The modified molecular interaction volume model(M-MIVM)was used to calculate the activity values and their deviations from experimental data for Ag-Cu and Ag-Sb binary alloys.Subsequently,theoretical vapor-liquid equi...The modified molecular interaction volume model(M-MIVM)was used to calculate the activity values and their deviations from experimental data for Ag-Cu and Ag-Sb binary alloys.Subsequently,theoretical vapor-liquid equilibrium phase diagrams(T-x-y and p-x-y)were plotted via combining M-MIVM and vacuum theory.The vapor-liquid phase equilibrium(VLE)experiments were conducted on the Ag-Cu alloy at 1500-1560 K and 10-15 Pa and Ag-Sb alloys at 950-1350 K and 10 Pa.The results showed that the average relative deviation and average standard deviation of activity were lower than 5%and 0.02,respectively.A comparison of theoretical and experiment results for VLE revealed that the simulated data on the T-x-y diagram were well consistent with experimental values.Therefore,the VLE phase diagrams can serve as a guide in vacuum separation experiments and industrial production for Ag-Cu and Ag-Sb binary alloys.展开更多
In October 2012,an evaluation using potential ecological hazard risk index was carried out on soil heavy metal pollution around AgSb deposit tailing areas in northeastern Guangdong. Results indicate that( i) soil heav...In October 2012,an evaluation using potential ecological hazard risk index was carried out on soil heavy metal pollution around AgSb deposit tailing areas in northeastern Guangdong. Results indicate that( i) soil heavy metal pollution is mainly Cd-Ni compound pollution,including Cd content 0. 31- 2. 66 mg / kg( average content is 1. 11 mg / kg),the situation of exceeding standard is serious( the rate of exceeding standard is 100%); the total potential ecological hazard risk index( RI) is between 50 and 300,and it is moderate pollution;( ii) in soil heavy metal content,only Ni and Cu are positively correlated. Since there is certain degree of Ni pollution in this deposit,the synergetic effect of Cu and Ni may deteriorate Ni pollution.展开更多
This paper presents comparative review of experimental and thermodynamic assessment of ternary Ag-Sb-Zn system. Isothermal section of the Ag-Sb-Zn system at 300 ~C has been calculated by CALPHAD method using ther- mod...This paper presents comparative review of experimental and thermodynamic assessment of ternary Ag-Sb-Zn system. Isothermal section of the Ag-Sb-Zn system at 300 ~C has been calculated by CALPHAD method using ther- modynamic parameters from literature. Microstructural analysis of a number of alloys was carried out by scanning electron microscopy and optical microscopy, whereas chemical composition of observed phases was analyzed using energy- dispersive X-ray spectroscopy. Hardness of selected alloys from four vertical sections was determined using Brinell hardness test and additionally by micro Vickers hardness test. Electrical conductivity of a number of alloys in the ternary Ag-Sb-Zn system was experimentally determined. Good overall agreement between experimental and calculated values was obtained.展开更多
1 Geological setting and samples Songxi Ag-Sb ore deposit is located in the southern margin of Yongding-Mexian Paleozoic depressionof South China Caledonian orogenic belt, and the northern margin of Zhaigang Mesozoic ...1 Geological setting and samples Songxi Ag-Sb ore deposit is located in the southern margin of Yongding-Mexian Paleozoic depressionof South China Caledonian orogenic belt, and the northern margin of Zhaigang Mesozoic volcanic basin,where a series of faults and folds formed with northwest tectonic directions. The sedimentary rocks arecomposed of Songling Group of low Jurassic system, Zhangping Group of middle Jurassic system and Quaternary System in which Songling Group can be divided into 3 lithostratigraphic units regionally, where thetwo of the units can be found there, i.e. the middle unit with gray-yellow quartz sandstone, fine sandstone and siltstone, and the upper with black shale and tuff, in which layered Ag-Sb ore bodies are deposited, and especially in the low part of quartz sandstone, siltstone, bioclastic limestone and the alteredbasalt are the main ore-bearing rocks. The ore bodies can be divided into two types of mineralization, i.e. bedded or bedded-like types and vein type.展开更多
THE Songxi Ag-Sb ore deposit is situated 28 km northeast of Meizhou city in Guangdong. It is on thenorth edge of the volcanic fault depression of the Saigangshang, which belongs to the upper Palaeozoicfault basin belt...THE Songxi Ag-Sb ore deposit is situated 28 km northeast of Meizhou city in Guangdong. It is on thenorth edge of the volcanic fault depression of the Saigangshang, which belongs to the upper Palaeozoicfault basin belt of Yong’an-Meizhou, and at the intersection of Dadong-Guidong-Jiaoling EW fault zone,Lianhuashan-Heyuan NE fault zone and Jiaoling-Shantou NW fault zone. Ag-Sb ore body occurs at thebottom of the upper part of the lower Jurassic Jingji Group (J<sub>lje-l</sub>), which is a formation of detrital rocksconsisting mainly of carbonaceous shale. 1 Geological characteristics of the ore展开更多
基金financially supported by the National Natural Science Foundation of China(No.52274352)。
文摘The modified molecular interaction volume model(M-MIVM)was used to calculate the activity values and their deviations from experimental data for Ag-Cu and Ag-Sb binary alloys.Subsequently,theoretical vapor-liquid equilibrium phase diagrams(T-x-y and p-x-y)were plotted via combining M-MIVM and vacuum theory.The vapor-liquid phase equilibrium(VLE)experiments were conducted on the Ag-Cu alloy at 1500-1560 K and 10-15 Pa and Ag-Sb alloys at 950-1350 K and 10 Pa.The results showed that the average relative deviation and average standard deviation of activity were lower than 5%and 0.02,respectively.A comparison of theoretical and experiment results for VLE revealed that the simulated data on the T-x-y diagram were well consistent with experimental values.Therefore,the VLE phase diagrams can serve as a guide in vacuum separation experiments and industrial production for Ag-Cu and Ag-Sb binary alloys.
