Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits ...Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.展开更多
Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl m...Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.展开更多
The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.A...The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.展开更多
In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,eff...In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).展开更多
Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics i...Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.展开更多
Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the ...Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the configuration of photovoltaic(3.8 MW),wind power(2.5 MW),energy storage(2.2 MWh),and SVC(1.2 Mvar)through interaction between upper and lower layers,and modifies lines 2–3,8–9,etc.to improve transmission capacity and voltage stability.The author uses normal distribution and Monte Carlo method to model load uncertainty,and combines Weibull distribution to describe wind speed characteristics.Compared to the traditional three-layer model(TLM),Benders decomposition-based two-layer model(BLBD)has a 58.1%reduction in convergence time(5.36 vs.12.78 h),a 51.1%reduction in iteration times(23 vs.47 times),a 8.07%reduction in total cost(12.436 vs.13.528 million yuan),and a 9.62%reduction in carbon emissions(12,456 vs.13,782 t).After optimization,the peak valley difference decreased from4.1 to 2.9MW,the renewable energy consumption rate reached 93.4%,and the energy storage efficiency was 87.6%.Themodel has been validated in the IEEE 33 node system,demonstrating its superiority in terms of economy,low-carbon,and reliability.展开更多
The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 M...The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 MPa and an elastic modulus of 145.8 GPa.After aging for 240 min at 500℃,the elastic modulus of the alloy reached 149.5 GPa,which was among the highest values reported for Cu alloys.It was worth mentioning that the tensile strength increased rapidly from 740 to 934 MPa after aging for 5 min at 500℃,which was close to the maximum tensile strength(978 MPa).Analysis of the underlying strengthening mechanisms and phase transformation behavior revealed that the Cu−19Ni−6Cr−7Mn alloy underwent spinodal decomposition and DO_(22) ordering during the first 5 min of aging at 500℃,and L1_(2) ordered phases and bcc-Cr precipitates appeared.Therefore,the enhanced mechanical properties of the Cu−19Ni−6Cr−7Mn alloy can be attributed to the stress field generated by spinodal decomposition and the presence of nanoscale ordered phase and Cr precipitates.展开更多
Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and ...Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and diversity on leaf litter decomposition in forests remains understudied.By controlling for macroclimate,soil properties,and litter substrate in a mature common garden,we investigated whether a three-month tea bag incubation of standardized green and rooibos tea substrate is driven by canopy tree species characteristics and diversity.Our study hypothesized two primary pathways:a chemical engineering effect,where trees alter soil properties and decomposer communities through litter input,and a physical engineering effect,where tree canopy structure modulates the local microclimate.The results showed that even under uniform macroclimatic and initial soil conditions,mass loss rates varied widely for green tea(27.4%–73.2%)and rooibos tea(6.1%–34.7%),comparable as found in other research between distinct biomes.While substrate quality was the dominant factor,both engineering pathways and,to a minor extent,tree diversity modulated mass losses.For green tea,tree chemical and physical characteristics seemed equally important,while the physical environment showed an increased importance for rooibos.Incubation depth played a key role,where forest floor decomposition rates are more susceptible to temporal climate variations,and soil-layer decomposition rates are less susceptible to climate variations and more determined by tree species identity.Our findings suggest that tea bag experiments focusing solely on topsoil burial may underestimate processes in the forest floor and the mineralorganic boundary layer.This study underscores the critical role of litter substrate quality in decomposition while demonstrating that tree community composition and the associated herbaceous layer,through both chemical and physical engineering pathways,strongly modulate decomposition rates.展开更多
In dry-coupled ultrasonic thickness measurement,thick rubber layers introduce high-amplitude parasitic echoes that obscure defect signals and degrade thickness accuracy.Existing methods struggle to resolve overlap-pin...In dry-coupled ultrasonic thickness measurement,thick rubber layers introduce high-amplitude parasitic echoes that obscure defect signals and degrade thickness accuracy.Existing methods struggle to resolve overlap-ping echoes under variable coupling conditions and non-stationary noise.This study proposes a novel dual-criterion framework integrating energy contribution and statistical impulsivity metrics to isolate specimen re-flections from coupling-layer interference.By decomposing A-scan signals into Intrinsic Mode Functions(IMFs),the framework employs energy contribution thresholds(>85%)and kurtosis indices(>3)to autonomously select IMFs containing valid specimen echoes.Hybrid time-frequency thresholding further suppresses interference through amplitude filtering and spectral focusing.Experimental results demonstrate the framework’s robustness,achieving 92.3%thickness accuracy for 5 mm steel specimens with 5 mm rubber coupling,outperforming conventional methods by up to 18.7%.The dual-criterion approach reduces operator dependency by 37%and maintainsΔT<0.03 mm under surface roughness up to 6.3μm,offering a practical solution for industrial nondestructive testing with thick dry-coupled interfaces.展开更多
