Photothermal synergistic catalytic systems for treating volatile organic compounds(VOCs)have attracted signif-icant attention due to their energy efficiency and potential to reduce carbon emissions.However,the mechani...Photothermal synergistic catalytic systems for treating volatile organic compounds(VOCs)have attracted signif-icant attention due to their energy efficiency and potential to reduce carbon emissions.However,the mechanism underlying the synergistic reaction remains a critical issue.This study introduces a photothermal synergistic system for the removal of ethyl acetate(EA)by synthesizing Cu-doped OMS-2(denoted as Cu-OMS-2).Under ultraviolet-visible(UV–Vis)irradiation in a flow system,the Cu-OMS-2 catalyst exhibited significantly enhanced performance in the EA degradation process,nearly doubling the effectiveness of pure OMS-2,and increasing carbon dioxide yield by 20%.This exceptional performance is attributed to the synergistic effect of increased oxygen vacancies(OV)at OMS-2 active sites and Cu doping,as confirmed by H2-TPR,O_(2)-TPD,and CO consump-tion measurements.This study clarifies the catalytic mechanism of light-assisted thermocatalysis and offers a novel strategy for designing photothermal catalysts with homogeneous Cu-doped nanorods for VOC removal.展开更多
管道输送CO_(2)作为碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)产业链的关键环节之一,在海上CCUS发展中发挥着越来越重要的作用。高压密相CO_(2)管道泄压所造成的管道低温脆性断裂、干冰堵塞等问题,严重影响海...管道输送CO_(2)作为碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)产业链的关键环节之一,在海上CCUS发展中发挥着越来越重要的作用。高压密相CO_(2)管道泄压所造成的管道低温脆性断裂、干冰堵塞等问题,严重影响海上平台CO_(2)输送管道的安全运行。针对海上平台间高压密相CO_(2)管道,采用LedaFlow动态模拟软件建立CO_(2)输送管道泄压模型,分析海上冬季和夏季环境条件下管道沿程温度、压力和泄压量的变化趋势,并对比管道不同初始输送压力、初始输量和泄压对管道流体低温的影响情况。结果表明,冬季泄压造成的海底管道低温要比夏季泄压时低,故推荐在夏季进行泄压操作。在冬季最低环境温度条件下,适当减小泄压口径能够有效避免沿程温度、压力的大幅变化而导致的管道低温情况。研究成果可为实际海上高压密相CO_(2)输送管道的泄压操作提供参考。展开更多
A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the ph...A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.展开更多
Global investment in ethylene(C_(2)H_(4))production via nonpetroleum pathways is rising,highlighting its growing importance in the energy and environmental sectors.The electroreduction of carbon dioxide(CO_(2))to C_(2...Global investment in ethylene(C_(2)H_(4))production via nonpetroleum pathways is rising,highlighting its growing importance in the energy and environmental sectors.The electroreduction of carbon dioxide(CO_(2))to C_(2)H_(4) inflow cells is emerging as a promising technology with broad practical applications.Direct delivery of gaseous CO_(2) to the cathode catalyst layer overcomes mass transfer limitations,enhancing reaction rates and enabling high current density.This review summarizes recent research progress in the electrocatalytic CO_(2) reduction reaction(eCO_(2)RR)for selective C_(2)H_(4) production inflow cells.It outlines the principles of eCO_(2)RR to C_(2)H_(4) and discusses the influence of copper-based catalyst morphology,crystal facet,oxidation state,surface modification strategy,and synergistic effects on catalytic performance.In addition,it highlights the compositional structure of theflow cell,and the selection and optimization of operating conditions,including gas diffusion electrodes,electrolytes,ion exchange membranes,and alternative anode reaction types beyond the oxygen evolution reaction.Finally,advances in machine learning are presented for accelerating catalyst screening and predicting dynamic changes in catalysts during reduction.This comprehensive review serves as a valuable reference for the development of efficient catalysts and the construction of electrolytic devices for the electrocatalytic reduction of CO_(2) to C_(2)H_(4).展开更多
Geological CO_(2) storage is a promising strategy for reducing greenhouse gas emissions;however,its underlying multiphase reactive flow mechanisms remain poorly understood.We conducted steady-state imbibition relative...Geological CO_(2) storage is a promising strategy for reducing greenhouse gas emissions;however,its underlying multiphase reactive flow mechanisms remain poorly understood.We conducted steady-state imbibition relative permeability experiments on sandstone from a proposed storage site,comple-mented by in situ X-ray imaging and ex situ analyses using scanning electron microscopy(SEM)and energy-dispersive X-ray spectroscopy(EDS).Despite our use of a brine that was pre-equilibrated with CO_(2),there was a significant reduction in both CO_(2) relative permeability and absolute permeability during multiphase flow due to chemical reactions.This reduction was driven by decreased pore and throat sizes,diminished connectivity,and increased irregularity of pore and throat shapes,as revealed by in situ pore-scale imaging.Mineral dissolution,primarily of feldspar,albite,and calcite,along with precipitation resulting from feldspar-to-kaolinite transformation and fines migration,were identified as contributing factors through SEM-EDS analysis.This work provides a benchmark for storage in mineralogically complex sandstones,for which the impact of chemical reactions on multiphase flow properties has been measured.展开更多
