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GC-PID法检测天然气中加臭剂的分析方法
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作者 陈梓浔 张镨 +1 位作者 宋柯静 周理 《石油与天然气化工》 北大核心 2026年第1期122-127,共6页
目的天然气加臭是保障天然气泄漏迅速识别和安全使用的重要手段,为保证加臭剂质量浓度符合标准规范且避免过量加臭,建立一种准确高效的分析方法对天然气中加臭剂进行检测。方法采用光离子化气相色谱法(gas chromatography with photoion... 目的天然气加臭是保障天然气泄漏迅速识别和安全使用的重要手段,为保证加臭剂质量浓度符合标准规范且避免过量加臭,建立一种准确高效的分析方法对天然气中加臭剂进行检测。方法采用光离子化气相色谱法(gas chromatography with photoionization detection,GC-PID),设置操作流程,优选分析参数,通过实验室评价和现场应用,系统考察GC-PID法的有效性、抗干扰性、检出限、重复性、准确性和现场适用性,验证其对四氢噻吩和无硫加臭剂的检测能力。结果建立的方法对加臭剂具有高选择性,定量准确性高,在2.00~150.00 mg/m^(3)范围内,对四氢噻吩的相对标准偏差<1.5%,检出限为0.40 mg/m^(3)。GC-PID法具有良好的现场适用性,具有良好的数据准确性和稳定性。结论基于GC-PID法开发的该天然气中四氢噻吩和无硫加臭剂的检测方法,为加臭剂质量浓度的在线监测和便携检测提供了新途径,具有实际应用价值与推广前景。 展开更多
关键词 天然气 光离子化气相色谱 加臭剂 四氢噻吩
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基于GC-MS、网络药理学和分子对接的松花粉油脂抗动脉粥样硬化作用机制探讨
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作者 余少君 刘浩 +4 位作者 于晗 杨国华 杨玉升 张园园 刘永刚 《中国现代中药》 2026年第1期102-112,I0015,I0016,共13页
目的:通过气相色谱-质谱法(GC-MS)分析松花粉油脂的化学成分并基于网络药理学和分子对接技术研究其抗动脉粥样硬化(AS)的潜在作用机制。方法:采用GC-MS对松花粉油脂的成分进行鉴定;采用PubChem和SwissTargetPrediction数据库获取松花粉... 目的:通过气相色谱-质谱法(GC-MS)分析松花粉油脂的化学成分并基于网络药理学和分子对接技术研究其抗动脉粥样硬化(AS)的潜在作用机制。方法:采用GC-MS对松花粉油脂的成分进行鉴定;采用PubChem和SwissTargetPrediction数据库获取松花粉油脂活性成分的靶点蛋白质;采用GeneCards、DrugBank、PharmGKB、Therapeutic Target Database及OMIM数据库检索AS的疾病靶点;利用STRING数据库构建蛋白质-蛋白质相互作用(PPI)网络并进行拓扑学分析;利用DAVID数据库进行基因本体(GO)和京都基因与基因组百科全书(KEGG)富集分析;通过Cytoscape 3.10软件构建活性成分-核心靶点-通路网络;使用AutoDock Vina 1.1.2和PyMol 2.5.4软件计算结合能并进行分子对接可视化。结果:筛选得到松花粉油脂中35个活性成分,其中油酸相对质量分数(19.79%)最高,其次是芳香杂环化合物2,3-二氢苯并呋喃(17.36%)、黄酮类多酚化合物丁香醛(7.84%);筛选出核心靶点10个,分别为丝裂原活化蛋白激酶3(MAPK3)、表皮生长因子受体(EGFR)、MAPK1、磷脂酰肌醇-3-激酶催化亚基α(PIK3CA)、连环蛋白β1(CTNNB1)、原癌基因酪氨酸蛋白激酶Src(SRC)、Janus激酶2(JAK2)、蛋白酪氨酸磷酸酶非受体型11(PTPN11)、雌激素受体1(ESR1)、信号转导与转录激活因子3(STAT3);GO分析得到其主要涉及的生物过程包括RNA聚合酶Ⅱ对转录的正向调控、炎症反应、对脂多糖的反应、细胞外信号调节激酶1(ERK1)和ERK2级联的正向调节等;KEGG富集分析得到其作用的通路主要涉及癌症的途径、EGFR酪氨酸激酶抑制剂耐药性、Ras相关蛋白1信号通路等。结论:松花粉油脂的主要活性成分可通过靶向SRC、MAPK1等核心靶点发挥抗AS作用。 展开更多
关键词 松花粉油脂 气相色谱-质谱法 网络药理学 动脉粥样硬化 分子对接
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GC-IMS结合多元统计学比较不同产区市售酱香型白酒挥发性风味成分
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作者 冯雪莹 倪慧 +3 位作者 侯强川 叶明波 郭壮 王玉荣 《中国酿造》 北大核心 2026年第1期282-287,共6页
该研究将4个产自茅台镇和4个产自其他地区的市售酱香型白酒作为研究对象,采用气相色谱-离子迁移谱(GC-IMS)技术结合多元统计学方法,比较分析了不同产区市售酱香型白酒挥发性风味成分的差异。结果表明,8个白酒样品中共检出51种挥发性风... 该研究将4个产自茅台镇和4个产自其他地区的市售酱香型白酒作为研究对象,采用气相色谱-离子迁移谱(GC-IMS)技术结合多元统计学方法,比较分析了不同产区市售酱香型白酒挥发性风味成分的差异。结果表明,8个白酒样品中共检出51种挥发性风味成分,包括酯类24种、醇类9种、醛类10种和酮类8种。主成分分析(PCA)结果表明,茅台镇和其他产区酱香型白酒挥发性风味成分存在差异。基于相对气味活度值(ROAV)共筛选出6种关键挥发性风味化合物(ROAV>1),其中,对茅台镇酱香型白酒香气贡献更突出的为异戊酸乙酯、辛酸乙酯和乙酸异戊酯,ROAV分别为82.25、5.56、1.52,对其他产区酱香型白酒香气贡献更突出的为己酸乙酯、戊酸乙酯和丁酸乙酯,ROAV分别为33.19、32.55、10.48。 展开更多
关键词 酱香型白酒 茅台镇和其他地区 气相色谱-离子迁移谱 多元统计学分析 关键差异挥发性风味化合物
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A New Inversion-free Iterative Method for Solving the Nonlinear Matrix Equation and Its Application in Optimal Control
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作者 GAO Xiangyu XIE Weiwei ZHANG Lina 《应用数学》 北大核心 2026年第1期143-150,共8页
In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to ... In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method. 展开更多
关键词 Nonlinear matrix equation Maximal positive definite solution Inversion-free iterative method Optimal control
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基于GC-IMS分析不同精炼程度山茶油风味差异的研究
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作者 黄泽宇 曾慧琳 +2 位作者 马思婷 吉贵林 黎冬明 《粮食与油脂》 北大核心 2026年第2期53-57,共5页
