To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ me...To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ method for synthesising Au nanoparticles on ZIF-67.In this study,an Au@ZIF-67 composite humidity-sensitive material was combined with flexible polyethylene terephthalate interdigitated electrodes to create an Au@ZIF-67 flexible humidity sensor.The prepared samples were characterised using X-ray diffraction,X-ray photoelectron spectroscopy,and transmission electron microscopy.The humidity-sensitive properties of the sensor were investigated,and its monitoring capabilities in applications involving respiration,gestures,skin,and baby diapers were tested.The experimental results indicate that compared with a pure ZIF-67 humidity sensor,the Au@ZIF-67(0.1Au@Z)flexible humidity sensor exhibits a 158.07%decrease in baseline resistance and a 51.66%increase in sensitivity to 95%relative humidity,and the hysteresis,response time,and recovery time are significantly reduced.Furthermore,the sensor exhibits excellent characteristics such as high resolution,repeatability,and stability.The obtained results regarding the material properties,humidity sensitivity,and practical application of non-contact humidity monitoring demonstrate that the prepared sensors exhibit excellent and comprehensive performance,indicating their broad prospects in wearable medical devices,wireless Internet of Things,humidity detection in complex environments,and intelligent integrated systems.展开更多
Position sensitive device(PSD)sensor is a vital optical element that is mainly used in tracking systems for visible light communication(VLC).Recently,a new reconfigurable PSD architecture emerged.The proposed architec...Position sensitive device(PSD)sensor is a vital optical element that is mainly used in tracking systems for visible light communication(VLC).Recently,a new reconfigurable PSD architecture emerged.The proposed architecture makes the PSD perform more functions by modifying its architecture.As the PSD is mainly formed of an array of photodiodes.The primary concept involves employing transistors to alternate between the operating modes of the photodiodes(photoconductive and photovoltaic).Additionally,alternating among output pins can be done based on the required function.This paper presents the mathematical modeling and simulation of a reconfigurable-multifunctional optical sensor which can perform energy harvesting and data acquisition,as well as positioning,which is not available in the traditional PSDs.Simulation using the MATLAB software tool was achieved to demonstrate the modeling.The simulation results confirmed the validity of the mathematical modeling and proved that the modified sensor architecture,as depicted by the equations,accurately describes its behavior.The proposed sensor is expected to extend the battery's lifecycle,reduce its physical size,and increase the integration and functionality of the system.The presented sensor might be used in free space optical(FSO)communication like cube satellites or even in underwater wireless optical communication(UWOC).展开更多
Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexib...Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexible fiber sensors.Through the preform-tofiber manufacturing technique,a variety of fiber sensors with complex functionalities spanning from the nanoscale to kilometer scale can be automated in a short time.Examples include temperature,acoustic,mechanical,chemical,biological,optoelectronic,and multifunctional sensors,which operate on diverse sensing principles such as resistance,capacitance,piezoelectricity,triboelectricity,photoelectricity,and thermoelectricity.This review outlines the principles of the thermal drawing process and provides a detailed overview of the latest advancements in various thermally drawn fiber sensors.Finally,the future developments of thermally drawn fiber sensors are discussed.展开更多
Hydrogel strain sensors represent an importan development for research into flexible electronics,being able to convert external stimuli into easily monitored electrical signals.However,finding simple and rapid prepara...Hydrogel strain sensors represent an importan development for research into flexible electronics,being able to convert external stimuli into easily monitored electrical signals.However,finding simple and rapid preparation methods,as well as ensuring compatibility between conductive fillers and the polymer matrix are stil the main challenges for conductive hydrogel applications In this work,we utilize MXene to coat liquid metal dro plets that have been broken by ultrasound while incorpo rating cellulose nanofibers to make them stably dispersed Electron paramagnetic resonance spectroscopy revealed that the obtained composite filler could catalyze the releas of additional hydroxyl radicals from ammonium persulfat to enable the rapid gelation of acrylic acid under ambien conditions.This unique property allows for the mold-based fabrication of hydrogels in various shapes,and we also explored the use of microfluidic devices for printing.Th conductive hydrogels showed good tensile properties small hysteresis loops,high self-healing efficiency(97%conductive recovery),and antimicrobial properties.When assembled into flexible sensors,the hydrogel can accu rately monitor body movements with stable repeatability The outstanding characteristics of the hydrogel not only offer a material basis for the development of novel flexibl sensors,but also have the potential for rapid,large-scale and customized preparation through fast gelation.展开更多
Monitoring biogenic amines,which are metabolic byproducts of shrimp spoilage,is crucial for assessing food quality.Currently,most detection methods for biogenic amines suffer from limitations such as time-consuming pr...Monitoring biogenic amines,which are metabolic byproducts of shrimp spoilage,is crucial for assessing food quality.Currently,most detection methods for biogenic amines suffer from limitations such as time-consuming procedures,complex operations,and delayed results.Colorimetric analysis techniques have gained attention in recent years due to their advantages of short analysis time,simple operation,and suitability for on-site testing.This study successfully developed a series of colorimetric sensor platforms for biogenic amines by loading the natural active ingredient curcumin(CUR)and its derivative of Boron complex BFCUR onto filter paper and electrospun nanofibre films(ENFs),respectively.By analyzing the color response differences of these sensors upon contact with biogenic amines,the colorimetric sensors with superior detection performance were selected and further applied to the visual monitoring and indication of shrimp spoilage processes.展开更多