基金Supported by Science and Technology Planning Project of Guangdong Province(2012A030700006)Key Sci-tech Innovation Project for Institutions of Higher Education in Guangdong Province(cxzd 1132)Joint Natural Science Project of Meizhou and Jiaying University(2011KJM08)
文摘In October 2012,an evaluation using potential ecological hazard risk index was carried out on soil heavy metal pollution around AgSb deposit tailing areas in northeastern Guangdong. Results indicate that( i) soil heavy metal pollution is mainly Cd-Ni compound pollution,including Cd content 0. 31- 2. 66 mg / kg( average content is 1. 11 mg / kg),the situation of exceeding standard is serious( the rate of exceeding standard is 100%); the total potential ecological hazard risk index( RI) is between 50 and 300,and it is moderate pollution;( ii) in soil heavy metal content,only Ni and Cu are positively correlated. Since there is certain degree of Ni pollution in this deposit,the synergetic effect of Cu and Ni may deteriorate Ni pollution.
基金The financial support of the Ministry of Education,Science and Technological Development of the Republic of Serbia under the Project ON172037
文摘This paper presents comparative review of experimental and thermodynamic assessment of ternary Ag-Sb-Zn system. Isothermal section of the Ag-Sb-Zn system at 300 ~C has been calculated by CALPHAD method using ther- modynamic parameters from literature. Microstructural analysis of a number of alloys was carried out by scanning electron microscopy and optical microscopy, whereas chemical composition of observed phases was analyzed using energy- dispersive X-ray spectroscopy. Hardness of selected alloys from four vertical sections was determined using Brinell hardness test and additionally by micro Vickers hardness test. Electrical conductivity of a number of alloys in the ternary Ag-Sb-Zn system was experimentally determined. Good overall agreement between experimental and calculated values was obtained.
文摘1 Geological setting and samples Songxi Ag-Sb ore deposit is located in the southern margin of Yongding-Mexian Paleozoic depressionof South China Caledonian orogenic belt, and the northern margin of Zhaigang Mesozoic volcanic basin,where a series of faults and folds formed with northwest tectonic directions. The sedimentary rocks arecomposed of Songling Group of low Jurassic system, Zhangping Group of middle Jurassic system and Quaternary System in which Songling Group can be divided into 3 lithostratigraphic units regionally, where thetwo of the units can be found there, i.e. the middle unit with gray-yellow quartz sandstone, fine sandstone and siltstone, and the upper with black shale and tuff, in which layered Ag-Sb ore bodies are deposited, and especially in the low part of quartz sandstone, siltstone, bioclastic limestone and the alteredbasalt are the main ore-bearing rocks. The ore bodies can be divided into two types of mineralization, i.e. bedded or bedded-like types and vein type.
文摘THE Songxi Ag-Sb ore deposit is situated 28 km northeast of Meizhou city in Guangdong. It is on thenorth edge of the volcanic fault depression of the Saigangshang, which belongs to the upper Palaeozoicfault basin belt of Yong’an-Meizhou, and at the intersection of Dadong-Guidong-Jiaoling EW fault zone,Lianhuashan-Heyuan NE fault zone and Jiaoling-Shantou NW fault zone. Ag-Sb ore body occurs at thebottom of the upper part of the lower Jurassic Jingji Group (J<sub>lje-l</sub>), which is a formation of detrital rocksconsisting mainly of carbonaceous shale. 1 Geological characteristics of the ore
