Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesi...Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesized and character-ized by FTIR,thermogravimetric analysis(TGA),powder and single crystal X-ray diffraction.MOF 1 crystallizes in the triclinic system with a P1 space group and contains two crystallographically different Coions.Each trans-[CoO_(6)]octahedron is connected byμ_(2)-H_(2)O and L^(2-)ligand with a bis(unidentate)coordination mode to produce a 2D sql topological network.MOF 2 crystallizes in the monoclinic system with a C2/c space group.The Mncation adopts a cis-[MnO_(4)N_(2)]octahedron as a 6-connected node and is linked by L^(2-)ligand as a 4-connected node to gener-ate a binodal(4,6)-connected 3D fsc framework.The intermolecular interactions in 1 and 2 have been investigated by 3D Hirshfeld surface analyses and 2D fingerprint plots to reveal that the main interactions are H…H and O…H/H…O contacts in 1,and H…H and C…H/H…C contacts in 2.The TGA indicated that 1 and 2 were stable below 390 and 370℃,respectively.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.21968032)the Fundamental Research Funds of Central Universities-Innovation Team Cultivation Project (Grant No.31920190012)+1 种基金the Northwest Minzu University′s Double First-class and Characteristic Development Guide Special Funds-Chemistry Key Disciplines in Gansu Province (Grant No.11080316)the Teaching Quality and Reform Engineering Project of Gansu University (Grants No.2019GSSYJXSFZX01, 2019GSJXCGPY-16)
基金supported by the Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province,China(Xiang Tong Jiao[2012]318)Hunan Provincial Natural Science Foundation,China(12JJ2029)+2 种基金Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province,China(12K030)Scientific Research Fund of Changde Municipal Science and Technology Bureau,Hunan Province,China(2014JF15)Provincial Science and Technology Project,China(2013FJ4220)~~
文摘Two metal-organic frameworks(MOFs),trans-[Co(L)(μ_(2)-H_(2)O)(H_(2)O)2]·2H_(2)O(1)and cis-[Mn(L)(Bipy)](2)(H_(2)L=2,2'-dimethyl-4,4'-biphenyldicarboxylic acid,Bipy=4,4'-bipyridine),have been synthesized and character-ized by FTIR,thermogravimetric analysis(TGA),powder and single crystal X-ray diffraction.MOF 1 crystallizes in the triclinic system with a P1 space group and contains two crystallographically different Coions.Each trans-[CoO_(6)]octahedron is connected byμ_(2)-H_(2)O and L^(2-)ligand with a bis(unidentate)coordination mode to produce a 2D sql topological network.MOF 2 crystallizes in the monoclinic system with a C2/c space group.The Mncation adopts a cis-[MnO_(4)N_(2)]octahedron as a 6-connected node and is linked by L^(2-)ligand as a 4-connected node to gener-ate a binodal(4,6)-connected 3D fsc framework.The intermolecular interactions in 1 and 2 have been investigated by 3D Hirshfeld surface analyses and 2D fingerprint plots to reveal that the main interactions are H…H and O…H/H…O contacts in 1,and H…H and C…H/H…C contacts in 2.The TGA indicated that 1 and 2 were stable below 390 and 370℃,respectively.
基金supported by the National Natural Science Foundation of China (Grants No.51563022,21761018)the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (Grant No.201706)~~