The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recogni...The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.展开更多
Tactile sensing of subcutaneous organ vibrations provides a promising route toward human-machine interfaces and wear-able diagnostics,particularly for voice rehabilitation and silent-speech communication.Here,we prese...Tactile sensing of subcutaneous organ vibrations provides a promising route toward human-machine interfaces and wear-able diagnostics,particularly for voice rehabilitation and silent-speech communication.Here,we present a bioinspired piezoelectric vibration sensor that mimics the graded stiffness and stress-based transduction mechanism of otolithic cilia in the human vestibular system.The device consists of a trapezoidal cantilever array with tip inertial masses,fabricated through a hybrid stereolithography 3D printing and laser micromachining process for rapid prototyping without cleanroom facilities.Finite-element modeling and experimental measurements demonstrate a fundamental resonance near 1.2 kHz,a 5%flat-bandwidth of 350 Hz,and an in-band charge sensitivity of 3.17 pC/g.A wearable proof-of-concept test further verifies the sensor's ability to reproducibly distinguish phoneme-specific vibration patterns in both time and frequency domains.This work establishes a foundation for bioinspired tactile sensing front-ends in wearable voice interfaces and other intelligent diagnostic systems integrated with machine-learning algorithms.展开更多
Dear Editor,This letter presents a new approach to developing interpretable and reliable soft sensors for Industry 5.0 applications.Although sophisticated machine learning methods have made remarkable strides in soft-...Dear Editor,This letter presents a new approach to developing interpretable and reliable soft sensors for Industry 5.0 applications.Although sophisticated machine learning methods have made remarkable strides in soft-sensor predictive accuracy,ensuring interpretability and reliable performance across varying industrial operating conditions remains a challenge[1]–[4].This is precisely what Industry 5.0,proposed by the European Commission in 2021,advocates[5],[6].It integrates various cutting-edge technologies,such as human-machine interaction,digital twins,cybersecurity and artificial intelligence,to facilitate the development of better soft sensors.展开更多
Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations...Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations remain in unit-level reconfiguration,multiaxial force and motion sensing,and robust operation across dynamically changing or irregular surfaces.Herein,we develop a reconfigurable omnidirectional triboelectric whisker sensor array(RO-TWSA)comprising multiple sensing units that integrate a triboelectric whisker structure(TWS)with an untethered hydro-sealing vacuum sucker(UHSVS),enabling reversibly portable deployment and omnidirectional perception across diverse surfaces.Using a simple dual-triangular electrode layout paired with MXene/silicone nanocomposite dielectric layer,the sensor unit achieves precise omnidirectional force and motion sensing with a detection threshold as low as 0.024 N and an angular resolution of 5°,while the UHSVS provides reliable and reversible multi-surface anchoring for the sensor units by involving a newly designed hydrogel combining high mechanical robustness and superior water absorption.Extensive experiments demonstrate the effectiveness of RO-TWSA across various interactive scenarios,including teleoperation,tactile diagnostics,and robotic autonomous exploration.Overall,RO-TWSA presents a versatile and high-resolution tactile interface,offering new avenues for intelligent perception and interaction in complex real-world environments.展开更多
This survey presents a comprehensive examination of sensor fusion research spanning four decades,tracing the methodological evolution,application domains,and alignment with classical hierarchical models.Building on th...This survey presents a comprehensive examination of sensor fusion research spanning four decades,tracing the methodological evolution,application domains,and alignment with classical hierarchical models.Building on this long-term trajectory,the foundational approaches such as probabilistic inference,early neural networks,rulebasedmethods,and feature-level fusion established the principles of uncertainty handling andmulti-sensor integration in the 1990s.The fusion methods of 2000s marked the consolidation of these ideas through advanced Kalman and particle filtering,Bayesian–Dempster–Shafer hybrids,distributed consensus algorithms,and machine learning ensembles for more robust and domain-specific implementations.From 2011 to 2020,the widespread adoption of deep learning transformed the field driving some major breakthroughs in the autonomous vehicles domain.A key contribution of this work is the assessment of contemporary methods against the JDL model,revealing gaps at higher levels-especially in situation and impact assessment.Contemporary methods offer only limited implementation of higher-level fusion.The survey also reviews the benchmark multi-sensor datasets,noting their role in advancing the field while identifying major shortcomings like the lack of domain diversity and hierarchical coverage.By synthesizing developments across decades and paradigms,this survey provides both a historical narrative and a forward-looking perspective.It highlights unresolved challenges in transparency,scalability,robustness,and trustworthiness,while identifying emerging paradigms such as neuromorphic fusion and explainable AI as promising directions.This paves the way forward for advancing sensor fusion towards transparent and adaptive next-generation autonomous systems.展开更多
Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bot...Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bottleneck,severely affecting device stability and long-term operational performance.Herein,we present a multifunctional strategy by incorporating highly thermally conductive Ti_(3)C_(2)T_(X) MXene nanosheets into the perovskite layer to simultaneously enhance thermal management and optoelectronic properties.The Ti_(3)C_(2)T_(X) nanosheets,embedded at perovskite grain boundaries,construct efficient thermal conduction pathways,significantly improving the thermal conductivity and diffusivity of the film.This leads to a notable reduction in the device’s steady-state operating temperature from 42.96 to 39.97 under 100 mW cm^(−2) illumination,thereby alleviating heat-induced performance degradation.Beyond thermal regulation,Ti_(3)C_(2)T_(X),with high conductivity and negatively charged surface terminations,also serves as an effective defect passivation agent,reducing trap-assisted recombination,while simultaneously facilitating charge extraction and transport by optimizing interfacial energy alignment.As a result,the Ti_(3)C_(2)T_(X)-modified PSC achieve a champion PCE of 25.13%and exhibit outstanding thermal stability,retaining 80%of the initial PCE after 500 h of thermal aging at 85 and 30±5%relative humidity.(In contrast,control PSC retain only 58%after 200 h.)Moreover,under continuous maximum power point tracking in N2 atmosphere,Ti_(3)C_(2)T_(X)-modified PSC retained 70%of the initial PCE after 500 h,whereas the control PSC drop sharply to 20%.These findings highlight the synergistic role of Ti_(3)C_(2)T_(X) in thermal management and optoelectronic performance,paving the way for the development of high-efficiency and heat-resistant perovskite photovoltaics.展开更多
Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ion...Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ionic liquid(IL),using 1-ethyl-3-methylimidazolium bromide([EMIM]Br)IL as solvent.Benefiting from the compatibility of ILs and alkene-PR,the cross-linked network slide-ring gel not only maintains excellent conductivity(1.52×10^(−2) S/m),but also has effectively improved mechanical properties(513%fracture strain,0.713 MPa fracture stress,211 kPa elastic modulus and 1366 kJ/m^(3) toughness)and adhesive properties(472.3±25.9 kPa).The supramolecular gel can be used as a strain sensor to efficiently monitor deformation signals in real-time at least 200 times.Especially,the slide-ring gel can self-power generated by triboelectric effect and electrostatic induction between the skin layer and the polydimethylsiloxane(PDMS)layer that encapsulates the gel,achieving reversible and durable motion sensing,which provides a convenient pathway for constructing supramolecular self-powered flexible electronic materials.展开更多
Formation control of multiple spacecraft has attracted extensive research attention.However,achieving reliable performance under sensor failures remains a significant challenge.This paper develops an integrated framew...Formation control of multiple spacecraft has attracted extensive research attention.However,achieving reliable performance under sensor failures remains a significant challenge.This paper develops an integrated framework that jointly designs distributed observers and local controllers to ensure robust formation control in the presence of external disturbances and sensor malfunctions.Treating the spacecraft formation as a single interconnected system,each spacecraft constructs a distributed observer that estimates the overall system state by incorporating both its own measurements and the predicted control information shared among the spacecraft.Based on the observer estimates,a local control law is synthesized to maintain the desired formation.Rigorous theoretical analysis and numerical simulations demonstrate that the proposed integrated approach effectively guarantees formation stability and resilience against sensor failures and disturbances.展开更多
Wearable sensors integrated with deep learning techniques have the potential to revolutionize seamless human-machine interfaces for real-time health monitoring,clinical diagnosis,and robotic applications.Nevertheless,...Wearable sensors integrated with deep learning techniques have the potential to revolutionize seamless human-machine interfaces for real-time health monitoring,clinical diagnosis,and robotic applications.Nevertheless,it remains a critical challenge to simultaneously achieve desirable mechanical and electrical performance along with biocompatibility,adhesion,self-healing,and environmental robustness with excellent sensing metrics.Herein,we report a multifunctional,anti-freezing,selfadhesive,and self-healable organogel pressure sensor composed of cobalt nanoparticle encapsulated nitrogen-doped carbon nanotubes(CoN CNT)embedded in a polyvinyl alcohol-gelatin(PVA/GLE)matrix.Fabricated using a binary solvent system of water and ethylene glycol(EG),the CoN CNT/PVA/GLE organogel exhibits excellent flexibility,biocompatibility,and temperature tolerance with remarkable environmental stability.Electrochemical impedance spectroscopy confirms near-stable performance across a broad humidity range(40%-95%RH).Freeze-tolerant conductivity under sub-zero conditions(-20℃)is attributed to the synergistic role of CoN CNT and EG,preserving mobility and network integrity.The Co N CNT/PVA/GLE organogel sensor exhibits high sensitivity of 5.75 k Pa^(-1)in the detection range from 0 to 20 k Pa,ideal for subtle biomechanical motion detection.A smart human-machine interface for English letter recognition using deep learning achieved 98%accuracy.The organogel sensor utility was extended to detect human gestures like finger bending,wrist motion,and throat vibration during speech.展开更多
Silicone-based pressure-sensitive adhesives(Si-PSAs)are valued for their thermal stability,flexibility,and biocompatibility,but their weak bonding strength restricts high-performance use.Polyurethane-modified Si-PSAs ...Silicone-based pressure-sensitive adhesives(Si-PSAs)are valued for their thermal stability,flexibility,and biocompatibility,but their weak bonding strength restricts high-performance use.Polyurethane-modified Si-PSAs enhance adhesion,however diisocyanates remain essential.The raw materials of isocyanates are toxic,and their synthesis involves phosgene.To make up for those shortcomings,a series of poly(hydroxy urethane-siloxane)PSAs,named as PHUSi here,were synthesized through the ring-opening reaction of cyclic carbonate-functionalized polysiloxanes(PSi_(x)-VEC_(z))with various aliphatic diamines.The PSi_(x)-VEC_(z) precursors were prepared via the hydrosilylation of hydrogen-containing polysiloxanes(PSi_(x)-H_(y))with 4-vinyl-1,3-dioxolan-2-one(VEC).The chemical structures of PSi_(x)-H_(y),PSi_(x)-VEC_(z) and PHUSi were characterized,and bonding properties of PHUSi were systematically evaluated.The influence of architectures on adhesive performance was elucidated through comprehensive analyses,including rheology,crosslink density assessment,and so on.These studies revealed that the tailored design of PHUSi adhesives combine the advantages of traditional Si-PSAs with enhanced adhesion while eliminating isocyanate toxicity.The optimized PHUSi formulation achieved remarkable 180°peel strength(76.5 N/m on skin)and maximum probe tack force(1.61 N),enabling secure 24 h attachment of flexible sensors to skin.These properties make PHUSi particularly suitable for medical applications,as demonstrated by successful implementation in flexible electrocardiogram devices,offering a biocompatible,high-performance adhesive.展开更多
