摘要
The Ordovician Majiagou Formation(O1m)in the Ordos Basin is a crucial exploration field for natural gas,and exploration of the Ordovician middle assemblage(O_(1)m_(5)^(5-7))has recently yielded great breakthrough.The Daniudi gas field provides a good case study to determine the gas source for the strata.The O_(1)m_(5)^(5-7)gas displays C1/C1-5 ratios of 0.932-0.985 and CO_(2)contents of 1.56%-11.75%,and the detectable H2S content ranges from 0.0002%to 1.8617%.Theδ^(13)C1,δ^(13)C2,δ^(13)CCO_(2),andδD_(1)values are−39.7‰to−35.6‰,−30.4‰to−23.7‰,−12.4‰to−4.6‰,and−204‰to−185‰,respectively.Identification of the gas origin and source indicates that the gaseous alkanes are commonly coal-derived gas.The gas was generated from the coal measures in the Taiyuan Formation(C_(3t))and subsequently migrated.A small amount of oil-associated gas,mainly from O1m carbonate source rocks,has been incorporated into the gas reservoir.The natural gas has experienced insignificant alteration by thermochemical sulfate reduction,and the relatively high levels of CO_(2)are probably associated with corrosion alteration of carbonate reservoirs by injected fluid during acid fracturing.
基金
sponsored by National Natural Science Foundation of China(Grant Nos.U2244209,42172149,42488101,and 42141021).