摘要
Possessing excellent mechanical properties,a high-coverage slide-ring conductive gel is constructed by in situ polymerization ofα-cyclodextrin(α-CD)polyrotaxane(PR)and 1-vinyl-3-ethylimidazolium bromide([VEIM]Br)ionic liquid(IL),using 1-ethyl-3-methylimidazolium bromide([EMIM]Br)IL as solvent.Benefiting from the compatibility of ILs and alkene-PR,the cross-linked network slide-ring gel not only maintains excellent conductivity(1.52×10^(−2) S/m),but also has effectively improved mechanical properties(513%fracture strain,0.713 MPa fracture stress,211 kPa elastic modulus and 1366 kJ/m^(3) toughness)and adhesive properties(472.3±25.9 kPa).The supramolecular gel can be used as a strain sensor to efficiently monitor deformation signals in real-time at least 200 times.Especially,the slide-ring gel can self-power generated by triboelectric effect and electrostatic induction between the skin layer and the polydimethylsiloxane(PDMS)layer that encapsulates the gel,achieving reversible and durable motion sensing,which provides a convenient pathway for constructing supramolecular self-powered flexible electronic materials.
基金
Natural Science Foundation of China(NSFC,No.22131008)
Natural Science Foundation of Tianjin(No.22JCYBJC00500)
the Haihe Laboratory of Sustainable Chemical Transformations for financial support.