The two-phase flow in porous media is affected by multiple factors.In the present study,a two-dimensional numerical model of porous media was developed using the actual pore structure of the core sample.The phase fiel...The two-phase flow in porous media is affected by multiple factors.In the present study,a two-dimensional numerical model of porous media was developed using the actual pore structure of the core sample.The phase field method was utilized to simulate the impact of displacement velocity,the water-gas viscosity ratio,and the density ratio on the flow behavior of two-phase fluids in porous media.The effectiveness of displacement was evaluated by analyzing CO_(2)saturation levels.The results indicate that the saturation of CO_(2)in porous media increased as the displacement velocity increased.When the displacement velocity exceeded 0.01 m/s,there was a corresponding increase in CO_(2)saturation.Conversely,when the displacement velocity was below this threshold,the impact on CO_(2)saturation was minimal.An“inflection point,”M3,was present in the viscosity ratio.When the viscosity of CO_(2)is less than 8.937×10^(-5)Pa·s(viscosity ratio below M3),variations in the viscosity of CO_(2)had little impact on its saturation.Conversely,when the viscosity of CO_(2)exceeded 8.937×10^(-5)Pa·s(viscosity ratio greater than M3),saturation increased with an increase in the viscosity ratio.In terms of the density ratio,the saturation of CO_(2)increased monotonically with an increase in the density ratio.Similarly,increasing density ratios resulted in a monotonic increase in CO_(2)saturation,though this trend was less pronounced in numerical simulations.Analysis results of displacement within dead-end pores using pressure and velocity diagrams reveal eddy currents as contributing factors.Finally,the impact of pore throat structure on the formation of dominant channels was examined.展开更多
This study introduces a Transformer-based multimodal fusion framework for simulating multiphase flow and heat transfer in carbon dioxide(CO_(2))–water enhanced geothermal systems(EGS).The model integrates geological ...This study introduces a Transformer-based multimodal fusion framework for simulating multiphase flow and heat transfer in carbon dioxide(CO_(2))–water enhanced geothermal systems(EGS).The model integrates geological parameters,thermal gradients,and control schedules to enable fast and accurate prediction of complex reservoir dynamics.The main contributions are:(i)development of a workflow that couples physics-based reservoir simulation with a Transformer neural network architecture,(ii)design of physics-guided loss functions to enforce conservation of mass and energy,(iii)application of the surrogate model to closed-loop optimization using a differential evolution(DE)algorithm,and(iv)incorporation of economic performance metrics,such as net present value(NPV),into decision support.The proposed framework achieves root mean square error(RMSE)of 3–5%,mean absolute error(MAE)below 4%,and coefficients of determination greater than 0.95 across multiple prediction targets,including production rates,pressure distributions,and temperature fields.When compared with recurrent neural network(RNN)baselines such as gated recurrent units(GRU)and long short-term memory networks(LSTM),as well as a physics-informed reduced-order model,the Transformer-based approach demonstrates superior accuracy and computational efficiency.Optimization experiments further show a 15–20%improvement in NPV,highlighting the framework’s potential for real-time forecasting,optimization,and decision-making in geothermal reservoir engineering.展开更多
CO_(2)capture and storage technology is favorable for the reduction of CO_(2)emissions.In recent years,a great number of research achievements have been obtained on CO_(2)geological storage from nano scale to oil/gas ...CO_(2)capture and storage technology is favorable for the reduction of CO_(2)emissions.In recent years,a great number of research achievements have been obtained on CO_(2)geological storage from nano scale to oil/gas reservoir scale,but most studies only focus on theflow behaviors in single-dimension porous media.Besides,the physical experiment method is influenced by many uncertain factors and consumes a lot of time and cost.In order to deeply understand theflow behaviors in the process of CO_(2)geological storage in microscopic view and increase the volume of CO_(2)geological storage,this paper established 2D and 3D models by using VOF(Volume of Fluid)method which can track the dynamic change of two-phase interface,to numerically simulate supercritical CO_(2)-brine two-phaseflow.Then,the distribution characteristics of CO_(2)clusters and the variation laws of CO_(2)saturation