Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibite...Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibited very high performance in peroxymonosulfate activation.The Fe single-atom filled an N vacancy on the triazine ring edge of C_(3)N_(4),as confirmed through X-ray absorption fine structure,density functional calculation and elec-tron paramagnetic resonance.The SAFe_(0.4)–C_(3)N_(4)/PMS system could completely remove phenol(20 mg/L)within 10 min and its first-order kinetic constant was 12.3 times that of the Fe_(3)O_(4)/PMS system.Under different ini-tial pH levels and in various anionic environments,SAFe_(0.4)–C_(3)N_(4) still demonstrated excellent catalytic activity,achieving a removal rate of over 90%for phenol within 12 min.In addition,SAFe_(0.4)–C_(3)N_(4) exhibited outstanding selectivity in reaction systems with different pollutants,showing excellent degradation effects on electron-rich pollutants only.Hydroxyl radicals(•OH),singlet oxygen(1O_(2))and high-valent iron oxide(Fe(Ⅳ)=O)were de-tected in the SAFe_(0.4)–C_(3)N_(4)/PMS system through free radical capture experiments.Further experiments on the quenching of active species and a methyl phenyl sulfoxide probe confirmed that 1O_(2) and Fe(Ⅳ)=O played dom-inant roles.Additionally,the change in the current response after adding PMS and phenol in succession proved that a direct electron transfer path between organic matter and the catalyst surface was unlikely to exist in the SAFe_(0.4)–C_(3)N_(4)/PMS/Phenol degradation system.This study provides a new demonstration of the catalytic mech-anism of single-atom catalysts.展开更多
Peroxymonosulfate(PMS)-assisted visible-light photocatalytic degradation of organic pollutants using graphitic carbon nitride(g-C_(3)N_(4))presents a promising and environmentally friendly approach.However,pristine g-...Peroxymonosulfate(PMS)-assisted visible-light photocatalytic degradation of organic pollutants using graphitic carbon nitride(g-C_(3)N_(4))presents a promising and environmentally friendly approach.However,pristine g-C_(3)N_(4) suffers from limited visible-light absorption and low charge-carrier mobility.In this study,a phosphorus-doped tubular carbon nitride(5P-TCN)was synthesized via a precursor self-assembly method using phosphoric acid and melamine as raw materials,eliminating the need for organic solvents or templates.The 5P-TCN catalyst demonstrated enhanced visible-light absorption,improved charge transfer capability,and a 5.25-fold increase in specific surface area(31.092 m^(2)/g),which provided abundant active sites to efficiently drive the PMS-assisted photocatalytic reaction.The 5P-TCN/vis/PMS system exhibited exceptional degradation performance for organic pollutants across a broad pH range(3–9),achieving over 92%degradation of Rhodamine B(RhB)within 15 min.Notably,the system retained>98%RhB degradation efficiency after three consecutive operational cycles,demonstrating robust operational stability and reusability.Moreover,key parameters influencing,active radi-cals,degradation pathways,and potential mechanisms for RhB degradation were systematically investigated.This work proposes a green and cost-effective strategy for developing high-efficiency photocatalysts,while demon-strating the exceptional capability of a PMS-assisted photocatalytic system for rapid degradation of RhB.展开更多
为了解决航天发射场复杂可维修多阶段任务系统(phased-mission system,PMS)的任务可靠性评估问题,依据考虑维修的多阶段任务系统(phased-mission system considering maintenance,PMSCM)理论和蒙特卡罗方法,基于系统特殊的任务成功定义...为了解决航天发射场复杂可维修多阶段任务系统(phased-mission system,PMS)的任务可靠性评估问题,依据考虑维修的多阶段任务系统(phased-mission system considering maintenance,PMSCM)理论和蒙特卡罗方法,基于系统特殊的任务成功定义规则,通过任务阶段的形式化描述与零部件的虚节点处理,建立可靠性评估仿真模型。将模型应用于航天发射场垂直总装厂房液压系统,成功分析了系统多阶段任务的可靠性均值、方差和置信区间。仿真结果表明:该模型能够找出系统的关键部件,为垂直总装厂房及航天发射场系统总体任务进行可靠性预计、分配和评估提供重要参考和决策支持。展开更多
In permanent magnet synchronous machine(PMSM) drives, temperature information is critical to achieve reliable and high-performance control. The popular model-based estimation methods are based on extracting temperatur...In permanent magnet synchronous machine(PMSM) drives, temperature information is critical to achieve reliable and high-performance control. The popular model-based estimation methods are based on extracting temperature dependent terms from the voltages using the machine model. The estimation accuracy under low speed or load can be greatly affected by the model uncertainty and noise due to low signal-tonoise ratio. This paper presents a high frequency(HF) position offset injection-based winding and permanent magnet(PM) temperature decoupled estimation approach for PMSMs to achieve accurate and robust temperature estimation among a wide speed range especially under low-speed conditions. In the proposed approach, a small HF position offset is injected into the machine to construct a decoupled winding and PM temperature estimation model, in which the winding and PM temperatures are independently estimated from HF excitations. The temperature estimation is independent from the fundamental model and parameter variation, and it achieves high signal-tonoise ratio under low-speed conditions. Moreover, the temperature estimation is also not affected by magnetic saturation and inverter distortion, which can improve the accuracy and robustness of temperature estimation. The proposed approach is validated with experiments and comparisons on a laboratory machine under various operating conditions.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22406081,22276086,22306086)the Natural Science Foundation of Jiangxi Province(No.20232BAB213029),all of which are greatly acknowledged by the authors.
