Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petro...Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petrography,mineral chemistry,phase equilibria modeling and SHRIMP zircon U-Pb dating to constrain their metamorphic evolution and tectonic significance.Both the pelitic granulites(garnet-kyanite-perthite-biotite-quartz)and the mafic granulites(garnet-clinopyroxene-amphibole-plagioclase-quartz)reached high-pressure granulite-facies conditions of 1.2-1.4 GPa/820-900℃,and recorded three metamorphic stages along a clockwise P-T path with post-peak isothermal decompression.This trajectory indicated rapid exhumation of thickened continental crust during collisional orogeny.Metamorphic ages of 254±3 Ma,262±4 Ma and 259±3 Ma were obtained for mafic granulite,pelitic granulite and marble,respectively,and were consistent with the emplacement age of 259±4 Ma for a pegmatite vein.Detrital zircons in metasediments spanned 2706-330 Ma,which constrained the latest deposition to~330 Ma;thus represented mid-Paleozoic sediment metamorphosed during the late Paleozoic rather than Precambrian basement.We conclude that the Indosinian tectonothermal event in the Cathaysia Block had originated from late Paleozoic-early Mesozoic collisional orogeny between the South China Plate to the north and the Indochina Block to the south.展开更多
This paper examines how natural gas disperses vertically when high-pressure pipelines with large openings fail in unconfined environments,providing insight into hazardous gas cloud development and behavior.A comprehen...This paper examines how natural gas disperses vertically when high-pressure pipelines with large openings fail in unconfined environments,providing insight into hazardous gas cloud development and behavior.A comprehensive study was conducted using a full-scale field experiment(1,219 mm diameter,12 MPa pressure,100 mm aperture)combined with a validated computational fluid dynamics(CFD)numerical simulation model to systematically analyze the coupling effects of pipeline pressure and ambient wind speed.The results indicate that:(1)Pipeline pressure determines the vertical jet scale,where jet height is positively correlated with pressure;at 12 MPa,the maximum jet height reaches 69.4 m(approximately 2.65 times that at 4 MPa),and the lower explosive limit(LEL)cloud area follows a quadratic polynomial trend.(2)Ambient wind speed significantly alters the diffusion trajectory;at a wind speed of 10 m/s,the LEL gas cloud area expands by 1.69 times compared to calm conditions,while the jet height is suppressed to 29.9%of the calm wind value.(3)Our developed dynamic prediction model for the hazardous gas-cloud region achieves a determination coefficient of 0.975 and maintaining prediction errors maintained within approximately 12%.The proposed empirical correlations and dynamic prediction model provide essential quantitative data support for safety-distance design and emergency-response decision-making for high-pressure natural gas pipelines.展开更多
Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temper...Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temperature and highpressure dissolution kinetic simulations were conducted.The results demonstrate that the intensity of burial dissolution is controlled by temperature and pressure,while tectonic-fluid activity influences the development pattern of burial dissolution,ultimately determining the direction of its differential modification.Extensive burial dissolution is likely to occur primarily at relatively shallow depths,significantly influencing reservoir formation,preservation,modification,and adjustment.The development of faults facilitates the maintenance of the intensity of burial dissolution.The maximum intensity of burial dissolution occurs at the tips and overlap zones of faults and intersections of multiple faults.The larger the scale of the faults,the more conducive it is to the development of burial dissolution.Burial dissolution fosters the formation of fault networks characterized by enhanced reservoir capacity and permeability.Burial dissolution controlled by episodic tectonic-fluid activity is a plausible explanation for forming the Tarim Basin's ultra-deep fault-controlled“stringbead-like”reservoirs.展开更多
High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress aro...High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.展开更多
Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elasti...Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elastic modulus and degradable properties.The Mg-3Zn-1Ca-0.5Sr(wt%)alloy is considered a competitor in the biomaterial field thanks to its unique composition of essential nutrients and excellent mechanical properties.However,the presence of coarse second-phase particles in the alloy accelerates its degradation rate and causes excessive gas formation during implantation,which restricts the alloy's potential for clinical device applications.In order to further optimize the properties of the alloy,extrusion combined with high-pressure torsion(HPT)was adopted for deformation processing.The results show that by optimizing the material processing means,the grain can be refined and broken,and the second-phase distribution can be improved,thus improving the microstructure,mechanical properties,and corrosion resistance of the alloy.After 15 cycles of HPT processing,the grains of the alloy are significantly refined to the nanometer scale,reaching approximately 98 nm.Additionally,the second-phase distribution is greatly improved,transforming the original streamlined structure into a more dispersed distribution.This change in microstructure leads to a significant strengthening effect on the alloy,with a noticeable increase in hardness from 60.3 HV in the as-extruded state to 98.5 HV.展开更多
