Hydrocarbon contamination from oil spills presents geoenvironmental and geoengineering challenges,notably in Eleme,Nigeria.This study integrates electrical resistivity tomography(ERT),soil total petroleum hydrocarbon(...Hydrocarbon contamination from oil spills presents geoenvironmental and geoengineering challenges,notably in Eleme,Nigeria.This study integrates electrical resistivity tomography(ERT),soil total petroleum hydrocarbon(TPH)analysis,and geotechnical testing for treated spill site monitoring and characterization over six months.Four 100 m ERT lines,L1 to L4,with spacings at 1.5 m,3 m,6 m,9 m,12 m,and 15 m,were established for the first and second sampling phases.Twenty-one soil samples,12 TPH,and 9 mechanical analyses,were obtained from 5 boreholes,BH1 to BH4,for the study site and the BH5 control site across the phases at 0.5 m,3.0 m,and 5.0 m depths along ERT lines.ERT results reveal resistivity reductions averaging 18%in shallow zones of active degradation,correlating with an average 41%TPH-decrease.Specific gravity averaged 2.49 in the spill soils,compared to 2.58 in control samples,reflecting hydrocarbon-induced density reductions of 3.5%.Particle size showed spill soils contained>50%fines,increasing water retention and reducing permeability by 30%.Consolidation tests highlighted increased compressibility,with settlements of 1.89 mm in spill soils versus 1.01 mm in control samples,indicating a 47%increase in settlement from hydrocarbon reduction.Correlation analysis shows slower consolidation at BH3(−0.62 Cv)with moderate settlement increase(0.25),while BH4 exhibits much higher compressibility(0.95)but minimal Cv impact(0.23),indicating increased structural weakness with higher residual TPH.Spill degradation reduced TPH by 19%-64%in shallow zones,with persistent contamination at deeper layers exceeding the regulatory limits,emphasising the need for ongoing monitoring and targeted remediation for long-term stability and sustainability.展开更多
An integrated study on source rock characterization and hydrocarbon generation potential modeling was conducted for the selected Dingo Claystone,Barrow Sub-basin,Australia.In this study,data were collected solely from...An integrated study on source rock characterization and hydrocarbon generation potential modeling was conducted for the selected Dingo Claystone,Barrow Sub-basin,Australia.In this study,data were collected solely from two wells represented by the Bambra-1 and Bambra-2 wells.The collected data include those from bulk geochemical analyses of cuttings and sidewall cores sampled from the Late Jurassic Dingo Claystone.Geochemical data obtained from Rock-Eval pyrolysis and gas chromatography(GC)of extracted organic matter were integrated for source rock characterization and the construction of burial history and hydrocarbon generation in the Dingo Claystone.To improve the accuracy of thermal maturity estimations,only samples with S2 greater than 1 were considered due to potential issues with peak integration and uncertainties of Tmax determination in samples with lower S2 values.Furthermore,Rock-Eval data from the Bambra wells may be unreliable due to the contamination of cuttings and sidewall core(SWC)samples by drilling mud additives and natural hydrocarbons,which could impact the reliability of the data for determining thermal maturity.This study reveals that the Dingo Claystone Formation has total organic carbon(TOC)contents ranging from 0.66%to 8.31%.A poor to good hydrocarbon generation potential is indicated,with a production yield(PY=S_(1)+S_(2))ranging from 1.37 to 10.44 mg HC/g rock.Hydrogen index values vary between 42 and 226 mg HC/g TOC,confirming that the Dingo Claystone is dominantly kerogen TypeⅢ,with minor contributions from typesⅡ/ⅢandⅣ.Thermal maturity ranges from immature to late mature and is mostly in the oil window.This is indicated by T_(max)values of 398-462℃and vitrinite reflectance(Ro,%)of 0.47-1.99.Some samples show suppressed T_(max)and a higher production index,which is typical for samples affected by drilling fluids during drilling operations.Additionally,gas chromatography(GC)analyses are used to interpret the paleodepositional environment showing mixed input between marine and terrestrial origins of the source rocks.One-dimensional basin modeling for the Bambra-1 and Bambra-2 wells was carried out to evaluate the burial and thermal history of the formation.The transformation ratio suggests that hydrocarbon generation has not reached its peak and is still in an ongoing phase.An indication of hydrocarbon migration can be observed in this formation based on the transformation ratio.The effects of contamination warrant further investigation,as it could significantly impact maturity estimates and data reliability.展开更多
In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented...In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.展开更多
Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the i...Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.展开更多
The growing volume of end-of-life lithium-ion batteries(LIBs)represents both an urgent environmental challenge and a critical resource opportunity,especially for cathode materials.Among commercial cathodes,LiFePO4(LFP...The growing volume of end-of-life lithium-ion batteries(LIBs)represents both an urgent environmental challenge and a critical resource opportunity,especially for cathode materials.Among commercial cathodes,LiFePO4(LFP)dominates the market due to its favorable properties;thus,a substantial amount of LFP cathode materials is expected to retire in the near future.The conventional hydrometallurgical method suffers from high costs and serious pollution.Direct regeneration technologies,especially solid-state sintering,provide a more efficient and environmentally benign alternative by repairing cathode structures through high-temperature solid-phase reactions without extra chemical reagents.Traditional solid-state sintering faces challenges in processing spent LFP from diverse sources,struggling to achieve the homogenization of physical–chemical properties and electrochemical performance.To address the limitations above,phase homogenization with a lattice reconstruction strategy has been investigated,which can enable effective lattice reconstruction and microstructural homogenization,demonstrating robust adaptability to spent samples from variable sources.This review systematically summarizes the mechanisms,detailed steps,characterization techniques,and advances in pre-oxidation optimization(including ion-doping and coated carbon layer modification),as well as future research directions for sustainable LFP recycling.Given this,this review is expected to offer theoretical guidance for achieving homogeneous regeneration of LFP cathode.展开更多
The Ordovician Majiagou Formation(O1m)in the Ordos Basin is a crucial exploration field for natural gas,and exploration of the Ordovician middle assemblage(O_(1)m_(5)^(5-7))has recently yielded great breakthrough.The ...The Ordovician Majiagou Formation(O1m)in the Ordos Basin is a crucial exploration field for natural gas,and exploration of the Ordovician middle assemblage(O_(1)m_(5)^(5-7))has recently yielded great breakthrough.The Daniudi gas field provides a good case study to determine the gas source for the strata.The O_(1)m_(5)^(5-7)gas displays C1/C1-5 ratios of 0.932-0.985 and CO_(2)contents of 1.56%-11.75%,and the detectable H2S content ranges from 0.0002%to 1.8617%.Theδ^(13)C1,δ^(13)C2,δ^(13)CCO_(2),andδD_(1)values are−39.7‰to−35.6‰,−30.4‰to−23.7‰,−12.4‰to−4.6‰,and−204‰to−185‰,respectively.Identification of the gas origin and source indicates that the gaseous alkanes are commonly coal-derived gas.The gas was generated from the coal measures in the Taiyuan Formation(C_(3t))and subsequently migrated.A small amount of oil-associated gas,mainly from O1m carbonate source rocks,has been incorporated into the gas reservoir.The natural gas has experienced insignificant alteration by thermochemical sulfate reduction,and the relatively high levels of CO_(2)are probably associated with corrosion alteration of carbonate reservoirs by injected fluid during acid fracturing.展开更多
The characterization of track irregularities is crucial in railway dynamics,as track irregularities are the primary source of internal excitation in railway systems.In this paper,three mathematical models are proposed...The characterization of track irregularities is crucial in railway dynamics,as track irregularities are the primary source of internal excitation in railway systems.In this paper,three mathematical models are proposed to characterize the track irregularities under different circumstances.The first model is a novel explicit track spectrum function,which performs better in reflecting the inherent periodic components of track irregularities than the existing track spectra.On this foundation,the second model,a parameterized track spectrum random model,is proposed to represent the vast measured track irregularities from the probabilistic perspective.Finally,the third model,an imprecise track spectrum interval model based on a neighborhood uniform sampling Bootstrap method,is presented to identify the confidential interval of the track spectra when the track irregularity data are limited.Three examples are illustrated to demonstrate the feasibility of the three track irregularity models in characterizing the track irregularities in different conditions.This research can help capture the railway deformation status and optimize track maintenance strategies.展开更多
