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Alternating Copolymerization of Dihydrocoumarin and Epoxides Catalyzed by 1-Ethyl-3-methylimidazolium Chloride
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作者 Jing-Jing Yu Yong-Li Li +4 位作者 Xue Wu Zhi-Dong Li Ye-Fan Liu Yang Zhang Peng-Fei Song 《Chinese Journal of Polymer Science》 2025年第8期1269-1276,共8页
The ring-opening alternating copolymerization(ROAC)of 3,4-dihydrocoumarin(DHC)/epoxides has been successfully developed using an imidazolium salt of 1-ethyl-3-methylimidazolium chloride(EMIMCl)as a catalyst.The result... The ring-opening alternating copolymerization(ROAC)of 3,4-dihydrocoumarin(DHC)/epoxides has been successfully developed using an imidazolium salt of 1-ethyl-3-methylimidazolium chloride(EMIMCl)as a catalyst.The resulting copolymer has a molecular weight of 13.7kg·mol^(-1),a narrow molecular weight distribution of 1.03 and a strictly alternating structure.The MALDI-TOF MS characterization and DFT calculations including electrostatic potential(ESP),hydrogen-atom abstraction(HAA),independent gradient model based on hirshfeld partition(IGMH)and atoms-in-molecules(AIM)analysis were used to investigate the metal-free catalytic process.The synergistic effect of anions and cations of EMIMCl for ROAC of DHC and epoxides was demonstrated.This study provides a metal-free catalytic system for the facile synthesis of alternating polyesters from DHC. 展开更多
关键词 alternating copolymerization Dihydrocoumarin EPOXIDES Imidazolium salt Metal-free catalysis
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The role of Mn in the stabilization of adiabatic temperature changes of LaFe_(11.2-x)Mn_(x)Co_(0.7)Si_(1.1)alloys in an alternating magnetic field
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作者 Adler Gamzatov Nurizhat Abdulkadirova +4 位作者 Kamil Kamilov Akhmed Batdalov Akhmed Aliev Piotr Gebara Hu Zhang 《Rare Metals》 2025年第6期4074-4085,共12页
The results of the study of the effect of partial substitution of Fe by Mn in the La Fe_(11.2-x)Mn_(x)Co_(0.7)Si_(1.1)system on magnetization,specific heat,magnetostriction and magnetocaloric effect are presented.Dire... The results of the study of the effect of partial substitution of Fe by Mn in the La Fe_(11.2-x)Mn_(x)Co_(0.7)Si_(1.1)system on magnetization,specific heat,magnetostriction and magnetocaloric effect are presented.Direct measurements of the adiabatic temperature change(ΔT_(ad))were carried out in alternating magnetic fields(AMF)using the magnetic field modulation method.Partial substitution of Fe atoms by Mn atoms leads to a shift in the Curie temperature(T_(C))towards lower temperatures without a noticeable deterioration in magnetic properties.A correlation was found between the structural component of the magnetocaloric effect and the stability of the frequency of theΔT_(ad)in the AMFs—an increase in the manganese concentration leads to a decrease in magnetostriction and to a lower dependence ofΔT_(ad)on the frequency of the magnetic field.Estimates of the specific cooling power Q_(C)as a function of the frequency of the AMF showed that the highest value of Q_(C)at f=20 Hz in a magnetic field of 12k Oe is 26.3 W g^(-1)and is observed for the composition with x=0.1.This value is higher than that of Gd,for which,under the same conditions,Q_(C)=21.6 W g^(-1).All the samples studied show stability of the value ofΔT_(ad)without any sign of deterioration of the effect up to 60,000cycles of switching on/off of the magnetic field of 12 k Oe.The discovered frequency and cyclic stability ofΔT_(ad)of the studied samples increase their prospects for application in magnetic cooling technology. 展开更多
关键词 MAGNETIZATION MAGNETOSTRICTION Magnetocaloric effect Pulsed fields alternating magnetic fields
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Effect of theta-transcranial alternating current stimulation on working memory performance among healthy adults:A systematic review and meta-analysis
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作者 Tian-Ya Hou Xiao-Fei Mao Rui-Ke Zhang 《World Journal of Psychiatry》 2025年第9期328-341,共14页