With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mecha...With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mechanical properties of PDC incurs prohibitively elevated costs and stringent technological challenges.Here,we present a two-stage high-pressure infiltration(HPI)methodology involving cobalt removal pretreatment followed by lubricant infiltration.The successful infiltration of lubricants into diamond micropores has been systematically verified,and the effects of lubricant phase composition,infiltration pressure,and temperature on infiltration depth have been thoroughly investigated.Fractal dimension analysis characterizes the pore structure of cobalt-removed diamonds,revealing a strong correlation between the fractal dimension and friction coefficient reduction.Tribological testing confirms the formation of lubricating films at friction interfaces,achieving a 71.5%reduction in the coefficient of friction for lubricant-containing diamond materials.This straightforward strategy opens a gate to developing the next generation of self-lubricating diamond materials.展开更多
A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machine...A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machinery.After the end face of the guide sleeve wears out,it still tightly adheres to the sealing valve seat under the pressure difference,achieving automatic wear compensation.Based on fluid-solid coupling technology,the structural strength of the rotary sealing device was checked.The influence of factors on the sealing performance of rotary sealing devices was studied using the control variable method.The results show that as the pressure of water increases,the leakage rate of the sealing device decreases,and after 30 MPa,the leakage rate is almost 0 mL/h.The temperature of the rotating sealing device increases with the increase of rotation speed or pressure,and the temperature is more affected by the rotation speed factor.The frictional torque increases with increasing pressure and is independent of rotational speed.Comprehensive analysis shows that the wear resistance and reliability level of the sealing guide sleeve material is PVDF>PEEK>PE>PA.This study designs a high-pressure automatic compensation wear rotary sealing device and selects the optimal sealing material,providing technical support for the application of high-pressure water jet in mining machinery.展开更多
Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results...Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.展开更多
The utilization of ironsand for preparing oxidized pellets poses challenges,including slow oxidation and low consolidation strength.The effects and function mechanisms of high-pressure grinding roll(HPGR)pretreatment ...The utilization of ironsand for preparing oxidized pellets poses challenges,including slow oxidation and low consolidation strength.The effects and function mechanisms of high-pressure grinding roll(HPGR)pretreatment on the oxidation and consolidation of ironsand pellets were investigated,and the energy utilization efficiency of HPGR with different roller pressure intensities was evaluated.The results indicate that HPGR pretreatment at 8 MPa improves the ironsand properties,with the specific surface area increasing by 740 cm^(2) g^(-1) and mechanical energy storage increasing by 2.5 kJ mol^(-1),which is conducive to oxidation and crystalline connection of particles.As roller pressure intensity increases to 16 MPa,more mechanical energy of HPGR is applied for crystal activation,with mechanical energy storage further rising by 18.1 kJ mol^(-1).The apparent activation energy for pellet oxidation initially decreases and then increases,reaching a minimum at 12 MPa.Simultaneously,the roasted pellets porosity decreases by 2.8%,while the compressive strength increases by 789 N.At higher roller pressure intensity,the densely connected structure between particles impedes gas diffusion within the pellets,diminishing the beneficial effects of HPGR on pellet oxidation.Moreover,excessive roller pressure intensity decreases the HPGR energy utilization efficiency.The optimal HPGR roller pressure intensity for ironsand is 12 MPa,at which the specific surface area increases by 790 cm^(2) g^(-1),mechanical energy storage increases by 10.6 kJ mol^(-1),the compressive strength of roasted pellets rises to 2816 N,and the appropriate preheating and roasting temperatures decrease by 250 and 125°C,respectively.展开更多
The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of th...The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of them were approved as new minerals which include tuite,xieite,wangdaodeite,chenmingite,hemleyite,poirierite,asimowite,hiroseite,elgoresyite,and ohtaniite,by the Commission on New Minerals,Nomenclature and Classification of the International Mineralogical Association.Other high-pressure phases identified from the meteorite are ahrensite,akimotoite,bridgmanite,lingunite,magnesiowüstite,majorite,majorite-pyrope_(ss),maskelynite,riesite,ringwoodite,wadsleyite,and 5 other phases including phase A,vitrified phase B and phase C,phase D(Ca-rich majorite),and partly inverted ringwoodite.The occurrence and abundance of high-pressure phases makes this meteorite the one with the richest variety of high-pressure minerals to date.展开更多
The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volca...The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volcanic rock samples from the Yingcheng Formation and Huoshiling Formation in the Longfengshan area of the Changling Fault Depression in the Songliao Basin were selected for this study.The pore structures of the volcanic rocks in the study area were investigated using high-pressure mercury injection,X-ray diffraction combined with fractal theory.The relationships between the fractal dimension and physical properties characteristics,pore structure parameters,and mineral content were analyzed to provide guidance for the development of volcanic rock gas reservoirs.The results show that the reservoir can be divided into 3 types(I,II,and III)based on the shape of the capillary pressure curve,and the physical properties deteriorate successively.Different types of reservoirs exhibit different fractal characteristics.For typesⅠ,ⅡandⅢ,the average total fractal dimensions were 2.3418,2.6850,and 2.9203,respectively.The larger the fractal dimension,the stronger the heterogeneity of reservoir.A small number of macro-pores primarily contributed to permeability.The fractal dimension was negatively correlated with porosity and permeability.The fractal dimension of the rock was strongly correlated with quartz and feldspar contents,and the mineral composition and content are closely related to the pore evolution of the reservoir,which are the internal factors affecting the fractal dimension of volcanic rock.展开更多