Machine-learning is a robust technique for understanding pollution characteristics of surface ozone,which are at high levels in urban China.This study introduced an innovative approach combining trend decomposition wi...Machine-learning is a robust technique for understanding pollution characteristics of surface ozone,which are at high levels in urban China.This study introduced an innovative approach combining trend decomposition with Random Forest algorithm to investigate ozone dynamics and formation regimes in a coastal area of China.During the period of 2017–2022,significant inter-annual fluctuations emerged,with peaks in mid-2017 attributed to volatile organic compounds(VOCs),and in late-2019 influenced by air temperature.Multifaceted periodicities(daily,weekly,holiday,and yearly)in ozone were revealed,elucidating substantial influences of daily and yearly components on ozone periodicity.A VOC-sensitive ozone formation regime was identified,characterized by lower VOCs/NO_(x) ratios(average=0.88)and significant positive correlations between ozone and VOCs.This interplay manifested in elevated ozone duringweekends,holidays,and pandemic lockdowns.Key variables influencing ozone across diverse timescaleswere uncovered,with solar radiation and temperature driving daily and yearly ozone variations,respectively.Precursor substances,particularly VOCs,significantly shaped weekly/holiday patterns and long-term trends of ozone.Specifically,acetone,ethane,hexanal,and toluene had a notable impact on the multi-year ozone trend,emphasizing the urgency of VOC regulation.Furthermore,our observations indicated that NO_(x) primarily drived the stochastic variations in ozone,a distinguishing characteristic of regions with heavy traffic.This research provides novel insights into ozone dynamics in coastal urban areas and highlights the importance of integrating statistical and machinelearning methods in atmospheric pollution studies,with implications for targeted mitigation strategies beyond this specific region and pollutant.展开更多
Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. Ho...Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. However, such fascinating properties do not bring long-term cyclability of h-LMBs. One of critical challenges is the interface instability in contacting with the Li metal anode, as fiuorinated solvents are highly susceptible to exceptionally reductive metallic Li attributed to its low lowest unoccupied molecular orbital(LUMO), which leads to significant consumption of the fiuorinated components upon cycling.Herein, attenuating reductive decomposition of fiuorinated electrolytes is proposed to circumvent rapid electrolyte consumption. Specifically, the vinylene carbonate(VC) is selected to tame the reduction decomposition by preferentially forming protective layer on the Li anode. This work, experimentally and computationally, demonstrates the importance of pre-passivation of Li metal anodes at high voltage to attenuate the decomposition of fiuoroethylene carbonate(FEC). It is expected to enrich the understanding of how VC attenuate the reactivity of FEC, thereby extending the cycle life of fiuorinated electrolytes in high-voltage Li-metal batteries.展开更多
To overcome the challenges of poor real-time performance,limited scalability,and low intelligence in conventional jamming pattern recognition methods,this paper proposes a method based on Wavelet Packet Decomposition(...To overcome the challenges of poor real-time performance,limited scalability,and low intelligence in conventional jamming pattern recognition methods,this paper proposes a method based on Wavelet Packet Decomposition(WPD)and enhanced deep learning techniques.In the proposed method,an agent at the receiver processes the received signal using WPD to generate an initial Spectrogram Waterfall(SW),which is subsequently segmented using a sliding window to serve as the input for the jamming recognition network.The network employs a bilateral filter to preprocess the input SW,thereby enhancing the edge features of the jamming signals.To extract abstract features,depthwise separable convolution is utilized instead of traditional convolution,thereby reducing the network’s parameter count and enhancing real-time performance.A pyramid pooling layer is integrated before the fully connected layer to enable the network to process input SW of varying sizes,thus enhancing scalability.During network training,adaptive moment estimation is employed as the optimizer,allowing the network to dynamically adjust the learning rate and accelerate convergence.A comprehensive comparison between the proposed jamming recognition network and six other models is conducted,along with Ablation Experiments(AE)based on numerical simulations.Simulation results demonstrate that the proposed method based on WPD and enhanced deep learning achieves high-precision recognition of various jamming patterns while maintaining a favorable balance among prediction accuracy,network complexity,and prediction time.展开更多
