
State-selective single-and double-electron capture processes in collisions of S^(5+)ions with helium at energies ranging from 50.8 keV to 100 keV were investigated using cold target recoil ion momentum spectroscopy(CO... State-selective single-and double-electron capture processes in collisions of S^(5+)ions with helium at energies ranging from 50.8 keV to 100 keV were investigated using cold target recoil ion momentum spectroscopy(COLTRIMS).Q-value spectra and projectile scattering angle distributions were obtained.For single-electron capture,single electron capture into n=3 states of the projectile ion is dominant.As the projectile energy increases,the contribution of single electron capture into n=4 states is observed.Experimental relative cross-sections for single-electron capture into different projectile final states were compared with theoretical predictions based on the molecular orbital close-coupling(MOCC)method.In double-electron capture,two-electron populating into the 3s^(2)3p and 3s3p^(2)states of projectile dominates.The reaction window calculated from the classical molecular Coulombic barrier model can qualitatively explain the experimental results.The scattering angle distribution of the multi-peak structure of the double-electron capture process is observed.The database is openly available in Science Data Bank at https://doi.org/10.57760/sciencedb.j00113.00233. 展开更多
关键词 state-selective electron-capture sulfur ion low-energy collisions cold target recoil ion momentum spectroscopy(COLTRIMS)
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Facilitating ultra-fast lithium ion diffusion in face-centered cubic oxides via over-stoichiometric face-sharing configurations
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作者 Xiaohan Zhang Bo Xiao 《Chinese Journal of Structural Chemistry》 2025年第2期3-4,共2页
As an important sustainable energy source,Li-ion batteries have been widely used in mobile phones,electric vehicles,large-scale energy storage and aerospace.However,due to the inevitable safety risks of traditional li... As an important sustainable energy source,Li-ion batteries have been widely used in mobile phones,electric vehicles,large-scale energy storage and aerospace.However,due to the inevitable safety risks of traditional liquid Li-ion batteries,the use of all-solid-state batteries to replace organic liquid electrolytes has become one of the most effective ways to solve safety problem.Solid-state electrolyte(SSE)is the core part of allsolid-state Li-ion battery,and ideal SSE has the characteristics of high ionic conductivity,wide enough electrochemical stability window,suitable mechanical strength and excellent chemical stability,the first among which is particularly an essential prerequisite.While,so far only a few SSEs exhibit the Li ionic conductivities higher than 10^(-4) S/cm at room temperature. 展开更多
关键词 ultra fast lithium ion diffusion safety risks safety problemsolid state stoichiometric face sharing configurations all solid state batteries organic liquid electrolytes sustainable energy sourceli ion face centered cubic oxides
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Fragmentation dynamics of nitric oxide induced by low-energy heavy ions
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作者 Zhixin Li Kaizhao Lin +7 位作者 Xiaolong Zhu Zhiliang Li Hang Yuan Yong Gao Dalong Guo Dongmei Zhao Shaofeng Zhang Xinwen Ma 《Chinese Physics B》 2025年第5期379-383,共5页
We study the fragmentation of NO^(q+)(q=2,3)molecular ions produced by collisions between 96 keV O^(6+)ions and neutral nitric oxide(NO)molecules,using the cold target recoil ion momentum spectrometer(COLTRIMS).The ki... We study the fragmentation of NO^(q+)(q=2,3)molecular ions produced by collisions between 96 keV O^(6+)ions and neutral nitric oxide(NO)molecules,using the cold target recoil ion momentum spectrometer(COLTRIMS).The kinetic energy release(KER)for various dissociation channels is obtained.For the channel NO^(2+)→N^(+)+O^(+),double-electron capture followed by autoionization of the projectile ions is the dominant process,which can be explained by the recapture of loosely bound electrons into highly excited states of the target.For NO3+trication,two dissociation channels,i.e.,(a)N^(+)+O^(2+)and(b)N^(2+)+O^(+),are observed,where channel(b)is the dominant channel.Moreover,for dissociation channels originating from the same parent molecular ion,the dissociation channel with a higher charge for the oxygen ion fragment exhibits a higher most probable KER,which is consistent with studies of CO fragmentation by Rajput et al.Additionally,it is observed that as capture stability increases,the average KER shifts to higher values. 展开更多
关键词 heavy ion collisions molecular fragmentation cold target recoil ion momentum spectroscopy
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Engineering of sulfate ions migration in Fe_(2)O_(3)-doped NiSO_(4)/Al_(2)O_(3) catalysts to enhance the selective trimerization of propylene
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作者 Xu Liu Yu Ling +1 位作者 Xiao Chen Changhai Liang 《Chinese Journal of Catalysis》 2025年第5期376-391,共16页