为探究精炼工艺对山茶油风味物质的影响,采用气相色谱-离子迁移谱(GC-IMS)技术对毛油、脱胶油、脱色油及成品油中的挥发性成分进行检测。结果表明:在不同精炼程度的山茶油中共鉴定出68种挥发性物质,包括醛类20种、酮类13种、醇类12种、... 为探究精炼工艺对山茶油风味物质的影响,采用气相色谱-离子迁移谱(GC-IMS)技术对毛油、脱胶油、脱色油及成品油中的挥发性成分进行检测。结果表明:在不同精炼程度的山茶油中共鉴定出68种挥发性物质,包括醛类20种、酮类13种、醇类12种、酯类7种、酸类5种、杂环类6种及其他类5种。醛类为山茶油主要风味成分,随着精炼的进行,青草香型醛类增加,而脂肪香型醛类减少。主成分分析(PCA)显示,成品油与其他样品在风味上差异较大,表明脱色之后的精炼工序对风味具有较大的影响。研究结果可为优化山茶油适度精炼和保留特征风味提供理论依据。 展开更多
关键词 山茶油 气相色谱-离子迁移谱 精炼工艺 挥发性成分 风味物质
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Broadband ground motion simulation and analysis of a near-fault 3D basin-mountain coupling site based on the hybrid method
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作者 Liu Zhongxian Tang Kang +2 位作者 Li Chengcheng Yuan Xiaoming Zhang Hai 《Earthquake Engineering and Engineering Vibration》 2026年第1期87-110,共24页
This study presents an effective hybrid simulation approach for simulating broadband ground motion in complex near-fault locations.The approach utilizes a deterministic approach based on the spectral element method(SE... This study presents an effective hybrid simulation approach for simulating broadband ground motion in complex near-fault locations.The approach utilizes a deterministic approach based on the spectral element method(SEM),which is used to simulate low-frequency ground motion(f<1 Hz)by incorporating an innovative efficient discontinuous Galerkin(DG)method for grid division to accurately model basin sedimentary layers at reduced costs.It also introduces a comprehensive hybrid source model for high-frequency random scattering and a nonlinear analysis module for basin sedimentary layers.Deterministic outcomes are combined with modified three-dimensional stochastic finite fault method(3D-EXSIM)simulations of high-frequency ground motion(f>1 Hz).A fourth-order Butterworth filter with zero phase shift is employed for time-domain filtering of low-and high-frequency time series at a crossover frequency of 1 Hz,merging the low and high-frequency ground motions into a broadband time series.Taking an Ms 6.8 Luding earthquake,as an example,this hybrid method was used for a rapid and efficient simulation analysis of broadband ground motion in the region.The accuracy and efficiency of this hybrid method were verified through comparisons with actually observed station data and empirical attenuation curves.Deterministic method simulation results revealed the effects of mountainous topography,basin effects,nonlinear effects within the basin’s sedimentary layers,and a coupling interaction between the basin and the mountains.The findings are consistent with similar studies,showing that near-fault sedimentary basins significantly focus and amplify strong ground motion,and the soil’s nonlinear behavior in the basin influences ground motion to varying extents at different distances from the fault.The mountainous topography impacts the basin’s response to ground motion,leading to barrier effects.This research provides a scientific foundation for seismic zoning,urban planning,and seismic design in nearfault mountain basin regions. 展开更多
关键词 hybrid ground motion simulation method spectral element method three-dimensional stochastic finite fault method near-fault basin-mountain coupling effect basin effect nonlinear effect
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融合注意力机制的GCN-BiGRU剩余油预测方法
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作者 王梅 娄金香 +1 位作者 郭军辉 董驰 《当代化工》 2026年第1期128-133,共6页
剩余油分布影响因素复杂,注采井不仅受自身历史开发的影响,还受周围注采井的影响。针对上述问题,构建了一个融合注意力机制的自适应GCN-BiGRU剩余油预测模型,利用自适应图卷积神经网络(GCN)模块提取每层注采井与周围注采井的空间依赖关... 剩余油分布影响因素复杂,注采井不仅受自身历史开发的影响,还受周围注采井的影响。针对上述问题,构建了一个融合注意力机制的自适应GCN-BiGRU剩余油预测模型,利用自适应图卷积神经网络(GCN)模块提取每层注采井与周围注采井的空间依赖关系,在此基础上融入注意力机制的双向门控循环神经网络(BiGRU),可以更好地学习目标注采井的时序依赖关系。实验结果表明,该模型与CNN-LSTM、GCN-LSTM、CNN-GRU等相比性能均有显著提升。通过该模型得到每层各井点预测的含水饱和度,结合克里金插值法得到每层含水饱和度场,能有效预测剩余油有利区域。 展开更多
