During ultradeep oil and gas drilling,fluid loss reducers are highly important for water-based drilling fluids,while preparing high temperature-and salt-resistance fluid loss reducers with excellent rheology and filtr...During ultradeep oil and gas drilling,fluid loss reducers are highly important for water-based drilling fluids,while preparing high temperature-and salt-resistance fluid loss reducers with excellent rheology and filtration performance remains a challenge.Herein,a micro-crosslinked amphoteric hydrophobic association copolymer(i.e.,DADC)was synthesized using N,N-dimethyl acrylamide,diallyl dimethyl ammonium chloride,2-acrylamido-2-methylpropane sulfonic acid,hydrophobic monomer,and pentaerythritol triallyl ether crosslinker.Due to the synergistic effects of hydrogen bonds,electrostatic interaction,hydrophobic association,and micro-crosslinking,the DADC copolymer exhibited outstanding temperature-and salt-resistance.The rheological experiments have shown that the DADC copolymer had excellent shear dilution performance and a certain degree of salt-responsive viscosity-increasing performance.The DADC copolymer could effectively adsorb on the surface of bentonite particles through electrostatic interaction and hydrogen bonds,which bring more negative charge to the bentonite,thus improving the hydration and dispersion of bentonite particles as well as the colloidal stability of the drilling fluids.Moreover,the drilling fluids constructed based on the DADC copolymer exhibited satisfactory rheological and filtration properties(FLHTHP=12 m L)after aging at high temperatures(up to200℃)and high salinity(saturated salt)environments.Therefore,this work provided new insights into designing and fabricating high-performance drilling fluid treatment agents,demonstrating good potential applications in deep and ultradeep drilling engineering.展开更多
Wellbore instability is an issue that,if left untreated,can cause wells to collapse,resulting in human,environmental,equipment,and revenue losses.Drilling fluids have been used to enhance the drilling process by lubri...Wellbore instability is an issue that,if left untreated,can cause wells to collapse,resulting in human,environmental,equipment,and revenue losses.Drilling fluids have been used to enhance the drilling process by lubricating and cooling the drill bit,eliminating cuttings,and most importantly,by improving the stability of the well by preventing fluid loss.However,there has been an increase in operational demands and challenges that call for drilling fluids to be more effective,economical,sustainable,and environmentally friendly.With shales that have infinitesimally small pores,nanoparticle additives in drilling fluids can be crucial in providing the properties that are necessary to prevent fluid loss and provide wellbore stability while meeting the operational demands of the present day.Therefore,this paper examines the use of nanoparticle additives including copper(Ⅱ)oxide(CuO),magnesium oxide(MgO),and aluminum oxide(Al_(2)O_(3))where they are tested under three conditions using the permeable plugging tester(PPT),high-temperature high-pressure(HTHP)fluid loss apparatus,and API low-temperature e low-pressure(LTLP)fluid loss apparatus under concentrations of 0.03%and 0.10%.Finally,based on the results,each nanoparticle sample(particle sizes between one and 100 nm)performed well in contributing to the aim of this project.CuO is the most effective inhibitor across all concentrations and under the three different conditions.It contributed to reducing the fluid loss from 37.6 mL to 18.2 and 13.2 mL,which is between 52%and 65%of fluid reduction.For MgO,it contributed to fluid loss reduction to 23.8 mL and 15 mL,which translated to 37%e60%of fluid loss reduction.The use of Al_(2)O_(3) nanoparticles resulted in a fluid loss reduction to 33.6 mL and 17.8 mL,reducing the fluid loss up to 11%,at HTHP and up to 53%at LTLP.Unlike CuO and MgO,Al_(2)O_(3) was less effective under HTHP conditions when compared to LTLP conditions.Al_(2)O_(3) did not suffer as a significant diminishing benefit with increasing concentration in LTLP conditions however which means that at a higher concentration,it may begin to be more effective.Each material used in this study has its own specific and technical characteristics that will help create a progressive amount of property,such as providing stability and withstanding the high-temperature and highpressure condition downhole.展开更多
