Soil organic carbon and nitrogen are used as indexes of soil quality assessment and sustainable land use management. At the same time, soil C/N ratio is a sensitive indicator of soil quality and for assessing the carb...Soil organic carbon and nitrogen are used as indexes of soil quality assessment and sustainable land use management. At the same time, soil C/N ratio is a sensitive indicator of soil quality and for assessing the carbon and nitrogen nutrition balance of soils. We studied the characteristics of soil organic carbon and total nitrogen by investigating a large number of apple orchards in major apple production areas in China. High apple orchard soil organic carbon content was observed in the provinces of Heilongjiang, Xinjiang, and Yunnan, whereas low content was found in the provinces of Shandong, Henan, Hebei, and Shaanxi, with the values ranging between 6.44 and 7.76 g·kg-1. Similar to soil organic carbon, soil total nitrogen content also exhibited obvious differences in the 12 major apple producing provinces. Shandong apple orchard soil had the highest total nitrogen content (1.26 g·kg-1), followed by Beijing (1.23 g·kg-1). No significant difference was noted between these two regions, but their total nitrogen content was significantly higher than the other nine provinces, excluding Yunnan. The soil total nitrogen content for Xinjiang, Heilongjiang, Hebei, Henan, and Gansu was between 0.87 and 1.03 g·kg-1, which was significantly lower than that in Shandong and Beijing, but significantly higher than that in Liaoning, Shanxi, and Shaanxi. Six provinces exhibited apple orchard soil C/N ratio higher than 10, including Heilongjiang (15.42), Xinjiang (13.38), Ningxia (14.45), Liaoning (12.24), Yunnan (11.03), and Gansu (10.63). The soil C/N ratio was below 10 in the remaining six provinces, in which the highest was found in Shaanxi (9.47), followed by Beijing (8.98), Henan (7.99), and Shanxi (7.62), and the lowest was found in Hebei (6.80) and Shandong (6.05). Therefore, the improvement of soil organic carbon should be given more attention to increase the steady growth of soil C/N ratio.展开更多
目的探讨补肾壮骨汤对膝骨关节炎(knee osteoarthritis,KOA)患者总Ⅰ型前胶原氨基端前肽(total N-terminal propeptide of typeⅠprocollagen,t-PINP)、β-Ⅰ型胶原C末端肽(β-C-terminal telopeptide of typeⅠcollagen,β-CTX)的影响...目的探讨补肾壮骨汤对膝骨关节炎(knee osteoarthritis,KOA)患者总Ⅰ型前胶原氨基端前肽(total N-terminal propeptide of typeⅠprocollagen,t-PINP)、β-Ⅰ型胶原C末端肽(β-C-terminal telopeptide of typeⅠcollagen,β-CTX)的影响。方法选取2021年6月至2024年4月于杭州市临平区中医院诊治的120例肝肾亏虚型KOA患者,根据随机数字表法将其分为研究组和对照组,每组60例。对照组患者给予依托考昔和奥美拉唑口服治疗,研究组患者在对照组基础上给予补肾壮骨汤口服治疗,两组患者均持续治疗1个月。比较两组患者的临床疗效、中医证候积分、血清t-PINP和β-CTX水平、t-PINP/β-CTX、西安大略和麦克马斯特大学骨关节炎指数(Western Ontario and Mcmaster Universities osteoarthritis index,WOMAC)评分及治疗期间的不良反应。结果研究组患者的总有效率显著高于对照组(χ^(2)=4.513,P=0.034);治疗后,两组患者的中医证候积分、血清t-PINP和β-CTX水平、WOMAC各维度评分均显著低于本组治疗前,t-PINP/β-CTX均显著高于本组治疗前(P<0.05),研究组患者的中医证候积分、血清t-PINP和β-CTX水平、WOMAC各维度评分均显著低于对照组,t-PINP/β-CTX显著高于对照组(P<0.05)。两组患者的不良反应发生率比较差异无统计学意义(χ^(2)=0.686,P=0.408)。结论补肾壮骨汤可提高肝肾亏虚型KOA患者的临床疗效,缓解临床症状和疼痛,升高t-PINP/β-CTX,且不良反应发生率低。展开更多
壤全氮、土壤有机质的测定对农业生产和科学研究都有重要意义。因此在许多实验室里,土壤全氮、土壤有机质都被作为一项常规分析项目。土壤全氮量的测定百余年来沿用杜马氏法和凯氏定氮法。测定土壤有机质的方法主要有3种:干烧法、化学...壤全氮、土壤有机质的测定对农业生产和科学研究都有重要意义。因此在许多实验室里,土壤全氮、土壤有机质都被作为一项常规分析项目。土壤全氮量的测定百余年来沿用杜马氏法和凯氏定氮法。测定土壤有机质的方法主要有3种:干烧法、化学氧化法、灼烧法,1989年农业部颁布了国标GB9843-88《土壤有机质测定法》。近年来使用元素分析仪(Elementar Vario MACRO)测定土壤C、N也越来越广泛,元素分析仪是一台用于快速,定量测定元素C、H、N、S的全自动分析仪。用元素分析仪测定C、H、N的方法属于灼烧法,灼烧温度为960摄氏度,对酸性、中性土壤的测定无疑是省时准确的首选。石灰性土壤中由于碳酸盐的存在,在高温灼烧时碳酸盐分解,形成CO2,使土壤有机质的测定结果偏高。降低燃烧管温度测定(630摄氏度),由于样品用锡箔纸包裹,锡箔纸在燃烧管内燃烧生成氧化锡为放热反应,增加燃烧管内的温度高于设定温度,增加碳酸钙的分解测定值偏高,燃烧管温度设定在低于碳酸盐分解点时仪器密封不严实,使测定结果偏低。用盐酸处理土壤中碳酸盐,其后测定有机质时,因土壤中的富里酸溶于酸,使测定结果偏低。因此元素分析仪不适于石灰性土壤有机质的测定。展开更多