关键词 剩余油预测 图卷积神经网络 双向门控循环神经网络 克里金插值法
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LLE-GC-MS法测定左氧氟沙星中硫酸二甲酯
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作者 周盼 齐明燕 +3 位作者 孙春艳 路珊珊 张宝军 王如伟 《山东化工》 2026年第1期153-156,161,共5页
本研究建立了一种液液萃取(LLE)前处理结合气相色谱—质谱联用仪(GC-MS)检测左氧氟沙星中基因毒性杂质硫酸二甲酯(DMS)含量的方法。该方法利用二次液液萃取净化后,采用GC-MS选择离子监测模式(SIM)测定,以外标法定量。实验结果表明,空白... 本研究建立了一种液液萃取(LLE)前处理结合气相色谱—质谱联用仪(GC-MS)检测左氧氟沙星中基因毒性杂质硫酸二甲酯(DMS)含量的方法。该方法利用二次液液萃取净化后,采用GC-MS选择离子监测模式(SIM)测定,以外标法定量。实验结果表明,空白溶剂不干扰检测,硫酸二甲酯在40~200 ng/mL质量浓度范围内线性关系良好,R^(2)>0.9999;硫酸二甲酯加标供试品溶液回收率均在95.0%~105.0%;100%水平加标供试品溶液在15 h内稳定。该方法灵敏、准确,可用于左氧氟沙星中硫酸二甲酯残留含量检测。 展开更多
关键词 二次液液萃取 气相色谱—质谱联用仪 基因毒性杂质 硫酸二甲酯
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Healthcare professionals’perspectives on disclosure of diagnosis and related issues in childhood cancer:A mixed methods systematic review
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作者 Run Xie Xiaoyan Huang +4 位作者 Yiran Du Ying Gu Qiongfang Kang Hongsheng Wang Daqian Zhu 《International Journal of Nursing Sciences》 2026年第1期96-104,I0006,共10页
Objectives This review aimed to systematically synthesize the available research on the disclosure of diagnosis and related issues in childhood cancer from the perspectives of healthcare professionals,with the goal of... Objectives This review aimed to systematically synthesize the available research on the disclosure of diagnosis and related issues in childhood cancer from the perspectives of healthcare professionals,with the goal of informing the optimization of disclosure processes and meeting the communication needs of affected families.Methods In accordance with the Joanna Briggs Institute(JBI)methodology for mixed methods systematic reviews,the convergent segregated approach was used in this review.Articles were retrieved from 11 databases,including PubMed,Web of Science,CINAHL,CENTRAL,Embase,Ovid/Medline,PsycINFO,PsycArticles,Scopus,ERIC,and China National Knowledge Infrastructure(CNKI).The quality of the selected articles was assessed using the Mixed Method Appraisal Tool(MMAT).The review protocol was registered on PROSPERO(CRD42024542746).Results A total of 21 studies from 10 countries were included.Their methodological quality was generally medium to high,with MMAT scores ranging from 60%to 100%.The synthesis yielded three core themes:1)the spectrum of professional and societal attitudes toward disclosure;2)the dynamic practices of navigating disclosure amid uncertainty,including timing and environment,stakeholders,and content of disclosure;and 3)factors influencing disclosure,including children’s,parental,healthcare professionals’,and socio-cultural factors.Conclusions This review synthesized the perspectives and experiences of healthcare professionals regarding disclosure in childhood cancer,highlighting the complexity and multidimensional nature of this process in clinical practice.Future research should further investigate the experiences and needs of children and their parents,explore cultural variations in disclosure practices,develop context-appropriate assessment tools,and construct multidimensional intervention strategies to enhance the humanistic care and professional effectiveness of the disclosure process. 展开更多
关键词 Communication CANCER DISCLOSURE Healthcare professionals Mixed methods PEDIATRIC Systematic review
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基于HS-GC-IMS技术解析不同干燥工艺对西红花挥发性成分的影响