BACKGROUND Working memory serves as a fundamental cognitive function that substantially impacts performance in various cognitive tasks.Extensive neurophysiological research has established that theta oscillations(4-8 ... BACKGROUND Working memory serves as a fundamental cognitive function that substantially impacts performance in various cognitive tasks.Extensive neurophysiological research has established that theta oscillations(4-8 Hz)play an essential role in supporting working memory operations.Theta-band transcranial alternating current stimulation(tACS)offers a potential mechanism for working memory enhancement through direct modulation of these fundamental neural oscillations.Nevertheless,current empirical evidence shows substantial variability in the observed effects of theta-tACS across studies.AIM To conduct a systematic review and meta-analysis evaluating the effects of thetatACS on working memory performance in healthy adults.METHODS A systematic literature search was performed on PubMed,EMBASE,and Web of Science up to March 10,2025.Effect sizes were computed using Hedges’g with 95%confidence intervals(CIs),with separate meta-analyses for all included studies and for distinct working memory paradigms[n-back and delayed matchto-sample(DMTS)tasks]to examine potential task-specific effects.Subgroup analyses and meta-regression were performed to evaluate the influence of key moderating variables.RESULTS The systematic review included 21 studies(67 effect sizes).Initial meta-analysis showed theta-tACS moderately improved working memory(Hedges’g=0.405,95%CI:0.212-0.598).However,this effect became nonsignificant after correcting for publication bias(trim-and-fill adjusted Hedges’g=0.082,95%CI:-0.052 to 0.217).Task-specific analyses revealed significant benefits in n-back tasks(Hedges’g=0.463,95%CI:0.193-0.733)but not in DMTS tasks(Hedges’g=0.257,95%CI:-0.186 to 0.553).Moderator analyses showed that performance in n-back tasks was influenced by stimulation frequency(P=0.001),concurrent status(P=0.014),task modality(P=0.005),and duration(P=0.013),whereas only the region of targeted stimulation(P=0.012)moderated DMTS tasks.CONCLUSION Theta-tACS enhances working memory in healthy adults,with effects modulated by the task type and protocol parameters,offering dual implications for cognitive enhancement and clinical interventions. 展开更多
关键词 Working memory Transcranial alternating current stimulation THETA Healthy adults N-BACK Delayed match-tosample task
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Influence of alternating magnetic field on corrosion and microstructure of 2205 duplex stainless steel welded joints
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作者 Yu-cheng Xing Zhen-bang Sun +1 位作者 Yong-quan Han Da-xing Zhang 《Journal of Iron and Steel Research International》 2025年第5期1341-1355,共15页
An alternating magnetic field(AMF)was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates.The corrosion performance of the welded joints was evaluated through e... An alternating magnetic field(AMF)was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates.The corrosion performance of the welded joints was evaluated through electrochemical studies.The results revealed that joints welded with the application of AMF had a lower corrosion current density compared to those welded without an external AMF.Additionally,these joints showed higher pitting potential and polarization resistance.Microscopic electrochemical analysis indicated that joints subjected to AMF exhibited minimal cathodic current in simulated seawater,with only slight fluctuations in the anodic current peak.Overall,the corrosion levels on the joint surfaces were relatively low.After 4 h of immersion in the corrosive medium,the average impedance of joints exposed to AMF increased by 60.7%compared to those not influenced by a magnetic field.These findings suggest that applying AMF during the narrow gap laser-arc hybrid welding process can significantly improve the corrosion resistance of duplex stainless steel welded joints,reducing their susceptibility to stress corrosion in seawater-like environments. 展开更多
关键词 Duplex stainless steel Narrow gap welding Laser-arc hybrid welding alternating magnetic field Corrosion resistance
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Progressive quantum algorithm for maximum independent set with quantum alternating operator ansatz
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作者 Xiao-Hui Ni Ling-Xiao Li +3 位作者 Yan-Qi Song Zheng-Ping Jin Su-Juan Qin Fei Gao 《Chinese Physics B》 2025年第7期75-87,共13页
The quantum alternating operator ansatz algorithm(QAOA+)is widely used for constrained combinatorial optimization problems(CCOPs)due to its ability to construct feasible solution spaces.In this paper,we propose a prog... The quantum alternating operator ansatz algorithm(QAOA+)is widely used for constrained combinatorial optimization problems(CCOPs)due to its ability to construct feasible solution spaces.In this paper,we propose a progressive quantum algorithm(PQA)to reduce qubit requirements for QAOA+in solving the maximum independent set(MIS)problem.PQA iteratively constructs a subgraph likely to include the MIS solution of the original graph and solves the problem on it to approximate the global solution.Specifically,PQA starts with a small-scale subgraph and progressively expands its graph size utilizing heuristic expansion strategies.After each expansion,PQA solves the MIS problem on the newly generated subgraph using QAOA+.In each run,PQA repeats the expansion and solving process until a predefined stopping condition is reached.Simulation results show that PQA achieves an approximation ratio of 0.95 using only 5.57%(2.17%)of the qubits and 17.59%(6.43%)of the runtime compared with directly solving the original problem with QAOA+on Erd?s-Rényi(3-regular)graphs,highlighting the efficiency and scalability of PQA. 展开更多