As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and el...As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.展开更多
Gas sensors are valuable tools for human applications,and extensive research has been conducted in this field.However,practical implementation has yet to be fully realized.In response,efforts have been made to explore...Gas sensors are valuable tools for human applications,and extensive research has been conducted in this field.However,practical implementation has yet to be fully realized.In response,efforts have been made to explore metal-organic frameworks(MOFs),a novel class of porous materials,as potential solutions.MOFs exhibit exceptional porosity and highly tunable chemical compositions and structures,giving rise to a wide range of unique physical and chemical properties.Significant progress has been achieved in developing MOF-based gas sensors,improving sensing performance for various gases.This review aims to provide a comprehensive understanding of MOF-based gas sensors,even for readers unfamiliar with MOFs and gas sensors.It covers the working principles of these sensors,fundamental concepts of MOFs,strategies for tuning MOF properties,fabrication techniques for MOF films,and recent studies on MOF and MOF-derivative gas sensors.Finally,current challenges,overlooked aspects,and future directions for fully exploiting the potential of MOFs in gas sensor development are discussed.展开更多
Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu prov...Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu province,a national leader in both economic and agricultural development,as a case area to construct a multidimensional framework for assessing the recessive morphological characteristics of multifunctional cultivated land use.We examine temporal dynamics,spatial heterogeneity,and propose an integrated zoning strategy based on empirical analysis.The results reveal that:(1)The recessive morphology index shows a consistent upward trend,with structural breaks in 2007 and 2013,and a spatial shift from“higher in the east and lower in the west”to“higher in the south and lower in the north.”(2)Coordination among sub-dimensions of the index has steadily improved.(3)The index is expected to continue rising in the next decade,though at a slower pace.(4)To promote coordinated multidimensional land-use development,we recommend a policy framework that reinforces existing strengths,addresses weaknesses,and adapts zoning schemes to current spatial conditions.This research offers new insights into multifunctional cultivated land systems and underscores their role in enhancing human well-being,securing food supply,and supporting sustainable urban-rural integration.展开更多
With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption ar...With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.展开更多
The development of intrinsically conductive piezoresistive sensors with high strain tolerance has garnered significant interest.While elastomeric polymers exhibit excellent strain capabilities,their utility in sensing...The development of intrinsically conductive piezoresistive sensors with high strain tolerance has garnered significant interest.While elastomeric polymers exhibit excellent strain capabilities,their utility in sensing applications has been limited by inherent challenges such as high electrical resistivity,poor aging resistance,and interfacial incompatibility.To address these limitations,hydroxyl-terminated polybutadiene(HTPB)-based polyurethane was chemically modified with acetylferrocene-polyaniline conductive moieties to enhance charge transport properties.Remarkably,this covalent functionalization endowed the resulting ferrocene-polyaniline hybrid polyurethane(FPHP)with a conductivity of2.33 n A at 1 V bias while preserving piezoresistive functionality.The FPHP demonstrated exceptional mechanical-electrical performance,achieving 254% elongation at break with strain-dependent gauge factors of 7.28(0%-12.5% strain,R^(2)=0.9504)and 19.66(12.5%-35.0% strain,R^(2)=0.9929).Further characterization revealed a rapid 0.60 s response time and stability over 3500 strain-release cycles at compression strain,underscoring its durability under repetitive loading.The FPHP sensor was capable of monitoring various human movements and recognizing writing signals.These advances establish a materials design paradigm for fabricating flexible sensors that synergistically integrate high deformability,tunable sensitivity,and robust operational stability,positioning FPHP as a promising candidate for next-generation wearable electronics and soft robotics.展开更多
基金supported by the Natural Science Project of Zhengzhou Science and Technology Bureau(No.21ZZXTCX12)the Key Research and Development Program of Henan Province(No.221111220300)+1 种基金the Key Program of the National Natural Science Foundation of China(No.62333013)the Youth Backbone Teacher Training Program of Henan University of Technology(No.21420154).
文摘To facilitate real-time monitoring and recording of humidity in the environment and to satisfy the requirement for strain performance in certain applications(such as wearable devices),this paper proposes an in-situ method for synthesising Au nanoparticles on ZIF-67.In this study,an Au@ZIF-67 composite humidity-sensitive material was combined with flexible polyethylene terephthalate interdigitated electrodes to create an Au@ZIF-67 flexible humidity sensor.The prepared samples were characterised using X-ray diffraction,X-ray photoelectron spectroscopy,and transmission electron microscopy.The humidity-sensitive properties of the sensor were investigated,and its monitoring capabilities in applications involving respiration,gestures,skin,and baby diapers were tested.The experimental results indicate that compared with a pure ZIF-67 humidity sensor,the Au@ZIF-67(0.1Au@Z)flexible humidity sensor exhibits a 158.07%decrease in baseline resistance and a 51.66%increase in sensitivity to 95%relative humidity,and the hysteresis,response time,and recovery time are significantly reduced.Furthermore,the sensor exhibits excellent characteristics such as high resolution,repeatability,and stability.The obtained results regarding the material properties,humidity sensitivity,and practical application of non-contact humidity monitoring demonstrate that the prepared sensors exhibit excellent and comprehensive performance,indicating their broad prospects in wearable medical devices,wireless Internet of Things,humidity detection in complex environments,and intelligent integrated systems.
