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Determinations of the Configuration of C-20 in Derivatives of Adynerin Using DFT/HF Methods 被引量:3

Determinations of the Configuration of C-20 in Derivatives of Adynerin Using DFT/HF Methods
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摘要 The configurations of C-20 in derivatives of novel 5α-adynerin type,co-existing glycoside in pair,were identified with the calculated chemical shifts of carbon at the B3LYP/6-311+G(2d,p)level.These glycosides are unusual cardic aglycones without the common olefin bond in ring E. The configurations of C-20 in derivatives of novel 5α-adynerin type,co-existing glycoside in pair,were identified with the calculated chemical shifts of carbon at the B3LYP/6-311+G(2d,p)level.These glycosides are unusual cardic aglycones without the common olefin bond in ring E.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2007年第5期592-597,共6页 高等学校化学研究(英文版)
基金 Supported by the Hundred Talents Program of Chinese Academic of Sciences the Science and Technology Committee ofYunnan Province,China.
关键词 Configuration determination Adynerin derivative B3LYP GIAO NMR computation Configuration determination Adynerin derivative B3LYP GIAO NMR computation
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