Multivariate time series forecasting iswidely used in traffic planning,weather forecasting,and energy consumption.Series decomposition algorithms can help models better understand the underlying patterns of the origin...Multivariate time series forecasting iswidely used in traffic planning,weather forecasting,and energy consumption.Series decomposition algorithms can help models better understand the underlying patterns of the original series to improve the forecasting accuracy of multivariate time series.However,the decomposition kernel of previous decomposition-based models is fixed,and these models have not considered the differences in frequency fluctuations between components.These problems make it difficult to analyze the intricate temporal variations of real-world time series.In this paper,we propose a series decomposition-based Mamba model,DecMamba,to obtain the intricate temporal dependencies and the dependencies among different variables of multivariate time series.A variable-level adaptive kernel combination search module is designed to interact with information on different trends and periods between variables.Two backbone structures are proposed to emphasize the differences in frequency fluctuations of seasonal and trend components.Mamba with superior performance is used instead of a Transformer in backbone structures to capture the dependencies among different variables.A new embedding block is designed to capture the temporal features better,especially for the high-frequency seasonal component whose semantic information is difficult to acquire.A gating mechanism is introduced to the decoder in the seasonal backbone to improve the prediction accuracy.A comparison with ten state-of-the-art models on seven real-world datasets demonstrates that DecMamba can better model the temporal dependencies and the dependencies among different variables,guaranteeing better prediction performance for multivariate time series.展开更多
The multi-objective particle swarm optimization algorithm(MOPSO)is widely used to solve multi-objective optimization problems.In the article,amulti-objective particle swarm optimization algorithmbased on decomposition...The multi-objective particle swarm optimization algorithm(MOPSO)is widely used to solve multi-objective optimization problems.In the article,amulti-objective particle swarm optimization algorithmbased on decomposition and multi-selection strategy is proposed to improve the search efficiency.First,two update strategies based on decomposition are used to update the evolving population and external archive,respectively.Second,a multiselection strategy is designed.The first strategy is for the subspace without a non-dominated solution.Among the neighbor particles,the particle with the smallest penalty-based boundary intersection value is selected as the global optimal solution and the particle far away fromthe search particle and the global optimal solution is selected as the personal optimal solution to enhance global search.The second strategy is for the subspace with a non-dominated solution.In the neighbor particles,two particles are randomly selected,one as the global optimal solution and the other as the personal optimal solution,to enhance local search.The third strategy is for Pareto optimal front(PF)discontinuity,which is identified by the cumulative number of iterations of the subspace without non-dominated solutions.In the subsequent iteration,a new probability distribution is used to select from the remaining subspaces to search.Third,an adaptive inertia weight update strategy based on the dominated degree is designed to further improve the search efficiency.Finally,the proposed algorithmis compared with fivemulti-objective particle swarm optimization algorithms and five multi-objective evolutionary algorithms on 22 test problems.The results show that the proposed algorithm has better performance.展开更多
To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explo...To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explores the feasibility of adaptive-signal-decomposition-based denoising methods to improve THz spectral quality.THz time-domain spectroscopy(THz-TDS)combined with an attenuated total reflection(ATR)accessory was used to collect THz absorbance spectra from 48 peanut samples.Taking the quantitative prediction model of peanut moisture content based on THz-ATR as an example,wavelet transform(WT),empirical mode decomposition(EMD),local mean decomposition(LMD),and its improved methods-segmented local mean decomposition(SLMD)and piecewise mirror extension local mean decomposition(PME-LMD)-were employed for spectral denoising.The applicability of different denoising methods was evaluated using a support vector regression(SVR)model.Experimental results show that the peanut moisture content prediction model constructed after PME-LMD denoising achieved the best performance,with a root mean square error(RMSE),coefficient of determination(R^(2)),and mean absolute percentage error(MAPE)of 0.010,0.912,and 0.040,respectively.Compared with traditional methods,PME-LMD significantly improved spectral quality and model prediction performance.The PME-LMD denoising strategy proposed in this study effectively suppresses non-uniform noise interference in THz spectral signals,providing an efficient and accurate preprocessing method for THz spectral analysis of agricultural products.This research provides theoretical support and technical guidance for the application of THz technology for detecting agricultural product quality.展开更多