The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and micr...The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and microstructural evolution of 304 stainless steel after HPT were investigated by X-ray diffraction(XRD)analysis,electron backscatter diffraction(EBSD)analysis,transmission electron microscopy(TEM),nanoindentation test and differential scanning calorimetry(DSC)analysis.The experimental results show that HPT causes elongated nanocrystalline grains of 25 nm width along the torsion direction.After 10 turns of HPT,the deformation-induced martensitic transformation is completed and the hardness increases from 3 GPa to 8.5 GPa at the edge of the disc.However,a local reverse phase transformation from martensite to austenite is observed in the peripheral regions of the sample after 30 turns of HPT,leading to a higher volume fraction of austenite,and the hardness of the sample also decreases accordingly.展开更多
Achieving optimal mechanical performance in high-pressure die-cast(HPDC)Mg-based alloys through experimental methods is both costly and time-intensive due to significant variations in composition.This study leverages ...Achieving optimal mechanical performance in high-pressure die-cast(HPDC)Mg-based alloys through experimental methods is both costly and time-intensive due to significant variations in composition.This study leverages machine learning(ML)techniques to accelerate the development of high-performance Mg-based alloys.Data on alloy composition and mechanical properties were collected from literature sources,focusing on HPDC Mg-based alloys.Six ML models—extra trees,CatBoost,k-nearest neighbors,random forest,gradient boosting,and decision tree—were trained to predict mechanical behavior.Cat Boost yielded the highest prediction accuracy with R^(2) scores of 0.95 for ultimate tensile strength(UTS)and 0.92 for yield strength(YS).Further validation using published datasets reaffirmed its reliability,demonstrating R^(2) values of 0.956(UTS)and 0.936(YS),MAE of 1%and 2.8%,and RMSE of 1%and 3.5%,respectively.Among these,the CatBoost model demonstrated the highest predictive accuracy,outperforming other ML techniques across multiple optimization metrics.展开更多
High-pressure water jet technology has emerged as a highly effective method for removing industrial-scale deposits from pipelines,offering a clean,efficient,and environmentally sustainable alternative to conventional ...High-pressure water jet technology has emerged as a highly effective method for removing industrial-scale deposits from pipelines,offering a clean,efficient,and environmentally sustainable alternative to conventional mechanical or chemical cleaning techniques.Among the many parameters influencing its performance,the geometry of the nozzle plays a decisive role in governing jet coherence,impact pressure distribution,and overall cleaning efficiency.In this study,a comprehensive numerical and experimental investigation is conducted to elucidate the influence of nozzle geometry on the behavior of high-pressure water jets.Using Computational Fluid Dynamics(CFD)simulations based on the Volume of Fluid(VOF)approach,the jet dynamics and impingement characteristics of three representative nozzle configurations—flat,conical,and tapered—are systematically analyzed.Particular attention is devoted to the tapered nozzle,where variations in the outlet diameter are explored to determine their effect on flow structure,jet stability,and impact performance.The numerical predictions are rigorously validated against experimental measurements,demonstrating excellent quantitative agreement and confirming the robustness of the computational model.Results show that the tapered nozzle,characterized by its elongated conical transition section,promotes a more stable jet core and superior efflux performance compared to flat and conical geometries.Furthermore,the exit diameter is found to exert a profound influence on jet development.At an inlet pressure of 130 MPa,increasing the tapered nozzle's outlet diameter from 0.8 mm to 1.2 mm enlarges the coherent core region,enhances jet stability,and improves hydraulic energy utilization.Under these conditions,the total impact pressure on the target surface increases by 33.14%,while the overall cleaning efficiency improves by 40.44%.展开更多
Al_(65)Cu_(20)Fe_(15)bulk is synthesized with the high-pressure synthesis(HPS)method.Various analytical techniques,such as single crystal x-ray diffraction(SXRD),scanning electron microscopy equipped with energy-dispe...Al_(65)Cu_(20)Fe_(15)bulk is synthesized with the high-pressure synthesis(HPS)method.Various analytical techniques,such as single crystal x-ray diffraction(SXRD),scanning electron microscopy equipped with energy-dispersive x-ray spectroscopy,and transmission electron microscopy,are employed to characterize the sintered bulk and confirmed its quasicrystalline structure.The electrical resistivity of the HPS quasicrystal specimen is measured from 2 K to 300 K,revealing a significantly elevated value in comparison to samples prepared via alternative methods.Nanoindentation testing demonstrates exceptional hardness and elastic modulus of our Al_(65)Cu_(20)Fe_(15)quasicrystal,consistent with existing results.The ratio of hardness to elastic modulus further highlight the potential superior wear resistance of the Al_(65)Cu_(20)Fe_(15)quasicrystal.Differential scanning calorimetry measurement conducted on the HPS Al_(65)Cu_(20)Fe_(15)quasicrystals reveal a high melting point of 877℃.展开更多
Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and...Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and intriguing electronic behaviors can be designed and synthesized. In this work, a novel oxynitride perovskite, CeNbO_(2)N, was prepared under high-temperature and high-pressure conditions. The compound crystallizes in an orthorhombic perovskite structure in Pnma symmetry with disordered N/O distribution. The x-ray absorption spectroscopy confirms the presence of a Nb^(4+) state with 4d^(1) electronic configuration in CeNbO_(2)N. As a result, the resistivity of CeNbO_(2)N is sharply reduced compared to its counterpart CeTa^(5+)ON_(2) and other Nb^(5+) compounds. No long-range spin order is found to occur with the temperature down to 2 K in CeNbO_(2)N, while a remarkable negative magnetoresistance effect shows up at lower temperatures, probably due to the magnetic scattering arising from short-range spin correlations.展开更多
Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challeng...Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challenge. Currently, experimental and theoretical results regarding the magnetic property of iron nitrides remain controversial. With the recent advancements in high-pressure technology, new synthetic pathways to iron nitrides have been proposed. High-pressure synthesis technology provides multidimensional possibilities for tuning the structure and magnetic properties of iron nitrides. This review summarizes recent progress in high-pressure synthesis of iron nitrides, especially the high-pressure solid-state metathesis reaction synthesis(HSM). We have summarized the reaction characteristics of HSM. The HSM reaction exhibits vector synthesis characteristics and promotes nitrogen disorder diffusion at high temperature. Due to this, the HSM reaction can achieve the synthesis of multinary iron-based metal nitrides and regulate the local magnetic moments. It serves as a powerful means for tuning the structure and magnetic properties of iron nitrides. Taking advantage of neutron diffraction in characterizing local magnetic moment and nitrogen disorder in iron nitrides, the relationship between iron local magnetic moment and nitrogen content has been elucidated. Moreover, the development of high-pressure in-situ imaging technology based on large-volume press allows the real-time observation of HSM reaction process. In this review, we also report our latest experiments on neutron diffraction and high-pressure in-situ image for the study of iron nitrides.展开更多
A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature （HPHT） synthesis method. The new phase was investigated by the Rietveld analysis of X-ray powder diffraction data, showing space gro...A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature （HPHT） synthesis method. The new phase was investigated by the Rietveld analysis of X-ray powder diffraction data, showing space group Pbcn （No. 60） symmetry and a = 13.6113（6）A （1A =0.1 nm）, b = 5.5809（1）A, c = 4.8566（3）A, V = 368.93（2）A3 （Z = 4）. High pressure behavior was studied by Raman spectroscopy at room temperature. Under 22.5 GPa, there was no sign of a structural phase transition in the spectra, demonstrating stability of the HPHT phase up to the highest pressure.展开更多
China’s first high-pressure hydraulically coupled rock-breaking tunnel boring machine(TBM) was designed to overcome the rock breaking problems of TBM in super-hard rock geology, where high-pressure water jet system i...China’s first high-pressure hydraulically coupled rock-breaking tunnel boring machine(TBM) was designed to overcome the rock breaking problems of TBM in super-hard rock geology, where high-pressure water jet system is configured, including high-flow pump sets, high-pressure rotary joint and high-pressure water jet injection device. In order to investigate the rock breaking performance of high-pressure water-jet-assisted TBM, in situ excavation tests were carried out at the Wan’anxi Water Diversion Project in Longyan, Fujian Province, China, under different water jet pressure and rotational speed. The rock-breaking performance of TBM was analyzed including penetration, cutterhead load, advance rate and field penetration index. The test results show that the adoption of high-pressure water-jet-assisted rock breaking technology can improve the boreability of rock mass, where the TBM penetration increases by 64% under the water jet pressure of 270 MPa. In addition, with the increase of the water jet pressure, the TBM penetration increases and the field penetration index decreases. The auxiliary rock-breaking effect of high-pressure water jet decreases with the increase of cutterhead rotational speed. In the case of the in situ tunneling test parameters of this study, the advance rate is the maximum when the pressure of the high-pressure water jet is 270 MPa and the cutterhead rotational speed is 6 r/min. The technical superiority of high-pressure water-jet-assisted rock breaking technology is highlighted and it provides guidance for the excavation parameter selection of high-pressure hydraulically coupled rock-breaking TBM.展开更多
The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages i...The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content （10%） of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline.展开更多
基金supported by the National Natural Science Foundation of China(42072223)Geological Survey project(DD20221649,DD20231429).
文摘Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petrography,mineral chemistry,phase equilibria modeling and SHRIMP zircon U-Pb dating to constrain their metamorphic evolution and tectonic significance.Both the pelitic granulites(garnet-kyanite-perthite-biotite-quartz)and the mafic granulites(garnet-clinopyroxene-amphibole-plagioclase-quartz)reached high-pressure granulite-facies conditions of 1.2-1.4 GPa/820-900℃,and recorded three metamorphic stages along a clockwise P-T path with post-peak isothermal decompression.This trajectory indicated rapid exhumation of thickened continental crust during collisional orogeny.Metamorphic ages of 254±3 Ma,262±4 Ma and 259±3 Ma were obtained for mafic granulite,pelitic granulite and marble,respectively,and were consistent with the emplacement age of 259±4 Ma for a pegmatite vein.Detrital zircons in metasediments spanned 2706-330 Ma,which constrained the latest deposition to~330 Ma;thus represented mid-Paleozoic sediment metamorphosed during the late Paleozoic rather than Precambrian basement.We conclude that the Indosinian tectonothermal event in the Cathaysia Block had originated from late Paleozoic-early Mesozoic collisional orogeny between the South China Plate to the north and the Indochina Block to the south.
