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Geometrical Langlands Ramifications and Differential Operators Classification by Coherent D-Modules in Field Theory 被引量:2
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作者 Francisco Bulnes 《Journal of Mathematics and System Science》 2013年第10期491-507,共17页
Spaces of equivalence modulo a relation of congruence are constructed on field solutions to establish a theory of the universe that includes the theory QFT (Quantum Field theory), the SUSY (Super-symmetry theory) ... Spaces of equivalence modulo a relation of congruence are constructed on field solutions to establish a theory of the universe that includes the theory QFT (Quantum Field theory), the SUSY (Super-symmetry theory) and HST (heterotic string theory) using the sheaves correspondence of differential operators of the field equations and sheaves of coherent D - Modules [1]. The above mentioned correspondence use a Zuckerman functor that is a factor of the universal functor of derived sheaves of Harish-Chandra to the Langlands geometrical program in mirror symmetry [2, 3]. The obtained development includes complexes of D - modules of infinite dimension, generalizing for this way, the BRST-cohomology in this context. With it, the class of the integrable systems is extended in mathematical physics and the possibility of obtaining a general theory of integral transforms for the space - time (integral operator cohomology [4]), and with it the measurement of many of their observables [5]. Also tends a bridge to complete a classification of the differential operators for the different field equations using on the base of Verma modules that are classification spaces of SO(l, n + 1), where elements of the Lie algebra al(1, n + 1), are differential operators, of the equations in mathematical physics [1]. The cosmological problem that exists is to reduce the number of field equations that are resoluble under the same gauge field (Verma modules) and to extend the gauge solutions to other fields using the topological groups symmetries that define their interactions. This extension can be given by a global Langlands correspondence between the Hecke sheaves category on an adequate moduli stack and the holomorphic L G - bundles category with a special connection (Deligne connection). The corresponding D - modules may be viewed as sheaves of conformal blocks (or co-invariants) (images under a version of the Penrose transform [1, 6]) naturally arising in the framework of conformal field theory. 展开更多
关键词 Langlands correspondence Hecke sheaves category moduli stacks Verma modules generalized d-modules Vermamodule extensions
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Quickly obtaining densely dispersed coherent particles in steel matrix and its related mechanical property
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作者 Xiaoxiao Wang Qingsong Huang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期111-118,共8页
Densely distributed coherent nanoparticles(DCN)in steel matrix can enhance the work-hardening ability and ductility of steel simultaneously.All the routes to this end can be generally classified into the liquid-solid ... Densely distributed coherent nanoparticles(DCN)in steel matrix can enhance the work-hardening ability and ductility of steel simultaneously.All the routes to this end can be generally classified into the liquid-solid route and the solid-solid route.However,the formation of DCN structures in steel requires long processes and complex steps.So far,obtaining steel with coherent particle enhancement in a short time remains a bottleneck,and some necessary steps remain unavoidable.Here,we show a high-efficiency liquid-phase refining process reinforced by a dynamic magnetic field.Ti-Y-Mn-O particles had an average size of around(3.53±1.21)nm and can be obtained in just around 180 s.These small nanoparticles were coherent with the matrix,implying no accumulated dislocations between the particles and the steel matrix.Our findings have a potential application for improving material machining capacity,creep resistance,and radiation resistance. 展开更多
关键词 ferritic steels coherent particles MICROSTRUCTURE compression test work hardening
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Spatial correlation singularities and orbital angular momentum spectra of partially coherent beams with noncanonical vortex pairs
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作者 MEI Chao CHENG Ke +2 位作者 YI Xiao-wen FU Cai-ying ZENG Ti-xian 《中国光学(中英文)》 北大核心 2025年第5期1243-1254,共12页