In this paper,we prove that L(K_(x,y))(λ),theλ-fold line graph of the complete bipartite graph Ka,y,has a C_(6)-decomposition if and only if ry≥6,λxy(c+y-2)=0(mod 12)and(x+y)=0(mod 2),where x,y are nonnegative int...In this paper,we prove that L(K_(x,y))(λ),theλ-fold line graph of the complete bipartite graph Ka,y,has a C_(6)-decomposition if and only if ry≥6,λxy(c+y-2)=0(mod 12)and(x+y)=0(mod 2),where x,y are nonnegative integers and(x,y)≠(2,4)or(2,5).展开更多
The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste g...The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.展开更多
The optical emission spectra(OES)reflect the presence of excited states in the gaseous discharge,which are directly linked to the decomposition characteristics of insulating gases.In this study,a pin/rod-plate dischar...The optical emission spectra(OES)reflect the presence of excited states in the gaseous discharge,which are directly linked to the decomposition characteristics of insulating gases.In this study,a pin/rod-plate discharge reactor driven by either a highvoltage direct current(DC)generator or a pulsed generator was developed to establish an effective platform for generating decomposition products of CF_(3)SO_(2)F and C_(4)F_(7)N.The experimental setup involved separate mixtures of CF_(3)SO_(2)F and C_(4)F_(7)N with different buffer gases(N_(2),CO_(2))under optimised operating conditions(maximum current)with varying mixture ratios.Through systematic investigation of emission spectrum characteristics under different gas mixing ratios,energy transitions of transient species induced by electrical excitation were captured using a high-resolution optical emission spectrometer.Under spark discharge conditions,transient decomposition products such as F-atoms,C-atoms and CN radicals were detected from CF_(3)SO_(2)F and C_(4)F_(7)N mixed with N_(2)or CO_(2),indicating that discharges induced the cleavage of C-S,C-F and C-C bonds,and revealing the decomposition characteristics of the two eco-friendly insulating gases in different buffer atmospheres.This work advances the understanding of decomposition mechanisms,providing valuable insights for fault diagnosis in gas-insulated electrical equipment.展开更多
In recent years,ozone has become one of the key pollutants affecting the urban air qual-ity.Direct catalytic decomposition of ozone emerges as an effective method for ozone re-moval.Field experimentswere conducted to ...In recent years,ozone has become one of the key pollutants affecting the urban air qual-ity.Direct catalytic decomposition of ozone emerges as an effective method for ozone re-moval.Field experimentswere conducted to evaluate the effectiveness of exteriorwall coat-ings with ozone decomposition catalysts for ozone removal in practical applications.ANSYS 2020R1 software was first used for simulation and analysis of ozone concentration and flow fields to investigate the decomposition boundary of these wall coatings.The results show that the exterior wall coatings with manganese-based catalysts can effectively reduce the ozone concentration near the wall coating.The ozone decomposition efficiency is nega-tively correlated with the distance fromthe coating and the decomposition boundary range is around 18 m.The decomposition boundary will increase with the increase of tempera-ture,and decrease with the increase of the wind speed and the relative humidity.These results underscore the viability of using exterior wall coatings with catalysts for controlling ozone pollution in atmospheric environments.This approach presents a promising avenue for addressing ozone pollution through self-purifying materials on building external wall.展开更多
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit...In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.展开更多
基金Supported by Innovative Research Groups of the National Natural Science Foundation of China(22021004)。
文摘Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.
基金sponsored by the Department of Defense,Defense Threat Reduction Agency under the Materials Science in Extreme Environments University Research Alliance,HDTRA1-20-2-0001。
文摘Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.
基金financially supported by the National Natural Science Foundation of China(Nos.52034002 and U2202254)the Fundamental Research Funds for the Central Universities,China(No.FRF-TT-19-001)。
文摘The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.
基金funded by Anhui Province University Key Science and Technology Project(2024AH053415)Anhui Province University Major Science and Technology Project(2024AH040229)+3 种基金Talent Research Initiation Fund Project of Tongling University(2024tlxyrc019)Tongling University School-Level Scientific Research Project(2024tlxyptZD07)TheUniversity Synergy Innovation Programof Anhui Province(GXXT-2023-050)Tongling City Science and Technology Major Special Project(Unveiling and Commanding Model)(200401JB004).
文摘In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).
基金supported by the Universidad del Rosario(Small grant ID:IV-FPD003)。
文摘Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.