under different wettability,capillary number and viscosity ratio conditions were compared,and the intrinsic mechanisms of CO_(2)storage at pore scale were revealed.And the following research results were obtained.First,with the increase of rock wettability to CO_(2),the sweep range of CO_(2)enlarged,and the disconnection frequency of CO_(2)clusters deceased,and thus the volume of CO_(2)storage increased.Second,with the increase of capillary number,the displacement mode transformed from capillaryfingering to stable displacement,and thus the volume of CO_(2)storage increased.Third,as the viscosity of injected supercritical CO_(2)gradually approached that of brine,theflow resistance between two-phasefluids decreased,promoting the"lubricating effect".As a result,theflow capacity of CO_(2)phase was improved,and thus the volume of CO_(2)storage was increased.Fourth,the influence degrees of wettability,capillary number and viscosity ratio on CO_(2)saturation were different in multi-dimensional porous media models.In conclusion,the CO_(2)-brine two-phaseflow simulation based on VOF method revealed theflow mechanisms in the process of CO_(2)geological storage at pore scale,which is of guiding significance to the development of CCUS technology and provides theoretical guidance and technical support for the study of CO_(2)geological storage in a larger scale.展开更多
Numerical simulation has been widely applied to the assessment of debris flow hazards. In East Asia and especially Taiwan, the most widely used numerical programs are FLO-2D and Debris-aD. Although these two programs ...Numerical simulation has been widely applied to the assessment of debris flow hazards. In East Asia and especially Taiwan, the most widely used numerical programs are FLO-2D and Debris-aD. Although these two programs are applied to the same engineering tasks, they are different in many aspects. These two programs were compared according to their fundamental theories, input and output data, computational algorithms and results. Using both programs, the simulations of a real debris flow with abundant granular material induced by landslides at Xinfa village in southern Taiwan are performed for comparison. The simulation results show that Debris- 2D gives better assessment in hazard area delineating and flow depth predicting. Therefore, Debris-2D is better for simulation of granular debris flows.展开更多
Aqueous Zn-ion battery(AZIB)has become an attractive technology because of its unique features of low cost,high safety and the eco-friendliness.MnO_(2) is the model cathode material for AZIB since the first report on ...Aqueous Zn-ion battery(AZIB)has become an attractive technology because of its unique features of low cost,high safety and the eco-friendliness.MnO_(2) is the model cathode material for AZIB since the first report on reversible Zn-MnO_(2) battery,but recent studies have unveiled different charge storage mechanisms.Due to revamping of the electrochemistry and redesigning of the electrolyte and interface,there is tremendous performance enhancement in AZIB.This mini Review will first give a brief introduction of ZIB,including fundamentals of materials and components,and the progress in recent years.Then,a general classification of working mechanisms related to MnO_(2) in neutral and mildly acidic electrolyte is elaborated.Our focus is put on the recent blossoming Zn-MnO_(2) electrolytic mechanism,which has given birth to the Zn-MnO_(2) redox flow batteries that are highly promising for large-scale static energy storage.展开更多
The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount...The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/（m^3.min） and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.展开更多
In order to predict the effects of cavitation on a hydrofoil, the state equations of the cavitation model were combined with a linear viscous turbulent method for mixed fluids in the computational fluid dynamics (CFD)...In order to predict the effects of cavitation on a hydrofoil, the state equations of the cavitation model were combined with a linear viscous turbulent method for mixed fluids in the computational fluid dynamics (CFD) software FLUENT to simulate steady cavitating flow. At a fixed attack angle, pressure distributions and volume fractions of vapor at different cavitation numbers were simulated, and the results on foil sections agreed well with experimental data. In addition, at the various cavitation numbers, the vapor fractions at different attack angles were also predicted. The vapor region moved towards the front of the airfoil and the length of the cavity grew with increased attack angle. The results show that this method of applying FLUENT to simulate cavitation is reliable.展开更多
基金supported by the Qilu University of Technology(Shandong Academy of Sciences),the Basic Research Project of Science,Education and Industry Integration Pilot Project(No.2022PY047).