By introducing noncanonical vortex pairs to partially coherent beams, spatial correlation singularity (SCS) and orbital angular momenta (OAM) of the resulting beams are studied using the Fraunhofer diffraction integra... By introducing noncanonical vortex pairs to partially coherent beams, spatial correlation singularity (SCS) and orbital angular momenta (OAM) of the resulting beams are studied using the Fraunhofer diffraction integral. The effect of noncanonical strength, off-axis distance and vortex sign on spatial correlation singularities in far field is stressed. Furthermore, far-field OAM spectra and densities are also investigated, and the OAM detection and crosstalk probabilities are discussed. The results show that the number of dislocations of SCS always equals the sum of absolute values of topological charges for canonical or noncanonical vortex pairs. Although the sum of the product of each OAM mode and its power weight equals the algebraic sum of topological charges for canonical vortex pairs, the relationship no longer holds in the noncanonical case except for opposite-charge vortex pairs. The changes of off-axis distance, noncanonical strength or coherence length can lead to a more dominant power in adjacent mode than that in center detection mode, which also indicates that crosstalk probabilities of adjacent modes exceed the center detection probability. This work may provide potential applications in OAM-based optical communication, imaging, sensing and computing. 展开更多
关键词 spatial correlation singularity orbital angular momentum noncanonical vortex partially coherent beam
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Earthquake as a Coherent Electromagnetic Emitter. Its Electromagnetic Voice May or May Not Sound
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作者 Anatoly L. Buchachenko 《Open Journal of Earthquake Research》 2025年第1期28-34,共7页
The idea of the earthquake (EQ) focus as a coherent electromagnetic (EM) emitter is suggested. This idea elucidates enigmatic properties of the EM voice of the focus: its emission is not continuous, occurring periodic... The idea of the earthquake (EQ) focus as a coherent electromagnetic (EM) emitter is suggested. This idea elucidates enigmatic properties of the EM voice of the focus: its emission is not continuous, occurring periodically in flashes, which are structured as the pulses occurring in bursts;the EM activity increases starting approximately two weeks before the EQ and becomes very weak or completely disappears one day before the EQ (gap of silence). The mechanism of coherency starts with electric discharges of any mini-cracks as a mini-capacitor, which generates EM waves;the latter induces discharges of other cracks, multiplying the amplitude of the wave and creating the pulse of seismic EM signal. It is an avalanche-like mechanism of coherency, which transforms even weak EM signals into intensive EM seismic flashes. 展开更多
关键词 EARTHQUAKE Electromagnetic Signal Mini-Cracks Discharges coherENCY Seismic Flashes Gap of Silence
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Analogous optical coherent state sourced by a partially coherent beam
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作者 Jinqi Song Fengqi Liu +9 位作者 Mingli Sun Bingsong Cao Zhifang Qiu Naichen Zhang Xiangyu Tong Wenzhe Wang Yuanxing Liu Kaikai Huang Xian Zhang Xuanhui Lu 《Advanced Photonics Nexus》 2025年第4期89-95,共7页
Based on the first-order correlation function of light,we propose analogous optical coherent states(AOCSs)sourced by partially coherent beams,which can nondiffractively propagate with sinusoidal oscillation in the har... Based on the first-order correlation function of light,we propose analogous optical coherent states(AOCSs)sourced by partially coherent beams,which can nondiffractively propagate with sinusoidal oscillation in the harmonic potential when the nondiffraction propagation matching condition(NPMC)is met.Unlike the traditional quantum coherent state,the minimum uncertainty of AOCS is related to the coherence of light,and only when the NPMC is met,its uncertainty is the least.Furthermore,based on the mathematical similarity between the Schrödinger and the Helmholtz equations,we find that our proposed AOCSs correspond to the partially coherent steady states of the harmonic oscillator.Our research not only increases the understanding of the coherence of light and enriches the types of nondiffraction beams but also increases the understanding of the quantum coherence regulating the evolution of probability waves. 展开更多
关键词 partially coherent beam NONDIFFRACTION coherent state harmonic potential
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Achieving Ultralong Spin Coherent Time of Single Nitrogen Vacancy Centers in Diamond
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作者 Xiaoran Zhang Xinyu Zhuang Xiaobing Liu 《Chinese Physics Letters》 2025年第4期177-187,共11页
