The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid ph...The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .展开更多
设计并合成了一种交叉共轭的(cross-conjugated)缺电子型聚合物单体——二溴代噻吩[2,3-b]并噻吩-吡咯[3,4-c]并吡咯(DPPTTZ)二酮,并将其分别与噻吩(T)、硒吩(Se)和N-甲基吡咯(Py)的双锡试剂进行共聚反应,获得了一类新的供体-受体(D-A)...设计并合成了一种交叉共轭的(cross-conjugated)缺电子型聚合物单体——二溴代噻吩[2,3-b]并噻吩-吡咯[3,4-c]并吡咯(DPPTTZ)二酮,并将其分别与噻吩(T)、硒吩(Se)和N-甲基吡咯(Py)的双锡试剂进行共聚反应,获得了一类新的供体-受体(D-A)型共轭聚合物光电材料.这类材料分子的最高占有轨道(HOMO)能级较低,因此其光电器件具有较高的开路电压(Voc),稳定性好.此外,它们在紫外-可见光区有较宽的吸收,最大吸收位于波长620 nm附近;能带隙(band gap)小,分别为1.86 e V(p DPPTTZ-T)、1.83 e V(p DPPTTZ-Se)和1.85 e V(p DPPTTZ-Py).器件初步测试结果表明,上述聚合物与PC71BM组成的本体异质结聚合物太阳能电池Voc在0.68~0.81 V之间,能量转化效率(PCE)最高达3.05%(p DPPTTZ-T).展开更多
In this paper,we report on the preparation of Li2FeSiO4,sintered Li2FeSiO4,and Li2FeSiO4-C composite with spindle-like morphologies and their application as cathode materials of lithium-ion batteries.Spindle-like Li2F...In this paper,we report on the preparation of Li2FeSiO4,sintered Li2FeSiO4,and Li2FeSiO4-C composite with spindle-like morphologies and their application as cathode materials of lithium-ion batteries.Spindle-like Li2FeSi04 was synthesized by a facile hydrothermal method with（NH4）2Fe（SO4）2 as the iron source.The spindle-like Li2FeSiO4 was sintered at 600 ℃ for 6 h in Ar atmosphere.Li2FeSiO4-C composite was obtained by the hydrothermal treatment of spindle-like Li2FeSiO4 in glucose solution at 190 ℃ for 3 h.Electrochemical measurements show that after carbon coating,the electrode performances such as discharge capacity and high-rate capability are greatly enhanced.In particular.Li2FeSiO4-C with carbon content of 7.21 wt%delivers the discharge capacities of 160.9 mAh·g-1 at room temperature and 213 mAh·g-1 at45℃（0.1 C）,revealing the potential application in lithium-ion batteries.展开更多
A series of 2,5-disubstituted pyrimido[5,4-c]quinoline derivatives were synthesized and their cytotoxic activity against H460, HT-29 and MDA-MB-231 cell lines was evaluated in vitro.It was found that most of the teste...A series of 2,5-disubstituted pyrimido[5,4-c]quinoline derivatives were synthesized and their cytotoxic activity against H460, HT-29 and MDA-MB-231 cell lines was evaluated in vitro.It was found that most of the tested compounds especially compound 17, shown stronger activity to the selected three cell lines than ZM447439.展开更多
Typically,conjugated polymers are composed of conjugated backbones and alkyl side chains.In this contribution,a cost-effective strategy of tailoring the length of alkyl side chain is utilized to design highperforming ...Typically,conjugated polymers are composed of conjugated backbones and alkyl side chains.In this contribution,a cost-effective strategy of tailoring the length of alkyl side chain is utilized to design highperforming thieno[3,4-c]pyrrole-4,6-dione(TPD)-based large bandgap polymer donors PBDT-BiTPD(Cχ)(χ=48,52,56),in which x represents the alkyl side chain length in term of the total carbon number.A combination of light absorption,device,and morphology examinations make clear that the shorter alkyl side chains yield(i) higher crystallinity and more predominant face-on crystallite orientation in their neat and BHJ blend films,(ii) higher charge