基金supported by the National Natural Science Foundation of China(Grant No.52574278)the Xinjiang Uygur Autonomous Region Key R&D Program Project(Grant No.2024B01003).
文摘This paper examines how natural gas disperses vertically when high-pressure pipelines with large openings fail in unconfined environments,providing insight into hazardous gas cloud development and behavior.A comprehensive study was conducted using a full-scale field experiment(1,219 mm diameter,12 MPa pressure,100 mm aperture)combined with a validated computational fluid dynamics(CFD)numerical simulation model to systematically analyze the coupling effects of pipeline pressure and ambient wind speed.The results indicate that:(1)Pipeline pressure determines the vertical jet scale,where jet height is positively correlated with pressure;at 12 MPa,the maximum jet height reaches 69.4 m(approximately 2.65 times that at 4 MPa),and the lower explosive limit(LEL)cloud area follows a quadratic polynomial trend.(2)Ambient wind speed significantly alters the diffusion trajectory;at a wind speed of 10 m/s,the LEL gas cloud area expands by 1.69 times compared to calm conditions,while the jet height is suppressed to 29.9%of the calm wind value.(3)Our developed dynamic prediction model for the hazardous gas-cloud region achieves a determination coefficient of 0.975 and maintaining prediction errors maintained within approximately 12%.The proposed empirical correlations and dynamic prediction model provide essential quantitative data support for safety-distance design and emergency-response decision-making for high-pressure natural gas pipelines.
基金supported by the National Natural Science Foundation of China(Grant No.U21B2062)supported by the Key Laboratory for Carbonate Reservoirs of China National Petroleum Corporation。
文摘Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temperature and highpressure dissolution kinetic simulations were conducted.The results demonstrate that the intensity of burial dissolution is controlled by temperature and pressure,while tectonic-fluid activity influences the development pattern of burial dissolution,ultimately determining the direction of its differential modification.Extensive burial dissolution is likely to occur primarily at relatively shallow depths,significantly influencing reservoir formation,preservation,modification,and adjustment.The development of faults facilitates the maintenance of the intensity of burial dissolution.The maximum intensity of burial dissolution occurs at the tips and overlap zones of faults and intersections of multiple faults.The larger the scale of the faults,the more conducive it is to the development of burial dissolution.Burial dissolution fosters the formation of fault networks characterized by enhanced reservoir capacity and permeability.Burial dissolution controlled by episodic tectonic-fluid activity is a plausible explanation for forming the Tarim Basin's ultra-deep fault-controlled“stringbead-like”reservoirs.
基金financially supported by the National Natural Science Foundation of China(Nos.52175284 and 52474396)the National Key Research and Development Program of China(No.2022YFB3404201)。
文摘High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.
基金National Key Research and Development Program of China(2021YFB3701004)。
文摘Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elastic modulus and degradable properties.The Mg-3Zn-1Ca-0.5Sr(wt%)alloy is considered a competitor in the biomaterial field thanks to its unique composition of essential nutrients and excellent mechanical properties.However,the presence of coarse second-phase particles in the alloy accelerates its degradation rate and causes excessive gas formation during implantation,which restricts the alloy's potential for clinical device applications.In order to further optimize the properties of the alloy,extrusion combined with high-pressure torsion(HPT)was adopted for deformation processing.The results show that by optimizing the material processing means,the grain can be refined and broken,and the second-phase distribution can be improved,thus improving the microstructure,mechanical properties,and corrosion resistance of the alloy.After 15 cycles of HPT processing,the grains of the alloy are significantly refined to the nanometer scale,reaching approximately 98 nm.Additionally,the second-phase distribution is greatly improved,transforming the original streamlined structure into a more dispersed distribution.This change in microstructure leads to a significant strengthening effect on the alloy,with a noticeable increase in hardness from 60.3 HV in the as-extruded state to 98.5 HV.
基金supported by the National Natural Science Foundation of China(grant number:52203375 and 52073254)。
文摘With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mechanical properties of PDC incurs prohibitively elevated costs and stringent technological challenges.Here,we present a two-stage high-pressure infiltration(HPI)methodology involving cobalt removal pretreatment followed by lubricant infiltration.The successful infiltration of lubricants into diamond micropores has been systematically verified,and the effects of lubricant phase composition,infiltration pressure,and temperature on infiltration depth have been thoroughly investigated.Fractal dimension analysis characterizes the pore structure of cobalt-removed diamonds,revealing a strong correlation between the fractal dimension and friction coefficient reduction.Tribological testing confirms the formation of lubricating films at friction interfaces,achieving a 71.5%reduction in the coefficient of friction for lubricant-containing diamond materials.This straightforward strategy opens a gate to developing the next generation of self-lubricating diamond materials.