There is a contradiction between the evolution rate of materials and the time resolution of SR-CT characterization in the in situ synchrotron radiation computed tomography(SR-CT)characterization of ultrafast evolution...There is a contradiction between the evolution rate of materials and the time resolution of SR-CT characterization in the in situ synchrotron radiation computed tomography(SR-CT)characterization of ultrafast evolution process.The sampling strategy of the ultra-sparse angle is an effective method for improving time resolution.Accurate reconstruction under sparse sampling conditions has always been a bottleneck problem.In recent years,convolutional neural networks have shown outstanding advantages in sparse-angle CT reconstruction given the development of deep learning.However,existing ideas did not consider the expression of high-frequency details in neural networks,limiting their application in accurate SR-CT characterization.A novel high-frequency information-constrained deep learning network(HFIC-Net)is proposed in response to this problem.Additional high-frequency information constraints are added to improve the accuracy of the reconstruction results.Further,a series of numerical reconstruction experiments are conducted to verify this new method,and the results indicate that the reconstruction results of HFIC-Net method effectively improve reconstruction quality.This new method uses only eight-angle projections to achieve the reconstruction effect of the filtered backprojection method(FBP)method in 360 projections.The results of the HFIC-Net method demonstrate clear boundaries and accurate detailed structures,correcting the misinformation caused by using other methods.For quantitative evaluation,the SSIM used to evaluate image structure similarity is increased from 0.1951,0.9212,and 0.9308 for FBP,FBP-Conv,and DDC-Net,respectively,to 0.9620 for HFIC-Net.Finally,the results of actual SR-CT experimental data indicate that the new method can suppress artifacts and achieve accurate reconstruction,and it is suitable for the in situ SR-CT accurate characterization of ultxafast evolution process.展开更多
The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment....The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.展开更多
Concentrations and distributions of Rb and Sr in loess and palaeosol samples from the Luochuan profile have been studied, in grain-size fractions and chemical forms. Results show that Rb is quite rich in the fraction ...Concentrations and distributions of Rb and Sr in loess and palaeosol samples from the Luochuan profile have been studied, in grain-size fractions and chemical forms. Results show that Rb is quite rich in the fraction of less than 2 μm, and exits only in the residual phase, while Sr is distributed in sand and silt fractions, occurring in the residual and carbonate phases. Therefore, variations of the concentrations of Rb and Sr in loess and palaeosols are closely related not only to dustfall compositions depending on winter monsoon wind strength but also to summer monsoon-induced pedogenic intensity. This indicates that variations of Rb/Sr ratio in Chinese loess sequences represent cyclic alternations of East Asian summer and winter monsoon climates on the orbital time-scale. Variations in Sr concentrations along the sequence bear a high similarity to the oxygen isotope record of the deep sea sediments over the past 2.5 Ma, whereas variations in Rb concentrations are in good agreement with the record of magnetic susceptibility determined with the duplicated samples from the same profile. This suggests that (1) the high-latitude ice volume is responsible for East Asian monsoon variations and (2) the signal of magnetic susceptibility depends dominantly on pedogenesis in Chinese loess sequences.展开更多
We present a compilation of published data(field,petrography,ages and geochemistry)from 73 ophiolitic complexes of the Central Asian Orogenic Belt.The ophiolitic complexes,ranging in age from Neoproterozoic to Triassi...We present a compilation of published data(field,petrography,ages and geochemistry)from 73 ophiolitic complexes of the Central Asian Orogenic Belt.The ophiolitic complexes,ranging in age from Neoproterozoic to Triassic.have been geochemically classified as subduction-related and subductionunrelated categories applying recent,well-established discrimination diagrams.The subductionunrelated category is further subdivided into Mid-Ocean Ridge type(MOR),a common rift-drift stage and Plume type,and the subduction-related category is subdivided into Backarc(BA),Forearc(FA).Backarc to Forearc(BA-FA)and Volcanic Arc(VA)types.The four subduction-related types define highly different geochemical features,with the BA and FA types defining end members showing subduction influence of 10%-100%and 90%-100%subduction influence,respectively,and the two other types(BAFA and VA)define values between the two end members.The subduction-related category comprises79%of the examined ophiolites,of which the BA type ophiolites is by far the dominant group,followed by the BA-FA type,and with FA and VA types as subordinate groups.The Neoproterozoic and Ordovician complexes exhibit the highest,whereas those of Silurian age exhibit the lowest subduction-influence.Of the remaining 21%subduction-unrelated ophiolites,the MOR type dominates.Both the subductionrelated and subduction-unrelated types,in particular the latter,are commonly associated with alkaline basalts taken to represent ocean island magmatism.Harzburgite,dunite,gabbro and basalt are the common lithologies in all ophiolite types,whereas the BA-FA,FA and VA types generally contain intermediate to felsic rocks,and in the FA type boninites occur.The subduction-related ophiolites types generally show low metamorphic grade,whereas greenschist.amphibolite and blueschist grades occur in the subduction-unrelated and BA types.The highly different subduction contribution(from 0 to 100%in the MOR and FA,respectively),attest to variable dips of the subducting slab,as well as variable flux of subduction-related elements into the mantle above subducting slabs,from where the ophiolite magmas got their geochemical fingerprints.As most MOR ophiolites get subducted to the deep mantle,the subduction-related ophiolites have become a dominant ophiolitic type on Earth’s surface through all times supporting the idea about the early start of Plate Tectonics.展开更多
This paper aims to compare the geochemical characteristics of loess-paleosol sequences in the upper reaches of the Hanjiang and Weihe river valleyswhich are located in the semi-humid temperate zone and humid subtropic...This paper aims to compare the geochemical characteristics of loess-paleosol sequences in the upper reaches of the Hanjiang and Weihe river valleyswhich are located in the semi-humid temperate zone and humid subtropical zonerespectively. The Mituosi（MTS） profile in the upper reaches of the Hanjiang River valley and the Yaohecun（YHC） profile in the Weihe River valley were selected for this comparative research. The stratigraphic characteristicscompositionchemical weathering intensityleaching rates of Ca and Namobility of major elementsand transport features of Na and Fe were analyzed with respect to depth and compared between the two profiles. This study reached the following conclusions.（1） The composition of the loess-paleosol sequences in two regions are quite similar to the average composition of the upper continental crust（UCC）indicating that the loess in the two regions came from multiple sources and was mixed well. Thereforethe loess in the two regions is considered aeolian loess.（2） Compared with the loess-paleosol sequence in the Weihe River valleythe loess-paleosol sequence in the upper reaches of the Hanjiang River valley features a darker color; a higher chemical index of alteration（CIA） value; higher leaching rates of Na and Ca; higher migration ratio（relative to K） of AlSiMgand Na; and lower migration ratio of Fe and Ca. This evidence indicates that the loess-paleosol sequence in the humid subtropical environment experienced stronger chemical weathering intensity than the loess-paleosol sequence in the semi-humid temperate zone.（3） Both the YHC profile and MTS profile record a period of climate deterioration at 6000–5000 a BP. The period punctuated the mid-Holocene Climatic Optimum（8500–3100 a BP） in the study area.展开更多