文摘Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the configuration of photovoltaic(3.8 MW),wind power(2.5 MW),energy storage(2.2 MWh),and SVC(1.2 Mvar)through interaction between upper and lower layers,and modifies lines 2–3,8–9,etc.to improve transmission capacity and voltage stability.The author uses normal distribution and Monte Carlo method to model load uncertainty,and combines Weibull distribution to describe wind speed characteristics.Compared to the traditional three-layer model(TLM),Benders decomposition-based two-layer model(BLBD)has a 58.1%reduction in convergence time(5.36 vs.12.78 h),a 51.1%reduction in iteration times(23 vs.47 times),a 8.07%reduction in total cost(12.436 vs.13.528 million yuan),and a 9.62%reduction in carbon emissions(12,456 vs.13,782 t).After optimization,the peak valley difference decreased from4.1 to 2.9MW,the renewable energy consumption rate reached 93.4%,and the energy storage efficiency was 87.6%.Themodel has been validated in the IEEE 33 node system,demonstrating its superiority in terms of economy,low-carbon,and reliability.
基金supported by the National Key R&D Program of China (No. 2021YFB3700700)the Henan Province Top Talent Training Program Project, China (No. 244500510020)the High-level Talent Research Start-up Project Funding of Henan Academy of Sciences, China (No. 242017001)。
文摘The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 MPa and an elastic modulus of 145.8 GPa.After aging for 240 min at 500℃,the elastic modulus of the alloy reached 149.5 GPa,which was among the highest values reported for Cu alloys.It was worth mentioning that the tensile strength increased rapidly from 740 to 934 MPa after aging for 5 min at 500℃,which was close to the maximum tensile strength(978 MPa).Analysis of the underlying strengthening mechanisms and phase transformation behavior revealed that the Cu−19Ni−6Cr−7Mn alloy underwent spinodal decomposition and DO_(22) ordering during the first 5 min of aging at 500℃,and L1_(2) ordered phases and bcc-Cr precipitates appeared.Therefore,the enhanced mechanical properties of the Cu−19Ni−6Cr−7Mn alloy can be attributed to the stress field generated by spinodal decomposition and the presence of nanoscale ordered phase and Cr precipitates.
基金funded by the Global PhD Scholarship between KU Leuven and UCLouvain。
文摘Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and diversity on leaf litter decomposition in forests remains understudied.By controlling for macroclimate,soil properties,and litter substrate in a mature common garden,we investigated whether a three-month tea bag incubation of standardized green and rooibos tea substrate is driven by canopy tree species characteristics and diversity.Our study hypothesized two primary pathways:a chemical engineering effect,where trees alter soil properties and decomposer communities through litter input,and a physical engineering effect,where tree canopy structure modulates the local microclimate.The results showed that even under uniform macroclimatic and initial soil conditions,mass loss rates varied widely for green tea(27.4%–73.2%)and rooibos tea(6.1%–34.7%),comparable as found in other research between distinct biomes.While substrate quality was the dominant factor,both engineering pathways and,to a minor extent,tree diversity modulated mass losses.For green tea,tree chemical and physical characteristics seemed equally important,while the physical environment showed an increased importance for rooibos.Incubation depth played a key role,where forest floor decomposition rates are more susceptible to temporal climate variations,and soil-layer decomposition rates are less susceptible to climate variations and more determined by tree species identity.Our findings suggest that tea bag experiments focusing solely on topsoil burial may underestimate processes in the forest floor and the mineralorganic boundary layer.This study underscores the critical role of litter substrate quality in decomposition while demonstrating that tree community composition and the associated herbaceous layer,through both chemical and physical engineering pathways,strongly modulate decomposition rates.
基金funded by the National Natural Science Foundation of China,grant number U24A20135Inner Mongolia Natural Science Foundation major project,grant number 2023ZD12+7 种基金Inner Mongolia Autonomous Region key research and development and achievement transformation plan project,grant number 2023YFHH0090Natural Science Foundation of Inner Mongolia,grant number 2022MS05006Inner Mongolia Autonomous Region Talent Development FundUniversity basic research business expenses,grant number 2023RCTD012University basic research business expenses,grant number 2023QNJS075Postgraduate Research Innovation Program and of Inner Mongolia Autonomous Region,grant number KC2024053BUniversity basic research business expenses,grant number 2024YXXS012National Key Laboratory of Special Vehicle Design and Manufacturing Integration Technology,grant number GZ2023KF012.