The pressure loss of cross-flow perforated of physical modeling, simulation and data processing. muffler has been computed with the procedure Three-dimensional computational fluid dynamics （CFD） has been used to inv...The pressure loss of cross-flow perforated of physical modeling, simulation and data processing. muffler has been computed with the procedure Three-dimensional computational fluid dynamics （CFD） has been used to investigate the relations of porosities, flow velocity and diameter of the holes with the pressure loss. Accordingly, some preliminary results have been obtained that pressure loss increases with porosity descent as nearly a hyperbolic trend, rising flow velocity of the input makes the pressure loss increasing with parabola trend, diameter of holes affects little about pressure loss of the muffler. Otherwise, the holes on the perforated pipes make the air flow gently and meanly, which decreases the air impact to the wall and pipes in the muffler. A practical perforated muffler is used to illustrate the available of this method for pressure loss computation, and the comparison shows that the computation results with the method of CFD has reference value for muffler design.展开更多
CoFe2O4 nanoparticles(NPs)and surface modified with gold(Au)have been synthesized by a thermal decomposition method.The obtained NPs and formation of CoFe2O4@Au core–shell(CS)were confirmed by characterizing their st...CoFe2O4 nanoparticles(NPs)and surface modified with gold(Au)have been synthesized by a thermal decomposition method.The obtained NPs and formation of CoFe2O4@Au core–shell(CS)were confirmed by characterizing their structural and optical properties using X-ray powder diffraction(XRD)patterns,Fourier transform infrared spectroscopy,Raman spectroscopy,UV–Visible and photoluminescence studies.Morphological and compositional studies were carried out using high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy,while the magnetic properties were determined using alternating gradient magnetometer and Mossbauer to define the magneto-structural effects of shell formation on the core NPs.Induction heating properties of CoFe2O4 and CoFe2O4@Au CS magnetic nanoparticles(MNPs)have been investigated and correlated with magneto-structural properties.Specific absorption rate and intrinsic loss power were calculated for these MNPs within the human tolerable range of frequency and amplitude,suggesting their potential in magnetic fluid hyperthermia therapy for possible cancer treatment.展开更多
基金the National Natural Science Foundation of China(No.52204023)China Postdoctoral Science Foundation(2022M713465)Postdoctoral Innovation Talent Support of Shandong Province(SDBX2022033)。
文摘During ultradeep oil and gas drilling,fluid loss reducers are highly important for water-based drilling fluids,while preparing high temperature-and salt-resistance fluid loss reducers with excellent rheology and filtration performance remains a challenge.Herein,a micro-crosslinked amphoteric hydrophobic association copolymer(i.e.,DADC)was synthesized using N,N-dimethyl acrylamide,diallyl dimethyl ammonium chloride,2-acrylamido-2-methylpropane sulfonic acid,hydrophobic monomer,and pentaerythritol triallyl ether crosslinker.Due to the synergistic effects of hydrogen bonds,electrostatic interaction,hydrophobic association,and micro-crosslinking,the DADC copolymer exhibited outstanding temperature-and salt-resistance.The rheological experiments have shown that the DADC copolymer had excellent shear dilution performance and a certain degree of salt-responsive viscosity-increasing performance.The DADC copolymer could effectively adsorb on the surface of bentonite particles through electrostatic interaction and hydrogen bonds,which bring more negative charge to the bentonite,thus improving the hydration and dispersion of bentonite particles as well as the colloidal stability of the drilling fluids.Moreover,the drilling fluids constructed based on the DADC copolymer exhibited satisfactory rheological and filtration properties(FLHTHP=12 m L)after aging at high temperatures(up to200℃)and high salinity(saturated salt)environments.Therefore,this work provided new insights into designing and fabricating high-performance drilling fluid treatment agents,demonstrating good potential applications in deep and ultradeep drilling engineering.