To evaluate contamination caused by petroleum, surface soil samples were collected from both upland and paddy fields along the irrigation canals in the Hunpu wastewater irrigation region in northeast China. N-alkanes,...To evaluate contamination caused by petroleum, surface soil samples were collected from both upland and paddy fields along the irrigation canals in the Hunpu wastewater irrigation region in northeast China. N-alkanes, terpanes, steranes, and phospholipid fatty acids （PLFA） in the surface soil samples were analyzed. The aliphatic hydrocarbon concentration was highest in the samples obtained from the upland field near an operational oil well; it was lowest at I-3P where wastewater irrigation promoted the downward movement of hydrocarbons. The Hunpu region was found contaminated by heavy petroleum from oxic lacustrine fresh water or marine deltaic source rocks. Geochemical parameters also indicated significantly heavier contamination and degradation in the upland fields compared with the paddy fields. Principal component analysis based on PLFA showed various microbial communities between petroleum contaminated upland and paddy fields. Gram-negative bacteria indicated by 15：0, 3OH 12：0, and 16：1（9） were significantly higher in the paddy fields, whereas Gram-positive bacteria indicated by i16：0 and 18：1（9）c were significantly higher in the upland fields （p 〈 0.05）. These PLFAs were related to petroleum contamination. Poly-unsaturated PLFA （18：2ω6, 9; indicative of hydrocarbon- degrading bacteria and fungi） was also significantly elevated in the upland fields. This paper recommends more sensitive indicators of contamination and degradation of petroleum in soil. The results also provide guidelines on soil pollution control and remediation in the Hunpu region and other similar regions.展开更多
Geochemical studies of sandstones from the three lithostratigraphic successions in the southern Benue Trough of Nigeria were undertaken for a geochemical characterization of the sandstones, and to assess their strati-...Geochemical studies of sandstones from the three lithostratigraphic successions in the southern Benue Trough of Nigeria were undertaken for a geochemical characterization of the sandstones, and to assess their strati-graphic and source evolution. Major and trace elements data were obtained from outcrop sandstone samples. The SiO2/Al2O3, Fe2O3/K2O ratios and CaO contents have been used to characterize the Cretaceous sandstones into Al-rich and high and low Fe2O3/K2O ratio sandstones. Results indicate that there are geochemical features that display stratigraphic trends across the succession from the Asu River Group, Eze-Aku Group to the proto-Niger Delta succession which may imply a discontinuous evolution from different source terrains of Precambrian and Mesozoic ages that supplied the sediments. The Asu River Group sandstones have lower SiO2, Al2O3, Fe2O3 and higher MgO; the Eze-Aku sandstones have higher TiO2, CaO, alkalis and lower MgO while the proto-Niger Delta sandstones have higher SiO2, Al2O3, Fe2O3 and lower alkalis and CaO. These discontinuities signify the influence of tectonic impulses that af- fected the southern Benue Trough during the Cretaceous time. Changes in ratios of TiO2/Al2O3, Fe2O3, Cr and Zr suggest an increasingly mafic contribution to the depositional basin with time. The chemical index of alteration increases with time, possibly suggesting that a more intense weathering regime in the hinterland developed with time.展开更多
This study aimed at the assessment of applicability of static supercritical carbon dioxide extraction method (SFE) in biogeochemical characterization of oil shales as an alternative to the standard Soxhlet extration. ...This study aimed at the assessment of applicability of static supercritical carbon dioxide extraction method (SFE) in biogeochemical characterization of oil shales as an alternative to the standard Soxhlet extration. A comparative investigation on yields and compositions of the solvent soluble bitumoids and their constituents extracted from Estonian Kukersite and Dictyonema oil shales by using Soxhlet extraction method (SEM) and static CO2 supercritical fluid extraction in an autoclave at varied subpyrolysis temperatures was carried out. Resulting from TLC- and GC-MS-analyses, aliphatic and aromatic hydrocarbons and neutral oxygen compounds were separated and identified. For the first time, in the composition of the Kukersite bitumoid, homologous series of n-alkanones-3 to n-alkanones-7 were detected. The extracts obtained were similar in both group and individual composition, and geochemical parametres calculated on the basis of aliphatic hydrocarbons including that made static SFE applicable to geochemical investigation of oil shales.展开更多
The usefulness of limestone as an industrial raw material is dependent on the level of its purity, largely controlled by diagenesis and the depositional setting. Limestone samples (83) obtained from the Ewekoro Format...The usefulness of limestone as an industrial raw material is dependent on the level of its purity, largely controlled by diagenesis and the depositional setting. Limestone samples (83) obtained from the Ewekoro Formation exposed in quarry sections at Shagamu were analyzed using X-Ray Fluorescence spectrometry (XRF). A geochemical characterization of result was done to evaluate the purity levels and the implications on provenance, diagenesis, and depositional setting of the limestone. Five limestone beds from quarry sections (15 locations) were logged. Beds “E”, “D”, “C”, “B”, and “A” comprised sandy algal in sparry calcite cement, sandy biomicrite, algal biomicrite, sandy algal biomicrite, and the intra-sparite facies respectively. Results of major elements che- mistry indicated concentrations (in wt%) as follows: CaO (33.71 - 59.99), MgO (0.39 - 3.15), Al<sub>2</sub>O<sub>3</sub> (0.47 - 3.23), Fe<sub>2</sub>O<sub>3</sub> (0.51 - 3.43), SiO<sub>2</sub> (0.47 - 45.98), SO<sub>3</sub> (0.10 - 2.27), K<sub>2</sub>O (0.02 - 0.28), Na<sub>2</sub>O (0.00 - 10.0), TiO<sub>2</sub> (0.00 - 0.27), P<sub>2</sub>O<sub>5</sub> (0.02 - 0.92), MnO (0.01 - 0.06) and Loss on ignition (17.64 - 45.20). Geochemical result showed that the samples are enriched in CaO, while SiO<sub>2</sub> varies widely, likely due to hinterland input. Plots of SiO<sub>2</sub> versus CaO concentrations depicted a negative correlation attributable to chemical diagenetic processes. Diagenesis of the carbonate in form of reversible replacement of SiO<sub>2</sub> with CaO and vice versa occurred under a shallow marine condition. This negative correlation between these oxides (CaO and SiO<sub>2</sub>) dictates zones of high purity limestones that are of desirable industrial applications. Relatively high silica content in the northwestern part is possible indication of outlets to the continental or inland areas where clastic sediment source may have been prominent. Ratios of Ca/Mg and Mg/Ca indicated a relatively low rate of evaporation of sea water and palaeo-salinity conditions marked by precipitation of limestone. Intermittent increase in palaeo-salinity and sea water evaporation level gave rise to the magnesian limestone.展开更多
The present work assesses the temporal distribution pattern and geochemical changes of rare earth elements and Yttrium, Scandium, Thorium, and Uranium delivery into the Oualidia lagoon. Two sediment cores were retriev...The present work assesses the temporal distribution pattern and geochemical changes of rare earth elements and Yttrium, Scandium, Thorium, and Uranium delivery into the Oualidia lagoon. Two sediment cores were retrieved from the Oualidia lagoon and analyzed using neutron activation analysis. The results indicated that heavy rare earth elements are slightly enriched the sediment cores over light rare earth elements. The highest values of REEs were recorded in the top layers of the cores and depleted with depth, suggesting a possible change in factors controlling their accumulation, including mechanical, chemical, and environmental parameters such as weathering intensity, grain size, and Fe-Mn oxides. The sediments display positive Ce anomalies, which are probably related to the submarine weathering process and detrital input. Noting also the variation of hydrodynamics conditions and confinement of the upstream part of the lagoon played a key role in changing the sediment origins.Thus, further investigation of REEs origin in the Oualidia lagoon sediment is required to identify their sources,provenances, and the factors controlling their spatial and vertical distributions. However, these results provide baseline data of occurring changes in REEs geochemical composition and constitute a typical study case to understand the link between sedimentary and geochemistry processes in a lagoonal ecosystem.展开更多