文摘Position sensitive device(PSD)sensor is a vital optical element that is mainly used in tracking systems for visible light communication(VLC).Recently,a new reconfigurable PSD architecture emerged.The proposed architecture makes the PSD perform more functions by modifying its architecture.As the PSD is mainly formed of an array of photodiodes.The primary concept involves employing transistors to alternate between the operating modes of the photodiodes(photoconductive and photovoltaic).Additionally,alternating among output pins can be done based on the required function.This paper presents the mathematical modeling and simulation of a reconfigurable-multifunctional optical sensor which can perform energy harvesting and data acquisition,as well as positioning,which is not available in the traditional PSDs.Simulation using the MATLAB software tool was achieved to demonstrate the modeling.The simulation results confirmed the validity of the mathematical modeling and proved that the modified sensor architecture,as depicted by the equations,accurately describes its behavior.The proposed sensor is expected to extend the battery's lifecycle,reduce its physical size,and increase the integration and functionality of the system.The presented sensor might be used in free space optical(FSO)communication like cube satellites or even in underwater wireless optical communication(UWOC).
基金supported by the National Key Research and Development Program of China(2023YFB3809800)the National Natural Science Foundation of China(52172249,52525601)+2 种基金the Chinese Academy of Sciences Talents Program(E2290701)the Jiangsu Province Talents Program(JSSCRC2023545)the Special Fund Project of Carbon Peaking Carbon Neutrality Science and Technology Innovation of Jiangsu Province(BE2022011).
文摘Flexible fiber sensors,However,traditional methods face challenges in fabricating low-cost,large-scale fiber sensors.In recent years,the thermal drawing process has rapidly advanced,offering a novel approach to flexible fiber sensors.Through the preform-tofiber manufacturing technique,a variety of fiber sensors with complex functionalities spanning from the nanoscale to kilometer scale can be automated in a short time.Examples include temperature,acoustic,mechanical,chemical,biological,optoelectronic,and multifunctional sensors,which operate on diverse sensing principles such as resistance,capacitance,piezoelectricity,triboelectricity,photoelectricity,and thermoelectricity.This review outlines the principles of the thermal drawing process and provides a detailed overview of the latest advancements in various thermally drawn fiber sensors.Finally,the future developments of thermally drawn fiber sensors are discussed.
基金financially supported by China Scholarship Council program(No.202306380028)the National Natural Science Foundation of China(No.11204097)+3 种基金the Spanish Ministry of Science(Nos.RYC2020-945030119-I and PID2023-151682NA-I00 funded by MCIN/AEI/10.13039/501100011033/and FEDER)Unidades de Excelencia Maria de Maeztu 2021(No.CEX2021-001202-M)the Spanish Ministry of Science,Innovation and Universities(MCIU),State Bureau of Investigation(AIE),the European Regional Development Fund(FEDER)(No.PGC2018-096958-B-I00)the Catalonian Government(No.2021 SGR00646)
文摘Hydrogel strain sensors represent an importan development for research into flexible electronics,being able to convert external stimuli into easily monitored electrical signals.However,finding simple and rapid preparation methods,as well as ensuring compatibility between conductive fillers and the polymer matrix are stil the main challenges for conductive hydrogel applications In this work,we utilize MXene to coat liquid metal dro plets that have been broken by ultrasound while incorpo rating cellulose nanofibers to make them stably dispersed Electron paramagnetic resonance spectroscopy revealed that the obtained composite filler could catalyze the releas of additional hydroxyl radicals from ammonium persulfat to enable the rapid gelation of acrylic acid under ambien conditions.This unique property allows for the mold-based fabrication of hydrogels in various shapes,and we also explored the use of microfluidic devices for printing.Th conductive hydrogels showed good tensile properties small hysteresis loops,high self-healing efficiency(97%conductive recovery),and antimicrobial properties.When assembled into flexible sensors,the hydrogel can accu rately monitor body movements with stable repeatability The outstanding characteristics of the hydrogel not only offer a material basis for the development of novel flexibl sensors,but also have the potential for rapid,large-scale and customized preparation through fast gelation.
基金Supported by the Guangdong-Hong Kong-Macao Joint Laboratory on Micro-Nano Manufacturing Technology,China(No.2021LSYS004)Guangdong Provincial Key Laboratory of Sustainable Biomimetic Materials and Green Energy,China(No.2024B1212010003)。
文摘Monitoring biogenic amines,which are metabolic byproducts of shrimp spoilage,is crucial for assessing food quality.Currently,most detection methods for biogenic amines suffer from limitations such as time-consuming procedures,complex operations,and delayed results.Colorimetric analysis techniques have gained attention in recent years due to their advantages of short analysis time,simple operation,and suitability for on-site testing.This study successfully developed a series of colorimetric sensor platforms for biogenic amines by loading the natural active ingredient curcumin(CUR)and its derivative of Boron complex BFCUR onto filter paper and electrospun nanofibre films(ENFs),respectively.By analyzing the color response differences of these sensors upon contact with biogenic amines,the colorimetric sensors with superior detection performance were selected and further applied to the visual monitoring and indication of shrimp spoilage processes.
文摘The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.
文摘Tactile sensing of subcutaneous organ vibrations provides a promising route toward human-machine interfaces and wear-able diagnostics,particularly for voice rehabilitation and silent-speech communication.Here,we present a bioinspired piezoelectric vibration sensor that mimics the graded stiffness and stress-based transduction mechanism of otolithic cilia in the human vestibular system.The device consists of a trapezoidal cantilever array with tip inertial masses,fabricated through a hybrid stereolithography 3D printing and laser micromachining process for rapid prototyping without cleanroom facilities.Finite-element modeling and experimental measurements demonstrate a fundamental resonance near 1.2 kHz,a 5%flat-bandwidth of 350 Hz,and an in-band charge sensitivity of 3.17 pC/g.A wearable proof-of-concept test further verifies the sensor's ability to reproducibly distinguish phoneme-specific vibration patterns in both time and frequency domains.This work establishes a foundation for bioinspired tactile sensing front-ends in wearable voice interfaces and other intelligent diagnostic systems integrated with machine-learning algorithms.
