The low-melting glass of Bi2O_(3)-B2O_(3)-SiO_(2)(BiBSi)system was used for the first time for laser sealing of vacuum glazing.Under the condition of constant boron content,how the structure and properties vary with B...The low-melting glass of Bi2O_(3)-B2O_(3)-SiO_(2)(BiBSi)system was used for the first time for laser sealing of vacuum glazing.Under the condition of constant boron content,how the structure and properties vary with Bi/Si ratio in low-melting glass was investigated.In addition,the relationships between laser power,low-melting glass solder with different Bi/Si ratios and laser sealing shear strength were revealed.The results show that a decrease in the Bi/Si ratio can cause a contraction of the glass network of the low-melting glass,leading to an increase of its characteristic temperature and a decrease of its coefficient of thermal expansion.During laser sealing,the copper ions in the low-melting glass play an endothermic role.A change in the Bi/Si ratio will affect the valence state transition of the copper ions in the low-melting glass.The absorbance of the low-melting glass does not follow the expected correlation with the Bi/Si ratio,but shows a linear correlation with the content of divalent copper ions.The greater the concentration of divalent copper ions,the greater the absorbance of the low-melting glass,and the lower the laser power required for laser sealing.The shear strength of the low melting glass solder after laser sealing was tested,and it was found that the maximum shear strength of Z1 glass sample was the highest up to 2.67 MPa.展开更多
The effect of Mg/Si mass ratio on the microstructure and mechanical properties of Al-Mg-Si cast aluminum alloys under sub-rapid solidification conditions was investigated.This study utilized four different Mg/Si ratio...The effect of Mg/Si mass ratio on the microstructure and mechanical properties of Al-Mg-Si cast aluminum alloys under sub-rapid solidification conditions was investigated.This study utilized four different Mg/Si ratios:2.83,1.91,1.73,and 1.53.To analyze the evolution of the microstructure,particularly the second phase,various techniques were employed:optical microscopy(OM),scanning electron microscopy(SEM),energy dispersive spectrometry(EDS),and electron backscatter diffraction(EBSD).Additionally,thermodynamic calculations were performed using the Thermal-calc software to further understand the microstructural changes.Results show that as the Mg/Si ratio decreases from 2.83 to 1.53,α-Al grains become more uniformly distributed.Meanwhile,the morphology of the Mg_(2)Si phases changes from skeletal to short stick shapes with a decreasing aspect ratio.An as-cast Al-Mg-Si alloy with a Mg/Si ratio of 1.53 exhibits high strength,achieving an ultimate tensile strength(UTS)of 320.6 MPa and a yield strength(YS)of 249.9 MPa.The cast alloy with a Mg/Si ratio of 2.83exhibits the highest elongation,reaching 5.31%.This superior elongation is attributed to the uniform distribution of Mg_(2)Si phases,which possess a long skeletal shape.Conversely,the alloy with a Mg/Si ratio of 1.53 demonstrates the lowest elongation,primarily due to the central concentration of Mg_(2)Si phases,which are characterized by their short stick shapes.展开更多
This study employed a wet impregnation method to synthesize five types of Cu/HZSM-5 adsorbents with Si/Al ratios of 25,50,85,200,and 300,used for the removal of H_(2)S in lowtemperature,low-oxygen environments.The imp...This study employed a wet impregnation method to synthesize five types of Cu/HZSM-5 adsorbents with Si/Al ratios of 25,50,85,200,and 300,used for the removal of H_(2)S in lowtemperature,low-oxygen environments.The impact of different Si/Al ratios on the adsorption oxidative performance of Cu_(30)/HZSM-5–85 adsorbents was investigated.According to the performance test results,Cu_(30)/HZSM-5–85 exhibited the highest breakthrough capacity,reaching 231.75 mg H_(2)S/g_(sorbent).Cu/HZSM-5 sorbent maintains a strong ability to remove H_(2)S even under humid conditions and shows excellent water resistance.XRD,BET,and XPS results revealed that CuO is the primary active species,with Cu_(30)/HZSM-5–85 having the largest surface area and highest CuO content,providing more active sites for H_(2)S adsorption.H_(2)-TPR and O_(2)-TPD results confirmed that Cu_(30)/HZSM-5–85 sorbent exhibits outstanding redox properties and oxygen storage capacity,contributing to excellent oxygen transferability in the molecular sieve adsorption-oxidation process.With notable characteristics such as a large surface area,high desulfurization efficiency,and water resistance,Cu_(30)/HZSM-5–85 sorbents hold significant importance for industrial applications.展开更多