Ophiolites consist predominantly of mafic-ultramafic rocks but also contain in subordinate amounts intermediate to silicic intrusive–extrusive rocks in them.These rocks,although not in large volumes in comparison to ...Ophiolites consist predominantly of mafic-ultramafic rocks but also contain in subordinate amounts intermediate to silicic intrusive–extrusive rocks in them.These rocks,although not in large volumes in comparison to mafic–ultramafic units,reveal significant clues about melt evolution,magmatic accretion processes,and partial melting of pre-existing oceanic crust during ophiolite evolution.They also yield ample accessory minerals,such as zircon and monazite,which are widely used to date the timing of oceanic crust generation.We present a global synthesis of the occurrence of such leucocratic,intrusive and volcanic rocks from 150 Phanerozoic to Archean ophiolites,and evaluate models for their genesis during the development of oceanic crust in different tectonic environments.In the ophiolite complexes we have investigated,intrusive and extrusive rocks show a wide range in composition.Intermediate rocks（with Si O2 between 52and 63 wt.%）include andesite and diorite,whereas the silicic rocks（with Si O2 more than 63 wt.%）include dacite,trondhjemite,tonalite and granite.For subduction-relatedandsubduction-unrelated MORB-type ophiolites in the Phanerozoic orogenic belts,the most commonly reported intermediate to silicic intrusive rocks,independent of their original tectonic setting,are trondhjemite,plagiogranite and tonalite,and less commonly quartz-diorite and diorite.These rock types have been documented from 80 percent of the 104ophiolites included in this study.Intermediate to silicic lavas and/or pyroclastic rocks（basaltic andesite,andesite,dacite and rhyolite）are less abundant,and have been reported from only 35 percent of the 104 ophiolites.Trachyte occurs in some of the Rift/Continental Margintype,subduction-unrelated ophiolitesEvolvedrocksinsubduction-unrelated,Rift/Continental Margin ophiolites are predominantly basaltic andesite and andesite,whereas MOR type（mid-ocean ridge）ophiolites exhibit nearly equal proportions of basaltic andesite/andesite and rhyodacite and Plume/MOR type ophiolites are characterized by rhyolites.Intermediate to silicic volcanic uints in the Backarc sub-group of subduction-related ophiolites are characterized by similar amounts of basaltic andesite/andesite and rhyodacite,whereas in the Backarc to Forearc,Forearc,and Volcanic Arc sub-groups they are mainly basaltic andesite/andesite.Intermediate to silicic rocks in Rift/Continental Margin and Plume/MOR type ophiolites are generally LREE-enriched,whereas those in the MOR type vary from LREE-depleted to LREE-enriched.The Backarc and Backarc to Forearc types are similar to the MOR type;silicic rocks of the Forearc and Volcanic Arc types are generally LREE-enriched.The main process in the formation of the majority of the intermediate to silicic rocks in both subduction-unrelated and subduction-related ophiolites is partial melting of basaltic and/or gabbroic rocks beneath the spreading centers,whereas a minor volume in subduction-related ophiolites are adakites that were produced from partial melting of a subducting slab.Silcic to intermediate rocks in Plume/MOR type ophiolites are generated by fractional crystallization of basaltic melt.The incompatible,non-conservative elements,such as Ba and Th,are weakly to strongly enriched in subduction-related ophiolites as a result of shallow to deep enrichment associated with subduction zone processes.The field occurrence and the geochemical character of leucocratic rocks in ophiolites show considerable variations,providing additional constraints on the petrogenesis of ophiolites in different tectonic settings.Fractional crystallization appears to have been an important process in the formation of the intermediate to silicic rocks in Rift/CM and P/MOR ophiolites in the subduction-unrelated class,as well as VA ophiolites in the subduction-related class.In these types of ophiolites magma chambers might have operated as closed-systems for a sufficient amount of time for fractionation and compositional zoning of the magma to take place（Fig.1C1）.Fractional crystallization was of subordinate importance during the igneous construction of the MOR,BA,FA,and BA-FA ophiolites.Instead,partial melting of hydrothermally altered crust was the most common process resulting in the majority of the intermediate to felsic rocks of the Rift/CM（estimated to 60%）,MOR（estimated to 95%）,and the BA,FA and BA-FA（estimated to 75%）ophiolites,as well as a high proportion of the VA ophiolites（;0%）(Fig.1C2).Slab-generated melts that result in the production of intermediate to silicic rocks of adakitic character represent a relatively small fraction（;5%in Phanerozoic ophiolites）of subduction-related ophiolites（Fig.1C3）.Some adakites are very low in incompatible elements（e.g.,La）,suggesting that these melts were generated from highly depleted MORB.Precambrian ophiolites contain a higher percentage of adakites（ca.35%）,indicating that physical conditions were more favorable for slab melting during the Precambrian than in the Phanerozoic.This phenomenon may have resulted from higher geothermal gradient along relatively shallow-dippingsubductionzonesduringthe Precambrian.展开更多
The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but...The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but no data are available on these materials and they are relatively unknown. Mineralogical, geochemical and physico-chemical characteristics were studied, using X-ray diffraction, X-ray fluorescence and physico-chemical analyses. Mineralogically, quartz was the most abundant mineral in the studied raw materials. It is associated to abundant quantity of smectite, kaolinite and K-feldspars, and slightly abundant to traces of hematite and amphibole. Geochemically, those clayey soils are more siliceous (SiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, 51% - 59%) with significant amount of aluminum (Al</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 15% - 19%) followed by iron oxides (Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 3% - 10%). Other oxides (K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MgO, TiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MnO, CaO and P</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">5</span></sub><span style="font-family:Verdana;">) are in relatively lower proportion. High level of silica content explains the sandy nature of these clays. The results of granulometric analysis show that the studied raw material contain sand (39% - 68%) as major grain size followed by clay particles (17% - 38%), silt (1% - 36%) and gravels (0% - 16%). The studied clayey soils were moderately plastic, with plasticity index values ranging from 13% to 30%, and are also characterized by very high liquidity limits of 34% - 63%.展开更多
Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the preven...Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the prevention and control of LF.Methods Samples of cerebrospinal fluid(CSF),blood,urine,saliva,and environmental materials were collected from the patient and their close contacts for LASV nucleotide detection.Whole-genome sequencing was performed on positive samples to analyze the genetic characteristics of the virus.Results LASV was detected in the patient’s CSF,blood,and urine,while all samples from close contacts and the environment tested negative.The virus belongs to the lineage IV strain and shares the highest homology with strains from Sierra Leone.The variability in the glycoprotein complex(GPC)among different strains ranged from 3.9%to 15.1%,higher than previously reported for the seven known lineages.Amino acid mutation analysis revealed multiple mutations within the GPC immunogenic epitopes,increasing strain diversity and potentially impacting immune response.Conclusion The case was confirmed through nucleotide detection,with no evidence of secondary transmission or viral spread.The LASV strain identified belongs to lineage IV,with broader GPC variability than previously reported.Mutations in the immune-related sites of GPC may affect immune responses,necessitating heightened vigilance regarding the virus.展开更多
基金funded by the Petroleum Technology Development Fund(PTDF),Nigeria.(Award No.:PTDF/ED/OSS/PHD/NOA/1714/20).
文摘Hydrocarbon contamination from oil spills presents geoenvironmental and geoengineering challenges,notably in Eleme,Nigeria.This study integrates electrical resistivity tomography(ERT),soil total petroleum hydrocarbon(TPH)analysis,and geotechnical testing for treated spill site monitoring and characterization over six months.Four 100 m ERT lines,L1 to L4,with spacings at 1.5 m,3 m,6 m,9 m,12 m,and 15 m,were established for the first and second sampling phases.Twenty-one soil samples,12 TPH,and 9 mechanical analyses,were obtained from 5 boreholes,BH1 to BH4,for the study site and the BH5 control site across the phases at 0.5 m,3.0 m,and 5.0 m depths along ERT lines.ERT results reveal resistivity reductions averaging 18%in shallow zones of active degradation,correlating with an average 41%TPH-decrease.Specific gravity averaged 2.49 in the spill soils,compared to 2.58 in control samples,reflecting hydrocarbon-induced density reductions of 3.5%.Particle size showed spill soils contained>50%fines,increasing water retention and reducing permeability by 30%.Consolidation tests highlighted increased compressibility,with settlements of 1.89 mm in spill soils versus 1.01 mm in control samples,indicating a 47%increase in settlement from hydrocarbon reduction.Correlation analysis shows slower consolidation at BH3(−0.62 Cv)with moderate settlement increase(0.25),while BH4 exhibits much higher compressibility(0.95)but minimal Cv impact(0.23),indicating increased structural weakness with higher residual TPH.Spill degradation reduced TPH by 19%-64%in shallow zones,with persistent contamination at deeper layers exceeding the regulatory limits,emphasising the need for ongoing monitoring and targeted remediation for long-term stability and sustainability.