文摘Dear Editor,This letter presents a new approach to developing interpretable and reliable soft sensors for Industry 5.0 applications.Although sophisticated machine learning methods have made remarkable strides in soft-sensor predictive accuracy,ensuring interpretability and reliable performance across varying industrial operating conditions remains a challenge[1]–[4].This is precisely what Industry 5.0,proposed by the European Commission in 2021,advocates[5],[6].It integrates various cutting-edge technologies,such as human-machine interaction,digital twins,cybersecurity and artificial intelligence,to facilitate the development of better soft sensors.
基金supported by the National Natural Science Foundation of China(General Program)under Grant 52571385National Key R&D Program of China(Grant No.2024YFC2815000 and No.2024YFB3816000)+12 种基金Open Fund of State Key Laboratory of Deep-sea Manned Vehicles(Grant No.2025SKLDMV07)Shenzhen Science and Technology Program(WDZC20231128114452001,JCYJ20240813112107010 and JCYJ20240813111910014)the Tsinghua SIGS Scientific Research Startup Fund(QD2022021C)the Dreams Foundation of Jianghuai Advance Technology Center(2023-ZM 01 Z006)the Ocean Decade International Cooperation Center(ODCC)(GHZZ3702840002024020000026)Shenzhen Key Laboratory of Advanced Technology for Marine Ecology(ZDSYS20230626091459009)Shenzhen Science and Technology Program(No.KJZD20240903100905008)the National Natural Science Foundation of China(No.22305141)Pearl River Talent Program(No.2023QN10C114)General Program of Guangdong Province(No.2025A1515011700)the Guangdong Innovative and Entrepreneurial Research Team Program(2023ZT10C040)Scientific Research Foundation from Shenzhen Finance Bureau(No.GJHZ20240218113600002)Tsinghua University(JC2023001).
文摘Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations remain in unit-level reconfiguration,multiaxial force and motion sensing,and robust operation across dynamically changing or irregular surfaces.Herein,we develop a reconfigurable omnidirectional triboelectric whisker sensor array(RO-TWSA)comprising multiple sensing units that integrate a triboelectric whisker structure(TWS)with an untethered hydro-sealing vacuum sucker(UHSVS),enabling reversibly portable deployment and omnidirectional perception across diverse surfaces.Using a simple dual-triangular electrode layout paired with MXene/silicone nanocomposite dielectric layer,the sensor unit achieves precise omnidirectional force and motion sensing with a detection threshold as low as 0.024 N and an angular resolution of 5°,while the UHSVS provides reliable and reversible multi-surface anchoring for the sensor units by involving a newly designed hydrogel combining high mechanical robustness and superior water absorption.Extensive experiments demonstrate the effectiveness of RO-TWSA across various interactive scenarios,including teleoperation,tactile diagnostics,and robotic autonomous exploration.Overall,RO-TWSA presents a versatile and high-resolution tactile interface,offering new avenues for intelligent perception and interaction in complex real-world environments.
文摘This survey presents a comprehensive examination of sensor fusion research spanning four decades,tracing the methodological evolution,application domains,and alignment with classical hierarchical models.Building on this long-term trajectory,the foundational approaches such as probabilistic inference,early neural networks,rulebasedmethods,and feature-level fusion established the principles of uncertainty handling andmulti-sensor integration in the 1990s.The fusion methods of 2000s marked the consolidation of these ideas through advanced Kalman and particle filtering,Bayesian–Dempster–Shafer hybrids,distributed consensus algorithms,and machine learning ensembles for more robust and domain-specific implementations.From 2011 to 2020,the widespread adoption of deep learning transformed the field driving some major breakthroughs in the autonomous vehicles domain.A key contribution of this work is the assessment of contemporary methods against the JDL model,revealing gaps at higher levels-especially in situation and impact assessment.Contemporary methods offer only limited implementation of higher-level fusion.The survey also reviews the benchmark multi-sensor datasets,noting their role in advancing the field while identifying major shortcomings like the lack of domain diversity and hierarchical coverage.By synthesizing developments across decades and paradigms,this survey provides both a historical narrative and a forward-looking perspective.It highlights unresolved challenges in transparency,scalability,robustness,and trustworthiness,while identifying emerging paradigms such as neuromorphic fusion and explainable AI as promising directions.This paves the way forward for advancing sensor fusion towards transparent and adaptive next-generation autonomous systems.
基金the National Natural Science Foundation of China(Nos.62374029,22175029,62474033,and W2433038)the Young Elite Scientists Sponsorship Program by CAST(No.YESS20220550)+2 种基金the Sichuan Science and Technology Program(No.2024NSFSC0250)the Natural Science Foundation of Shenzhen Innovation Committee(JCYJ20210324135614040)the Fundamental Research Funds for the Central Universities of China(No.ZYGX2022J032).