关键词 quantum alternating operator ansatz algorithm(QAOA+) constrained combinatorial optimization problems(CCOPs) maximum independent set(MIS) feasible space
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Evaluation of the dynamic sealing performance of cap rocks of underground gas storage under multi-cycle alternating loads 被引量:5
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作者 Lidong Mi Yandong Guo +3 位作者 Yanfeng Li Daqian Zeng Chunhua Lu Guangquan Zhang 《Energy Geoscience》 EI 2024年第4期125-132,共8页
The static sealing of underground gas storage(UGS),including the integrity of cap rocks and the stability of faults,is analyzed from a macro perspective using a comprehensive geological evaluation method.Changes in po... The static sealing of underground gas storage(UGS),including the integrity of cap rocks and the stability of faults,is analyzed from a macro perspective using a comprehensive geological evaluation method.Changes in pore structure,permeability,and mechanical strength of cap rocks under cyclic loads may impact the rock sealing integrity during the injection and recovery phases of UGS.In this work,the mechanical deformation and failure tests of rocks,as well as rock damage tests under alternating loads,are conducted to analyze the changes in the strength and permeability of rocks under multiple-cycle intense injection and recovery of UGS.Additionally,this study proposes an evaluation method for the dynamic sealing performance of UGS cap rocks under multi-cycle alternating loads.The findings suggest that the failure strength(70%)can be used as the critical value for rock failure,thus providing theoretical support for determining the upper limit of operating pressure and the number of injection-recovery cycles for the safe operation of a UGS system. 展开更多
关键词 alternating load Cap rock Dynamic sealing performance Underground gas storage
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Alternating current heating techniques for lithium-ion batteries in electric vehicles:Recent advances and perspectives
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作者 Xinrong Huang Jinhao Meng +5 位作者 Wei Jiang Wenjie Liu Kailong Liu Yipu Zhang Daniel-Ioan Stroe Remus Teodorescu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期679-697,共19页
The significant decrease in battery performance at low temperatures is one of the critical challenges that electric vehicles(EVs)face,thereby affecting the penetration rate in cold regions.Alternating current(AC)heati... The significant decrease in battery performance at low temperatures is one of the critical challenges that electric vehicles(EVs)face,thereby affecting the penetration rate in cold regions.Alternating current(AC)heating has attracted widespread attention due to its low energy consumption and uniform heating advantages.This paper introduces the recent advances in AC heating from the perspective of practical EV applications.First,the performance degradation of EVs in low-temperature environments is introduced briefly.The concept of AC heating and its research methods are provided.Then,the effects of various AC heating methods on battery heating performance are reviewed.Based on existing studies,the main factors that affect AC heating performance are analyzed.Moreover,various heating circuits based on EVs are categorized,and their cost,size,complexity,efficiency,reliability,and heating rate are elaborated and compared.The evolution of AC heaters is presented,and the heaters used in brand vehicles are sorted out.Finally,the perspectives and challenges of AC heating are discussed.This paper can guide the selection of heater implementation methods and the optimization of heating effects for future EV applications. 展开更多
关键词 Lithium-ion battery Low temperature alternating current heating HEATER Electric vehicle
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Wetting alternating with partial drying during grain filling increases lysine biosynthesis in inferior rice grain
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作者 Yi Jiang Wenli Tao +2 位作者 Weiyang Zhang Zhiqin Wang Jianchang Yang 《The Crop Journal》 SCIE CSCD 2024年第1期262-270,共9页