Single negatively charged nitrogen vacancy(NV-)centers in diamond have emerged as promising platforms for quantum information science,where long coherence times are essential for advancing quantum technologies.However... Single negatively charged nitrogen vacancy(NV-)centers in diamond have emerged as promising platforms for quantum information science,where long coherence times are essential for advancing quantum technologies.However,traditional fabrication methods often introduce lattice damage during the irradiation process used to create vacancies,significantly impairing the spin coherence properties of NV-centers. 展开更多
关键词 lattice damage nitrogen vacancy centers DIAMOND irradiation process ultralong spin coherent time fabrication methods spin coherence properties quantum information sciencewhere
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Coherent feedback ground-state cooling of mechanical resonators assisted by a quantum well
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作者 Qinghong Liao Songyun Ouyang +1 位作者 Shaoping Cheng Yiping Cheng 《Chinese Physics B》 2025年第4期405-411,共7页
We theoretically investigate a cooling scheme assisted by a quantum well(QW)and coherent feedback within a hybrid optomechanical system.Although the exciton mode in the QW and the mechanical resonator(MR)are initially... We theoretically investigate a cooling scheme assisted by a quantum well(QW)and coherent feedback within a hybrid optomechanical system.Although the exciton mode in the QW and the mechanical resonator(MR)are initially uncoupled,their interaction via the microcavity field leads to an indirect exciton-mode–mechanical-mode coupling.The coherent feedback loop is applied by feeding back a fraction of the output field of the cavity through a controllable beam splitter to the cavity’s input mirror.It is shown that the cooling capability is enhanced by effectively suppressing the Stokes process through coupling with the QW.Furthermore,the effect of the anti-Stokes process is enhanced through the application of the coherent feedback loop.This particular system configuration enables cooling of the mechanical resonator even in the unresolved sideband regime(USR).This study has some important guiding significance in the field of quantum information processing. 展开更多
关键词 ground-state cooling quantum well coherent feedback optomechanical system
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Some results on A-coherent rings
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作者 ZHUO Yuanfan GU Qinqin 《纯粹数学与应用数学》 2025年第4期647-656,共10页
In this paper,we introduce a new generalization of coherent rings using the Auslander class.A ring R is called an A-coherent ring in case every nitely generated submodule of a free R-module in AC(R)is nitely presented... In this paper,we introduce a new generalization of coherent rings using the Auslander class.A ring R is called an A-coherent ring in case every nitely generated submodule of a free R-module in AC(R)is nitely presented,where C is a semidualizing module.Firstly,A-injective and A-at modules are introduced and their properties are studied.Further,we characterize A-coherent rings in various ways,using A-injective,A-at modules,and cotorsion theories. 展开更多
关键词 Auslander class coherent cotorsion theory
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Coherent states associated with integral multi-index Mittag-Leffler functions
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作者 Dušan Popov 《Chinese Physics B》 2025年第6期234-249,共16页
The purpose of this paper is to show that by using a certain type of discrete-continuous limit, a series of integral entities can be defined(Mittag-Leffler multi-index functions, associated coherent states and their p... The purpose of this paper is to show that by using a certain type of discrete-continuous limit, a series of integral entities can be defined(Mittag-Leffler multi-index functions, associated coherent states and their properties), which are counterparts of the corresponding discrete entities. We built and examine the properties of a new aspect of generalized integral multi-index Mittag-Leffler functions and we constructed and examined the properties of coherent states associated with this new function. This approach is motivated through the fact that these functions can be connected with the coherent states of the continuous spectrum, as well as with so-called nu-function. 展开更多
关键词 Mittag-Leffler coherent states density operator continuous spectrum
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Coherence CLEAN-SC(C-CLEAN-SC) phased array processing for coherent sound source localization