Transport of organic carbon via rivers to estuary is a significant geochemical proc- ess in the global carbon cycle. This paper presents bulk total organic carbon （TOC） from the Dongjiang catchment to the adjacent H...Transport of organic carbon via rivers to estuary is a significant geochemical proc- ess in the global carbon cycle. This paper presents bulk total organic carbon （TOC） from the Dongjiang catchment to the adjacent Humen outlet, and discusses the applicability of 613C and ratio of carbon to nitrogen （C/N） as indicators for sources of organic matter in the surface sediments. Survey results showed that organic carbon concentration in summer were higher than in the winter. An elevated trend of TOC occurred along the river to the Humen outlet in both surveys, and the highest mean values of dissolved and particular organic carbon （DOC-279 μmol L-1 and POC-163μmol L-1） were observed in the urban deltaic region in summer flood flow. Winter samples had a wide range of b＇13C and C/N （5-3C -24.6%o to -30.0%o, C/N 4-13）, and summer ones varied slightly （8-3C -24.2%o to -27.6%0, C/N 6-18）. As results suggest that POC in the three zones of upstream-delta-outlet dominantly came from riverbank soil, phytoplankton and agricultural C3 plants in winter, whereas main sources were from the riverbank and mangrove soil in summer. Moreover, anthropogenic sewage inputs had 11% and 7% contribution to POC in the deltaic and outlet. Transport accompanied with seasonal freshwater variation, phytoplankton production and degradation, and removal be- havior caused variation of organic carbon concentration. The results also discovered that TOC export bulk in Dongjiang was approximately one quarter of Humen flux in the dry flow, and anthropogenic activity significantly impacted the river export contribution.展开更多
The objective of this study was to determine the impact of frequency of broad-leaf crops canola and pea in various crop rotations on pH, total organic C (TOC), total organic N (TON), light fraction organic C (LFOC) an...The objective of this study was to determine the impact of frequency of broad-leaf crops canola and pea in various crop rotations on pH, total organic C (TOC), total organic N (TON), light fraction organic C (LFOC) and light fraction organic N (LFON) in the 0 - 7.5 and 7.5 - 15 cm soil depths in autumn 2009 after 12 years (1998-2009) on a Dark Brown Chernozem (Typic Boroll) loam at Scott, Saskatchewan, Canada. The field ex-periment contained monoculture canola (herbicide tolerant and blackleg resistant hybrid) and monoculture pea compared with rotations that contained these crops every 2-, 3-, and 4-yr with wheat. There was no effect of crop rotation duration and crop phase on soil pH. Mass of TOC and TON in the 0 - 15 cm soil was greater in canola phase than pea phase in the 1-yr (monoculture) and 2-yr crop rotations, while the opposite was true in the 3-yr and 4-yr crop rotations. Mass of TOC and TON (averaged across crop phases,) in soil generally increased with increasing crop rotation duration, with the maximum in the 4-yr rotation while no difference in the 1-yr and 2-yr rotations. Mass of LFOC and LFON in soil was greater in canola phase than pea phase in the 1-yr, 2-yr and 3-yr rotations, but the opposite was true in the 4-yr rotation. There was no consistent effect of crop rotation duration on mass of LFOC and LFON. The N balance sheet over the 1998 to 2009 period indicated large amounts of unaccounted N for monoculture pea, suggesting a great potential for N loss from the soil-plant system in this treatment through nitrate leaching and/or denitrification. In conclusion, the findings suggest that the quantity of organic C and N can be maximized by increasing duration of crop rotation and by including hybrid canola in the rotation.展开更多