Thus far,metal-bonding has presented high efficacy in improving the mechanical,thermal conductive,and anti-corrosion properties of La(Fe,Si)_(13)-based hydrides.However,to ensure high performance,the proportion of met...Thus far,metal-bonding has presented high efficacy in improving the mechanical,thermal conductive,and anti-corrosion properties of La(Fe,Si)_(13)-based hydrides.However,to ensure high performance,the proportion of metal bonders has to be as high as 20 wt%,thereby significantly weakening the magnetocaloric effect(MCE).In this work,small amounts of graphene nanosheets(up to 2 wt%)with high thermal conductivity and specific surface area were incorporated into the La_(0.8)Ce_(0.2)Fe_(11.7)Si_(1.3)Hymatrix through a cold-pressing and sintering process.X-ray diffraction analysis indicates that carbon from graphene can easily diffuse into the lattice of La(Fe,Si)13main phase as an interstitial atom,resulting in a significant increase of the lattice constant accompanied by a significant decrease of the Curie temperature and H content of the composites.While 0.3 wt%graphene doping only has minor improvements in the thermal conductivityλand corrosion resistance of the parent La_(0.8)Ce_(0.2)Fe_(11.7)Si_(1.3)H_(y),further increase of graphene content to 1 wt%causes a significant increase ofλfrom 1.4 W/(m·K)for the parent material to~2 W/(m·K)and a decrease of corrosion current density from 1.43×10^(-5)to 9.63×10^(-6)A/cm^(2).When the graphene content is lower than 0.3 wt%,the large MCE does not significantly deteriorate.In 0-1.5 T,the maximal magnetic-entropy change ASm of 11.5 J/(kg·K)at 336 K for the parent material decreases to 8.2 J/(kg·K)at 306 K for the 2 wt%graphene-dop ed composite.展开更多
Self-designed Al8Si0.4Mg0.4Fe aluminium alloy was modified with Sr,followed by solid solution and aging treatments to regulate its microstructure and mechanical/electrical properties.The results show that after the mo...Self-designed Al8Si0.4Mg0.4Fe aluminium alloy was modified with Sr,followed by solid solution and aging treatments to regulate its microstructure and mechanical/electrical properties.The results show that after the modification treatment,the room-temperature tensile strength of the alloy remains nearly unchanged,the elongation at break slightly increases from 1.82%to 3.34%,and the electrical conductivity significantly increases from 40.1%international annealed copper standard(IACS)to 42.0%IACS.After the modification,the alloy was subjected to solid solution treatment at 515℃for 8 h,followed by aging treatment at 180,200,220 and 240℃for 6 h.With increasing aging temperature,the electrical conductivity increases monotonously from 41.4%IACS to 45.5%IACS,while the room-temperature tensile strength initially increases and then decreases.At 200℃,the alloy achieves an optimal balance between electrical conductivity and room-temperature tensile strength:the electrical conductivity is 42.5%IACS,and the room-temperature tensile strength is 282.9 MPa.When the aging temperature continues to rise,the alloy undergoes overaging.Although the conductivity continues to increase,the room-temperature tensile strength drops sharply,and it is only 177.1 MPa at 240℃.展开更多
The effects of Al(Fe,Mn)Si particles controlled by different hot-rolling deformations on the microstructure evolution,texture evolution,and formabilities of Al−Mg−Si−Zn alloy were systematically investigated using OM,...The effects of Al(Fe,Mn)Si particles controlled by different hot-rolling deformations on the microstructure evolution,texture evolution,and formabilities of Al−Mg−Si−Zn alloy were systematically investigated using OM,SEM,TEM,XRD,and tensile tests.The results indicate that Al(Fe,Mn)Si particles with different size and number distribution characteristics can be obtained by adjusting the hot-rolling deformation degree(59%,74%and 87%),and these differences in particle distribution are the main factors affecting the recrystallization nucleation and grain growth during solution treatment.After T4P treatment,the grain orientations in the Al−Mg−Si−Zn alloy sheets with 59%and 74%hot-rolling deformation tend to be randomly distributed.In comparison,the sheet with 87%hot-rolling deformation consists of R{124}<211>,CubeND{100}<013>,Copper{112}<111>and Brass{011}<211>texture components.The medium size and number of Al(Fe,Mn)Si particles obtained at 74%hot-rolling deformation cause fine grains and randomly distributed texture,which significantly improves the formability of Al−Mg−Si−Zn alloy.展开更多