基金Supported by Jiangsu Provincial Natural Science Foundation(Grant No.BK20231497)Jiangsu Provincial Post graduate Research&Practice Innovation Program(Grant No.KYCX25_2982)+3 种基金China University of Mining and Technology Graduate Innovation Program(Grant No.2025WLKXJ094)National Natural Science Foundation of China(Grant No.51975573)National Key R&D Program of China(Grant No.2022YFC2905600)Priority Academic Program Development of Jiangsu Higher Education Institute of China.
文摘A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machinery.After the end face of the guide sleeve wears out,it still tightly adheres to the sealing valve seat under the pressure difference,achieving automatic wear compensation.Based on fluid-solid coupling technology,the structural strength of the rotary sealing device was checked.The influence of factors on the sealing performance of rotary sealing devices was studied using the control variable method.The results show that as the pressure of water increases,the leakage rate of the sealing device decreases,and after 30 MPa,the leakage rate is almost 0 mL/h.The temperature of the rotating sealing device increases with the increase of rotation speed or pressure,and the temperature is more affected by the rotation speed factor.The frictional torque increases with increasing pressure and is independent of rotational speed.Comprehensive analysis shows that the wear resistance and reliability level of the sealing guide sleeve material is PVDF>PEEK>PE>PA.This study designs a high-pressure automatic compensation wear rotary sealing device and selects the optimal sealing material,providing technical support for the application of high-pressure water jet in mining machinery.
基金supported by the National Natural Science Foundation of China(No.52204126)the Shandong Provincial Natural Science Foundation(Nos.ZR2022ME077,ZR2022QE060,and ZR2023ME119).
文摘Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.
基金financially supported by the General Program of National Natural Science Foundation of China(No.52174330)Hunan Provincial Innovation Foundation for Postgraduate(No.QL20220069)Postgraduate Innovative Project of Central South University(No.1053320214756).
文摘The utilization of ironsand for preparing oxidized pellets poses challenges,including slow oxidation and low consolidation strength.The effects and function mechanisms of high-pressure grinding roll(HPGR)pretreatment on the oxidation and consolidation of ironsand pellets were investigated,and the energy utilization efficiency of HPGR with different roller pressure intensities was evaluated.The results indicate that HPGR pretreatment at 8 MPa improves the ironsand properties,with the specific surface area increasing by 740 cm^(2) g^(-1) and mechanical energy storage increasing by 2.5 kJ mol^(-1),which is conducive to oxidation and crystalline connection of particles.As roller pressure intensity increases to 16 MPa,more mechanical energy of HPGR is applied for crystal activation,with mechanical energy storage further rising by 18.1 kJ mol^(-1).The apparent activation energy for pellet oxidation initially decreases and then increases,reaching a minimum at 12 MPa.Simultaneously,the roasted pellets porosity decreases by 2.8%,while the compressive strength increases by 789 N.At higher roller pressure intensity,the densely connected structure between particles impedes gas diffusion within the pellets,diminishing the beneficial effects of HPGR on pellet oxidation.Moreover,excessive roller pressure intensity decreases the HPGR energy utilization efficiency.The optimal HPGR roller pressure intensity for ironsand is 12 MPa,at which the specific surface area increases by 790 cm^(2) g^(-1),mechanical energy storage increases by 10.6 kJ mol^(-1),the compressive strength of roasted pellets rises to 2816 N,and the appropriate preheating and roasting temperatures decrease by 250 and 125°C,respectively.
基金Science and Technology Planning Project of Guangdong Province(2023B1212060048).
文摘The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of them were approved as new minerals which include tuite,xieite,wangdaodeite,chenmingite,hemleyite,poirierite,asimowite,hiroseite,elgoresyite,and ohtaniite,by the Commission on New Minerals,Nomenclature and Classification of the International Mineralogical Association.Other high-pressure phases identified from the meteorite are ahrensite,akimotoite,bridgmanite,lingunite,magnesiowüstite,majorite,majorite-pyrope_(ss),maskelynite,riesite,ringwoodite,wadsleyite,and 5 other phases including phase A,vitrified phase B and phase C,phase D(Ca-rich majorite),and partly inverted ringwoodite.The occurrence and abundance of high-pressure phases makes this meteorite the one with the richest variety of high-pressure minerals to date.
基金Supported by Key Scientific and Technological Projects of Sinopec(No.P21104-2).
文摘The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volcanic rock samples from the Yingcheng Formation and Huoshiling Formation in the Longfengshan area of the Changling Fault Depression in the Songliao Basin were selected for this study.The pore structures of the volcanic rocks in the study area were investigated using high-pressure mercury injection,X-ray diffraction combined with fractal theory.The relationships between the fractal dimension and physical properties characteristics,pore structure parameters,and mineral content were analyzed to provide guidance for the development of volcanic rock gas reservoirs.The results show that the reservoir can be divided into 3 types(I,II,and III)based on the shape of the capillary pressure curve,and the physical properties deteriorate successively.Different types of reservoirs exhibit different fractal characteristics.For typesⅠ,ⅡandⅢ,the average total fractal dimensions were 2.3418,2.6850,and 2.9203,respectively.The larger the fractal dimension,the stronger the heterogeneity of reservoir.A small number of macro-pores primarily contributed to permeability.The fractal dimension was negatively correlated with porosity and permeability.The fractal dimension of the rock was strongly correlated with quartz and feldspar contents,and the mineral composition and content are closely related to the pore evolution of the reservoir,which are the internal factors affecting the fractal dimension of volcanic rock.