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作者 Ce ZHANG Wei MA 《Chinese Journal of Aeronautics》 2025年第7期140-146,共7页
Deconvolution methods are commonly used to improve the performance of phased array beamforming for sound source localization. However, for coherent sources localization, existing deconvolution methods are either highl... Deconvolution methods are commonly used to improve the performance of phased array beamforming for sound source localization. However, for coherent sources localization, existing deconvolution methods are either highly computationally demanding or sensitive to parameters.A deconvolution method, based on modifications of Clean based on Source Coherence(CLEAN-SC), is proposed for coherent sources localization. This method is called Coherence CLEAN-SC(C–CLEAN-SC). C–CLEAN-SC is able to locate coherent and incoherent sources in simulation and experimental cases. It has a high computational efficiency and does not require pre-set parameters. 展开更多
关键词 coherent source localization Phased array BEAMFORMING CLEAN-SC DECONVOLUTION
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Measurement and Characterization of Micro Corner-Cube Reflectors Array Using Coherent Denoising Interference and Physical Model-Based Neural Network
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作者 Xinlan Tang Lingbao Kong +4 位作者 Zhenzhen Ding Yuhan Wang Bo Wang Huixin Song Yanwen Shen 《Chinese Journal of Mechanical Engineering》 2025年第3期61-76,共16页
In modern industrial design trends featuring with integration,miniaturization,and versatility,there is a growing demand on the utilization of microstructural array devices.The measurement of such microstructural array... In modern industrial design trends featuring with integration,miniaturization,and versatility,there is a growing demand on the utilization of microstructural array devices.The measurement of such microstructural array components often encounters challenges due to the reduced scale and complex structures,either by contact or noncontact optical approaches.Among these microstructural arrays,there are still no optical measurement methods for micro corner-cube reflector arrays.To solve this problem,this study introduces a method for effectively eliminating coherent noise and achieving surface profile reconstruction in interference measurements of microstructural arrays.The proposed denoising method allows the calibration and inverse solving of system errors in the frequency domain by employing standard components with known surface types.This enables the effective compensation of the complex amplitude of non-sample coherent light within the interferometer optical path.The proposed surface reconstruction method enables the profile calculation within the situation that there is complex multi-reflection during the propagation of rays in microstructural arrays.Based on the measurement results,two novel metrics are defined to estimate diffraction errors at array junctions and comprehensive errors across multiple array elements,offering insights into other types of microstructure devices.This research not only addresses challenges of the coherent noise and multi-reflection,but also makes a breakthrough for quantitively optical interference measurement of microstructural array devices. 展开更多
关键词 Microstructural arrays measurement Optical measurement coherent denoising Neural network Multi-reflection
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Diagnosis of focal spots at relativistic intensity utilizing coherent radiation from laser-driven flying electron sheets
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作者 Shirui Xu Zhuo Pan +22 位作者 Ying Gao Jiarui Zhao Shiyou Chen Zhusong Mei Xun Chen Ziyang Peng Xuan Liu Yulan Liang Tianqi Xu Tan Song Qingfan Wu Yujia Zhang Zhipeng Liu Zihao Zhang Haoran Chen Qihang Han Jundong Shen Chenghao Hua Kun Zhu Yanying Zhao Chen Lin Xueqing Yan Wenjun Ma 《Matter and Radiation at Extremes》 2025年第2期16-23,共8页
Experimental validation of laser intensity is particularly important for the study of fundamental physics at extremely high intensities.However,reliable diagnosis of the focal spot and peak intensity faces huge challe... Experimental validation of laser intensity is particularly important for the study of fundamental physics at extremely high intensities.However,reliable diagnosis of the focal spot and peak intensity faces huge challenges.In this work,we demonstrate for the firs time that the coherent radiation farfiel patterns from laser–foil interactions can serve as an in situ,real-time,and easy-to-implement diagnostic for an ultraintense laser focus.The laser-driven electron sheets,curved by the spatially varying laser fiel and leaving the targets at nearly the speed of light,produce doughnut-shaped patterns depending on the shapes of the focal spot and the absolute laser intensities.Assisted by particle-in-cell simulations,we can achieve measurements of the intensity and the focal spot,and provide immediate feedback to optimize the focal spots for extremely high intensity. 展开更多