文摘Perovskite solar cells(PSCs)have emerged as promising photovoltaic technologies owing to their remarkable power conversion efficiency(PCE).However,heat accumulation under continuous illumination remains a critical bottleneck,severely affecting device stability and long-term operational performance.Herein,we present a multifunctional strategy by incorporating highly thermally conductive Ti_(3)C_(2)T_(X) MXene nanosheets into the perovskite layer to simultaneously enhance thermal management and optoelectronic properties.The Ti_(3)C_(2)T_(X) nanosheets,embedded at perovskite grain boundaries,construct efficient thermal conduction pathways,significantly improving the thermal conductivity and diffusivity of the film.This leads to a notable reduction in the device’s steady-state operating temperature from 42.96 to 39.97 under 100 mW cm^(−2) illumination,thereby alleviating heat-induced performance degradation.Beyond thermal regulation,Ti_(3)C_(2)T_(X),with high conductivity and negatively charged surface terminations,also serves as an effective defect passivation agent,reducing trap-assisted recombination,while simultaneously facilitating charge extraction and transport by optimizing interfacial energy alignment.As a result,the Ti_(3)C_(2)T_(X)-modified PSC achieve a champion PCE of 25.13%and exhibit outstanding thermal stability,retaining 80%of the initial PCE after 500 h of thermal aging at 85 and 30±5%relative humidity.(In contrast,control PSC retain only 58%after 200 h.)Moreover,under continuous maximum power point tracking in N2 atmosphere,Ti_(3)C_(2)T_(X)-modified PSC retained 70%of the initial PCE after 500 h,whereas the control PSC drop sharply to 20%.These findings highlight the synergistic role of Ti_(3)C_(2)T_(X) in thermal management and optoelectronic performance,paving the way for the development of high-efficiency and heat-resistant perovskite photovoltaics.
基金Natural Science Foundation of China(NSFC,No.22131008)Natural Science Foundation of Tianjin(No.22JCYBJC00500)the Haihe Laboratory of Sustainable Chemical Transformations for financial support.
文摘Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ionic liquid(IL),using 1-ethyl-3-methylimidazolium bromide([EMIM]Br)IL as solvent.Benefiting from the compatibility of ILs and alkene-PR,the cross-linked network slide-ring gel not only maintains excellent conductivity(1.52×10^(−2) S/m),but also has effectively improved mechanical properties(513%fracture strain,0.713 MPa fracture stress,211 kPa elastic modulus and 1366 kJ/m^(3) toughness)and adhesive properties(472.3±25.9 kPa).The supramolecular gel can be used as a strain sensor to efficiently monitor deformation signals in real-time at least 200 times.Especially,the slide-ring gel can self-power generated by triboelectric effect and electrostatic induction between the skin layer and the polydimethylsiloxane(PDMS)layer that encapsulates the gel,achieving reversible and durable motion sensing,which provides a convenient pathway for constructing supramolecular self-powered flexible electronic materials.
基金supported by the National Natural Science Foundation of China(62088101,62522307,62273045,U2341213)Beijing Nova Program(20230484481)。
文摘Formation control of multiple spacecraft has attracted extensive research attention.However,achieving reliable performance under sensor failures remains a significant challenge.This paper develops an integrated framework that jointly designs distributed observers and local controllers to ensure robust formation control in the presence of external disturbances and sensor malfunctions.Treating the spacecraft formation as a single interconnected system,each spacecraft constructs a distributed observer that estimates the overall system state by incorporating both its own measurements and the predicted control information shared among the spacecraft.Based on the observer estimates,a local control law is synthesized to maintain the desired formation.Rigorous theoretical analysis and numerical simulations demonstrate that the proposed integrated approach effectively guarantees formation stability and resilience against sensor failures and disturbances.
基金supported by the Basic Science Research Program(2023R1A2C3004336,RS-202300243807)&Regional Leading Research Center(RS-202400405278)through the National Research Foundation of Korea(NRF)grant funded by the Korea Government(MSIT)。
文摘Wearable sensors integrated with deep learning techniques have the potential to revolutionize seamless human-machine interfaces for real-time health monitoring,clinical diagnosis,and robotic applications.Nevertheless,it remains a critical challenge to simultaneously achieve desirable mechanical and electrical performance along with biocompatibility,adhesion,self-healing,and environmental robustness with excellent sensing metrics.Herein,we report a multifunctional,anti-freezing,selfadhesive,and self-healable organogel pressure sensor composed of cobalt nanoparticle encapsulated nitrogen-doped carbon nanotubes(CoN CNT)embedded in a polyvinyl alcohol-gelatin(PVA/GLE)matrix.Fabricated using a binary solvent system of water and ethylene glycol(EG),the CoN CNT/PVA/GLE organogel exhibits excellent flexibility,biocompatibility,and temperature tolerance with remarkable environmental stability.Electrochemical impedance spectroscopy confirms near-stable performance across a broad humidity range(40%-95%RH).Freeze-tolerant conductivity under sub-zero conditions(-20℃)is attributed to the synergistic role of CoN CNT and EG,preserving mobility and network integrity.The Co N CNT/PVA/GLE organogel sensor exhibits high sensitivity of 5.75 k Pa^(-1)in the detection range from 0 to 20 k Pa,ideal for subtle biomechanical motion detection.A smart human-machine interface for English letter recognition using deep learning achieved 98%accuracy.The organogel sensor utility was extended to detect human gestures like finger bending,wrist motion,and throat vibration during speech.
基金financially supported by the Shandong Provincial Natural Science Foundation,China(Nos.ZR2022MB051 and ZR2021MB112)Postdoctoral Science Foundation of China(No.2022M712343)+2 种基金Jinan City University Integration Development Strategy Project(No.JNSX2024030)Key Laboratory of Special Functional Aggregates of the Ministry of Education,Shandong University(No.JJT-2023-02)Shandong SD-Link New Material Technology Co.,LTD.