mobilities(6.7×10^(-4) cm~2 V^(-1) s^(-1) for C48 vs.3.2×10^(-4) cm~2 V^(-1) s^(-1) for C56),and negligible charge recombination,consequently,(iii) significantly improved fill-factor(FF) and short current(J_(SC)),while almost the same open circuit voltage(V_(OC)) of ca.0.82 V in their corresponding BHJ devices.In parallel,as alkyl side chain lengths decrease from C56 to C48,power conversion efficiencies(PCEs) increased from 7.8% for C56 to 11.1% for C52,and further to14.1% for C48 in their BHJ solar cells made with a narrow bandgap non-fullerene acceptor Y6.This systematic study declares that shortening the side chain,if providing appropriate solubility in device solution processing solvents,is of essential significance for developing high-performing polymer donors and further improving device photovoltaic performance.展开更多
Mixed mode Ⅰ/Ⅱ fracture erperiments of LC4-CS aluminum alloy were conductedby using tension--shear specimens with thicknesses of 2, 4, 8 and 14mm. Fracturemechanisms of thickness effect on mixed mode Ⅰ/Ⅱ fracture ...Mixed mode Ⅰ/Ⅱ fracture erperiments of LC4-CS aluminum alloy were conductedby using tension--shear specimens with thicknesses of 2, 4, 8 and 14mm. Fracturemechanisms of thickness effect on mixed mode Ⅰ/Ⅱ fracture were first examined fromfracture surface morphology to correlate with the macroscopic fracture behavior andstress state. It is found that specimen thickness has a strong influence on mixed modefracture. As thickness varies from thin to thick the macroscopic fracture surfacesappear the characteristics of plane stress state (2mm, 4mm--thick specimen), three--dimensional stress state (8mm--thick specimens), and plane strain state (14mm--thickspecimens), respectively. The specimens of all kinds of thicknesses are typical of ten-sile type failure under mode Ⅰ loading condition and shear type failure under mode Ⅱloading condition. Two distinct features coexist on the fracture surfaces under mixedmode loading conditions, and the corresponding proportion varies with loading mix-ity. Void--growth processes are the failure mechanism in both predominately tensile-and shears--type fractures. The size and depth of dimples on the fracture surface varygreatly with thickness. Therefore, it is extraordinary necessary to take into accountthe thickness effect when a mixed mode fracture criterion is being established.展开更多
文摘The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University,China(IRT1238)National Natural Science Foundation of China(21275041,21235002,J1210040)+2 种基金Foundation for Innovative Research Groups of National Natural Science Foundation of China(21221003)Hunan Provincial Natural Science Foundation,China(12JJ2010)Specialized Research Fund for the Doctoral Program of Higher Education,China(20110161110009)~~
文摘设计并合成了一种交叉共轭的(cross-conjugated)缺电子型聚合物单体——二溴代噻吩[2,3-b]并噻吩-吡咯[3,4-c]并吡咯(DPPTTZ)二酮,并将其分别与噻吩(T)、硒吩(Se)和N-甲基吡咯(Py)的双锡试剂进行共聚反应,获得了一类新的供体-受体(D-A)型共轭聚合物光电材料.这类材料分子的最高占有轨道(HOMO)能级较低,因此其光电器件具有较高的开路电压(Voc),稳定性好.此外,它们在紫外-可见光区有较宽的吸收,最大吸收位于波长620 nm附近;能带隙(band gap)小,分别为1.86 e V(p DPPTTZ-T)、1.83 e V(p DPPTTZ-Se)和1.85 e V(p DPPTTZ-Py).器件初步测试结果表明,上述聚合物与PC71BM组成的本体异质结聚合物太阳能电池Voc在0.68~0.81 V之间,能量转化效率(PCE)最高达3.05%(p DPPTTZ-T).