关键词 diagnosis focal spot peak intensity laser foil interactions laser fi coherent radiation farfiel patterns laser driven electron sheets experimental validation laser intensity focal spot coherent radiation
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Quantum-enhanced interferometry with unbalanced entangled coherent states
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作者 Jun Tang Zi-Hang Du +2 位作者 Wei Zhong Lan Zhou Yu-Bo Sheng 《Chinese Physics B》 2025年第2期54-62,共9页
We propose a quantum-enhanced metrological scheme utilizing unbalanced entangled coherent states(ECSs) generated by passing a coherent state and a coherent state superposition through an unbalanced beam splitter(BS). ... We propose a quantum-enhanced metrological scheme utilizing unbalanced entangled coherent states(ECSs) generated by passing a coherent state and a coherent state superposition through an unbalanced beam splitter(BS). We identify the optimal phase sensitivity of this scheme by maximizing the quantum Fisher information(QFI) with respect to the BS transmission ratio. Our scheme outperforms the conventional scheme with a balanced BS, particularly in the presence of single-mode photon loss. Notably, our scheme retains quantum advantage in phase sensitivity in the limit of high photon intensity, where the balanced scheme offers no advantage over the classical strategy. 展开更多
关键词 quantum-enhanced interferometry entangled coherent state quantum Fisher information
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A coherent generator group identification algorithm under extreme conditions
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作者 Yizhe Zhu Yulin Chen +3 位作者 Li Li Donglian Qi Jinhua Huang Xudong Song 《Global Energy Interconnection》 2025年第1期92-105,共14页
With the rapid development of large-scale regional interconnected power grids,the risk of cascading failures under extreme condi-tions,such as natural disasters and military strikes,has increased significantly.To enha... With the rapid development of large-scale regional interconnected power grids,the risk of cascading failures under extreme condi-tions,such as natural disasters and military strikes,has increased significantly.To enhance the response capability of power systems to extreme events,this study focuses on a method for generator coherency detection.To overcome the shortcomings of the traditional slow coherency method,this paper introduces a novel coherent group identification algorithm based on the theory of nonlinear dynam-ical systems.By analyzing the changing trend of the Euclidean norm of the state variable derivatives in the reduced system,the algorithm can accurately identify the magnitude of the disturbances.Based on the slow coherency methods,the algorithm can correctly recognize coherent generator groups by analyzing system characteristics under varying disturbance magnitudes.This improvement enhances the applicability and accuracy of the coherency detection algorithm under extreme conditions,providing support for emergency control and protection in the power system.Simulations and comparison analyses on IEEE 39-bus system are conducted to validate the accuracy and superiority of the proposed coherent generator group identification method under extreme conditions. 展开更多
关键词 Generator grouping Slow coherency method Nonlinear dynamical system BCU method Energy function
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Partially coherent optical chip enables physical-layer public-key encryption
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作者 Bo Wu Wenkai Zhang +3 位作者 Hailong Zhou Jianji Dong Yilun Wang Xinliang Zhang 《Opto-Electronic Advances》 2025年第11期21-30,共10页