Phosphorus loading and measurement is of concern on lands where biosolids have been applied. Traditional soil testing for plant-available P may be inadequate for the accurate assessment of P loadings in a regulatory e...Phosphorus loading and measurement is of concern on lands where biosolids have been applied. Traditional soil testing for plant-available P may be inadequate for the accurate assessment of P loadings in a regulatory environment as the reported levels may not correlate well with environmental risk. In order to accurately assess potential P runoff and leaching, as well as plant uptake, we must be able to measure organic P mineralized by the biotic community in the soil. Soils with varying rates of biosolid application were evaluated for mineralized organic P during a 112-day incubation using the difference between P measured using a rapid-flow analyzer (RFA) and an axial flow Varian ICP-OES. An increase in the P mineralized from the treated soils was observed from analysis with the Varian ICP-OES, but not with the RFA. These results confirm that even though organic P concentrations have increased due to increasing biosolid application, traditional soil testing using an RFA for detection, would not accurately portray P concentration and potential P loading from treated soils.展开更多
文摘Soil organic carbon and nitrogen are used as indexes of soil quality assessment and sustainable land use management. At the same time, soil C/N ratio is a sensitive indicator of soil quality and for assessing the carbon and nitrogen nutrition balance of soils. We studied the characteristics of soil organic carbon and total nitrogen by investigating a large number of apple orchards in major apple production areas in China. High apple orchard soil organic carbon content was observed in the provinces of Heilongjiang, Xinjiang, and Yunnan, whereas low content was found in the provinces of Shandong, Henan, Hebei, and Shaanxi, with the values ranging between 6.44 and 7.76 g·kg-1. Similar to soil organic carbon, soil total nitrogen content also exhibited obvious differences in the 12 major apple producing provinces. Shandong apple orchard soil had the highest total nitrogen content (1.26 g·kg-1), followed by Beijing (1.23 g·kg-1). No significant difference was noted between these two regions, but their total nitrogen content was significantly higher than the other nine provinces, excluding Yunnan. The soil total nitrogen content for Xinjiang, Heilongjiang, Hebei, Henan, and Gansu was between 0.87 and 1.03 g·kg-1, which was significantly lower than that in Shandong and Beijing, but significantly higher than that in Liaoning, Shanxi, and Shaanxi. Six provinces exhibited apple orchard soil C/N ratio higher than 10, including Heilongjiang (15.42), Xinjiang (13.38), Ningxia (14.45), Liaoning (12.24), Yunnan (11.03), and Gansu (10.63). The soil C/N ratio was below 10 in the remaining six provinces, in which the highest was found in Shaanxi (9.47), followed by Beijing (8.98), Henan (7.99), and Shanxi (7.62), and the lowest was found in Hebei (6.80) and Shandong (6.05). Therefore, the improvement of soil organic carbon should be given more attention to increase the steady growth of soil C/N ratio.
