Laying emphasis on the preparation of Bi based 2212 single phase superconducting powder, some technological parameters, which effect the single phase degree and uniformity of powder, such as prebaking, sintering and ...Laying emphasis on the preparation of Bi based 2212 single phase superconducting powder, some technological parameters, which effect the single phase degree and uniformity of powder, such as prebaking, sintering and heat treatment were investigated and discussed. Ensuring the powder T c at 83～85 K, the crucial impurity carbon was reduced to 0.03% and less. Adopting uncommon technique made the powder size to micrometer level, meanwhile the superconducting performance of the powder was unchanged. The fine superconducting powder was characterized. This process of Bi based 2212 superconducting powder was successful.展开更多
As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, ther...As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, there are different structural versions for phase III, most of which are determined by x-ray diffraction(XRD) technology. Using x-ray absorption fine structure(XAFS) measurements combined with ab initio calculations, we show that the proposed incommensurate composite structure of bismuth of the three configurations is the best option. An abnormal continuous increase of the nearest-neighbor distance of phase III with elevated pressure is also observed. The electronic structure transformation from semimetal to metal is responsible for the complex behavior of structure transformation.展开更多
Powder segregation induced by mold filling is an important phenomenon that affects the final quality of metal injection molding （MIM）. The prediction of segregation in MIM requires a bi-phase flow model to describe ...Powder segregation induced by mold filling is an important phenomenon that affects the final quality of metal injection molding （MIM）. The prediction of segregation in MIM requires a bi-phase flow model to describe distinctly the flows of metallic powder and polymer binder. Viscous behaviors for the flows of each phase should hence be determined. The coefficient of interaction between the flows of two phases should also be evaluated. However, only viscosity of the mixed feedstock is measurable by capillary tests. Wall sticking is supposed in the traditional model for capillary tests, while the wall slip is important to be taken into account in MIM injection. Objective of the present paper is to introduce the slip effect in bi-phase simulation, and search the suitable way to determine the viscous behaviors for each phase with the consideration of wall slip in capillary tests. Analytical and numerical methods were proposed to realize such a specific purpose. The proposed method is based on the mass conservation between the capillary flows in mono-phase model for the mixed feedstock and in bi-phase model for the flows of two phases. Examples of the bi-phase simulation in MIM were realized with the software developed by research team. The results show evident segregation, which is valuable for improving the mould designs.展开更多
Powder in tube process（PIT） was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment（HT1）, intermediate rolling（IR）, and second heat treat...Powder in tube process（PIT） was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment（HT1）, intermediate rolling（IR）, and second heat treatment（HT2） was performed. The phase evolution mechanism and microstructure changes during these heat treatment processes were systematically discussed. The influences of HT1 parameters on the phase evolution process of Bi-2223 tapes were discussed. With the optimized HT1 process, a proper Bi-2223 content of about 90% was achieved. HT2 process was also optimized by adding a post annealing process. An obvious increase of current capacity was obtained due to the enhancement of intergrain connections. Single filament Bi-2223 tapes with the critical current of Ic-90 A were fabricated with the optimized sintering process.展开更多
The phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method is studied with different heat treatment parameters. The results show that the reaction temperature and phase composition of precursor...The phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method is studied with different heat treatment parameters. The results show that the reaction temperature and phase composition of precursor powder depend on heat treatment atmosphere. Phase assemblage of(Bi,Pb)-2212, AEC, CuO, and small Bi-2201 can be obtained by heat-treated in N2-0.1%O_2 atmosphere. For precursor powder, there is sufficient reaction process at 770℃, and the dimension of Bi-2212 phase increases rapidly with the increase of heat treatment temperature and time. The dimension of AEC phase also increases by extending heat treatment time. As a balance among phase assemblage, dimension of particle and adequate reaction, a reasonable precursor powder can be obtained by heat-treated at 770℃ for 12 h–16 h in N2-0.1%O_2 atmosphere. Critical current of 37-filament Bi-2223 tape is about 120 A, which confirms that these heat treatment parameters are reasonable.展开更多
A phase-selective,bis-urea organogelator with a curved bis-naphthalene core was synthesized and characterized.This gelator is capable of gelating a variety of hydrocarbons and oils.The resulting gels have been charact...A phase-selective,bis-urea organogelator with a curved bis-naphthalene core was synthesized and characterized.This gelator is capable of gelating a variety of hydrocarbons and oils.The resulting gels have been characterized by rheology,SEM,and molecular modelling.The gelator can be applied in the powder form for the recovery of a thin layer of petrol oil spill in water.展开更多
Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary system have been studied by means of room and high temperature X-ray diffraction and quenching.
文摘Laying emphasis on the preparation of Bi based 2212 single phase superconducting powder, some technological parameters, which effect the single phase degree and uniformity of powder, such as prebaking, sintering and heat treatment were investigated and discussed. Ensuring the powder T c at 83～85 K, the crucial impurity carbon was reduced to 0.03% and less. Adopting uncommon technique made the powder size to micrometer level, meanwhile the superconducting performance of the powder was unchanged. The fine superconducting powder was characterized. This process of Bi based 2212 superconducting powder was successful.