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作者 王嘉习 吴凤云 +7 位作者 张弛 骆紫义 洪丹尧 高爽 栾洁 巴剑波 陆颖洁 韩婷 《分析测试学报》 北大核心 2026年第1期50-60,共11页
该研究通过顶空-气相色谱-离子迁移谱(HS-GC-IMS)技术,对西红花鲜样和不同干燥方法(阴干、加热板干燥、烘箱干燥、真空干燥及冻干)样品中的75个挥发性化合物进行定性和相对定量分析,并构建了西红花挥发性成分的指纹图谱。通过聚焦于西... 该研究通过顶空-气相色谱-离子迁移谱(HS-GC-IMS)技术,对西红花鲜样和不同干燥方法(阴干、加热板干燥、烘箱干燥、真空干燥及冻干)样品中的75个挥发性化合物进行定性和相对定量分析,并构建了西红花挥发性成分的指纹图谱。通过聚焦于西红花不同干燥过程中挥发性成分的动态变化,运用主成分分析、偏最小二乘判别分析和聚类热图对样品进行识别和差异性分析,筛选出27种关键差异化合物,解析不同干燥工艺对西红花中挥发性成分的影响,揭示了不同干燥方法通过不同程度作用于西红花中物理(高温挥发)、化学(光热分解)、生化反应影响西红花中的挥发性成分,造成西红花药材品质的多样性。阴干样本中的挥发性成分种类最丰富,加热板干燥样本中的藏红花醛含量最高(2.91 mg/g),烘箱和真空干燥样本中的酯类和酮类丰度最高,冻干样本中的成分稳定性最高。研究可为未来根据实际应用场景选择不同的干燥方法提供理论指导。 展开更多
关键词 西红花 干燥工艺 挥发性成分 顶空-气相色谱-离子迁移谱 藏红花醛
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基于GC-MS指纹图谱和化学计量学评价重楼挥发油质量
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作者 董雨欣 陈建辉 +5 位作者 李娜 朱童岩 于永洲 崔晓燕 赵春颖 熊辉 《中成药》 北大核心 2026年第1期23-27,共5页
目的评价重楼挥发油质量。方法指纹图谱建立采用Shimadzu HP-5MS毛细管柱(30 m×0.25 mm,0.25μm);载气高纯氦气;体积流量1.0 mL/mL;进样口温度250℃;程序升温;电子轰击离子源,轰击能量70 eV;全扫描数据方式。再进行主成分分析和正... 目的评价重楼挥发油质量。方法指纹图谱建立采用Shimadzu HP-5MS毛细管柱(30 m×0.25 mm,0.25μm);载气高纯氦气;体积流量1.0 mL/mL;进样口温度250℃;程序升温;电子轰击离子源,轰击能量70 eV;全扫描数据方式。再进行主成分分析和正交偏最小二乘判别分析。结果20批样品指纹图谱中有21个共有峰,指认出21种成分,相似度均大于0.800(CL006除外)。各批样品(CL038、CL046除外)分为3类,花生酸和反油酸乙酯为潜在质量标志物。结论该方法稳定可靠,可有效识别不同地区重楼挥发油的质量差异,从而为完善该药材质量标准提供理论依据。 展开更多
关键词 重楼 挥发油 质量评价 gc-MS指纹图谱 主成分分析 正交偏最小二乘判别分析
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基于GC-MS比较分析不同品牌红烧肉调料包挥发性风味成分
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作者 杨琳 杨宇 +3 位作者 何玉贞 段丽丽 戢得蓉 李杨 《农产品加工》 2026年第2期89-96,共8页
为快速、精准地鉴别红烧肉调料包的整体风味成分,利用气相色谱与质谱联用(GC-MS)、主成分分析和感官评价对12种知名品牌红烧肉调料包制作的红烧肉中挥发性物质的种类、相对含量进行分析比较。研究表明,12种红烧肉调料包共检出153种挥发... 为快速、精准地鉴别红烧肉调料包的整体风味成分,利用气相色谱与质谱联用(GC-MS)、主成分分析和感官评价对12种知名品牌红烧肉调料包制作的红烧肉中挥发性物质的种类、相对含量进行分析比较。研究表明,12种红烧肉调料包共检出153种挥发性成分,主要含有烯类33种、烷类27种、酯类17种、醇类15种等物质。不同品牌调料包特征物质各异,样品E风味物质种类最多(共43种,烷类和烯类的含量高),样品H烷类物质丰富,样品I烯类物质含量高,样品C具有醛类物质多样,样品B、样品D富含烷类和酸类物质,样品G挥发性成分含量和感官评分最高。但主要风味物质均为烃类、酯类和醛类,其中醛类对红烧肉的整体风味显著影响,因而改进红烧肉调料包需要提高醛类物质含量。 展开更多
关键词 红烧肉调料包 气相色谱-质谱法 主成分分析 挥发性风味 感官评价
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Crushing evolution in pebble bed based on a novel method:a crushable DEM study
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作者 Jian Wang Ming‑Zhun Lei +4 位作者 Ming‑Zong Liu Qi‑Gang Wu Zi‑Cong Cai Kai‑Song Wang Hai‑Shun Deng 《Nuclear Science and Techniques》 2026年第1期212-224,共13页
In this paper,a novel method for investigating the particle-crushing behavior of breeding particles in a fusion blanket is proposed.The fractal theory and Weibull distribution are combined to establish a theoretical m... In this paper,a novel method for investigating the particle-crushing behavior of breeding particles in a fusion blanket is proposed.The fractal theory and Weibull distribution are combined to establish a theoretical model,and its validity was verified using a simple impact test.A crushable discrete element method(DEM)framework is built based on the previously established theoretical model.The tensile strength,which considers the fractal theory,size effect,and Weibull variation,was assigned to each generated particle.The assigned strength is then used for crush detection by comparing it with its maximum tensile stress.Mass conservation is ensured by inserting a series of sub-particles whose total mass was equal to the quality loss.Based on the crushable DEM framework,a numerical simulation of the crushing behavior of a pebble bed with hollow cylindrical geometry under a uniaxial compression test was performed.The results of this investigation showed that the