文摘Wellbore instability is an issue that,if left untreated,can cause wells to collapse,resulting in human,environmental,equipment,and revenue losses.Drilling fluids have been used to enhance the drilling process by lubricating and cooling the drill bit,eliminating cuttings,and most importantly,by improving the stability of the well by preventing fluid loss.However,there has been an increase in operational demands and challenges that call for drilling fluids to be more effective,economical,sustainable,and environmentally friendly.With shales that have infinitesimally small pores,nanoparticle additives in drilling fluids can be crucial in providing the properties that are necessary to prevent fluid loss and provide wellbore stability while meeting the operational demands of the present day.Therefore,this paper examines the use of nanoparticle additives including copper(Ⅱ)oxide(CuO),magnesium oxide(MgO),and aluminum oxide(Al_(2)O_(3))where they are tested under three conditions using the permeable plugging tester(PPT),high-temperature high-pressure(HTHP)fluid loss apparatus,and API low-temperature e low-pressure(LTLP)fluid loss apparatus under concentrations of 0.03%and 0.10%.Finally,based on the results,each nanoparticle sample(particle sizes between one and 100 nm)performed well in contributing to the aim of this project.CuO is the most effective inhibitor across all concentrations and under the three different conditions.It contributed to reducing the fluid loss from 37.6 mL to 18.2 and 13.2 mL,which is between 52%and 65%of fluid reduction.For MgO,it contributed to fluid loss reduction to 23.8 mL and 15 mL,which translated to 37%e60%of fluid loss reduction.The use of Al_(2)O_(3) nanoparticles resulted in a fluid loss reduction to 33.6 mL and 17.8 mL,reducing the fluid loss up to 11%,at HTHP and up to 53%at LTLP.Unlike CuO and MgO,Al_(2)O_(3) was less effective under HTHP conditions when compared to LTLP conditions.Al_(2)O_(3) did not suffer as a significant diminishing benefit with increasing concentration in LTLP conditions however which means that at a higher concentration,it may begin to be more effective.Each material used in this study has its own specific and technical characteristics that will help create a progressive amount of property,such as providing stability and withstanding the high-temperature and highpressure condition downhole.
文摘The pressure loss of cross-flow perforated of physical modeling, simulation and data processing. muffler has been computed with the procedure Three-dimensional computational fluid dynamics （CFD） has been used to investigate the relations of porosities, flow velocity and diameter of the holes with the pressure loss. Accordingly, some preliminary results have been obtained that pressure loss increases with porosity descent as nearly a hyperbolic trend, rising flow velocity of the input makes the pressure loss increasing with parabola trend, diameter of holes affects little about pressure loss of the muffler. Otherwise, the holes on the perforated pipes make the air flow gently and meanly, which decreases the air impact to the wall and pipes in the muffler. A practical perforated muffler is used to illustrate the available of this method for pressure loss computation, and the comparison shows that the computation results with the method of CFD has reference value for muffler design.
基金Author (Sandip Sabale) is thankful to University Grants Commission, New Delhi, India, for Raman Fellowship to work in USA (F. No. 5-105/2016 (IC), February 10, 2016
文摘CoFe2O4 nanoparticles(NPs)and surface modified with gold(Au)have been synthesized by a thermal decomposition method.The obtained NPs and formation of CoFe2O4@Au core–shell(CS)were confirmed by characterizing their structural and optical properties using X-ray powder diffraction(XRD)patterns,Fourier transform infrared spectroscopy,Raman spectroscopy,UV–Visible and photoluminescence studies.Morphological and compositional studies were carried out using high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy,while the magnetic properties were determined using alternating gradient magnetometer and Mossbauer to define the magneto-structural effects of shell formation on the core NPs.Induction heating properties of CoFe2O4 and CoFe2O4@Au CS magnetic nanoparticles(MNPs)have been investigated and correlated with magneto-structural properties.Specific absorption rate and intrinsic loss power were calculated for these MNPs within the human tolerable range of frequency and amplitude,suggesting their potential in magnetic fluid hyperthermia therapy for possible cancer treatment.