文摘目的探讨补肾壮骨汤对膝骨关节炎(knee osteoarthritis,KOA)患者总Ⅰ型前胶原氨基端前肽(total N-terminal propeptide of typeⅠprocollagen,t-PINP)、β-Ⅰ型胶原C末端肽(β-C-terminal telopeptide of typeⅠcollagen,β-CTX)的影响。方法选取2021年6月至2024年4月于杭州市临平区中医院诊治的120例肝肾亏虚型KOA患者,根据随机数字表法将其分为研究组和对照组,每组60例。对照组患者给予依托考昔和奥美拉唑口服治疗,研究组患者在对照组基础上给予补肾壮骨汤口服治疗,两组患者均持续治疗1个月。比较两组患者的临床疗效、中医证候积分、血清t-PINP和β-CTX水平、t-PINP/β-CTX、西安大略和麦克马斯特大学骨关节炎指数(Western Ontario and Mcmaster Universities osteoarthritis index,WOMAC)评分及治疗期间的不良反应。结果研究组患者的总有效率显著高于对照组(χ^(2)=4.513,P=0.034);治疗后,两组患者的中医证候积分、血清t-PINP和β-CTX水平、WOMAC各维度评分均显著低于本组治疗前,t-PINP/β-CTX均显著高于本组治疗前(P<0.05),研究组患者的中医证候积分、血清t-PINP和β-CTX水平、WOMAC各维度评分均显著低于对照组,t-PINP/β-CTX显著高于对照组(P<0.05)。两组患者的不良反应发生率比较差异无统计学意义(χ^(2)=0.686,P=0.408)。结论补肾壮骨汤可提高肝肾亏虚型KOA患者的临床疗效,缓解临床症状和疼痛,升高t-PINP/β-CTX,且不良反应发生率低。
文摘壤全氮、土壤有机质的测定对农业生产和科学研究都有重要意义。因此在许多实验室里,土壤全氮、土壤有机质都被作为一项常规分析项目。土壤全氮量的测定百余年来沿用杜马氏法和凯氏定氮法。测定土壤有机质的方法主要有3种:干烧法、化学氧化法、灼烧法,1989年农业部颁布了国标GB9843-88《土壤有机质测定法》。近年来使用元素分析仪(Elementar Vario MACRO)测定土壤C、N也越来越广泛,元素分析仪是一台用于快速,定量测定元素C、H、N、S的全自动分析仪。用元素分析仪测定C、H、N的方法属于灼烧法,灼烧温度为960摄氏度,对酸性、中性土壤的测定无疑是省时准确的首选。石灰性土壤中由于碳酸盐的存在,在高温灼烧时碳酸盐分解,形成CO2,使土壤有机质的测定结果偏高。降低燃烧管温度测定(630摄氏度),由于样品用锡箔纸包裹,锡箔纸在燃烧管内燃烧生成氧化锡为放热反应,增加燃烧管内的温度高于设定温度,增加碳酸钙的分解测定值偏高,燃烧管温度设定在低于碳酸盐分解点时仪器密封不严实,使测定结果偏低。用盐酸处理土壤中碳酸盐,其后测定有机质时,因土壤中的富里酸溶于酸,使测定结果偏低。因此元素分析仪不适于石灰性土壤有机质的测定。
基金National Natural Science Foundation of China, No.41101152 No.40901090+5 种基金 No.41172315 The Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry The talents in- troduced into Universities Foundation of Guangdong Province of China The China Scholarship Council （CSC） funding in 2013 The Universities Disciplinary and Special Construction Funds of Guangdong Prov- ince Foundation, No.C 10092 The Scientific Research Foundation of Graduate School of South China Nor- mal University
文摘Transport of organic carbon via rivers to estuary is a significant geochemical proc- ess in the global carbon cycle. This paper presents bulk total organic carbon （TOC） from the Dongjiang catchment to the adjacent Humen outlet, and discusses the applicability of 613C and ratio of carbon to nitrogen （C/N） as indicators for sources of organic matter in the surface sediments. Survey results showed that organic carbon concentration in summer were higher than in the winter. An elevated trend of TOC occurred along the river to the Humen outlet in both surveys, and the highest mean values of dissolved and particular organic carbon （DOC-279 μmol L-1 and POC-163μmol L-1） were observed in the urban deltaic region in summer flood flow. Winter samples had a wide range of b＇13C and C/N （5-3C -24.6%o to -30.0%o, C/N 4-13）, and summer ones varied slightly （8-3C -24.2%o to -27.6%0, C/N 6-18）. As results suggest that POC in the three zones of upstream-delta-outlet dominantly came from riverbank soil, phytoplankton and agricultural C3 plants in winter, whereas main sources were from the riverbank and mangrove soil in summer. Moreover, anthropogenic sewage inputs had 11% and 7% contribution to POC in the deltaic and outlet. Transport accompanied with seasonal freshwater variation, phytoplankton production and degradation, and removal be- havior caused variation of organic carbon concentration. The results also discovered that TOC export bulk in Dongjiang was approximately one quarter of Humen flux in the dry flow, and anthropogenic activity significantly impacted the river export contribution.