particle withstands the external load by contact and sliding at the beginning of the compression process,and the results confirmed that crushing can be considered an important method of resisting the increasing external load.A relatively regular particle arrangement aids in resisting the load and reduces the occurrence of particle crushing.However,a limit exists to the promotion of resistance.When the strain increases beyond this limit,the distribution of the crushing position tends to be isotropic over the entire pebble bed.The theoretical model and crushable DEM framework provide a new method for exploring the pebble bed in a fusion reactor,considering particle crushing. 展开更多
关键词 Crushing behavior Granular material Discrete element method Pebble bed Fractal theory
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ANALYSIS OF A QUADRILATERAL EDGE ELEMENT METHOD FOR MAXWELL EQUATIONS
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作者 Zhijie DU Huoyuan DUAN Caihong WANG 《Acta Mathematica Scientia》 2026年第1期275-292,共18页
A new quadrilateral edge element method is proposed and analyzed for Maxwell equations.This proposed method is based on Duan-Liang quadrilateral element(Math.Comp.73(2004),pp.1–18).When applied to the eigenvalue prob... A new quadrilateral edge element method is proposed and analyzed for Maxwell equations.This proposed method is based on Duan-Liang quadrilateral element(Math.Comp.73(2004),pp.1–18).When applied to the eigenvalue problem,the method is spectral-correct and spurious-free.Stability and error estimates are obtained,including the interpolation error estimates and the error estimates between the finite element solution and the exact solution.The method is suitable for singular solution as well as smooth solution,and consequently,the method is valid for nonconvex domains which may have a number of reentrant corners.Of course,the method is suitable for arbitrary quadrilaterals(under the usual shape-regular condition). 展开更多
关键词 Maxwell equations finite element method quadrilateral mesh STABILITY error bound spectral approximation
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A Deep Reinforcement Learning-Based Partitioning Method for Power System Parallel Restoration
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作者 Changcheng Li Weimeng Chang +1 位作者 Dahai Zhang Jinghan He 《Energy Engineering》 2026年第1期243-264,共22页
Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision... Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision process is formulated as a Markov decision process(MDP)model to maximize the modularity.Corresponding key partitioning constraints on parallel restoration are considered.Second,based on the partitioning objective and constraints,the reward function of the partitioning MDP model is set by adopting a relative deviation normalization scheme to reduce mutual interference between the reward and penalty in the reward function.The soft bonus scaling mechanism is introduced to mitigate overestimation caused by abrupt jumps in the reward.Then,the deep Q network method is applied to solve the partitioning MDP model and generate partitioning schemes.Two experience replay buffers are employed to speed up the training process of the method.Finally,case studies on the IEEE 39-bus test system demonstrate that the proposed method can generate a high-modularity partitioning result that meets all key partitioning constraints,thereby improving the parallelism and reliability of the restoration process.Moreover,simulation results demonstrate that an appropriate discount factor is crucial for ensuring both the convergence speed and the stability of the partitioning training. 展开更多