文摘An integrated study on source rock characterization and hydrocarbon generation potential modeling was conducted for the selected Dingo Claystone,Barrow Sub-basin,Australia.In this study,data were collected solely from two wells represented by the Bambra-1 and Bambra-2 wells.The collected data include those from bulk geochemical analyses of cuttings and sidewall cores sampled from the Late Jurassic Dingo Claystone.Geochemical data obtained from Rock-Eval pyrolysis and gas chromatography(GC)of extracted organic matter were integrated for source rock characterization and the construction of burial history and hydrocarbon generation in the Dingo Claystone.To improve the accuracy of thermal maturity estimations,only samples with S2 greater than 1 were considered due to potential issues with peak integration and uncertainties of Tmax determination in samples with lower S2 values.Furthermore,Rock-Eval data from the Bambra wells may be unreliable due to the contamination of cuttings and sidewall core(SWC)samples by drilling mud additives and natural hydrocarbons,which could impact the reliability of the data for determining thermal maturity.This study reveals that the Dingo Claystone Formation has total organic carbon(TOC)contents ranging from 0.66%to 8.31%.A poor to good hydrocarbon generation potential is indicated,with a production yield(PY=S_(1)+S_(2))ranging from 1.37 to 10.44 mg HC/g rock.Hydrogen index values vary between 42 and 226 mg HC/g TOC,confirming that the Dingo Claystone is dominantly kerogen TypeⅢ,with minor contributions from typesⅡ/ⅢandⅣ.Thermal maturity ranges from immature to late mature and is mostly in the oil window.This is indicated by T_(max)values of 398-462℃and vitrinite reflectance(Ro,%)of 0.47-1.99.Some samples show suppressed T_(max)and a higher production index,which is typical for samples affected by drilling fluids during drilling operations.Additionally,gas chromatography(GC)analyses are used to interpret the paleodepositional environment showing mixed input between marine and terrestrial origins of the source rocks.One-dimensional basin modeling for the Bambra-1 and Bambra-2 wells was carried out to evaluate the burial and thermal history of the formation.The transformation ratio suggests that hydrocarbon generation has not reached its peak and is still in an ongoing phase.An indication of hydrocarbon migration can be observed in this formation based on the transformation ratio.The effects of contamination warrant further investigation,as it could significantly impact maturity estimates and data reliability.
基金Supported by the National Key Research and Development Program of Traditional Chinese Medicine Modernization Project,China(No.2023YFC3504000)the Science and Technology Development Project of Jilin Province,China(No.20240404043ZP)the Science and Technology Innovation Cooperation Project of Changchun Science and Technology Bureau and Chinese Academy of Sciences,China(No.23SH14)。
文摘In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.
基金the China Scholarship Council(CSC)the Uplifting Reciprocal Research Scholarship Program for sponsoring Shixuan Lyu+1 种基金supported by MITACS Accelerate(No.IT39116)the Okanagan Basin Water Board water conservation and quality improvement grant program。
文摘Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.
基金financially supported by National Natural Science Key Foundation of China(52534010)National Natural Science Foundation of China(52374288,52204298)+2 种基金Young Elite Scientists Sponsorship Program by China Association for Science and Technology(2022QNRC001)National Key Research and Development Program of China(2022YFC3900805-4/7)Collaborative Innovation Centre for Clean and Efficient Utilization of Strategic Metal Mineral Resources,Found of State Key Laboratory of Mineral Processing(BGRIMM-KJSKL-2017-13).
文摘The growing volume of end-of-life lithium-ion batteries(LIBs)represents both an urgent environmental challenge and a critical resource opportunity,especially for cathode materials.Among commercial cathodes,LiFePO4(LFP)dominates the market due to its favorable properties;thus,a substantial amount of LFP cathode materials is expected to retire in the near future.The conventional hydrometallurgical method suffers from high costs and serious pollution.Direct regeneration technologies,especially solid-state sintering,provide a more efficient and environmentally benign alternative by repairing cathode structures through high-temperature solid-phase reactions without extra chemical reagents.Traditional solid-state sintering faces challenges in processing spent LFP from diverse sources,struggling to achieve the homogenization of physical–chemical properties and electrochemical performance.To address the limitations above,phase homogenization with a lattice reconstruction strategy has been investigated,which can enable effective lattice reconstruction and microstructural homogenization,demonstrating robust adaptability to spent samples from variable sources.This review systematically summarizes the mechanisms,detailed steps,characterization techniques,and advances in pre-oxidation optimization(including ion-doping and coated carbon layer modification),as well as future research directions for sustainable LFP recycling.Given this,this review is expected to offer theoretical guidance for achieving homogeneous regeneration of LFP cathode.
基金sponsored by National Natural Science Foundation of China(Grant Nos.U2244209,42172149,42488101,and 42141021).
文摘The Ordovician Majiagou Formation(O1m)in the Ordos Basin is a crucial exploration field for natural gas,and exploration of the Ordovician middle assemblage(O_(1)m_(5)^(5-7))has recently yielded great breakthrough.The Daniudi gas field provides a good case study to determine the gas source for the strata.The O_(1)m_(5)^(5-7)gas displays C1/C1-5 ratios of 0.932-0.985 and CO_(2)contents of 1.56%-11.75%,and the detectable H2S content ranges from 0.0002%to 1.8617%.Theδ^(13)C1,δ^(13)C2,δ^(13)CCO_(2),andδD_(1)values are−39.7‰to−35.6‰,−30.4‰to−23.7‰,−12.4‰to−4.6‰,and−204‰to−185‰,respectively.Identification of the gas origin and source indicates that the gaseous alkanes are commonly coal-derived gas.The gas was generated from the coal measures in the Taiyuan Formation(C_(3t))and subsequently migrated.A small amount of oil-associated gas,mainly from O1m carbonate source rocks,has been incorporated into the gas reservoir.The natural gas has experienced insignificant alteration by thermochemical sulfate reduction,and the relatively high levels of CO_(2)are probably associated with corrosion alteration of carbonate reservoirs by injected fluid during acid fracturing.
基金supported by the National Natural Science Foundation of China(Grant No.52208445,52478321,52378468)the Fundamental Research Funds for the Central Universities(Grant No.G2021KY05105)+7 种基金the Basic Research Program of Natural Science in Shaanxi Province(Grant No.2022JQ-369)the Open Foundation of National Engineering Laboratory for High Speed Railway Construction(No.HSR202001)the Youth Talent Support Program Project of Xi’an Association for Science and Technology(Grant No.959202413090)Science and Technology Research and Development Program Project of China railway group limited(Major Special Project,No.:2020-Special-022021-Special-082023-Special-07)Innovation-driven project of Central South University(2023CXQD072)the National Natural Science Foundation of Hunan Province(Grant No.:2022-JJ-20071).