Lysine content is a criterion of the nutritional quality of rice.Understanding the process of lysine biosynthesis in early-flowering superior grain(SG)and late-flowering inferior grain(IG)of rice would advance breedin... Lysine content is a criterion of the nutritional quality of rice.Understanding the process of lysine biosynthesis in early-flowering superior grain(SG)and late-flowering inferior grain(IG)of rice would advance breeding and cultivation to improve nutritional quality.However,little information is available on differences in lysine anabolism between SG and IG and the underlying mechanism,and whether and how irrigation regimes affect lysine anabolism in these grains.A japonica rice cultivar was grown in the field and two irrigation regimes,continuous flooding(CF)and wetting alternating with partial drying(WAPD),were imposed from heading to the mature stage.Lysine content and activities of key enzymes of lysine biosynthesis,and levels of brassinosteroids(BRs)were lower in the IG than in the SG at the early grainfilling stage but higher at middle and late grain-filling stages.WAPD increased activities of these key enzymes,BR levels,and contents of lysine and total amino acids in IG,but not SG relative to CF.Application of 2,4-epibrassinolide to rice panicles in CF during early grain filling reproduced the effects of WAPD,but neither treatment altered the activities of enzymes responsible for lysine catabolism in either SG or IG.WAPD and elevated BR levels during grain filling increased lysine biosynthesis in IG.Improvement in lysine biosynthesis in rice should focus on IG. 展开更多
关键词 BRASSINOSTEROIDS Inferior grain Lysine biosynthesis Rice Wetting alternating with partial drying
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Grain refinement of 5A06 aluminum alloy welds caused by tungsten inert gas welding arc characteristics under Ar-He alternating gas supply conditions:a coupled method of water-cooled copper plate test/numerical simulation
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作者 Hong-bin Dai Jian Miao Jia-xin Lin 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2024年第3期767-777,共11页
The welding arc,as a carrier for the conversion of electrical energy to thermal energy,has a direct impact on the quality of welding by its properties and states.In the tungsten inert gas(TIG)welding process under the... The welding arc,as a carrier for the conversion of electrical energy to thermal energy,has a direct impact on the quality of welding by its properties and states.In the tungsten inert gas(TIG)welding process under the condition of Ar-He alternating gas supply,the arc is alternately converted between Ar arc and He arc with an alternating gas supply cycle,which has obvious arc change characteristics.The FLUENT software was used to numerically simulate the characteristics of the TIG arc under the condition of alternating gas supply,and the arc temperature field,arc pressure,electric potential and current density distribution under the condition of alternating gas supply were obtained.Combined with the real-time data of arc pressure measured by the water-cooled copper plate with holes,it is proved that the TIG arc has obvious dynamic characteristics under the condition of Ar-He alternating gas supply.This unique dynamic TIG arc acts on the 5A06 aluminum alloy weld,causing the molten pool to stir,resulting in uniform microstructure and grain refinement at the weld,and thereby improving the mechanical properties of the welded joint. 展开更多
关键词 alternating gas supply Grain refinement Numerical simulation Tungsten argon arc morphology Microstructure Mechanical property
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Numerical study of steady flow characteristics of a rear variable-area bypass injector with alternating area regulator
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作者 Runfu LIU Zhenyao LI +3 位作者 Huiliu ZHANG Qixing WANG Yue HUANG Yancheng YOU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第5期180-198,共19页
The mixing effectiveness of the airflow between the inner and outer bypass inlets of a Rear Variable-Area Bypass Injector(RVABI)is the key to the afterburner performance of variable cycle engines.This paper describes ... The mixing effectiveness of the airflow between the inner and outer bypass inlets of a Rear Variable-Area Bypass Injector(RVABI)is the key to the afterburner performance of variable cycle engines.This paper describes an optimized RVABI design based on an alternating area regulator to improve the velocity/temperature uniformity of the incoming flow at the afterburner.Compared with a classical RVABI,numerical simulations show that the proposed alternating RVABI performs better in terms of thermal mixing efficiency and total pressure loss in different variable