文摘Silicone-based pressure-sensitive adhesives(Si-PSAs)are valued for their thermal stability,flexibility,and biocompatibility,but their weak bonding strength restricts high-performance use.Polyurethane-modified Si-PSAs enhance adhesion,however diisocyanates remain essential.The raw materials of isocyanates are toxic,and their synthesis involves phosgene.To make up for those shortcomings,a series of poly(hydroxy urethane-siloxane)PSAs,named as PHUSi here,were synthesized through the ring-opening reaction of cyclic carbonate-functionalized polysiloxanes(PSi_(x)-VEC_(z))with various aliphatic diamines.The PSi_(x)-VEC_(z) precursors were prepared via the hydrosilylation of hydrogen-containing polysiloxanes(PSi_(x)-H_(y))with 4-vinyl-1,3-dioxolan-2-one(VEC).The chemical structures of PSi_(x)-H_(y),PSi_(x)-VEC_(z) and PHUSi were characterized,and bonding properties of PHUSi were systematically evaluated.The influence of architectures on adhesive performance was elucidated through comprehensive analyses,including rheology,crosslink density assessment,and so on.These studies revealed that the tailored design of PHUSi adhesives combine the advantages of traditional Si-PSAs with enhanced adhesion while eliminating isocyanate toxicity.The optimized PHUSi formulation achieved remarkable 180°peel strength(76.5 N/m on skin)and maximum probe tack force(1.61 N),enabling secure 24 h attachment of flexible sensors to skin.These properties make PHUSi particularly suitable for medical applications,as demonstrated by successful implementation in flexible electrocardiogram devices,offering a biocompatible,high-performance adhesive.
基金supported by the NSFC(12474071)Natural Science Foundation of Shandong Province(ZR2024YQ051,ZR2025QB50)+6 种基金Guangdong Basic and Applied Basic Research Foundation(2025A1515011191)the Shanghai Sailing Program(23YF1402200,23YF1402400)funded by Basic Research Program of Jiangsu(BK20240424)Open Research Fund of State Key Laboratory of Crystal Materials(KF2406)Taishan Scholar Foundation of Shandong Province(tsqn202408006,tsqn202507058)Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2024QTB002)the Qilu Young Scholar Program of Shandong University。
文摘As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(RS-2024-00333650)supported by basic science research program through the National Research Foundation of Korea funded by the Ministry of Education(NRF-2019R1A6A1A11055660)+1 种基金supported by the Technology Innovation Program(“20013621”,Center for Super Critical Material Industrial Technology)funded By the Ministry of Trade,Industry&Energy(MOTIE,Korea)supported by Strategic Networking&Development Program funded by the Ministry of Science and ICT through the National Research Foundation of Korea(RS-2023-00268523)。
文摘Gas sensors are valuable tools for human applications,and extensive research has been conducted in this field.However,practical implementation has yet to be fully realized.In response,efforts have been made to explore metal-organic frameworks(MOFs),a novel class of porous materials,as potential solutions.MOFs exhibit exceptional porosity and highly tunable chemical compositions and structures,giving rise to a wide range of unique physical and chemical properties.Significant progress has been achieved in developing MOF-based gas sensors,improving sensing performance for various gases.This review aims to provide a comprehensive understanding of MOF-based gas sensors,even for readers unfamiliar with MOFs and gas sensors.It covers the working principles of these sensors,fundamental concepts of MOFs,strategies for tuning MOF properties,fabrication techniques for MOF films,and recent studies on MOF and MOF-derivative gas sensors.Finally,current challenges,overlooked aspects,and future directions for fully exploiting the potential of MOFs in gas sensor development are discussed.
基金National Natural Science Foundation of China,No.42101252。
文摘Rapid regional population shifts and spatial polarization have heightened pressure on cultivated land—a critical resource demanding urgent attention amid ongoing urban-rural transition.This study selects Jiangsu province,a national leader in both economic and agricultural development,as a case area to construct a multidimensional framework for assessing the recessive morphological characteristics of multifunctional cultivated land use.We examine temporal dynamics,spatial heterogeneity,and propose an integrated zoning strategy based on empirical analysis.The results reveal that:(1)The recessive morphology index shows a consistent upward trend,with structural breaks in 2007 and 2013,and a spatial shift from“higher in the east and lower in the west”to“higher in the south and lower in the north.”(2)Coordination among sub-dimensions of the index has steadily improved.(3)The index is expected to continue rising in the next decade,though at a slower pace.(4)To promote coordinated multidimensional land-use development,we recommend a policy framework that reinforces existing strengths,addresses weaknesses,and adapts zoning schemes to current spatial conditions.This research offers new insights into multifunctional cultivated land systems and underscores their role in enhancing human well-being,securing food supply,and supporting sustainable urban-rural integration.
基金financially supported by the Natural Science Foundation of Shandong Province(No.ZR2024QE446)。
文摘With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.
文摘The development of intrinsically conductive piezoresistive sensors with high strain tolerance has garnered significant interest.While elastomeric polymers exhibit excellent strain capabilities,their utility in sensing applications has been limited by inherent challenges such as high electrical resistivity,poor aging resistance,and interfacial incompatibility.To address these limitations,hydroxyl-terminated polybutadiene(HTPB)-based polyurethane was chemically modified with acetylferrocene-polyaniline conductive moieties to enhance charge transport properties.Remarkably,this covalent functionalization endowed the resulting ferrocene-polyaniline hybrid polyurethane(FPHP)with a conductivity of2.33 n A at 1 V bias while preserving piezoresistive functionality.The FPHP demonstrated exceptional mechanical-electrical performance,achieving 254% elongation at break with strain-dependent gauge factors of 7.28(0%-12.5% strain,R^(2)=0.9504)and 19.66(12.5%-35.0% strain,R^(2)=0.9929).Further characterization revealed a rapid 0.60 s response time and stability over 3500 strain-release cycles at compression strain,underscoring its durability under repetitive loading.The FPHP sensor was capable of monitoring various human movements and recognizing writing signals.These advances establish a materials design paradigm for fabricating flexible sensors that synergistically integrate high deformability,tunable sensitivity,and robust operational stability,positioning FPHP as a promising candidate for next-generation wearable electronics and soft robotics.