文摘The characterization of track irregularities is crucial in railway dynamics,as track irregularities are the primary source of internal excitation in railway systems.In this paper,three mathematical models are proposed to characterize the track irregularities under different circumstances.The first model is a novel explicit track spectrum function,which performs better in reflecting the inherent periodic components of track irregularities than the existing track spectra.On this foundation,the second model,a parameterized track spectrum random model,is proposed to represent the vast measured track irregularities from the probabilistic perspective.Finally,the third model,an imprecise track spectrum interval model based on a neighborhood uniform sampling Bootstrap method,is presented to identify the confidential interval of the track spectra when the track irregularity data are limited.Three examples are illustrated to demonstrate the feasibility of the three track irregularity models in characterizing the track irregularities in different conditions.This research can help capture the railway deformation status and optimize track maintenance strategies.
基金supported by the National Nature Science Foundation of China(Nos.12027901 and 12041202)Synchrotron Radiation Joint Fund of University of Science and Technology of China(Nos.KY2090000059 and KY2090000054)。
文摘There is a contradiction between the evolution rate of materials and the time resolution of SR-CT characterization in the in situ synchrotron radiation computed tomography(SR-CT)characterization of ultrafast evolution process.The sampling strategy of the ultra-sparse angle is an effective method for improving time resolution.Accurate reconstruction under sparse sampling conditions has always been a bottleneck problem.In recent years,convolutional neural networks have shown outstanding advantages in sparse-angle CT reconstruction given the development of deep learning.However,existing ideas did not consider the expression of high-frequency details in neural networks,limiting their application in accurate SR-CT characterization.A novel high-frequency information-constrained deep learning network(HFIC-Net)is proposed in response to this problem.Additional high-frequency information constraints are added to improve the accuracy of the reconstruction results.Further,a series of numerical reconstruction experiments are conducted to verify this new method,and the results indicate that the reconstruction results of HFIC-Net method effectively improve reconstruction quality.This new method uses only eight-angle projections to achieve the reconstruction effect of the filtered backprojection method(FBP)method in 360 projections.The results of the HFIC-Net method demonstrate clear boundaries and accurate detailed structures,correcting the misinformation caused by using other methods.For quantitative evaluation,the SSIM used to evaluate image structure similarity is increased from 0.1951,0.9212,and 0.9308 for FBP,FBP-Conv,and DDC-Net,respectively,to 0.9620 for HFIC-Net.Finally,the results of actual SR-CT experimental data indicate that the new method can suppress artifacts and achieve accurate reconstruction,and it is suitable for the in situ SR-CT accurate characterization of ultxafast evolution process.
基金support from the National Natural Science Foundation of China(Grant Nos.42177142 and 52378477)the Key Research and Development Program of Shaanxi(Grant No.2023-YBSF-486).
文摘The identification of rock mass hazard sources is fundamental for preventing rockfall and landslide disasters in mountainous regions,with rock mass structural characteristics playing a vital role in hazard assessment.In this study,terrestrial laser scanning(TLS)and unmanned aerial vehicle(UAV)technologies were integrated to enhance the evaluation methodology for rock mass hazard sources,focusing on the Sichuan Yanjiang Expressway project in China.The findings demonstrate that TLS-UAV technology enhanced both spatial coverage and data density in slope modeling.Through integrated algorithmic analysis,rock discontinuities within heterogeneous datasets were systematically identified,enabling quantitative extraction and statistical analysis of key geometric parameters,including orientation,trace length,spacing,and roughness.Furthermore,quantitative models were developed for cohesion,friction angle and the morphology parameter M of in situ discontinuities,respectively,facilitating efficient mechanical parameter acquisition.A novel rock mass hazard index(RHI)was developed incorporating discontinuity geometric rating(DGR),discontinuity mechanical rating(DMR),and slope mass rating(SMR).Field validation confirmed the methodology's effectiveness in evaluating risk levels and spatial heterogeneity of rock mass hazard sources,revealing the contribution of different discontinuity sets to the rock mass hazard and identifying the primary discontinuity sets controlling instability mechanisms.This study is of great significance for evaluating discontinuity-controlled rock mass hazard sources and preventing rockfall disasters.
基金This study was financially supported by the National Natural Science Foundation of China(Grant 49725307)the Doctoral Foundation of the Ministry of Educationof China.
文摘Concentrations and distributions of Rb and Sr in loess and palaeosol samples from the Luochuan profile have been studied, in grain-size fractions and chemical forms. Results show that Rb is quite rich in the fraction of less than 2 μm, and exits only in the residual phase, while Sr is distributed in sand and silt fractions, occurring in the residual and carbonate phases. Therefore, variations of the concentrations of Rb and Sr in loess and palaeosols are closely related not only to dustfall compositions depending on winter monsoon wind strength but also to summer monsoon-induced pedogenic intensity. This indicates that variations of Rb/Sr ratio in Chinese loess sequences represent cyclic alternations of East Asian summer and winter monsoon climates on the orbital time-scale. Variations in Sr concentrations along the sequence bear a high similarity to the oxygen isotope record of the deep sea sediments over the past 2.5 Ma, whereas variations in Rb concentrations are in good agreement with the record of magnetic susceptibility determined with the duplicated samples from the same profile. This suggests that (1) the high-latitude ice volume is responsible for East Asian monsoon variations and (2) the signal of magnetic susceptibility depends dominantly on pedogenesis in Chinese loess sequences.
基金supported by the Department of Earth Science,University of Bergen,Norwaysupported by the Ministry of Education and Science of the Russian Federation,grant#14.Y26.31.0018+1 种基金Foundation for Basic Research(Grant#16-05-00313)Scientific Project of IGM SB RAS No.0330-2016-0003
文摘We present a compilation of published data(field,petrography,ages and geochemistry)from 73 ophiolitic complexes of the Central Asian Orogenic Belt.The ophiolitic complexes,ranging in age from Neoproterozoic to Triassic.have been geochemically classified as subduction-related and subductionunrelated categories applying recent,well-established discrimination diagrams.The subductionunrelated category is further subdivided into Mid-Ocean Ridge type(MOR),a common rift-drift stage and Plume type,and the subduction-related category is subdivided into Backarc(BA),Forearc(FA).Backarc to Forearc(BA-FA)and Volcanic Arc(VA)types.The four subduction-related types define highly different geochemical features,with the BA and FA types defining end members showing subduction influence of 10%-100%and 90%-100%subduction influence,respectively,and the two other types(BAFA and VA)define values between the two end members.The subduction-related category comprises79%of the examined ophiolites,of which the BA type ophiolites is by far the dominant group,followed by the BA-FA type,and with FA and VA types as subordinate groups.The Neoproterozoic and Ordovician complexes exhibit the highest,whereas those of Silurian age exhibit the lowest subduction-influence.Of the remaining 21%subduction-unrelated ophiolites,the MOR type dominates.Both the subductionrelated and subduction-unrelated types,in particular the latter,are commonly associated with alkaline basalts taken to represent ocean island magmatism.Harzburgite,dunite,gabbro and basalt are the common lithologies in all ophiolite types,whereas the BA-FA,FA and VA types generally contain intermediate to felsic rocks,and in the FA type boninites occur.The subduction-related ophiolites types generally show low metamorphic grade,whereas greenschist.amphibolite and blueschist grades occur in the subduction-unrelated and BA types.The highly different subduction contribution(from 0 to 100%in the MOR and FA,respectively),attest to variable dips of the subducting slab,as well as variable flux of subduction-related elements into the mantle above subducting slabs,from where the ophiolite magmas got their geochemical fingerprints.As most MOR ophiolites get subducted to the deep mantle,the subduction-related ophiolites have become a dominant ophiolitic type on Earth’s surface through all times supporting the idea about the early start of Plate Tectonics.