文摘The objective of this study was to determine the impact of frequency of broad-leaf crops canola and pea in various crop rotations on pH, total organic C (TOC), total organic N (TON), light fraction organic C (LFOC) and light fraction organic N (LFON) in the 0 - 7.5 and 7.5 - 15 cm soil depths in autumn 2009 after 12 years (1998-2009) on a Dark Brown Chernozem (Typic Boroll) loam at Scott, Saskatchewan, Canada. The field ex-periment contained monoculture canola (herbicide tolerant and blackleg resistant hybrid) and monoculture pea compared with rotations that contained these crops every 2-, 3-, and 4-yr with wheat. There was no effect of crop rotation duration and crop phase on soil pH. Mass of TOC and TON in the 0 - 15 cm soil was greater in canola phase than pea phase in the 1-yr (monoculture) and 2-yr crop rotations, while the opposite was true in the 3-yr and 4-yr crop rotations. Mass of TOC and TON (averaged across crop phases,) in soil generally increased with increasing crop rotation duration, with the maximum in the 4-yr rotation while no difference in the 1-yr and 2-yr rotations. Mass of LFOC and LFON in soil was greater in canola phase than pea phase in the 1-yr, 2-yr and 3-yr rotations, but the opposite was true in the 4-yr rotation. There was no consistent effect of crop rotation duration on mass of LFOC and LFON. The N balance sheet over the 1998 to 2009 period indicated large amounts of unaccounted N for monoculture pea, suggesting a great potential for N loss from the soil-plant system in this treatment through nitrate leaching and/or denitrification. In conclusion, the findings suggest that the quantity of organic C and N can be maximized by increasing duration of crop rotation and by including hybrid canola in the rotation.
文摘Phosphorus loading and measurement is of concern on lands where biosolids have been applied. Traditional soil testing for plant-available P may be inadequate for the accurate assessment of P loadings in a regulatory environment as the reported levels may not correlate well with environmental risk. In order to accurately assess potential P runoff and leaching, as well as plant uptake, we must be able to measure organic P mineralized by the biotic community in the soil. Soils with varying rates of biosolid application were evaluated for mineralized organic P during a 112-day incubation using the difference between P measured using a rapid-flow analyzer (RFA) and an axial flow Varian ICP-OES. An increase in the P mineralized from the treated soils was observed from analysis with the Varian ICP-OES, but not with the RFA. These results confirm that even though organic P concentrations have increased due to increasing biosolid application, traditional soil testing using an RFA for detection, would not accurately portray P concentration and potential P loading from treated soils.