Public-key encryption is essential for secure communications,eliminating the need for pre-shared keys.However,traditional schemes such as RSA(Rivest-Shamir-Adleman)and elliptic curve cryptography rely on computational... Public-key encryption is essential for secure communications,eliminating the need for pre-shared keys.However,traditional schemes such as RSA(Rivest-Shamir-Adleman)and elliptic curve cryptography rely on computational complexity,making them increasingly susceptible to advances in computing power and algorithms.Physical-layer encryption,which leverages the intrinsic properties of physical systems,offers a promising alternative with security rooted in physics.Despite progress in this field,public-key encryption at the optical layer remains largely unexplored.Here,we propose a novel optical public-key encryption scheme based on partially coherent light sources.The cryptographic keys are encoded in the incoherent optical transmission matrix of an on-chip Mach-Zehnder interferometer mesh,providing high complexity and resilience to computational attacks.We experimentally demonstrate encrypted image transmission over 40 km of optical fiber with high decryption fidelity and achieve a 10 Gbit/s optical encryption rate using a lithium niobate photonic chip.This represents the first implementation of public-key encryption at the physical optical layer.The approach offers key advantages in security,cost,energy efficiency,and compatibility with commercial optical communication systems.By integrating public-key encryption into photonic hardware,this work opens a new direction for secure and high-speed optical communications in next-generation networks. 展开更多
关键词 public key encryption partially coherent source optical incoherent matrix
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GHZ state,spin squeezed state,and spin coherent state for frequency estimation under general Gaussian noises
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作者 Qi Chai Wen Yang 《Communications in Theoretical Physics》 2025年第6期102-111,共10页
Exploring the quantum advantages of various non-classical quantum states in noisy environments is a central subject in quantum sensing.Here we provide a complete picture for the frequency estimation precision of three... Exploring the quantum advantages of various non-classical quantum states in noisy environments is a central subject in quantum sensing.Here we provide a complete picture for the frequency estimation precision of three important states(the Greenberger-Horne-Zeilinger(GHZ)state,the maximal spin squeezed state,and the spin coherent state)of a spin-S under both individual dephasing and collective dephasing by general Gaussian noise,ranging from the Markovian limit to the extreme non-Markovian limit.Whether or not the noise is Markovian,the spin coherent state is always worse than the classical scheme under collective dephasing although it is equivalent to the classical scheme under individual dephasing.Moreover,the maximal spin squeezed state always give the best sensing precision(and outperforms the widely studied GHZ state)in all cases.This establishes the general advantage of the spin squeezed state for noisy frequency estimation in many quantum sensing platforms. 展开更多
关键词 cat state spin squeezed state spin coherent state quantum sensing
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Enhancement of four-wave mixing due to coherent hole burning in a degenerate two-level system
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作者 Zhi-Yuan Liu Yi-Fan Yao +2 位作者 Yue Sun Jia-Yu Han Ying-Jie Du 《Chinese Physics B》 2025年第5期406-413,共8页
We present a theoretical study of four-wave mixing(FWM)in a degenerate two-level atomic system subject to a magnetic field whose Zeeman sublevels constitute a tripod-type atomic system,which is driven by a linearly po... We present a theoretical study of four-wave mixing(FWM)in a degenerate two-level atomic system subject to a magnetic field whose Zeeman sublevels constitute a tripod-type atomic system,which is driven by a linearly polarized field,and coupled and probed by two sets of left and right circularly polarized fields.The optical effects of coherent hole burning(CHB)and electromagnetically induced transparency(EIT)are involved in the coherent system,among which the CHB has much larger response for the FWM than the EITs.Three situations of CHB are involved,and they are the solitary CHB,overlapped CHBs,and an overlap between CHB and EIT.The overlapped CHBs have the greatest magnitude of FWM signal among the three situations.Whereas,for the overlapped CHB and EIT,it has the smallest FWM magnitude,which is no more than one tenth of the former.While for the single CHB,the FWM magnitude is half of that of the overlapped CHBs.It is noted that,in the overlap between CHB and EIT,dual EIAs can be obtained,whose FWM signal also has an enhancement in comparison to no EIA. 展开更多
关键词 four-wave mixing coherent hole burning electromagnetically induced transparency electromagnetically induced absorption
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Super-resolving refractive index measurements with even coherent-state sources and parity detection
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作者 Qiang Wang Xiaohao Yang +1 位作者 Fu Song Lili Hao 《Chinese Physics B》 2025年第12期260-267,共8页