基金National Natural Science Foundation of China,No.41271108,No.41471071,No.41371029The Fundamental Research Funds for the Central Universities,No.XDJK2016C091,No.SWU114067
文摘This paper aims to compare the geochemical characteristics of loess-paleosol sequences in the upper reaches of the Hanjiang and Weihe river valleyswhich are located in the semi-humid temperate zone and humid subtropical zonerespectively. The Mituosi（MTS） profile in the upper reaches of the Hanjiang River valley and the Yaohecun（YHC） profile in the Weihe River valley were selected for this comparative research. The stratigraphic characteristicscompositionchemical weathering intensityleaching rates of Ca and Namobility of major elementsand transport features of Na and Fe were analyzed with respect to depth and compared between the two profiles. This study reached the following conclusions.（1） The composition of the loess-paleosol sequences in two regions are quite similar to the average composition of the upper continental crust（UCC）indicating that the loess in the two regions came from multiple sources and was mixed well. Thereforethe loess in the two regions is considered aeolian loess.（2） Compared with the loess-paleosol sequence in the Weihe River valleythe loess-paleosol sequence in the upper reaches of the Hanjiang River valley features a darker color; a higher chemical index of alteration（CIA） value; higher leaching rates of Na and Ca; higher migration ratio（relative to K） of AlSiMgand Na; and lower migration ratio of Fe and Ca. This evidence indicates that the loess-paleosol sequence in the humid subtropical environment experienced stronger chemical weathering intensity than the loess-paleosol sequence in the semi-humid temperate zone.（3） Both the YHC profile and MTS profile record a period of climate deterioration at 6000–5000 a BP. The period punctuated the mid-Holocene Climatic Optimum（8500–3100 a BP） in the study area.
基金supported by the National Basic Research Program of China (No.2004CB418501)the Key Project of Environmental Protection Science of Shandong Province (No.2006007)the National Natural Science Foundation of China (No.40801088/30970166)
文摘To evaluate contamination caused by petroleum, surface soil samples were collected from both upland and paddy fields along the irrigation canals in the Hunpu wastewater irrigation region in northeast China. N-alkanes, terpanes, steranes, and phospholipid fatty acids （PLFA） in the surface soil samples were analyzed. The aliphatic hydrocarbon concentration was highest in the samples obtained from the upland field near an operational oil well; it was lowest at I-3P where wastewater irrigation promoted the downward movement of hydrocarbons. The Hunpu region was found contaminated by heavy petroleum from oxic lacustrine fresh water or marine deltaic source rocks. Geochemical parameters also indicated significantly heavier contamination and degradation in the upland fields compared with the paddy fields. Principal component analysis based on PLFA showed various microbial communities between petroleum contaminated upland and paddy fields. Gram-negative bacteria indicated by 15：0, 3OH 12：0, and 16：1（9） were significantly higher in the paddy fields, whereas Gram-positive bacteria indicated by i16：0 and 18：1（9）c were significantly higher in the upland fields （p 〈 0.05）. These PLFAs were related to petroleum contamination. Poly-unsaturated PLFA （18：2ω6, 9; indicative of hydrocarbon- degrading bacteria and fungi） was also significantly elevated in the upland fields. This paper recommends more sensitive indicators of contamination and degradation of petroleum in soil. The results also provide guidelines on soil pollution control and remediation in the Hunpu region and other similar regions.
文摘Geochemical studies of sandstones from the three lithostratigraphic successions in the southern Benue Trough of Nigeria were undertaken for a geochemical characterization of the sandstones, and to assess their strati-graphic and source evolution. Major and trace elements data were obtained from outcrop sandstone samples. The SiO2/Al2O3, Fe2O3/K2O ratios and CaO contents have been used to characterize the Cretaceous sandstones into Al-rich and high and low Fe2O3/K2O ratio sandstones. Results indicate that there are geochemical features that display stratigraphic trends across the succession from the Asu River Group, Eze-Aku Group to the proto-Niger Delta succession which may imply a discontinuous evolution from different source terrains of Precambrian and Mesozoic ages that supplied the sediments. The Asu River Group sandstones have lower SiO2, Al2O3, Fe2O3 and higher MgO; the Eze-Aku sandstones have higher TiO2, CaO, alkalis and lower MgO while the proto-Niger Delta sandstones have higher SiO2, Al2O3, Fe2O3 and lower alkalis and CaO. These discontinuities signify the influence of tectonic impulses that af- fected the southern Benue Trough during the Cretaceous time. Changes in ratios of TiO2/Al2O3, Fe2O3, Cr and Zr suggest an increasingly mafic contribution to the depositional basin with time. The chemical index of alteration increases with time, possibly suggesting that a more intense weathering regime in the hinterland developed with time.
文摘This study aimed at the assessment of applicability of static supercritical carbon dioxide extraction method (SFE) in biogeochemical characterization of oil shales as an alternative to the standard Soxhlet extration. A comparative investigation on yields and compositions of the solvent soluble bitumoids and their constituents extracted from Estonian Kukersite and Dictyonema oil shales by using Soxhlet extraction method (SEM) and static CO2 supercritical fluid extraction in an autoclave at varied subpyrolysis temperatures was carried out. Resulting from TLC- and GC-MS-analyses, aliphatic and aromatic hydrocarbons and neutral oxygen compounds were separated and identified. For the first time, in the composition of the Kukersite bitumoid, homologous series of n-alkanones-3 to n-alkanones-7 were detected. The extracts obtained were similar in both group and individual composition, and geochemical parametres calculated on the basis of aliphatic hydrocarbons including that made static SFE applicable to geochemical investigation of oil shales.
文摘The usefulness of limestone as an industrial raw material is dependent on the level of its purity, largely controlled by diagenesis and the depositional setting. Limestone samples (83) obtained from the Ewekoro Formation exposed in quarry sections at Shagamu were analyzed using X-Ray Fluorescence spectrometry (XRF). A geochemical characterization of result was done to evaluate the purity levels and the implications on provenance, diagenesis, and depositional setting of the limestone. Five limestone beds from quarry sections (15 locations) were logged. Beds “E”, “D”, “C”, “B”, and “A” comprised sandy algal in sparry calcite cement, sandy biomicrite, algal biomicrite, sandy algal biomicrite, and the intra-sparite facies respectively. Results of major elements che- mistry indicated concentrations (in wt%) as follows: CaO (33.71 - 59.99), MgO (0.39 - 3.15), Al<sub>2</sub>O<sub>3</sub> (0.47 - 3.23), Fe<sub>2</sub>O<sub>3</sub> (0.51 - 3.43), SiO<sub>2</sub> (0.47 - 45.98), SO<sub>3</sub> (0.10 - 2.27), K<sub>2</sub>O (0.02 - 0.28), Na<sub>2</sub>O (0.00 - 10.0), TiO<sub>2</sub> (0.00 - 0.27), P<sub>2</sub>O<sub>5</sub> (0.02 - 0.92), MnO (0.01 - 0.06) and Loss on ignition (17.64 - 45.20). Geochemical result showed that the samples are enriched in CaO, while SiO<sub>2</sub> varies widely, likely due to hinterland input. Plots of SiO<sub>2</sub> versus CaO concentrations depicted a negative correlation attributable to chemical diagenetic processes. Diagenesis of the carbonate in form of reversible replacement of SiO<sub>2</sub> with CaO and vice versa occurred under a shallow marine condition. This negative correlation between these oxides (CaO and SiO<sub>2</sub>) dictates zones of high purity limestones that are of desirable industrial applications. Relatively high silica content in the northwestern part is possible indication of outlets to the continental or inland areas where clastic sediment source may have been prominent. Ratios of Ca/Mg and Mg/Ca indicated a relatively low rate of evaporation of sea water and palaeo-salinity conditions marked by precipitation of limestone. Intermittent increase in palaeo-salinity and sea water evaporation level gave rise to the magnesian limestone.
