Among various energy storage devices,lithium-sulfur batteries have attracted widespread attention due to their high theoretical energy density and specific capacity.To improve the performance and realize practical app...Among various energy storage devices,lithium-sulfur batteries have attracted widespread attention due to their high theoretical energy density and specific capacity.To improve the performance and realize practical applications of lithium-sulfur batteries,it is crucial to unravel the dynamic evolution and reaction mechanism at the electrode/electrolyte interfaces during cycling.Nevertheless,the details are still not well known despite generous efforts,which need more in situ and non-destructive imaging characterizations.Herein,we have combined AFM with an electrochemical workstation to dynamically visualize the morphological evolution and structural changes of the interfacial process,which reveals the lithium iodide-mediated interfacial reactions in lithium-sulfur batteries.In situ measurements showed that the electrode surface was coated by a reticular layer consists of elemental iodine and polyether with lithium iodide additive during charging,which could effectively prevent insolube sulfides from gathering on the surface and improve the cycling performances of lithium-sulfur batteries.These findings shed new light on the interfacial mechanism and establish design ideas for the future development of better electrolytes for lithium-sulfur batteries.展开更多
基金financially supported by the National Key Research and Development Program of China(Grant No.2021YFB2500300)CAS Project for Young Scientists in Basic Research(Grant No.YSBR-058)the National Nature Science Fund for Excellent Young Scholars(Grant No.21722508).
文摘Among various energy storage devices,lithium-sulfur batteries have attracted widespread attention due to their high theoretical energy density and specific capacity.To improve the performance and realize practical applications of lithium-sulfur batteries,it is crucial to unravel the dynamic evolution and reaction mechanism at the electrode/electrolyte interfaces during cycling.Nevertheless,the details are still not well known despite generous efforts,which need more in situ and non-destructive imaging characterizations.Herein,we have combined AFM with an electrochemical workstation to dynamically visualize the morphological evolution and structural changes of the interfacial process,which reveals the lithium iodide-mediated interfacial reactions in lithium-sulfur batteries.In situ measurements showed that the electrode surface was coated by a reticular layer consists of elemental iodine and polyether with lithium iodide additive during charging,which could effectively prevent insolube sulfides from gathering on the surface and improve the cycling performances of lithium-sulfur batteries.These findings shed new light on the interfacial mechanism and establish design ideas for the future development of better electrolytes for lithium-sulfur batteries.