文摘Photothermal synergistic catalytic systems for treating volatile organic compounds(VOCs)have attracted signif-icant attention due to their energy efficiency and potential to reduce carbon emissions.However,the mechanism underlying the synergistic reaction remains a critical issue.This study introduces a photothermal synergistic system for the removal of ethyl acetate(EA)by synthesizing Cu-doped OMS-2(denoted as Cu-OMS-2).Under ultraviolet-visible(UV–Vis)irradiation in a flow system,the Cu-OMS-2 catalyst exhibited significantly enhanced performance in the EA degradation process,nearly doubling the effectiveness of pure OMS-2,and increasing carbon dioxide yield by 20%.This exceptional performance is attributed to the synergistic effect of increased oxygen vacancies(OV)at OMS-2 active sites and Cu doping,as confirmed by H2-TPR,O_(2)-TPD,and CO consump-tion measurements.This study clarifies the catalytic mechanism of light-assisted thermocatalysis and offers a novel strategy for designing photothermal catalysts with homogeneous Cu-doped nanorods for VOC removal.
文摘管道输送CO_(2)作为碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)产业链的关键环节之一,在海上CCUS发展中发挥着越来越重要的作用。高压密相CO_(2)管道泄压所造成的管道低温脆性断裂、干冰堵塞等问题,严重影响海上平台CO_(2)输送管道的安全运行。针对海上平台间高压密相CO_(2)管道,采用LedaFlow动态模拟软件建立CO_(2)输送管道泄压模型,分析海上冬季和夏季环境条件下管道沿程温度、压力和泄压量的变化趋势,并对比管道不同初始输送压力、初始输量和泄压对管道流体低温的影响情况。结果表明,冬季泄压造成的海底管道低温要比夏季泄压时低,故推荐在夏季进行泄压操作。在冬季最低环境温度条件下,适当减小泄压口径能够有效避免沿程温度、压力的大幅变化而导致的管道低温情况。研究成果可为实际海上高压密相CO_(2)输送管道的泄压操作提供参考。
基金supported by the National Key R&D Program of China(2021YFF0500703)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.
基金supported by the National Natural Science Foundation of China(22272081 and 51802160)the Startup Foundation for Introducing Talent of NUIST(S8113082001).
文摘Global investment in ethylene(C_(2)H_(4))production via nonpetroleum pathways is rising,highlighting its growing importance in the energy and environmental sectors.The electroreduction of carbon dioxide(CO_(2))to C_(2)H_(4) inflow cells is emerging as a promising technology with broad practical applications.Direct delivery of gaseous CO_(2) to the cathode catalyst layer overcomes mass transfer limitations,enhancing reaction rates and enabling high current density.This review summarizes recent research progress in the electrocatalytic CO_(2) reduction reaction(eCO_(2)RR)for selective C_(2)H_(4) production inflow cells.It outlines the principles of eCO_(2)RR to C_(2)H_(4) and discusses the influence of copper-based catalyst morphology,crystal facet,oxidation state,surface modification strategy,and synergistic effects on catalytic performance.In addition,it highlights the compositional structure of theflow cell,and the selection and optimization of operating conditions,including gas diffusion electrodes,electrolytes,ion exchange membranes,and alternative anode reaction types beyond the oxygen evolution reaction.Finally,advances in machine learning are presented for accelerating catalyst screening and predicting dynamic changes in catalysts during reduction.This comprehensive review serves as a valuable reference for the development of efficient catalysts and the construction of electrolytic devices for the electrocatalytic reduction of CO_(2) to C_(2)H_(4).