cycle engine modes.Both the increasing air contact area between the inner and outer bypass of alternating structure RVABI,and a larger streamwise vortex in the inner bypass inlet due to the proposed alternating lobe structure in the RVABI contribute to the significantly increase of mixing effectiveness.Besides,the alternating regulator induces strong streamwise vortex,which helps to improve the airflow mixing with its vortex-induced velocity.The interaction between the streamwise vortex and azimuthal vortex further promises the velocity/temperature uniformity after the RVABI.With the increase of alternating lobe’s height ratio,the covering area of the streamwise vortex and the azimuthal vortex is enlarged,which further enhances the thermal mixing efficiency of the RVABI.This design gives an insight into the future design and optimization of RVABI. 展开更多
关键词 alternating area regulator Lobed mixer Variable cycle engine Rear Variable-Area Bypass Injector(RVABI) Streamwise vortex
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Suppression of stimulated Brillouin and Raman scatterings using an alternating frequency laser and transverse magnetic fields
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作者 程瑞锦 李晓旬 +11 位作者 王清 刘德基 黄卓明 吕帅宇 周远志 张舒童 李雪铭 陈祖杰 王强 刘占军 曹莉华 郑春阳 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期545-553,共9页
A novel scheme to suppress both stimulated Brillouin scattering(SBS) and stimulated Raman scattering(SRS) by combining an alternating frequency(AF) laser and a transverse magnetic field is proposed. The AF laser allow... A novel scheme to suppress both stimulated Brillouin scattering(SBS) and stimulated Raman scattering(SRS) by combining an alternating frequency(AF) laser and a transverse magnetic field is proposed. The AF laser allows the laser frequency to change discretely and alternately over time. The suppression of SBS is significant as long as the AF difference is greater than the linear growth rate of SBS or the alternating time of the laser frequency is shorter than the linear growth time of SBS. However, the AF laser proves ineffective in suppressing SRS, which usually has a much higher linear growth rate than SBS. To remedy that, a transverse magnetic field is included to suppress the SRS instability. The electrons trapped in the electron plasma waves(EPWs) of SRS can be accelerated by the surfatron mechanism in a transverse magnetic field and eventually detrapped. While continuously extracting energy from EPWs, the EPWs are dissipated and the kinetic inflation of SRS is suppressed. The one-dimensional particle-in-cell simulation results show that both SBS and SRS can be effectively suppressed by combining the AF laser with a transverse magnetic field with tens of Tesla. The total reflectivity can be dramatically reduced by more than one order of magnitude. These results provide a potential reference for controlling SBS and SRS under the related parameters of inertial confinement fusion. 展开更多
关键词 stimulated Brillouin scattering stimulated Raman scattering alternating frequency laser transverse magnetic field
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Diagnosing ratio of electron density to collision frequency of plasma surrounding scaled model in a shock tube using low-frequency alternating magnetic field phase shift
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作者 吴明兴 谢楷 +3 位作者 刘艳 徐晗 张宝 田得阳 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期519-530,共12页
A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic... A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic field through the plasma to directly measure the ratio of the plasma loop average electron density to collision frequency.An equivalent circuit model is used to analyze the relationship of the phase shift of the magnetic field component of LF electromagnetic waves with the plasma electron density and collision frequency.The applicable range of the LF method on a given plasma scale is analyzed.The upper diagnostic limit for the ratio of the electron density(unit:m^(-3))to collision frequency(unit:Hz)exceeds 1×10^(11),enabling an electron density to exceed 1×10^(20)m^(-3)and a collision frequency to be less than 1 GHz.In this work,the feasibility of using the LF phase shift to implement the plasma diagnosis is also assessed.Diagnosis experiments on shock tube equipment are conducted by using both the electrostatic probe method and LF method.By comparing the diagnostic results of the two methods,the inversion results are relatively consistent with each other,thereby preliminarily verifying the feasibility of the LF method.The ratio of the electron density to the collision frequency has a relatively uniform distribution during the plasma stabilization.The LF diagnostic path is a loop around the model,which is suitable for diagnosing the plasma that surrounds the model.Finally,the causes of diagnostic discrepancy between the two methods are analyzed.The proposed method provides a new avenue for diagnosing high-density enveloping plasma. 展开更多
