The structural parameters of low-stepped mirror which is the core component of a light Fourier transform infrared spectrometer(FTIRS) have important influence on the performance of the instrument. A simple method of m...The structural parameters of low-stepped mirror which is the core component of a light Fourier transform infrared spectrometer(FTIRS) have important influence on the performance of the instrument. A simple method of multiple deposition is proposed to fabricate a low-stepped mirror with step height of 625 nm, for its high precision, high efficiency and miniaturization. So the film stress will be introduced in the process of coating, which can lead to step deformation. We build a bending model of the low-stepped mirror and analyze the influence of its deformation. The light intensity and spectrum are changed by the step deformation. Therefore, the film stress should be reduced in order to ensure the accuracy of the spectral information. Increasing the thickness of substrate is proposed in this paper to reduce the step deformation, besides adjusting the coating temperature and adding sub-layer. Our results reveal that the basic requirements of the system are satisfied when the thickness of the substrate is 5 mm in the appropriate coating environment. An FTIRS based on stepped mirrors and grid beam splitter is assembled and corresponding experiment is carried out to obtain the spectrum curve of acetonitrile.展开更多
The in-situ FTIR spectroscopic results show that a hemi-ketal in- termediate may be produced in the electroreduction of benzoquinone or electro- oxidation of benzohydroquinone,which provides a valuable insight into th...The in-situ FTIR spectroscopic results show that a hemi-ketal in- termediate may be produced in the electroreduction of benzoquinone or electro- oxidation of benzohydroquinone,which provides a valuable insight into the me- chanism of the redox process.展开更多
Adsorption and oxidation of ethylene glyco(EG) on Pt(100) electrode were studied by in situ timeresolved FTIRS (TRFTIRS). The TRFTIR spectra recordedat 0.10 V illustrate that an IR band appears near 2050 cm?at t > ...Adsorption and oxidation of ethylene glyco(EG) on Pt(100) electrode were studied by in situ timeresolved FTIRS (TRFTIRS). The TRFTIR spectra recordedat 0.10 V illustrate that an IR band appears near 2050 cm?at t > 5 s, corresponding to linearly bonded CO formed indissociative adsorption of EG. The TRFTIR results haveconfirmed also that CO species are distributed uniformly onPt(100) surface. Another band appears near 2342 cm?1 at > 70 s, associating with IR absorption of CO2 produced inthe direct oxidation of EG. With the increase of electrodepotential, the direct oxidation of EG becomes gradually themain reaction. When the potential is above 0.40 V, the oxidation of EG occurs mainly via the reactive intermediates, i.especies containing –COOH determined by in situ TRFTIRS.展开更多
基金supported by the National Natural Science Foundation of China(Nos.61627819,61575193,61376122,617000222 and 6172780148)the Science and Technology Development Plan of Jilin Province(Nos.20150520101JH,20150101049JC,20150204072GX and 20170204077GX)the Youth Innovation Promotion Association of CAS(No.2014193)
文摘The structural parameters of low-stepped mirror which is the core component of a light Fourier transform infrared spectrometer(FTIRS) have important influence on the performance of the instrument. A simple method of multiple deposition is proposed to fabricate a low-stepped mirror with step height of 625 nm, for its high precision, high efficiency and miniaturization. So the film stress will be introduced in the process of coating, which can lead to step deformation. We build a bending model of the low-stepped mirror and analyze the influence of its deformation. The light intensity and spectrum are changed by the step deformation. Therefore, the film stress should be reduced in order to ensure the accuracy of the spectral information. Increasing the thickness of substrate is proposed in this paper to reduce the step deformation, besides adjusting the coating temperature and adding sub-layer. Our results reveal that the basic requirements of the system are satisfied when the thickness of the substrate is 5 mm in the appropriate coating environment. An FTIRS based on stepped mirrors and grid beam splitter is assembled and corresponding experiment is carried out to obtain the spectrum curve of acetonitrile.
文摘The in-situ FTIR spectroscopic results show that a hemi-ketal in- termediate may be produced in the electroreduction of benzoquinone or electro- oxidation of benzohydroquinone,which provides a valuable insight into the me- chanism of the redox process.
基金This work was supported by the National Natural Science Foundation of China(Gran:Nos.20373059 and 90206039)the“973"Program(Grant No.2002CB211804).
文摘Adsorption and oxidation of ethylene glyco(EG) on Pt(100) electrode were studied by in situ timeresolved FTIRS (TRFTIRS). The TRFTIR spectra recordedat 0.10 V illustrate that an IR band appears near 2050 cm?at t > 5 s, corresponding to linearly bonded CO formed indissociative adsorption of EG. The TRFTIR results haveconfirmed also that CO species are distributed uniformly onPt(100) surface. Another band appears near 2342 cm?1 at > 70 s, associating with IR absorption of CO2 produced inthe direct oxidation of EG. With the increase of electrodepotential, the direct oxidation of EG becomes gradually themain reaction. When the potential is above 0.40 V, the oxidation of EG occurs mainly via the reactive intermediates, i.especies containing –COOH determined by in situ TRFTIRS.