基金Funded by the National Natural Science Foundation of China(No.51905215)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.SJCX231233)。
文摘The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and microstructural evolution of 304 stainless steel after HPT were investigated by X-ray diffraction(XRD)analysis,electron backscatter diffraction(EBSD)analysis,transmission electron microscopy(TEM),nanoindentation test and differential scanning calorimetry(DSC)analysis.The experimental results show that HPT causes elongated nanocrystalline grains of 25 nm width along the torsion direction.After 10 turns of HPT,the deformation-induced martensitic transformation is completed and the hardness increases from 3 GPa to 8.5 GPa at the edge of the disc.However,a local reverse phase transformation from martensite to austenite is observed in the peripheral regions of the sample after 30 turns of HPT,leading to a higher volume fraction of austenite,and the hardness of the sample also decreases accordingly.
基金supported by Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(2021R1A6A1A10044950)。
文摘Achieving optimal mechanical performance in high-pressure die-cast(HPDC)Mg-based alloys through experimental methods is both costly and time-intensive due to significant variations in composition.This study leverages machine learning(ML)techniques to accelerate the development of high-performance Mg-based alloys.Data on alloy composition and mechanical properties were collected from literature sources,focusing on HPDC Mg-based alloys.Six ML models—extra trees,CatBoost,k-nearest neighbors,random forest,gradient boosting,and decision tree—were trained to predict mechanical behavior.Cat Boost yielded the highest prediction accuracy with R^(2) scores of 0.95 for ultimate tensile strength(UTS)and 0.92 for yield strength(YS).Further validation using published datasets reaffirmed its reliability,demonstrating R^(2) values of 0.956(UTS)and 0.936(YS),MAE of 1%and 2.8%,and RMSE of 1%and 3.5%,respectively.Among these,the CatBoost model demonstrated the highest predictive accuracy,outperforming other ML techniques across multiple optimization metrics.
基金the Natural Science Foundation of Shandong Province,China(No.ZR2021QE157).
文摘High-pressure water jet technology has emerged as a highly effective method for removing industrial-scale deposits from pipelines,offering a clean,efficient,and environmentally sustainable alternative to conventional mechanical or chemical cleaning techniques.Among the many parameters influencing its performance,the geometry of the nozzle plays a decisive role in governing jet coherence,impact pressure distribution,and overall cleaning efficiency.In this study,a comprehensive numerical and experimental investigation is conducted to elucidate the influence of nozzle geometry on the behavior of high-pressure water jets.Using Computational Fluid Dynamics(CFD)simulations based on the Volume of Fluid(VOF)approach,the jet dynamics and impingement characteristics of three representative nozzle configurations—flat,conical,and tapered—are systematically analyzed.Particular attention is devoted to the tapered nozzle,where variations in the outlet diameter are explored to determine their effect on flow structure,jet stability,and impact performance.The numerical predictions are rigorously validated against experimental measurements,demonstrating excellent quantitative agreement and confirming the robustness of the computational model.Results show that the tapered nozzle,characterized by its elongated conical transition section,promotes a more stable jet core and superior efflux performance compared to flat and conical geometries.Furthermore,the exit diameter is found to exert a profound influence on jet development.At an inlet pressure of 130 MPa,increasing the tapered nozzle's outlet diameter from 0.8 mm to 1.2 mm enlarges the coherent core region,enhances jet stability,and improves hydraulic energy utilization.Under these conditions,the total impact pressure on the target surface increases by 33.14%,while the overall cleaning efficiency improves by 40.44%.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52173231 and 51925105)the Natural Science Foundation of Hebei Province,China(Grant No.E2022203182)+1 种基金The Innovation Ability Promotion Project of Hebei supported by Hebei Key Laboratory for Optimizing Metal Product Technology and Performance(Grant No.22567609H)supported by the grants from Slovak National Agencies(Grant Nos.VEGA 2/0144/21,APVV19-0369,and APVV-20-0124)。
文摘Al_(65)Cu_(20)Fe_(15)bulk is synthesized with the high-pressure synthesis(HPS)method.Various analytical techniques,such as single crystal x-ray diffraction(SXRD),scanning electron microscopy equipped with energy-dispersive x-ray spectroscopy,and transmission electron microscopy,are employed to characterize the sintered bulk and confirmed its quasicrystalline structure.The electrical resistivity of the HPS quasicrystal specimen is measured from 2 K to 300 K,revealing a significantly elevated value in comparison to samples prepared via alternative methods.Nanoindentation testing demonstrates exceptional hardness and elastic modulus of our Al_(65)Cu_(20)Fe_(15)quasicrystal,consistent with existing results.The ratio of hardness to elastic modulus further highlight the potential superior wear resistance of the Al_(65)Cu_(20)Fe_(15)quasicrystal.Differential scanning calorimetry measurement conducted on the HPS Al_(65)Cu_(20)Fe_(15)quasicrystals reveal a high melting point of 877℃.