关键词 low-frequency alternating magnetic field phase shift shock-tube plasma diagnosis electron density collision frequency
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Preparation and Properties of Y_(2)O_(3)-PF Alternating Coating on Polymer Matrix Composite Material Surface
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作者 Li Xuewu Zhang Jiahao +5 位作者 Feng Yuxi Liu Ming Shi Tian Wang Haidou Bai Yu Wang Yu 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2024年第10期2777-2785,共9页
High-performance yttrium oxide-phenolic resin(Y_(2)O_(3)-PF)alternating coating was prepared on epoxy resin-based composite material using supersonic plasma spraying and dual-channel powder feeding technique.Y_(2)O_(3... High-performance yttrium oxide-phenolic resin(Y_(2)O_(3)-PF)alternating coating was prepared on epoxy resin-based composite material using supersonic plasma spraying and dual-channel powder feeding technique.Y_(2)O_(3)-coated PF(Y_(2)O_(3)/PF)powder was firstly sprayed onto the substrate,forming a transition layer,and then the spherical Y_(2)O_(3) powder and Y_(2)O_(3)/PF powder were alternately deposited to form the composite alternating coating.Results show that the alternating coating is mainly composed of deposited Y_(2)O_(3)/PF powder.The bonding strength between coating and substrate is as high as 26.48 MPa with the single-test maximum bonding strength of 28.10 MPa,and shear strength reaches 24.30 MPa.Additionally,the heat transfer effect caused by external Y_(2)O_(3) particles gradually softens and even melts PF,thus effectively avoiding the damage of high temperature to molecular structure and thereby promoting the crosslinking and curing effects of resin during the deposition process.In the meantime,the unmelted Y_(2)O_(3) powder results in the shot peening effect,which washes out and eliminates the powder particles with inferior deposition effect,ultimately improving the physical and chemical properties of the alternating coating. 展开更多
关键词 Y_(2)O_(3)-PF alternating coating epoxy resin composite material supersonic plasma spraying mechanical property
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Frequency Regulation of Alternating Current Microgrid Based on Hierarchical Control Using Fuzzy Logic
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作者 WU Xueyang SHAN Yinghao SHEN Bo 《Journal of Donghua University(English Edition)》 CAS 2024年第5期536-544,共9页
An alternating current(AC)microgrid is a system that integrates renewable power,power converters,controllers and loads.Hierarchical control can manage the frequency of the microgrid to prevent imbalance and collapse o... An alternating current(AC)microgrid is a system that integrates renewable power,power converters,controllers and loads.Hierarchical control can manage the frequency of the microgrid to prevent imbalance and collapse of the system.The existing frequency control methods use traditional proportion integration(PI)controllers,which cannot adjust PI parameters in real-time to respond to the status changes of the system.Hierarchical control driven by fuzzy logic allows real-time adjustment of the PI parameters and the method used a two-layer control structure.The primary control used droop control to adjust power distribution,and fuzzy logic was used in the voltage loop of the primary control.The secondary control was added to make up for frequency deviation caused by droop control,and fuzzy logic was used in the secondary frequency control to deal with the dynamic change of frequency caused by the disturbances of loads.The proposed method was simulated in Matlab/Simulink.In the primary control,the proposed method reduced the total harmonic distortion(THD)of two cycles of the output voltage from 4.19%to 3.89%;in the secondary control,the proposed method reduced the frequency fluctuation of the system by about 0.03 Hz and 0.04 Hz when the load was increased and decreased,respectively.The results show that the proposed methods have a better effect on frequency maintenance and voltage control of the AC microgrid. 展开更多
关键词 fuzzy logic hierarchical control frequency regulation droop control alternating current(AC)microgrid
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In Situ Coupling of Reduction and Oxidation Processes with Alternating Current-Driven Bioelectrodes for Efficient Mineralization of Refractory Pollutants