High-precision refractive index measurement has become a research hotspot in recent years.However,traditional refractive index measurement often adopts intensity detection,whose performance is restricted by the classi... High-precision refractive index measurement has become a research hotspot in recent years.However,traditional refractive index measurement often adopts intensity detection,whose performance is restricted by the classical detection limit and is thus hard to improve further.In order to break through this limitation,we propose a quantum-enhanced refractive index sensing scheme utilizing even-coherent-state sources in combination with parity detection.In this paper,we analyze the detection performance of the proposed system.Due to the inevitable photon loss in practical applications,the effects of photon loss on resolution and sensitivity are also investigated.Numerical results show that the resolution of the proposed strategy breaks through the Rayleigh limit and achieves super-resolving refractive index measurement.Relative to existing coherent-state schemes,our strategy leads to a twofold resolution improvement.Furthermore,the physical origins of the super-resolution are analyzed. 展开更多
关键词 refractive index measurement even coherent state parity photon counting DETECTION SUPER-RESOLUTION
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Coherent Compton scattering using a stretched off-axis paraboloid
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作者 Kai Zhao Chang-Bo Fu +1 位作者 Xiang-Jin Kong Yu-Gang Ma 《Nuclear Science and Techniques》 2025年第8期270-277,共8页
Extreme ultraviolet(EUV)lithography is crucial for advancing semiconductor manufacturing;however,current EUV light sources,such as laser-produced plasma(LPP),have significant limitations,including low energy-conversio... Extreme ultraviolet(EUV)lithography is crucial for advancing semiconductor manufacturing;however,current EUV light sources,such as laser-produced plasma(LPP),have significant limitations,including low energy-conversion efficiency and debris contamination.Various schemes,including optical free-electron laser undulators,have been studied to generate coherent EUV light.However,optical undulators suffer from limited focal lengths,which pose a significant challenge to achieving a higher gain.In this study,a novel approach is proposed that employs a stretched off-axis paraboloid(sOAP)mirror,thus extending the focus distance to the centimeter range while achieving a well-controlled periodic light field.This enables high-intensity 92-eV EUV sources to exceed 1016/s,as demonstrated in the simulations.The proposed setup provides an efficient and powerful solution for advanced applications including semiconductor lithography. 展开更多
关键词 Laser Compton scattering(LCS) coherent scattering Free-electron laser(FEL)
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Enhanced photocatalytic CO_(2) reduction of Bi_(2)WO_(6)-BiOCl heterostructure with coherent interface for charge utilization
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作者 Hui Li Chunlang Gao +6 位作者 Guo Yang Lu Xia Wulyu Jiang Cheng Wu Kaiwen Wang Yingtang Zhou Xiaodong Han 《Chinese Chemical Letters》 2025年第9期517-523,共7页
The photocatalytic reduction of CO_(2)presents a promising avenue for carbon fuel conversion.However,the efficiency of charge utilization remains a critical barrier to industrial applications.In this study,we introduc... The photocatalytic reduction of CO_(2)presents a promising avenue for carbon fuel conversion.However,the efficiency of charge utilization remains a critical barrier to industrial applications.In this study,we introduce a tandem design of Bi_(2)WO_(6)-BiOCl with an atomically matched interface,achieving highly efficient photoreduction of CO_(2)to CO.By incorporating WO_(4)^(2-)ions and tuning coordination environment,the(110)facet of BiOCl was in-situ grown on the(200)facet of Bi_(2)WO_(6).Compared to single phases and ball-milling samples,Bi_(2)WO_(6)-BiOCl exhibits a remarkable CO yield of 68.03μmol g^(-1)h^(-1)with a selectivity of 98%.Atomic visualization and coordination analysis confirm the formation of a coherent interface that facilitates charge migration for efficient electron transport.Density functional theory(DFT)calculations and in-situ Fourier transform infrared(FTIR)spectroscopy provide insights into the intrinsic active sites and reaction mechanisms.The proposed lattice engineering strategies offer a new paradigm for the rational design of heterostructures beyond traditional band alignment at the atomic scale. 展开更多
关键词 coherent interface Atomic precision Charge dynamics Photocatalytic CO_(2)reduction HETEROSTRUCTURE
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