关键词 Partitioning method parallel restoration deep reinforcement learning experience replay buffer partitioning modularity
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An improved open-top dynamic chambers method for measuring the exchange fluxes of N_(2)O,NO and NH_(3) from farmland
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作者 Minhang Tan Yining Hu +6 位作者 Yifei Song Zixuan Huang Yujing Mu Junfeng Liu Chenglong Zhang Pengfei Liu Yuanyuan Zhang 《Journal of Environmental Sciences》 2026年第1期535-545,共11页
The application of nitrogen fertilizers in agricultural fields can lead to the release of nitrogen-containing gases(NCGs),such as NO_(x),NH_(3) and N_(2)O,which can significantly impact regional atmospheric environmen... The application of nitrogen fertilizers in agricultural fields can lead to the release of nitrogen-containing gases(NCGs),such as NO_(x),NH_(3) and N_(2)O,which can significantly impact regional atmospheric environment and con-tribute to global climate change.However,there remain considerable research gaps in the accurate measurement of NCGs emissions from agricultural fields,hindering the development of effective emission reduction strategies.We improved an open-top dynamic chambers(OTDCs)system and evaluated the performance by comparing the measured and given fluxes of the NCGs.The results showed that the measured fluxes of NO,N_(2)O and NH_(3)were 1%,2%and 7%lower than the given fluxes,respectively.For the determination of NH_(3) concentration,we employed a stripping coil-ion chromatograph(SC-IC)analytical technique,which demonstrated an absorption efficiency for atmospheric NH_(3) exceeding 96.1%across sampling durations of 6 to 60 min.In the summer maize season,we utilized the OTDCs system to measure the exchange fluxes of NO,NH_(3),and N_(2)O from the soil in the North China Plain.Substantial emissions of NO,NH_(3) and N_(2)O were recorded following fertilization,with peaks of 107,309,1239 ng N/(m^(2)·s),respectively.Notably,significant NCGs emissions were observed following sus-tained heavy rainfall one month after fertilization,particularly with NH_(3) peak being 4.5 times higher than that observed immediately after fertilization.Our results demonstrate that the OTDCs system accurately reflects the emission characteristics of soil NCGs and meets the requirements for long-term and continuous flux observation. 展开更多
关键词 Open-top dynamic chambers Nitrogen-containing gases Soil emissions North China Plain method evaluation
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Centralized Circumcentered-Reflection Method for Solving the Convex Feasibility Problem in Sparse Signal Recovery
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作者 Chunmei LI Bangjun CHEN Xuefeng DUAN 《Journal of Mathematical Research with Applications》 2026年第1期119-133,共15页
Convex feasibility problems are widely used in image reconstruction, sparse signal recovery, and other areas. This paper is devoted to considering a class of convex feasibility problem arising from sparse signal recov... Convex feasibility problems are widely used in image reconstruction, sparse signal recovery, and other areas. This paper is devoted to considering a class of convex feasibility problem arising from sparse signal recovery. We first derive the projection formulas for a vector onto the feasible sets. The centralized circumcentered-reflection method is designed to solve the convex feasibility problem. Some numerical experiments demonstrate the feasibility and effectiveness of the proposed algorithm, showing superior performance compared to conventional alternating projection methods. 展开更多