Propylene,a readily accessible and economically viable light olefin,has garnered substantial interest for its potential conversion into valuable higher olefins through oligomerization processes.The distribution of pro... Propylene,a readily accessible and economically viable light olefin,has garnered substantial interest for its potential conversion into valuable higher olefins through oligomerization processes.The distribution of products is profoundly influenced by the catalyst structure.In this study,Fe_(2)O_(3)-doped NiSO_(4)/Al_(2)O_(3) catalysts have been meticulously developed to facilitate the selective trimerization of propylene under mild conditions.Significantly,the 0.25Fe_(2)O_(3)-NiSO_(4)/Al_(2)O_(3) catalyst demonstrates an enhanced reaction rate(48.5 mmol_(C3)/(g_(cat).·h)),alongside a high yield of C9(~32.2%),significantly surpassing the performance of the NiSO_(4)/Al_(2)O_(3) catalyst(C9:~24.1%).The incorporation of Fe_(2)O_(3) modifies the migration process of sulfate ions,altering the Lewis acidity of the electron-deficient Ni and Fe sites on the catalyst and resulting a shift in product distribution from a Schulz-Flory distribution to a Poisson distribution.This shift is primarily ascribed to the heightened energy barrier for theβ-H elimination reaction in the C6 alkyl intermediates on the doped catalyst,further promoting polymerization to yield a greater quantity of Type II C9.Furthermore,the validation of the Cossee-Arlman mechanism within the reaction pathway has been confirmed.It is noteworthy that the 0.25Fe_(2)O_(3)-NiSO_(4)/Al_(2)O_(3) catalyst exhibits remarkable stability exceeding 80 h in the selective trimerization of propylene.These research findings significantly enhance our understanding of the mechanisms underlying olefin oligomerization reactions and provide invaluable insights for the development of more effective catalysts. 展开更多
关键词 Propylene trimerization Fe_(2)O_(3)-doped NiSO_(4)/Al_(2)O_(3)catalyst Sulfate ions migration Poisson distribution Cossee-Arlman mechanism
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Single event burnout in SiC MOSFETs induced by nuclear reactions with high-energy oxygen ions
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作者 Shi-Wei Zhao Bing Ye +6 位作者 Yu-Zhu Liu Xiao-Yu Yan Pei-Pei Hu Teng Zhang Peng-Fei Zhai Jing-Lai Duan Jie Liu 《Chinese Physics B》 2025年第7期596-602,共7页
We investigate the impact of high-energy O ions on the occurrence of single-event burnout(SEB) in silicon carbide(Si C) metal–oxide–semiconductor field-effect transistors(MOSFETs) under various bias conditions. Thro... We investigate the impact of high-energy O ions on the occurrence of single-event burnout(SEB) in silicon carbide(Si C) metal–oxide–semiconductor field-effect transistors(MOSFETs) under various bias conditions. Through a combination of SRIM, GEANT4, and TCAD simulations, we explore the role of secondary ions generated by nuclear reactions between high-energy O ions and Si C materials. These secondary ions, with significantly higher linear energy transfer(LET) values, contribute to electron–hole pair generation, leading to SEB. Our results show that the energy deposition and penetration depth of these secondary ions, especially those with high LET, are sufficient to induce catastrophic SEB in Si C MOSFETs. The study also highlights the critical influence of reverse bias voltage on SEB occurrence and provides insights into the failure mechanisms induced by nuclear reactions with high-energy O ions. This work offers valuable understanding for improving the radiation resistance of Si C-based power devices used in space and high-radiation environments,contributing to the design of more reliable electronics for future space missions. 展开更多
关键词 heavy ion silicon carbide metal-oxide-semiconductor field-effect transistor(SiC MOSFET) nuclear reactions single-event burnout(SEB)
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Machine learning-assisted fluorescence visualization for sequential quantitative detection of aluminum and fluoride ions 被引量:2
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作者 Qiang Zhang Xin Li +5 位作者 Long Yu Lingxiao Wang Zhiqing Wen Pengchen Su Zhenli Sun Suhua Wang 《Journal of Environmental Sciences》 2025年第3期68-78,共11页
The presence of aluminum(Al^(3+))and fluoride(F^(−))ions in the environment can be harmful to ecosystems and human health,highlighting the need for accurate and efficient monitoring.In this paper,an innovative approac... The presence of aluminum(Al^(3+))and fluoride(F^(−))ions in the environment can be harmful to ecosystems and human health,highlighting the need for accurate and efficient monitoring.In this paper,an innovative approach is presented that leverages the power of machine learning to enhance the accuracy and efficiency of fluorescence-based detection for sequential quantitative analysis of aluminum(Al^(3+))and fluoride(F^(−))ions in aqueous solutions.The proposed method involves the synthesis of sulfur-functionalized carbon dots(C-dots)as fluorescence probes,with fluorescence enhancement upon interaction with Al^(3+)ions,achieving a detection limit of 4.2 nmol/L.Subsequently,in the presence of F^(−)ions,fluorescence is quenched,with a detection limit of 47.6 nmol/L.The fingerprints of fluorescence images are extracted using a cross-platform computer vision library in Python,followed by data preprocessing.Subsequently,the fingerprint data is subjected to cluster analysis using the K-means model from machine learning,and the average Silhouette Coefficient indicates excellent model performance.Finally,a regression analysis based on the principal component analysis method is employed to achieve more precise quantitative analysis of aluminum and fluoride ions.The results demonstrate that the developed model excels in terms of accuracy and sensitivity.This groundbreaking model not only showcases exceptional performance but also addresses the urgent need for effective environmental monitoring and risk assessment,making it a valuable tool for safeguarding our ecosystems and public health. 展开更多
关键词 Machine learning Aluminum ion detection Fluorine ion detection Fluorescence probe K-means model
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A narrow-band blue emitting phosphor by co-doping Bi^(3+)and alkali metal ions(Li^(+),Na^(+)and K^(+))with dual luminescence center 被引量:1
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作者 Lang Ruan Zeyun Zhou +5 位作者 Yi Hu Ruifeng Peng Xiaoyan Chen Ming Cheng Zhi Zhou Mao Xia 《Journal of Rare Earths》 2025年第3期543-551,I0005,共10页
The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are... The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays. 展开更多
关键词 Bismuth ion Alkali metal ion Narrow-band blue emitting Dual luminescent centers Rare earths
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