文摘In dry-coupled ultrasonic thickness measurement,thick rubber layers introduce high-amplitude parasitic echoes that obscure defect signals and degrade thickness accuracy.Existing methods struggle to resolve overlap-ping echoes under variable coupling conditions and non-stationary noise.This study proposes a novel dual-criterion framework integrating energy contribution and statistical impulsivity metrics to isolate specimen re-flections from coupling-layer interference.By decomposing A-scan signals into Intrinsic Mode Functions(IMFs),the framework employs energy contribution thresholds(>85%)and kurtosis indices(>3)to autonomously select IMFs containing valid specimen echoes.Hybrid time-frequency thresholding further suppresses interference through amplitude filtering and spectral focusing.Experimental results demonstrate the framework’s robustness,achieving 92.3%thickness accuracy for 5 mm steel specimens with 5 mm rubber coupling,outperforming conventional methods by up to 18.7%.The dual-criterion approach reduces operator dependency by 37%and maintainsΔT<0.03 mm under surface roughness up to 6.3μm,offering a practical solution for industrial nondestructive testing with thick dry-coupled interfaces.
基金supported by Ningbo Natural Science Foundation(No.2023J059)Ningbo Commonweal Programme Key Project(No.2023S038)Guangxi Key Research and Development Programme(No.GuikeAB21220063).
文摘Machine-learning is a robust technique for understanding pollution characteristics of surface ozone,which are at high levels in urban China.This study introduced an innovative approach combining trend decomposition with Random Forest algorithm to investigate ozone dynamics and formation regimes in a coastal area of China.During the period of 2017–2022,significant inter-annual fluctuations emerged,with peaks in mid-2017 attributed to volatile organic compounds(VOCs),and in late-2019 influenced by air temperature.Multifaceted periodicities(daily,weekly,holiday,and yearly)in ozone were revealed,elucidating substantial influences of daily and yearly components on ozone periodicity.A VOC-sensitive ozone formation regime was identified,characterized by lower VOCs/NO_(x) ratios(average=0.88)and significant positive correlations between ozone and VOCs.This interplay manifested in elevated ozone duringweekends,holidays,and pandemic lockdowns.Key variables influencing ozone across diverse timescaleswere uncovered,with solar radiation and temperature driving daily and yearly ozone variations,respectively.Precursor substances,particularly VOCs,significantly shaped weekly/holiday patterns and long-term trends of ozone.Specifically,acetone,ethane,hexanal,and toluene had a notable impact on the multi-year ozone trend,emphasizing the urgency of VOC regulation.Furthermore,our observations indicated that NO_(x) primarily drived the stochastic variations in ozone,a distinguishing characteristic of regions with heavy traffic.This research provides novel insights into ozone dynamics in coastal urban areas and highlights the importance of integrating statistical and machinelearning methods in atmospheric pollution studies,with implications for targeted mitigation strategies beyond this specific region and pollutant.
基金supported by the National Natural Science Foundation of China (Nos. 22379121, 62005216)Basic Public Welfare Research Program of Zhejiang (No. LQ22F050013)+1 种基金Zhejiang Province Key Laboratory of Flexible Electronics Open Fund (2023FE005)Shenzhen Foundation Research Program (No. JCYJ20220530112812028)。
文摘Fluoride-based electrolyte exhibits extraordinarily high oxidative stability in high-voltage lithium metal batteries(h-LMBs) due to the inherent low highest occupied molecular orbital(HOMO) of fiuorinated solvents. However, such fascinating properties do not bring long-term cyclability of h-LMBs. One of critical challenges is the interface instability in contacting with the Li metal anode, as fiuorinated solvents are highly susceptible to exceptionally reductive metallic Li attributed to its low lowest unoccupied molecular orbital(LUMO), which leads to significant consumption of the fiuorinated components upon cycling.Herein, attenuating reductive decomposition of fiuorinated electrolytes is proposed to circumvent rapid electrolyte consumption. Specifically, the vinylene carbonate(VC) is selected to tame the reduction decomposition by preferentially forming protective layer on the Li anode. This work, experimentally and computationally, demonstrates the importance of pre-passivation of Li metal anodes at high voltage to attenuate the decomposition of fiuoroethylene carbonate(FEC). It is expected to enrich the understanding of how VC attenuate the reactivity of FEC, thereby extending the cycle life of fiuorinated electrolytes in high-voltage Li-metal batteries.
基金supported by National Natural Science Foundation of China under Grant U23A20279China Electronics Tian’ao Innovation Theory and Technology Group Fund under Grand 20221193-04-04.