基金supported by the Programs of National 973(2011CB935900)NSFC(21231005)+1 种基金MOE(B12015 and 113016A)the Fundamental Research Funds for the Central Universities
文摘In this paper,we report on the preparation of Li2FeSiO4,sintered Li2FeSiO4,and Li2FeSiO4-C composite with spindle-like morphologies and their application as cathode materials of lithium-ion batteries.Spindle-like Li2FeSi04 was synthesized by a facile hydrothermal method with（NH4）2Fe（SO4）2 as the iron source.The spindle-like Li2FeSiO4 was sintered at 600 ℃ for 6 h in Ar atmosphere.Li2FeSiO4-C composite was obtained by the hydrothermal treatment of spindle-like Li2FeSiO4 in glucose solution at 190 ℃ for 3 h.Electrochemical measurements show that after carbon coating,the electrode performances such as discharge capacity and high-rate capability are greatly enhanced.In particular.Li2FeSiO4-C with carbon content of 7.21 wt%delivers the discharge capacities of 160.9 mAh·g-1 at room temperature and 213 mAh·g-1 at45℃（0.1 C）,revealing the potential application in lithium-ion batteries.
基金supported by the Grant from National S & T Major Project of China(No2009ZX09301-012)
文摘A series of 2,5-disubstituted pyrimido[5,4-c]quinoline derivatives were synthesized and their cytotoxic activity against H460, HT-29 and MDA-MB-231 cell lines was evaluated in vitro.It was found that most of the tested compounds especially compound 17, shown stronger activity to the selected three cell lines than ZM447439.
基金financially supported by the National Natural Science Foundation of China (Nos. 21805097, 21671071)the Basic and Applied Basic Research Major Program of Guangdong Province (No. 2019B030302007)+2 种基金the Guangdong Natural Science Foundation (Nos. 2019A1515012137, 2016A030310428)the Guangdong Applied Science and Technology Planning Project (Nos. 2015B010135009, and 2017B090917002)the Guangzhou Science and Technology Foundation (No. 201904010361)。
文摘Typically,conjugated polymers are composed of conjugated backbones and alkyl side chains.In this contribution,a cost-effective strategy of tailoring the length of alkyl side chain is utilized to design highperforming thieno[3,4-c]pyrrole-4,6-dione(TPD)-based large bandgap polymer donors PBDT-BiTPD(Cχ)(χ=48,52,56),in which x represents the alkyl side chain length in term of the total carbon number.A combination of light absorption,device,and morphology examinations make clear that the shorter alkyl side chains yield(i) higher crystallinity and more predominant face-on crystallite orientation in their neat and BHJ blend films,(ii) higher charge mobilities(6.7×10^(-4) cm~2 V^(-1) s^(-1) for C48 vs.3.2×10^(-4) cm~2 V^(-1) s^(-1) for C56),and negligible charge recombination,consequently,(iii) significantly improved fill-factor(FF) and short current(J_(SC)),while almost the same open circuit voltage(V_(OC)) of ca.0.82 V in their corresponding BHJ devices.In parallel,as alkyl side chain lengths decrease from C56 to C48,power conversion efficiencies(PCEs) increased from 7.8% for C56 to 11.1% for C52,and further to14.1% for C48 in their BHJ solar cells made with a narrow bandgap non-fullerene acceptor Y6.This systematic study declares that shortening the side chain,if providing appropriate solubility in device solution processing solvents,is of essential significance for developing high-performing polymer donors and further improving device photovoltaic performance.
文摘Mixed mode Ⅰ/Ⅱ fracture erperiments of LC4-CS aluminum alloy were conductedby using tension--shear specimens with thicknesses of 2, 4, 8 and 14mm. Fracturemechanisms of thickness effect on mixed mode Ⅰ/Ⅱ fracture were first examined fromfracture surface morphology to correlate with the macroscopic fracture behavior andstress state. It is found that specimen thickness has a strong influence on mixed modefracture. As thickness varies from thin to thick the macroscopic fracture surfacesappear the characteristics of plane stress state (2mm, 4mm--thick specimen), three--dimensional stress state (8mm--thick specimens), and plane strain state (14mm--thickspecimens), respectively. The specimens of all kinds of thicknesses are typical of ten-sile type failure under mode Ⅰ loading condition and shear type failure under mode Ⅱloading condition. Two distinct features coexist on the fracture surfaces under mixedmode loading conditions, and the corresponding proportion varies with loading mix-ity. Void--growth processes are the failure mechanism in both predominately tensile-and shears--type fractures. The size and depth of dimples on the fracture surface varygreatly with thickness. Therefore, it is extraordinary necessary to take into accountthe thickness effect when a mixed mode fracture criterion is being established.
