A BaF2 time differential perturbed angular distribution spectrometer has been established at the HI-13 tandem accelerator in CIAE. The time resolution of the spectrometer is 195 ps and the nonlinearity is less than 2 ...A BaF2 time differential perturbed angular distribution spectrometer has been established at the HI-13 tandem accelerator in CIAE. The time resolution of the spectrometer is 195 ps and the nonlinearity is less than 2 %. The spectrometer works very stably and no time drift is found over a period of experimelltal ruffs. This spectrometer has been successfully used in the g-factor measurement of 43 Sc (19/2-,3.1232 MeV).展开更多
Electrochemical measurements of the solid-oxide galvanic cell, Mo|Mo+MoO2|ZrO2 (MgO)| Fe+ (FexO)+Ag| Fe, have been made at temperatures of 1473K and 1573K in order to obtain the activities of FexO in BaO-BaF2-FexO sla...Electrochemical measurements of the solid-oxide galvanic cell, Mo|Mo+MoO2|ZrO2 (MgO)| Fe+ (FexO)+Ag| Fe, have been made at temperatures of 1473K and 1573K in order to obtain the activities of FexO in BaO-BaF2-FexO slags used for dephosphorization of chromium-containing hot metal. The FexO activities show a significant dependence upon the molar ratio of BaO/BaF2. Within the homogeneous liquid region, the substitution of BaF2 for BaO has an effect of raising the FexO activity. From these activity data, the phase diagrams of the system BaO -BaF2-FexO are drawn at 1473K and 1573K. The temperature dependence of the activity coefficient of FexO at a fixed BaO/ BaF2 molar ratio can be expressed by formula RTlnγ(FexO)=constant.展开更多
文摘A BaF2 time differential perturbed angular distribution spectrometer has been established at the HI-13 tandem accelerator in CIAE. The time resolution of the spectrometer is 195 ps and the nonlinearity is less than 2 %. The spectrometer works very stably and no time drift is found over a period of experimelltal ruffs. This spectrometer has been successfully used in the g-factor measurement of 43 Sc (19/2-,3.1232 MeV).
文摘Electrochemical measurements of the solid-oxide galvanic cell, Mo|Mo+MoO2|ZrO2 (MgO)| Fe+ (FexO)+Ag| Fe, have been made at temperatures of 1473K and 1573K in order to obtain the activities of FexO in BaO-BaF2-FexO slags used for dephosphorization of chromium-containing hot metal. The FexO activities show a significant dependence upon the molar ratio of BaO/BaF2. Within the homogeneous liquid region, the substitution of BaF2 for BaO has an effect of raising the FexO activity. From these activity data, the phase diagrams of the system BaO -BaF2-FexO are drawn at 1473K and 1573K. The temperature dependence of the activity coefficient of FexO at a fixed BaO/ BaF2 molar ratio can be expressed by formula RTlnγ(FexO)=constant.