基金Funded by the National Natural Science Foundation of China(No.52472012)Opening Project of State Silica-Based Materials Laboratory of Anhui Province(No.2022KF11)the Research and Development of Glass Powder for Laser Sealing and Its Sealing Technology(No.K24556)。
文摘The low-melting glass of Bi2O_(3)-B2O_(3)-SiO_(2)(BiBSi)system was used for the first time for laser sealing of vacuum glazing.Under the condition of constant boron content,how the structure and properties vary with Bi/Si ratio in low-melting glass was investigated.In addition,the relationships between laser power,low-melting glass solder with different Bi/Si ratios and laser sealing shear strength were revealed.The results show that a decrease in the Bi/Si ratio can cause a contraction of the glass network of the low-melting glass,leading to an increase of its characteristic temperature and a decrease of its coefficient of thermal expansion.During laser sealing,the copper ions in the low-melting glass play an endothermic role.A change in the Bi/Si ratio will affect the valence state transition of the copper ions in the low-melting glass.The absorbance of the low-melting glass does not follow the expected correlation with the Bi/Si ratio,but shows a linear correlation with the content of divalent copper ions.The greater the concentration of divalent copper ions,the greater the absorbance of the low-melting glass,and the lower the laser power required for laser sealing.The shear strength of the low melting glass solder after laser sealing was tested,and it was found that the maximum shear strength of Z1 glass sample was the highest up to 2.67 MPa.
基金supported by the WQ&UCS (Binzhou)Industrialization Research Institute。
文摘The effect of Mg/Si mass ratio on the microstructure and mechanical properties of Al-Mg-Si cast aluminum alloys under sub-rapid solidification conditions was investigated.This study utilized four different Mg/Si ratios:2.83,1.91,1.73,and 1.53.To analyze the evolution of the microstructure,particularly the second phase,various techniques were employed:optical microscopy(OM),scanning electron microscopy(SEM),energy dispersive spectrometry(EDS),and electron backscatter diffraction(EBSD).Additionally,thermodynamic calculations were performed using the Thermal-calc software to further understand the microstructural changes.Results show that as the Mg/Si ratio decreases from 2.83 to 1.53,α-Al grains become more uniformly distributed.Meanwhile,the morphology of the Mg_(2)Si phases changes from skeletal to short stick shapes with a decreasing aspect ratio.An as-cast Al-Mg-Si alloy with a Mg/Si ratio of 1.53 exhibits high strength,achieving an ultimate tensile strength(UTS)of 320.6 MPa and a yield strength(YS)of 249.9 MPa.The cast alloy with a Mg/Si ratio of 2.83exhibits the highest elongation,reaching 5.31%.This superior elongation is attributed to the uniform distribution of Mg_(2)Si phases,which possess a long skeletal shape.Conversely,the alloy with a Mg/Si ratio of 1.53 demonstrates the lowest elongation,primarily due to the central concentration of Mg_(2)Si phases,which are characterized by their short stick shapes.
基金supported by the National Natural Science Foundation of China(Nos.52270106 and 22266021)Yunnan Major Scientific and Technological Projects(No.202202AG050005)Yunnan Fundamental Research Projects(No.202201AT070116).
文摘This study employed a wet impregnation method to synthesize five types of Cu/HZSM-5 adsorbents with Si/Al ratios of 25,50,85,200,and 300,used for the removal of H_(2)S in lowtemperature,low-oxygen environments.The impact of different Si/Al ratios on the adsorption oxidative performance of Cu_(30)/HZSM-5–85 adsorbents was investigated.According to the performance test results,Cu_(30)/HZSM-5–85 exhibited the highest breakthrough capacity,reaching 231.75 mg H_(2)S/g_(sorbent).Cu/HZSM-5 sorbent maintains a strong ability to remove H_(2)S even under humid conditions and shows excellent water resistance.XRD,BET,and XPS results revealed that CuO is the primary active species,with Cu_(30)/HZSM-5–85 having the largest surface area and highest CuO content,providing more active sites for H_(2)S adsorption.H_(2)-TPR and O_(2)-TPD results confirmed that Cu_(30)/HZSM-5–85 sorbent exhibits outstanding redox properties and oxygen storage capacity,contributing to excellent oxygen transferability in the molecular sieve adsorption-oxidation process.With notable characteristics such as a large surface area,high desulfurization efficiency,and water resistance,Cu_(30)/HZSM-5–85 sorbents hold significant importance for industrial applications.