文摘Geological CO_(2) storage is a promising strategy for reducing greenhouse gas emissions;however,its underlying multiphase reactive flow mechanisms remain poorly understood.We conducted steady-state imbibition relative permeability experiments on sandstone from a proposed storage site,comple-mented by in situ X-ray imaging and ex situ analyses using scanning electron microscopy(SEM)and energy-dispersive X-ray spectroscopy(EDS).Despite our use of a brine that was pre-equilibrated with CO_(2),there was a significant reduction in both CO_(2) relative permeability and absolute permeability during multiphase flow due to chemical reactions.This reduction was driven by decreased pore and throat sizes,diminished connectivity,and increased irregularity of pore and throat shapes,as revealed by in situ pore-scale imaging.Mineral dissolution,primarily of feldspar,albite,and calcite,along with precipitation resulting from feldspar-to-kaolinite transformation and fines migration,were identified as contributing factors through SEM-EDS analysis.This work provides a benchmark for storage in mineralogically complex sandstones,for which the impact of chemical reactions on multiphase flow properties has been measured.
基金National Science Foundation of China,Grant/Award Number:5227090113Shenzhen Science and Technology Program,Grant/Award Numbers:KCXFZ20230731093901003,KCXFZ20211020163816023The Project of Hetao Shenzhen-Hong Kong Science and Technology Innovation Cooperation Zone,Grant/Award Number:HZQB-KCZYB-2020083。
文摘The two-phase flow in porous media is affected by multiple factors.In the present study,a two-dimensional numerical model of porous media was developed using the actual pore structure of the core sample.The phase field method was utilized to simulate the impact of displacement velocity,the water-gas viscosity ratio,and the density ratio on the flow behavior of two-phase fluids in porous media.The effectiveness of displacement was evaluated by analyzing CO_(2)saturation levels.The results indicate that the saturation of CO_(2)in porous media increased as the displacement velocity increased.When the displacement velocity exceeded 0.01 m/s,there was a corresponding increase in CO_(2)saturation.Conversely,when the displacement velocity was below this threshold,the impact on CO_(2)saturation was minimal.An“inflection point,”M3,was present in the viscosity ratio.When the viscosity of CO_(2)is less than 8.937×10^(-5)Pa·s(viscosity ratio below M3),variations in the viscosity of CO_(2)had little impact on its saturation.Conversely,when the viscosity of CO_(2)exceeded 8.937×10^(-5)Pa·s(viscosity ratio greater than M3),saturation increased with an increase in the viscosity ratio.In terms of the density ratio,the saturation of CO_(2)increased monotonically with an increase in the density ratio.Similarly,increasing density ratios resulted in a monotonic increase in CO_(2)saturation,though this trend was less pronounced in numerical simulations.Analysis results of displacement within dead-end pores using pressure and velocity diagrams reveal eddy currents as contributing factors.Finally,the impact of pore throat structure on the formation of dominant channels was examined.
文摘This study introduces a Transformer-based multimodal fusion framework for simulating multiphase flow and heat transfer in carbon dioxide(CO_(2))–water enhanced geothermal systems(EGS).The model integrates geological parameters,thermal gradients,and control schedules to enable fast and accurate prediction of complex reservoir dynamics.The main contributions are:(i)development of a workflow that couples physics-based reservoir simulation with a Transformer neural network architecture,(ii)design of physics-guided loss functions to enforce conservation of mass and energy,(iii)application of the surrogate model to closed-loop optimization using a differential evolution(DE)algorithm,and(iv)incorporation of economic performance metrics,such as net present value(NPV),into decision support.The proposed framework achieves root mean square error(RMSE)of 3–5%,mean absolute error(MAE)below 4%,and coefficients of determination greater than 0.95 across multiple prediction targets,including production rates,pressure distributions,and temperature fields.When compared with recurrent neural network(RNN)baselines such as gated recurrent units(GRU)and long short-term memory networks(LSTM),as well as a physics-informed reduced-order model,the Transformer-based approach demonstrates superior accuracy and computational efficiency.Optimization experiments further show a 15–20%improvement in NPV,highlighting the framework’s potential for real-time forecasting,optimization,and decision-making in geothermal reservoir engineering.
基金supported by the National Natural Science Foun-dation of China“Research on basic theory for development of deep and ultra-deep reservoirs”(No.52034010)“Flow control during drilling/production of ultra-deep oil and gas wells”(No.52288101).