基金Project supported by the National Key R&D Program of China (Grant No. 2021YFA1400300)the National Natural Science Foundation of China (Grant Nos. 12425403, 12261131499, 12304268, 12304159, 11934017, and 11921004)+1 种基金the China Postdoctoral Science Foundation (Grant No. 2023M743741)The synchrotron x-ray diffraction experiments were performed at SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (Grant Nos. 2023B1575, 2023B1976, 2024A1506, and 2024A1695)。
文摘Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and intriguing electronic behaviors can be designed and synthesized. In this work, a novel oxynitride perovskite, CeNbO_(2)N, was prepared under high-temperature and high-pressure conditions. The compound crystallizes in an orthorhombic perovskite structure in Pnma symmetry with disordered N/O distribution. The x-ray absorption spectroscopy confirms the presence of a Nb^(4+) state with 4d^(1) electronic configuration in CeNbO_(2)N. As a result, the resistivity of CeNbO_(2)N is sharply reduced compared to its counterpart CeTa^(5+)ON_(2) and other Nb^(5+) compounds. No long-range spin order is found to occur with the temperature down to 2 K in CeNbO_(2)N, while a remarkable negative magnetoresistance effect shows up at lower temperatures, probably due to the magnetic scattering arising from short-range spin correlations.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 12374013 and U2030107)the Fundamental Research Funds for the Central University (Grant No. 2020SCUNL107)+1 种基金The high-pressure in-situ imaging experiments were conducted at BL12SW of SSRF (Proposal No. 2024-SSRF-PT-505499)The NPD experiments were supported by Chinese Academy of Engineering Physics。
文摘Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challenge. Currently, experimental and theoretical results regarding the magnetic property of iron nitrides remain controversial. With the recent advancements in high-pressure technology, new synthetic pathways to iron nitrides have been proposed. High-pressure synthesis technology provides multidimensional possibilities for tuning the structure and magnetic properties of iron nitrides. This review summarizes recent progress in high-pressure synthesis of iron nitrides, especially the high-pressure solid-state metathesis reaction synthesis(HSM). We have summarized the reaction characteristics of HSM. The HSM reaction exhibits vector synthesis characteristics and promotes nitrogen disorder diffusion at high temperature. Due to this, the HSM reaction can achieve the synthesis of multinary iron-based metal nitrides and regulate the local magnetic moments. It serves as a powerful means for tuning the structure and magnetic properties of iron nitrides. Taking advantage of neutron diffraction in characterizing local magnetic moment and nitrogen disorder in iron nitrides, the relationship between iron local magnetic moment and nitrogen content has been elucidated. Moreover, the development of high-pressure in-situ imaging technology based on large-volume press allows the real-time observation of HSM reaction process. In this review, we also report our latest experiments on neutron diffraction and high-pressure in-situ image for the study of iron nitrides.
基金supported by the National Natural Science Foundation of China (Grant No. 51172091)the Program for New Century Excellent Talents in University
文摘A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature （HPHT） synthesis method. The new phase was investigated by the Rietveld analysis of X-ray powder diffraction data, showing space group Pbcn （No. 60） symmetry and a = 13.6113（6）A （1A =0.1 nm）, b = 5.5809（1）A, c = 4.8566（3）A, V = 368.93（2）A3 （Z = 4）. High pressure behavior was studied by Raman spectroscopy at room temperature. Under 22.5 GPa, there was no sign of a structural phase transition in the spectra, demonstrating stability of the HPHT phase up to the highest pressure.
基金Project(2020YFF0426370) supported by the National Key Research and Development Program of ChinaProject(SF-202010) supported by the Water Conservancy Technology Demonstration,China。
文摘China’s first high-pressure hydraulically coupled rock-breaking tunnel boring machine(TBM) was designed to overcome the rock breaking problems of TBM in super-hard rock geology, where high-pressure water jet system is configured, including high-flow pump sets, high-pressure rotary joint and high-pressure water jet injection device. In order to investigate the rock breaking performance of high-pressure water-jet-assisted TBM, in situ excavation tests were carried out at the Wan’anxi Water Diversion Project in Longyan, Fujian Province, China, under different water jet pressure and rotational speed. The rock-breaking performance of TBM was analyzed including penetration, cutterhead load, advance rate and field penetration index. The test results show that the adoption of high-pressure water-jet-assisted rock breaking technology can improve the boreability of rock mass, where the TBM penetration increases by 64% under the water jet pressure of 270 MPa. In addition, with the increase of the water jet pressure, the TBM penetration increases and the field penetration index decreases. The auxiliary rock-breaking effect of high-pressure water jet decreases with the increase of cutterhead rotational speed. In the case of the in situ tunneling test parameters of this study, the advance rate is the maximum when the pressure of the high-pressure water jet is 270 MPa and the cutterhead rotational speed is 6 r/min. The technical superiority of high-pressure water-jet-assisted rock breaking technology is highlighted and it provides guidance for the excavation parameter selection of high-pressure hydraulically coupled rock-breaking TBM.
基金support from Subtopics of National Science and Technology Major Project(2011ZX05026-004-03)the National Natural Science Foundation of China (51104167)
文摘The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content （10%） of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline.