基金supported by the National Natural Science Foundation of China(Grant Nos.10904133,11304294,11274281,11404006,and U1230201)the Development Foundation of China Academy of Engineering Physics(Grant Nos.2015B0101004,2013B0401062,and 2012A0101001)the Research Foundation of the Laboratory of Shock Wave and Detonation,China(Grant No.9140C670201140C67282)
文摘As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, there are different structural versions for phase III, most of which are determined by x-ray diffraction(XRD) technology. Using x-ray absorption fine structure(XAFS) measurements combined with ab initio calculations, we show that the proposed incommensurate composite structure of bismuth of the three configurations is the best option. An abnormal continuous increase of the nearest-neighbor distance of phase III with elevated pressure is also observed. The electronic structure transformation from semimetal to metal is responsible for the complex behavior of structure transformation.
基金Specialized Research Fund for the Doc-toral Program of Higher Education (No.20020613005)
文摘Powder segregation induced by mold filling is an important phenomenon that affects the final quality of metal injection molding （MIM）. The prediction of segregation in MIM requires a bi-phase flow model to describe distinctly the flows of metallic powder and polymer binder. Viscous behaviors for the flows of each phase should hence be determined. The coefficient of interaction between the flows of two phases should also be evaluated. However, only viscosity of the mixed feedstock is measurable by capillary tests. Wall sticking is supposed in the traditional model for capillary tests, while the wall slip is important to be taken into account in MIM injection. Objective of the present paper is to introduce the slip effect in bi-phase simulation, and search the suitable way to determine the viscous behaviors for each phase with the consideration of wall slip in capillary tests. Analytical and numerical methods were proposed to realize such a specific purpose. The proposed method is based on the mass conservation between the capillary flows in mono-phase model for the mixed feedstock and in bi-phase model for the flows of two phases. Examples of the bi-phase simulation in MIM were realized with the software developed by research team. The results show evident segregation, which is valuable for improving the mould designs.
基金Funded by the National Natural Science Foundation of China(No.51472206)the National ITER Program of China(2015GB115001)the Program for Innovative Research Team in Shaanxi Province(No.2013KCT-07)
文摘Powder in tube process（PIT） was adopted for the fabrication of single filament Bi-2223 tapes, and a heat treatment process including the first heat treatment（HT1）, intermediate rolling（IR）, and second heat treatment（HT2） was performed. The phase evolution mechanism and microstructure changes during these heat treatment processes were systematically discussed. The influences of HT1 parameters on the phase evolution process of Bi-2223 tapes were discussed. With the optimized HT1 process, a proper Bi-2223 content of about 90% was achieved. HT2 process was also optimized by adding a post annealing process. An obvious increase of current capacity was obtained due to the enhancement of intergrain connections. Single filament Bi-2223 tapes with the critical current of Ic-90 A were fabricated with the optimized sintering process.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFB0902303)the Key Research and Development Program of Shaanxi Province,China(Grant No.2018GY-121N)the National Key Project of Magneto Constrained Fusion Energy Development Program,China(Grant No.2015GB115001)
文摘The phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method is studied with different heat treatment parameters. The results show that the reaction temperature and phase composition of precursor powder depend on heat treatment atmosphere. Phase assemblage of(Bi,Pb)-2212, AEC, CuO, and small Bi-2201 can be obtained by heat-treated in N2-0.1%O_2 atmosphere. For precursor powder, there is sufficient reaction process at 770℃, and the dimension of Bi-2212 phase increases rapidly with the increase of heat treatment temperature and time. The dimension of AEC phase also increases by extending heat treatment time. As a balance among phase assemblage, dimension of particle and adequate reaction, a reasonable precursor powder can be obtained by heat-treated at 770℃ for 12 h–16 h in N2-0.1%O_2 atmosphere. Critical current of 37-filament Bi-2223 tape is about 120 A, which confirms that these heat treatment parameters are reasonable.
基金financially supported by the National Natural Science Foundation of China(Nos.21302090,21572097)South University of Science and Technology of Chinathe Shenzhen special funds for the development of biomedicine,internet,new energy,and new material industries(No. JCYJ20150331101823694)
文摘A phase-selective,bis-urea organogelator with a curved bis-naphthalene core was synthesized and characterized.This gelator is capable of gelating a variety of hydrocarbons and oils.The resulting gels have been characterized by rheology,SEM,and molecular modelling.The gelator can be applied in the powder form for the recovery of a thin layer of petrol oil spill in water.
文摘Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary system have been studied by means of room and high temperature X-ray diffraction and quenching.
基金National Natural Science Foundation of China(51902267)Shaanxi Province Key Research and Development Program(2022GY-391,2020ZDZX04-04-02)+1 种基金National Key Project of Magneto Constrained Fusion Energy Development Program(2017YFE0301402)Natural Science Foundation of Shaanxi Province(2020JM-648)。