文摘CO_(2)capture and storage technology is favorable for the reduction of CO_(2)emissions.In recent years,a great number of research achievements have been obtained on CO_(2)geological storage from nano scale to oil/gas reservoir scale,but most studies only focus on theflow behaviors in single-dimension porous media.Besides,the physical experiment method is influenced by many uncertain factors and consumes a lot of time and cost.In order to deeply understand theflow behaviors in the process of CO_(2)geological storage in microscopic view and increase the volume of CO_(2)geological storage,this paper established 2D and 3D models by using VOF(Volume of Fluid)method which can track the dynamic change of two-phase interface,to numerically simulate supercritical CO_(2)-brine two-phaseflow.Then,the distribution characteristics of CO_(2)clusters and the variation laws of CO_(2)saturation under different wettability,capillary number and viscosity ratio conditions were compared,and the intrinsic mechanisms of CO_(2)storage at pore scale were revealed.And the following research results were obtained.First,with the increase of rock wettability to CO_(2),the sweep range of CO_(2)enlarged,and the disconnection frequency of CO_(2)clusters deceased,and thus the volume of CO_(2)storage increased.Second,with the increase of capillary number,the displacement mode transformed from capillaryfingering to stable displacement,and thus the volume of CO_(2)storage increased.Third,as the viscosity of injected supercritical CO_(2)gradually approached that of brine,theflow resistance between two-phasefluids decreased,promoting the"lubricating effect".As a result,theflow capacity of CO_(2)phase was improved,and thus the volume of CO_(2)storage was increased.Fourth,the influence degrees of wettability,capillary number and viscosity ratio on CO_(2)saturation were different in multi-dimensional porous media models.In conclusion,the CO_(2)-brine two-phaseflow simulation based on VOF method revealed theflow mechanisms in the process of CO_(2)geological storage at pore scale,which is of guiding significance to the development of CCUS technology and provides theoretical guidance and technical support for the study of CO_(2)geological storage in a larger scale.
基金support from National Science Council of Chinese Taipei(Grant No.NSC 96-2625-Z-002-006-MY3)
文摘Numerical simulation has been widely applied to the assessment of debris flow hazards. In East Asia and especially Taiwan, the most widely used numerical programs are FLO-2D and Debris-aD. Although these two programs are applied to the same engineering tasks, they are different in many aspects. These two programs were compared according to their fundamental theories, input and output data, computational algorithms and results. Using both programs, the simulations of a real debris flow with abundant granular material induced by landslides at Xinfa village in southern Taiwan are performed for comparison. The simulation results show that Debris- 2D gives better assessment in hazard area delineating and flow depth predicting. Therefore, Debris-2D is better for simulation of granular debris flows.
基金supported by West Light Foundation of The Chinese Academy of Sciences(XAB2019AW09)Singapore Ministry of Education Tier 1 grants(RG 10/18,RG 157/19)。
文摘Aqueous Zn-ion battery(AZIB)has become an attractive technology because of its unique features of low cost,high safety and the eco-friendliness.MnO_(2) is the model cathode material for AZIB since the first report on reversible Zn-MnO_(2) battery,but recent studies have unveiled different charge storage mechanisms.Due to revamping of the electrochemistry and redesigning of the electrolyte and interface,there is tremendous performance enhancement in AZIB.This mini Review will first give a brief introduction of ZIB,including fundamentals of materials and components,and the progress in recent years.Then,a general classification of working mechanisms related to MnO_(2) in neutral and mildly acidic electrolyte is elaborated.Our focus is put on the recent blossoming Zn-MnO_(2) electrolytic mechanism,which has given birth to the Zn-MnO_(2) redox flow batteries that are highly promising for large-scale static energy storage.
基金Project supported by the Science Project of Harbin City(No. H2001-12)the Youth Foundation of School of Municipal and Environmental Engineering in Harbin Institute of Technology(No. 01306914).
文摘The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/（m^3.min） and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.
文摘In order to predict the effects of cavitation on a hydrofoil, the state equations of the cavitation model were combined with a linear viscous turbulent method for mixed fluids in the computational fluid dynamics (CFD) software FLUENT to simulate steady cavitating flow. At a fixed attack angle, pressure distributions and volume fractions of vapor at different cavitation numbers were simulated, and the results on foil sections agreed well with experimental data. In addition, at the various cavitation numbers, the vapor fractions at different attack angles were also predicted. The vapor region moved towards the front of the airfoil and the length of the cavity grew with increased attack angle. The results show that this method of applying FLUENT to simulate cavitation is reliable.