文摘To overcome the challenges of poor real-time performance,limited scalability,and low intelligence in conventional jamming pattern recognition methods,this paper proposes a method based on Wavelet Packet Decomposition(WPD)and enhanced deep learning techniques.In the proposed method,an agent at the receiver processes the received signal using WPD to generate an initial Spectrogram Waterfall(SW),which is subsequently segmented using a sliding window to serve as the input for the jamming recognition network.The network employs a bilateral filter to preprocess the input SW,thereby enhancing the edge features of the jamming signals.To extract abstract features,depthwise separable convolution is utilized instead of traditional convolution,thereby reducing the network’s parameter count and enhancing real-time performance.A pyramid pooling layer is integrated before the fully connected layer to enable the network to process input SW of varying sizes,thus enhancing scalability.During network training,adaptive moment estimation is employed as the optimizer,allowing the network to dynamically adjust the learning rate and accelerate convergence.A comprehensive comparison between the proposed jamming recognition network and six other models is conducted,along with Ablation Experiments(AE)based on numerical simulations.Simulation results demonstrate that the proposed method based on WPD and enhanced deep learning achieves high-precision recognition of various jamming patterns while maintaining a favorable balance among prediction accuracy,network complexity,and prediction time.
基金supported in part by the Interdisciplinary Project of Dalian University(DLUXK-2023-ZD-001).
文摘Multivariate time series forecasting iswidely used in traffic planning,weather forecasting,and energy consumption.Series decomposition algorithms can help models better understand the underlying patterns of the original series to improve the forecasting accuracy of multivariate time series.However,the decomposition kernel of previous decomposition-based models is fixed,and these models have not considered the differences in frequency fluctuations between components.These problems make it difficult to analyze the intricate temporal variations of real-world time series.In this paper,we propose a series decomposition-based Mamba model,DecMamba,to obtain the intricate temporal dependencies and the dependencies among different variables of multivariate time series.A variable-level adaptive kernel combination search module is designed to interact with information on different trends and periods between variables.Two backbone structures are proposed to emphasize the differences in frequency fluctuations of seasonal and trend components.Mamba with superior performance is used instead of a Transformer in backbone structures to capture the dependencies among different variables.A new embedding block is designed to capture the temporal features better,especially for the high-frequency seasonal component whose semantic information is difficult to acquire.A gating mechanism is introduced to the decoder in the seasonal backbone to improve the prediction accuracy.A comparison with ten state-of-the-art models on seven real-world datasets demonstrates that DecMamba can better model the temporal dependencies and the dependencies among different variables,guaranteeing better prediction performance for multivariate time series.
基金supported by National Natural Science Foundations of China(nos.12271326,62102304,61806120,61502290,61672334,61673251)China Postdoctoral Science Foundation(no.2015M582606)+2 种基金Industrial Research Project of Science and Technology in Shaanxi Province(nos.2015GY016,2017JQ6063)Fundamental Research Fund for the Central Universities(no.GK202003071)Natural Science Basic Research Plan in Shaanxi Province of China(no.2022JM-354).
文摘The multi-objective particle swarm optimization algorithm(MOPSO)is widely used to solve multi-objective optimization problems.In the article,amulti-objective particle swarm optimization algorithmbased on decomposition and multi-selection strategy is proposed to improve the search efficiency.First,two update strategies based on decomposition are used to update the evolving population and external archive,respectively.Second,a multiselection strategy is designed.The first strategy is for the subspace without a non-dominated solution.Among the neighbor particles,the particle with the smallest penalty-based boundary intersection value is selected as the global optimal solution and the particle far away fromthe search particle and the global optimal solution is selected as the personal optimal solution to enhance global search.The second strategy is for the subspace with a non-dominated solution.In the neighbor particles,two particles are randomly selected,one as the global optimal solution and the other as the personal optimal solution,to enhance local search.The third strategy is for Pareto optimal front(PF)discontinuity,which is identified by the cumulative number of iterations of the subspace without non-dominated solutions.In the subsequent iteration,a new probability distribution is used to select from the remaining subspaces to search.Third,an adaptive inertia weight update strategy based on the dominated degree is designed to further improve the search efficiency.Finally,the proposed algorithmis compared with fivemulti-objective particle swarm optimization algorithms and five multi-objective evolutionary algorithms on 22 test problems.The results show that the proposed algorithm has better performance.