关键词 convex feasibility problem centralized circumcentered-re ection method sparse signal recovery compressed sensing
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Numerical Simulation of the Welding Deformation of Marine Thin Plates Based on a Temperature Gradient-thermal Strain Method
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作者 Lin Wang Yugang Miao +3 位作者 Zhenjian Zhuo Chunxiang Lin Benshun Zhang Duanfeng Han 《哈尔滨工程大学学报(英文版)》 2026年第1期122-135,共14页
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t... Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates. 展开更多
关键词 Marine thin plate Welding deformation Numerical simulation Temperature gradient-thermal strain method Shell element
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A new ground-motion scaling and record selection procedure for asymmetric-plan buildings using the 2DOF-modal pushover method
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作者 Hamid Hojaji Mohammad Sadegh Birzhandi Mohammad Mahdi Zafarani 《Earthquake Engineering and Engineering Vibration》 2026年第1期71-86,共16页
Advanced intensity measures(IMs)based on an inelastic deformation spectrum improved the evaluation of the median engineering demand parameters(EDPs)and reduced dispersion.In this regard,an optimized two-degreefreedom(... Advanced intensity measures(IMs)based on an inelastic deformation spectrum improved the evaluation of the median engineering demand parameters(EDPs)and reduced dispersion.In this regard,an optimized two-degreefreedom(2DOF)modal pushover-based scaling procedure(2DMPS)has been developed for a nonlinear dynamic analysis of asymmetric in-plan buildings.The 2DMPS procedure scales ground motions to approach close enough to a target value of the inelastic displacement of the first-mode inelastic 2DOF modal stick,extended for structures with significant contributions of higher modes.Further,4-,6-and 13-story RC SMRF buildings were selected for analyses using ground motion records scaled by the 2DMPS procedure,the modal pushover-based scaling method(MPS),and ASCE/SEI 7-16 scaling procedures.The median values of EDPs on scaled records closely matched the benchmark results.The bias in the EDP values due to the scaled records in every group regarding their median value was lower than the dispersion of the 21 unscaled records.These results generally demonstrate the accuracy and efficiency of the 2DMPS method.Additionally,the 2DOF modal stick’s inelastic response spectra are better suited for calculating seismic demands for one-way asymmetric-plan structures than the SDOF inelastic response spectra. 展开更多
关键词 intensity measure record selection asymmetric structures modal pushover method record scaling inelastic response spectra
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Precision and trueness of a method for determing antimony content in groundwater using hydride generation-atomic fluorescence spectrometry
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作者 Bing-bing Liu Lin Zhang Ke Li 《Journal of Groundwater Science and Engineering》 2026年第1期49-58,共10页
At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systema... At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater. 展开更多
关键词 Mandel's h and k statistics Grubbs test Cochran test Repeatability limit Reproducibility limit method bias value
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