文摘The present work assesses the temporal distribution pattern and geochemical changes of rare earth elements and Yttrium, Scandium, Thorium, and Uranium delivery into the Oualidia lagoon. Two sediment cores were retrieved from the Oualidia lagoon and analyzed using neutron activation analysis. The results indicated that heavy rare earth elements are slightly enriched the sediment cores over light rare earth elements. The highest values of REEs were recorded in the top layers of the cores and depleted with depth, suggesting a possible change in factors controlling their accumulation, including mechanical, chemical, and environmental parameters such as weathering intensity, grain size, and Fe-Mn oxides. The sediments display positive Ce anomalies, which are probably related to the submarine weathering process and detrital input. Noting also the variation of hydrodynamics conditions and confinement of the upstream part of the lagoon played a key role in changing the sediment origins.Thus, further investigation of REEs origin in the Oualidia lagoon sediment is required to identify their sources,provenances, and the factors controlling their spatial and vertical distributions. However, these results provide baseline data of occurring changes in REEs geochemical composition and constitute a typical study case to understand the link between sedimentary and geochemistry processes in a lagoonal ecosystem.
文摘Ophiolites consist predominantly of mafic-ultramafic rocks but also contain in subordinate amounts intermediate to silicic intrusive–extrusive rocks in them.These rocks,although not in large volumes in comparison to mafic–ultramafic units,reveal significant clues about melt evolution,magmatic accretion processes,and partial melting of pre-existing oceanic crust during ophiolite evolution.They also yield ample accessory minerals,such as zircon and monazite,which are widely used to date the timing of oceanic crust generation.We present a global synthesis of the occurrence of such leucocratic,intrusive and volcanic rocks from 150 Phanerozoic to Archean ophiolites,and evaluate models for their genesis during the development of oceanic crust in different tectonic environments.In the ophiolite complexes we have investigated,intrusive and extrusive rocks show a wide range in composition.Intermediate rocks（with Si O2 between 52and 63 wt.%）include andesite and diorite,whereas the silicic rocks（with Si O2 more than 63 wt.%）include dacite,trondhjemite,tonalite and granite.For subduction-relatedandsubduction-unrelated MORB-type ophiolites in the Phanerozoic orogenic belts,the most commonly reported intermediate to silicic intrusive rocks,independent of their original tectonic setting,are trondhjemite,plagiogranite and tonalite,and less commonly quartz-diorite and diorite.These rock types have been documented from 80 percent of the 104ophiolites included in this study.Intermediate to silicic lavas and/or pyroclastic rocks（basaltic andesite,andesite,dacite and rhyolite）are less abundant,and have been reported from only 35 percent of the 104 ophiolites.Trachyte occurs in some of the Rift/Continental Margintype,subduction-unrelated ophiolitesEvolvedrocksinsubduction-unrelated,Rift/Continental Margin ophiolites are predominantly basaltic andesite and andesite,whereas MOR type（mid-ocean ridge）ophiolites exhibit nearly equal proportions of basaltic andesite/andesite and rhyodacite and Plume/MOR type ophiolites are characterized by rhyolites.Intermediate to silicic volcanic uints in the Backarc sub-group of subduction-related ophiolites are characterized by similar amounts of basaltic andesite/andesite and rhyodacite,whereas in the Backarc to Forearc,Forearc,and Volcanic Arc sub-groups they are mainly basaltic andesite/andesite.Intermediate to silicic rocks in Rift/Continental Margin and Plume/MOR type ophiolites are generally LREE-enriched,whereas those in the MOR type vary from LREE-depleted to LREE-enriched.The Backarc and Backarc to Forearc types are similar to the MOR type;silicic rocks of the Forearc and Volcanic Arc types are generally LREE-enriched.The main process in the formation of the majority of the intermediate to silicic rocks in both subduction-unrelated and subduction-related ophiolites is partial melting of basaltic and/or gabbroic rocks beneath the spreading centers,whereas a minor volume in subduction-related ophiolites are adakites that were produced from partial melting of a subducting slab.Silcic to intermediate rocks in Plume/MOR type ophiolites are generated by fractional crystallization of basaltic melt.The incompatible,non-conservative elements,such as Ba and Th,are weakly to strongly enriched in subduction-related ophiolites as a result of shallow to deep enrichment associated with subduction zone processes.The field occurrence and the geochemical character of leucocratic rocks in ophiolites show considerable variations,providing additional constraints on the petrogenesis of ophiolites in different tectonic settings.Fractional crystallization appears to have been an important process in the formation of the intermediate to silicic rocks in Rift/CM and P/MOR ophiolites in the subduction-unrelated class,as well as VA ophiolites in the subduction-related class.In these types of ophiolites magma chambers might have operated as closed-systems for a sufficient amount of time for fractionation and compositional zoning of the magma to take place（Fig.1C1）.Fractional crystallization was of subordinate importance during the igneous construction of the MOR,BA,FA,and BA-FA ophiolites.Instead,partial melting of hydrothermally altered crust was the most common process resulting in the majority of the intermediate to felsic rocks of the Rift/CM（estimated to 60%）,MOR（estimated to 95%）,and the BA,FA and BA-FA（estimated to 75%）ophiolites,as well as a high proportion of the VA ophiolites（;0%）(Fig.1C2).Slab-generated melts that result in the production of intermediate to silicic rocks of adakitic character represent a relatively small fraction（;5%in Phanerozoic ophiolites）of subduction-related ophiolites（Fig.1C3）.Some adakites are very low in incompatible elements（e.g.,La）,suggesting that these melts were generated from highly depleted MORB.Precambrian ophiolites contain a higher percentage of adakites（ca.35%）,indicating that physical conditions were more favorable for slab melting during the Precambrian than in the Phanerozoic.This phenomenon may have resulted from higher geothermal gradient along relatively shallow-dippingsubductionzonesduringthe Precambrian.
文摘The characterization of clay raw materials of three clay deposits from Northern Cameroon was investigated. The three deposits, located in Gaschiga, Sekandé and Boulgou, are locally used as building materials, but no data are available on these materials and they are relatively unknown. Mineralogical, geochemical and physico-chemical characteristics were studied, using X-ray diffraction, X-ray fluorescence and physico-chemical analyses. Mineralogically, quartz was the most abundant mineral in the studied raw materials. It is associated to abundant quantity of smectite, kaolinite and K-feldspars, and slightly abundant to traces of hematite and amphibole. Geochemically, those clayey soils are more siliceous (SiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, 51% - 59%) with significant amount of aluminum (Al</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 15% - 19%) followed by iron oxides (Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, 3% - 10%). Other oxides (K</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MgO, TiO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, Na</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, MnO, CaO and P</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">5</span></sub><span style="font-family:Verdana;">) are in relatively lower proportion. High level of silica content explains the sandy nature of these clays. The results of granulometric analysis show that the studied raw material contain sand (39% - 68%) as major grain size followed by clay particles (17% - 38%), silt (1% - 36%) and gravels (0% - 16%). The studied clayey soils were moderately plastic, with plasticity index values ranging from 13% to 30%, and are also characterized by very high liquidity limits of 34% - 63%.
基金supported by Public Health Talent Training and Surport Plan(National Administration of Disease Prevention and Control)Research and application of new technology for rapid monitoring and tracing of emergent infectious diseases among entry-exit population(2024YFFK0056)Monitoring,Early warning and Response of Major Infectious Diseases(2022ZDZX0017).
文摘Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the prevention and control of LF.Methods Samples of cerebrospinal fluid(CSF),blood,urine,saliva,and environmental materials were collected from the patient and their close contacts for LASV nucleotide detection.Whole-genome sequencing was performed on positive samples to analyze the genetic characteristics of the virus.Results LASV was detected in the patient’s CSF,blood,and urine,while all samples from close contacts and the environment tested negative.The virus belongs to the lineage IV strain and shares the highest homology with strains from Sierra Leone.The variability in the glycoprotein complex(GPC)among different strains ranged from 3.9%to 15.1%,higher than previously reported for the seven known lineages.Amino acid mutation analysis revealed multiple mutations within the GPC immunogenic epitopes,increasing strain diversity and potentially impacting immune response.Conclusion The case was confirmed through nucleotide detection,with no evidence of secondary transmission or viral spread.The LASV strain identified belongs to lineage IV,with broader GPC variability than previously reported.Mutations in the immune-related sites of GPC may affect immune responses,necessitating heightened vigilance regarding the virus.
