The quantum nature of bulk ensemble NMR quantum computing — the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a two-qubit liquid NMR quantum ...The quantum nature of bulk ensemble NMR quantum computing — the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a two-qubit liquid NMR quantum computation are analyzed. The main points in this paper are: i) Density matrix describes the 'state' of an average particle in an ensemble. It does not describe the state of an individual particle in an ensemble; ii) Entanglement is a property of the wave function of a microscopic particle (such as a molecule in a liquid NMR sample), and separability of the density matrix cannot be used to measure the entanglement of mixed ensemble; iii) The state evolution in bulk-ensemble NMR quantum computation is quantum-mechanical; iv) The coefficient before the effective pure state density matrix, ?, is a measure of the simultaneity of the molecules in an ensemble. It reflects the intensity of the NMR signal and has no significance in quantifying the entanglement in the bulk ensemble NMR system. The decomposition of the density matrix into product states is only an indication that the ensemble can be prepared by an ensemble with the particles unentangled. We conclude that effective-pure-state NMR quantum computation is genuine, not just classical simulations.展开更多
Four new rearranged 6/6/5/6-fused lanostane-type triterpenoids,kadcoccitanes A-D(1-4),were isolated from the roots of Kadsura coccinea,and their structures were mainly elucidated by comprehensive analysis of their spe...Four new rearranged 6/6/5/6-fused lanostane-type triterpenoids,kadcoccitanes A-D(1-4),were isolated from the roots of Kadsura coccinea,and their structures were mainly elucidated by comprehensive analysis of their spectroscopic data.Additionally,the structure of 1 was ambiguously verifed by single-crystal X-ray difraction,while the structure of 2,which features a novel 8,16-epoxy motif,was validated by quantum chemical calculation of NMR parameters and ECD spectrum.Moreover,1 and 4 were found to exhibited anticoagulant activity,while 3 and 4 were found to possess anti-platelet aggregation activity.展开更多
The configurations of C-20 in derivatives of novel 5α-adynerin type,co-existing glycoside in pair,were identified with the calculated chemical shifts of carbon at the B3LYP/6-311＋G（2d,p）level.These glycosides are ...The configurations of C-20 in derivatives of novel 5α-adynerin type,co-existing glycoside in pair,were identified with the calculated chemical shifts of carbon at the B3LYP/6-311＋G（2d,p）level.These glycosides are unusual cardic aglycones without the common olefin bond in ring E.展开更多
An important task for quantum cloud computing is to make sure that there is a real quantum computer running,instead of classical simulation.Here we explore the applicability of a cryptographic verification scheme for ...An important task for quantum cloud computing is to make sure that there is a real quantum computer running,instead of classical simulation.Here we explore the applicability of a cryptographic verification scheme for verifying quantum cloud computing.We provided a theoretical extension and implemented the scheme on a 5-qubit NMR quantum processor in the laboratory and a 5-qubit and 16-qubit processors of the IBM quantum cloud.We found that the experimental results of the NMR processor can be verified by the scheme with about 1.4%error,after noise compensation by standard techniques.However,the fidelity of the IBM quantum cloud is currently too low to pass the test(about 42%error).This verification scheme shall become practical when servers claim to offer quantum-computing resources that can achieve quantum supremacy.展开更多
文摘The quantum nature of bulk ensemble NMR quantum computing — the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a two-qubit liquid NMR quantum computation are analyzed. The main points in this paper are: i) Density matrix describes the 'state' of an average particle in an ensemble. It does not describe the state of an individual particle in an ensemble; ii) Entanglement is a property of the wave function of a microscopic particle (such as a molecule in a liquid NMR sample), and separability of the density matrix cannot be used to measure the entanglement of mixed ensemble; iii) The state evolution in bulk-ensemble NMR quantum computation is quantum-mechanical; iv) The coefficient before the effective pure state density matrix, ?, is a measure of the simultaneity of the molecules in an ensemble. It reflects the intensity of the NMR signal and has no significance in quantifying the entanglement in the bulk ensemble NMR system. The decomposition of the density matrix into product states is only an indication that the ensemble can be prepared by an ensemble with the particles unentangled. We conclude that effective-pure-state NMR quantum computation is genuine, not just classical simulations.
基金supported financially by the National Natural Science Foundation of China(Nos.81874298 and 81673329).
文摘Four new rearranged 6/6/5/6-fused lanostane-type triterpenoids,kadcoccitanes A-D(1-4),were isolated from the roots of Kadsura coccinea,and their structures were mainly elucidated by comprehensive analysis of their spectroscopic data.Additionally,the structure of 1 was ambiguously verifed by single-crystal X-ray difraction,while the structure of 2,which features a novel 8,16-epoxy motif,was validated by quantum chemical calculation of NMR parameters and ECD spectrum.Moreover,1 and 4 were found to exhibited anticoagulant activity,while 3 and 4 were found to possess anti-platelet aggregation activity.
基金Supported by the Hundred Talents Program of Chinese Academic of Sciences the Science and Technology Committee ofYunnan Province,China.
文摘The configurations of C-20 in derivatives of novel 5α-adynerin type,co-existing glycoside in pair,were identified with the calculated chemical shifts of carbon at the B3LYP/6-311＋G（2d,p）level.These glycosides are unusual cardic aglycones without the common olefin bond in ring E.
基金supported by National Key Research and Development Program of China (2018YFA0306600)the National Natural Science Foundation of China (11661161018, and 11927811)+7 种基金Anhui Initiative in Quantum Information Technologies (AHY050000)supported in part by the Australian Research Council (DE180100156)supported by the Natural Science Foundation of Guangdong Province (2017B030308003)the Key R&D Program of Guangdong province (2018B030326001)the Science, Technology and Innovation Commission of Shenzhen Municipality (JCYJ20170412152620376, JCYJ20170817105046702 and KYTDPT20181011104202253)the National Natural Science Foundation of China (11875160 and U1801661)the Economy, Trade and Information Commission of Shenzhen Municipality (201901161512)Guangdong Provincial Key Laboratory (2019B121203002)
文摘An important task for quantum cloud computing is to make sure that there is a real quantum computer running,instead of classical simulation.Here we explore the applicability of a cryptographic verification scheme for verifying quantum cloud computing.We provided a theoretical extension and implemented the scheme on a 5-qubit NMR quantum processor in the laboratory and a 5-qubit and 16-qubit processors of the IBM quantum cloud.We found that the experimental results of the NMR processor can be verified by the scheme with about 1.4%error,after noise compensation by standard techniques.However,the fidelity of the IBM quantum cloud is currently too low to pass the test(about 42%error).This verification scheme shall become practical when servers claim to offer quantum-computing resources that can achieve quantum supremacy.