基金Project supported by the National Natural Science Foundation of China(52171187,52271192)。
文摘Thus far,metal-bonding has presented high efficacy in improving the mechanical,thermal conductive,and anti-corrosion properties of La(Fe,Si)_(13)-based hydrides.However,to ensure high performance,the proportion of metal bonders has to be as high as 20 wt%,thereby significantly weakening the magnetocaloric effect(MCE).In this work,small amounts of graphene nanosheets(up to 2 wt%)with high thermal conductivity and specific surface area were incorporated into the La_(0.8)Ce_(0.2)Fe_(11.7)Si_(1.3)Hymatrix through a cold-pressing and sintering process.X-ray diffraction analysis indicates that carbon from graphene can easily diffuse into the lattice of La(Fe,Si)13main phase as an interstitial atom,resulting in a significant increase of the lattice constant accompanied by a significant decrease of the Curie temperature and H content of the composites.While 0.3 wt%graphene doping only has minor improvements in the thermal conductivityλand corrosion resistance of the parent La_(0.8)Ce_(0.2)Fe_(11.7)Si_(1.3)H_(y),further increase of graphene content to 1 wt%causes a significant increase ofλfrom 1.4 W/(m·K)for the parent material to~2 W/(m·K)and a decrease of corrosion current density from 1.43×10^(-5)to 9.63×10^(-6)A/cm^(2).When the graphene content is lower than 0.3 wt%,the large MCE does not significantly deteriorate.In 0-1.5 T,the maximal magnetic-entropy change ASm of 11.5 J/(kg·K)at 336 K for the parent material decreases to 8.2 J/(kg·K)at 306 K for the 2 wt%graphene-dop ed composite.
基金Applied Basic Research Program of Liaoning Province(CN)(2022JH2/101300078)。
文摘Self-designed Al8Si0.4Mg0.4Fe aluminium alloy was modified with Sr,followed by solid solution and aging treatments to regulate its microstructure and mechanical/electrical properties.The results show that after the modification treatment,the room-temperature tensile strength of the alloy remains nearly unchanged,the elongation at break slightly increases from 1.82%to 3.34%,and the electrical conductivity significantly increases from 40.1%international annealed copper standard(IACS)to 42.0%IACS.After the modification,the alloy was subjected to solid solution treatment at 515℃for 8 h,followed by aging treatment at 180,200,220 and 240℃for 6 h.With increasing aging temperature,the electrical conductivity increases monotonously from 41.4%IACS to 45.5%IACS,while the room-temperature tensile strength initially increases and then decreases.At 200℃,the alloy achieves an optimal balance between electrical conductivity and room-temperature tensile strength:the electrical conductivity is 42.5%IACS,and the room-temperature tensile strength is 282.9 MPa.When the aging temperature continues to rise,the alloy undergoes overaging.Although the conductivity continues to increase,the room-temperature tensile strength drops sharply,and it is only 177.1 MPa at 240℃.
基金the National Key R&D Program of China(Nos.2020YFF0218200,2016YFB0300802)for financial support。
文摘The effects of Al(Fe,Mn)Si particles controlled by different hot-rolling deformations on the microstructure evolution,texture evolution,and formabilities of Al−Mg−Si−Zn alloy were systematically investigated using OM,SEM,TEM,XRD,and tensile tests.The results indicate that Al(Fe,Mn)Si particles with different size and number distribution characteristics can be obtained by adjusting the hot-rolling deformation degree(59%,74%and 87%),and these differences in particle distribution are the main factors affecting the recrystallization nucleation and grain growth during solution treatment.After T4P treatment,the grain orientations in the Al−Mg−Si−Zn alloy sheets with 59%and 74%hot-rolling deformation tend to be randomly distributed.In comparison,the sheet with 87%hot-rolling deformation consists of R{124}<211>,CubeND{100}<013>,Copper{112}<111>and Brass{011}<211>texture components.The medium size and number of Al(Fe,Mn)Si particles obtained at 74%hot-rolling deformation cause fine grains and randomly distributed texture,which significantly improves the formability of Al−Mg−Si−Zn alloy.