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作者 Ye Yuan Junjie Zhang +7 位作者 Wanxin Yin Lulu Zhang Lin Li Tianming Chen Cheng Ding Wenzong Liu Aijie Wang Fan Chen 《Engineering》 CSCD 2024年第12期125-138,共14页
The effective elimination of aromatic compounds from wastewater is imperative for safeguarding the ecological environment.Bioelectrochemical processes that combine cathodic reduction and anodic oxidation represent a p... The effective elimination of aromatic compounds from wastewater is imperative for safeguarding the ecological environment.Bioelectrochemical processes that combine cathodic reduction and anodic oxidation represent a promising approach for the biomineralization of aromatic compounds.However,conventional direct current bioelectrochemical methods have intrinsic limitations.In this study,a low-frequency and low-voltage alternating current(LFV-AC)-driven bioelectrode offering periodic in situ coupling of reduction and oxidation processes was developed for the biomineralization of aromatic compounds,as exemplified by the degradation of alizarin yellow R(AYR).LFV-AC stimulated biofilm demonstrated efficient bidirectional electron transfer and oxidation–reduction bifunctionality,considerably boosting AYR reduction(63.07%±1.91%)and subsequent mineralization of intermediate products(98.63%±0.37%).LFV-AC stimulation facilitated the assembly of a collaborative microbiome dedicated to AYR metabolism,characterized by an increased abundance of functional consortia proficient in azo dye reduction(Stenotrophomonas and Bradyrhizobium),aromatic intermediate oxidation(Sphingopyxis and Sphingomonas),and electron transfer(Geobacter and Pseudomonas).The collaborative microbiome demonstrated a notable enrichment of functional genes encoding azo-and nitro-reductases,catechol oxygenases,and redox mediator proteins.These findings highlight the effectiveness of LFV-AC stimulation in boosting azo dye biomineralization,offering a novel and sustainable approach for the efficient removal of refractory organic pollutants from wastewater. 展开更多
关键词 alternating current Bioelectrode Redox process Bio-mineralization Electrode microbiome Refractory organic pollutants
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One-pot alternating current synthesis of SnO_(2) based composite with enhanced diffusion kinetic behaviors for lithium-ion batteries
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作者 ZHANG Guo-qiang JING Ming-jun +10 位作者 HE Li LI Dan WU Yu-feng YI Ming-guang LIU Cheng WANG Xing-yu HU Hong-hui WU Meng WU Tian-jing HUANG Yu-jie HOU Hong-shuai 《Journal of Central South University》 CSCD 2024年第12期4424-4436,共13页
SnO_(2)is used as electrode material with excellent properties,but it has some disadvantages such as slow reaction kinetics,low inherent conductivity and complex preparation process.Here,SnO_(2)@carbon nanotubes(SnO_(... SnO_(2)is used as electrode material with excellent properties,but it has some disadvantages such as slow reaction kinetics,low inherent conductivity and complex preparation process.Here,SnO_(2)@carbon nanotubes(SnO_(2)@CNTs)is synthesized through an efficient method of one-pot alternating current electrochemical dispersion.By using heat treatment at 400℃,the SnO_(2)@CNTs-400 composite material with abundant mesoporous structure is obtained,while the crystal particles are grown,and a strong bonding effect is formed with CNTs via powerful Sn-O-C bond.Benefiting from the introduction of high electrical conductivity CNTs and outstanding structural characteristics,as prepared composite material(SnO_(2)@CNTs-400)exhibit enhanced diffusion dynamics,lithium-ion transmission rate and structural steadiness.The specific capacity of SnO_(2)@CNTs and SnO_(2)@CNTs-400 as anodes for lithium-ion batteries can reach 690.2 mA·h/g and 836.5 mA·h/g,respectively,after 100 cycles at 0.5 A/g.The abundant chemical bonds and porous structure can be formed in composite via alternating current synthesis method,which takes significant in improving electrochemical properties. 展开更多
关键词 alternating current mesoporous structure bonding unit electrochemical behavior
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Block-transitive 3-designs Associated with Alternating Groups
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作者 Gan Yunsong Liu Weijun 《数学理论与应用》 2024年第4期19-30,共12页
A t-(v,k,λ)design is said to be G-point-primitive or G-block-transitive,if its automorphism group G acts primitively on the point set or transitively on the block set,respectively.In this paper we begin by extending ... A t-(v,k,λ)design is said to be G-point-primitive or G-block-transitive,if its automorphism group G acts primitively on the point set or transitively on the block set,respectively.In this paper we begin by extending some results on block-transitive Steiner 2-designs to block-transitive 3-designs,and then based on these results,investigate the G-point-primitive block-transitive 3-(v,k,λ)designs for alternating or symmetric groups G.We prove that when n≥min{λ^(2),30}the point stabilizer in G must be of intransitive type,and specifically,when n≥30 there exists no nontrivial G-point-primitive block-transitive 3-(v,k,2)design. 展开更多