基金Supported by the National Key R&D Program of China(2023YFD2101001)National Natural Science Foundation of China(32202144,61807001)。
文摘To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explores the feasibility of adaptive-signal-decomposition-based denoising methods to improve THz spectral quality.THz time-domain spectroscopy(THz-TDS)combined with an attenuated total reflection(ATR)accessory was used to collect THz absorbance spectra from 48 peanut samples.Taking the quantitative prediction model of peanut moisture content based on THz-ATR as an example,wavelet transform(WT),empirical mode decomposition(EMD),local mean decomposition(LMD),and its improved methods-segmented local mean decomposition(SLMD)and piecewise mirror extension local mean decomposition(PME-LMD)-were employed for spectral denoising.The applicability of different denoising methods was evaluated using a support vector regression(SVR)model.Experimental results show that the peanut moisture content prediction model constructed after PME-LMD denoising achieved the best performance,with a root mean square error(RMSE),coefficient of determination(R^(2)),and mean absolute percentage error(MAPE)of 0.010,0.912,and 0.040,respectively.Compared with traditional methods,PME-LMD significantly improved spectral quality and model prediction performance.The PME-LMD denoising strategy proposed in this study effectively suppresses non-uniform noise interference in THz spectral signals,providing an efficient and accurate preprocessing method for THz spectral analysis of agricultural products.This research provides theoretical support and technical guidance for the application of THz technology for detecting agricultural product quality.
文摘In this paper,we prove that L(K_(x,y))(λ),theλ-fold line graph of the complete bipartite graph Ka,y,has a C_(6)-decomposition if and only if ry≥6,λxy(c+y-2)=0(mod 12)and(x+y)=0(mod 2),where x,y are nonnegative integers and(x,y)≠(2,4)or(2,5).
基金supported by the National Natural Science Foundation of China(22178295,21706225)Natural Science Foundation of Hunan Province(2025JJ50085)Hunan Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization.
文摘The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.
基金supported by National Key Research and Development Programme of China,Grant/Award Number:2021YFB2401400.
文摘The optical emission spectra(OES)reflect the presence of excited states in the gaseous discharge,which are directly linked to the decomposition characteristics of insulating gases.In this study,a pin/rod-plate discharge reactor driven by either a highvoltage direct current(DC)generator or a pulsed generator was developed to establish an effective platform for generating decomposition products of CF_(3)SO_(2)F and C_(4)F_(7)N.The experimental setup involved separate mixtures of CF_(3)SO_(2)F and C_(4)F_(7)N with different buffer gases(N_(2),CO_(2))under optimised operating conditions(maximum current)with varying mixture ratios.Through systematic investigation of emission spectrum characteristics under different gas mixing ratios,energy transitions of transient species induced by electrical excitation were captured using a high-resolution optical emission spectrometer.Under spark discharge conditions,transient decomposition products such as F-atoms,C-atoms and CN radicals were detected from CF_(3)SO_(2)F and C_(4)F_(7)N mixed with N_(2)or CO_(2),indicating that discharges induced the cleavage of C-S,C-F and C-C bonds,and revealing the decomposition characteristics of the two eco-friendly insulating gases in different buffer atmospheres.This work advances the understanding of decomposition mechanisms,providing valuable insights for fault diagnosis in gas-insulated electrical equipment.
基金supported by the National Natural Science Foundation of China(Nos.52470114 and 52022104)the National Key R&D Program of China(No.2022YFC3702802)the Youth Innovation Promotion Association,CAS(No.Y2021020).
文摘In recent years,ozone has become one of the key pollutants affecting the urban air qual-ity.Direct catalytic decomposition of ozone emerges as an effective method for ozone re-moval.Field experimentswere conducted to evaluate the effectiveness of exteriorwall coat-ings with ozone decomposition catalysts for ozone removal in practical applications.ANSYS 2020R1 software was first used for simulation and analysis of ozone concentration and flow fields to investigate the decomposition boundary of these wall coatings.The results show that the exterior wall coatings with manganese-based catalysts can effectively reduce the ozone concentration near the wall coating.The ozone decomposition efficiency is nega-tively correlated with the distance fromthe coating and the decomposition boundary range is around 18 m.The decomposition boundary will increase with the increase of tempera-ture,and decrease with the increase of the wind speed and the relative humidity.These results underscore the viability of using exterior wall coatings with catalysts for controlling ozone pollution in atmospheric environments.This approach presents a promising avenue for addressing ozone pollution through self-purifying materials on building external wall.
基金sponsored by the National Natural Science Foundations of China under Grant Nos.12301315,12235007,11975131the Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ20A010009。
文摘In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.