文摘Fenton-like technology based on peroxymonosulfate activation has shown great potential in refractory organics degradation.In this work,single Fe atom catalysts were synthesized through facile ball milling and exhibited very high performance in peroxymonosulfate activation.The Fe single-atom filled an N vacancy on the triazine ring edge of C_(3)N_(4),as confirmed through X-ray absorption fine structure,density functional calculation and elec-tron paramagnetic resonance.The SAFe_(0.4)–C_(3)N_(4)/PMS system could completely remove phenol(20 mg/L)within 10 min and its first-order kinetic constant was 12.3 times that of the Fe_(3)O_(4)/PMS system.Under different ini-tial pH levels and in various anionic environments,SAFe_(0.4)–C_(3)N_(4) still demonstrated excellent catalytic activity,achieving a removal rate of over 90%for phenol within 12 min.In addition,SAFe_(0.4)–C_(3)N_(4) exhibited outstanding selectivity in reaction systems with different pollutants,showing excellent degradation effects on electron-rich pollutants only.Hydroxyl radicals(•OH),singlet oxygen(1O_(2))and high-valent iron oxide(Fe(Ⅳ)=O)were de-tected in the SAFe_(0.4)–C_(3)N_(4)/PMS system through free radical capture experiments.Further experiments on the quenching of active species and a methyl phenyl sulfoxide probe confirmed that 1O_(2) and Fe(Ⅳ)=O played dom-inant roles.Additionally,the change in the current response after adding PMS and phenol in succession proved that a direct electron transfer path between organic matter and the catalyst surface was unlikely to exist in the SAFe_(0.4)–C_(3)N_(4)/PMS/Phenol degradation system.This study provides a new demonstration of the catalytic mech-anism of single-atom catalysts.
文摘Peroxymonosulfate(PMS)-assisted visible-light photocatalytic degradation of organic pollutants using graphitic carbon nitride(g-C_(3)N_(4))presents a promising and environmentally friendly approach.However,pristine g-C_(3)N_(4) suffers from limited visible-light absorption and low charge-carrier mobility.In this study,a phosphorus-doped tubular carbon nitride(5P-TCN)was synthesized via a precursor self-assembly method using phosphoric acid and melamine as raw materials,eliminating the need for organic solvents or templates.The 5P-TCN catalyst demonstrated enhanced visible-light absorption,improved charge transfer capability,and a 5.25-fold increase in specific surface area(31.092 m^(2)/g),which provided abundant active sites to efficiently drive the PMS-assisted photocatalytic reaction.The 5P-TCN/vis/PMS system exhibited exceptional degradation performance for organic pollutants across a broad pH range(3–9),achieving over 92%degradation of Rhodamine B(RhB)within 15 min.Notably,the system retained>98%RhB degradation efficiency after three consecutive operational cycles,demonstrating robust operational stability and reusability.Moreover,key parameters influencing,active radi-cals,degradation pathways,and potential mechanisms for RhB degradation were systematically investigated.This work proposes a green and cost-effective strategy for developing high-efficiency photocatalysts,while demon-strating the exceptional capability of a PMS-assisted photocatalytic system for rapid degradation of RhB.
文摘为了解决航天发射场复杂可维修多阶段任务系统(phased-mission system,PMS)的任务可靠性评估问题,依据考虑维修的多阶段任务系统(phased-mission system considering maintenance,PMSCM)理论和蒙特卡罗方法,基于系统特殊的任务成功定义规则,通过任务阶段的形式化描述与零部件的虚节点处理,建立可靠性评估仿真模型。将模型应用于航天发射场垂直总装厂房液压系统,成功分析了系统多阶段任务的可靠性均值、方差和置信区间。仿真结果表明:该模型能够找出系统的关键部件,为垂直总装厂房及航天发射场系统总体任务进行可靠性预计、分配和评估提供重要参考和决策支持。
基金supported by Shenzhen Science and Technology Program under Grant JCYJ20250604175412017the National Natural Science Foundation of China under Grant 62473387+1 种基金the Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) under Grant SML2024SP007in part by the Department of Science and Technology of Guangdong Province under Grant. 2021QN020085。
文摘In permanent magnet synchronous machine(PMSM) drives, temperature information is critical to achieve reliable and high-performance control. The popular model-based estimation methods are based on extracting temperature dependent terms from the voltages using the machine model. The estimation accuracy under low speed or load can be greatly affected by the model uncertainty and noise due to low signal-tonoise ratio. This paper presents a high frequency(HF) position offset injection-based winding and permanent magnet(PM) temperature decoupled estimation approach for PMSMs to achieve accurate and robust temperature estimation among a wide speed range especially under low-speed conditions. In the proposed approach, a small HF position offset is injected into the machine to construct a decoupled winding and PM temperature estimation model, in which the winding and PM temperatures are independently estimated from HF excitations. The temperature estimation is independent from the fundamental model and parameter variation, and it achieves high signal-tonoise ratio under low-speed conditions. Moreover, the temperature estimation is also not affected by magnetic saturation and inverter distortion, which can improve the accuracy and robustness of temperature estimation. The proposed approach is validated with experiments and comparisons on a laboratory machine under various operating conditions.