关键词 Block-transitive design Primitive group alternating group
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Facile Synthesis of Polyisothioureas via Alternating Copolymerization of Aziridines and Isothiocayanates
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作者 Hao-Tian Zhang Ming-Xin Niu +2 位作者 Qi Zhang Chen-Yang Hu Xuan Pang 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2024年第3期292-298,I0005,共8页
Isothiourea is an important class of sulfur-containing molecules showing unique catalytic and biological activities. As such,polyisothiourea is envisioned to be an interesting type of polymer that potentially exhibits... Isothiourea is an important class of sulfur-containing molecules showing unique catalytic and biological activities. As such,polyisothiourea is envisioned to be an interesting type of polymer that potentially exhibits a number of interesting properties. However, there is no access to synthesizing well-defined polyisothiourea, and currently isothiourea-containing polymers are mainly prepared by immobilizing onto other polymer's side chain. Herein, we report the first facile synthesis of polyisothioureas via alternating copolymerization of aziridines and isothiocayanates. Mediated by the catalytic system of phosphazene superbases/alcohol, a broad scope of aziridines and isothiocayanates could be transformed into polyisothioureas with adjustable substitutions(11 examples). The structures of obtained polyisothioureas were fully characterized with ^(1)H-NMR, ^(13)C-NMR, and ^(1)H-^(13)C HMBC NMR. Moreover, the polyisothioureas show tunable thermal properties depending on substitutions on the isothiourea linkages. The novel structure of these polyisothioureas will enable a powerful platform for the discovery of nextgeneration functional plastics. 展开更多
关键词 Polyisothioureas Alternative copolymer AZIRIDINES Isothiocayanates
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Fast alternating direction method of multipliers for total-variation-based image restoration 被引量:1
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作者 陶敏 《Journal of Southeast University(English Edition)》 EI CAS 2011年第4期379-383,共5页
A novel algorithm, i.e. the fast alternating direction method of multipliers (ADMM), is applied to solve the classical total-variation ( TV )-based model for image reconstruction. First, the TV-based model is refo... A novel algorithm, i.e. the fast alternating direction method of multipliers (ADMM), is applied to solve the classical total-variation ( TV )-based model for image reconstruction. First, the TV-based model is reformulated as a linear equality constrained problem where the objective function is separable. Then, by introducing the augmented Lagrangian function, the two variables are alternatively minimized by the Gauss-Seidel idea. Finally, the dual variable is updated. Because the approach makes full use of the special structure of the problem and decomposes the original problem into several low-dimensional sub-problems, the per iteration computational complexity of the approach is dominated by two fast Fourier transforms. Elementary experimental results indicate that the proposed approach is more stable and efficient compared with some state-of-the-art algorithms. 展开更多
关键词 total variation DECONVOLUTION alternating direction method of multiplier
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HAUSDORFF DIMENSION OF SOME KIND OF ALTERNATING OPPENHEIM SERIES EXPANSION
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作者 Luming Shen Chao Ma Yuehua Liu 《Analysis in Theory and Applications》 2007年第2期171-179,共9页
For Oppenheim series epansions, the authors of [7] discussed the exceptional sets Bm={x∈(0,1]:1〈dj(x)/h(j-1)(d(j-1)(x))≤m for any j ≥2} In this paper, we investigate the Hausdorff dimension of a kind o... For Oppenheim series epansions, the authors of [7] discussed the exceptional sets Bm={x∈(0,1]:1〈dj(x)/h(j-1)(d(j-1)(x))≤m for any j ≥2} In this paper, we investigate the Hausdorff dimension of a kind of exceptional sets occurring in alternating Oppenheim series expansion. As an application, we get the exact Hausdorff dimension of the-set in Luroth series expansion, also we give an estimate of such dimensional number. 展开更多
关键词 alternating Oppenheim series expansion alternating Luroth series expansion Hausdorff dimension
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