增材制造技术(additive manufacturing,AM)的发展为高熔点难熔金属(如钨、钼、钽、铌及其合金)复杂构件的近净成形带来了革命性的新机遇。然而,难熔金属材料因熔点高等固有属性,使其增材制造过程呈现出显著有别于其他金属材料的特殊性...增材制造技术(additive manufacturing,AM)的发展为高熔点难熔金属(如钨、钼、钽、铌及其合金)复杂构件的近净成形带来了革命性的新机遇。然而,难熔金属材料因熔点高等固有属性,使其增材制造过程呈现出显著有别于其他金属材料的特殊性。本文基于激光选区熔化(selective laser melting,SLM)和电子束选区熔化(selective electron beam melting,SEBM)等金属粉末床熔融(powder bed fusion,PBF)增材制造技术,系统综述了钨、钼、钽、铌及其合金在增材制造领域的研究进展。重点聚焦于难熔金属粉末原料制备技术,以及成形过程中工艺缺陷(如孔隙率、裂纹、晶粒粗化等)调控策略和组织性能特点。此外,本文还总结了当前增材制造难熔金属在产业化进程中面临的关键挑战,并对未来发展趋势进行了展望。展开更多
针对GH4099合金复杂构件对成形精度与服役性能的高要求,本工作开展了基于粘结剂喷射3D打印(binder jetting 3D printing,BJ3DP)的成形工艺优化与组织性能研究。通过正交试验分析层厚、粘结剂饱和度、铺粉速度及干燥时间对生坯表面质量...针对GH4099合金复杂构件对成形精度与服役性能的高要求,本工作开展了基于粘结剂喷射3D打印(binder jetting 3D printing,BJ3DP)的成形工艺优化与组织性能研究。通过正交试验分析层厚、粘结剂饱和度、铺粉速度及干燥时间对生坯表面质量的影响,明确粘结剂饱和度为主控因素,优化参数显著提升了成形均匀性与尺寸稳定性。进一步探究了烧结温度对组织与性能的调控作用,研究发现1345℃条件下相对密度达98.4%,组织致密,析出大量共格的L1_(2)型Ni_(3)(Al,Ti)相,在该条件下表现出了最佳的力学性能,抗拉强度和屈服强度分别为669和590 MPa。研究建立了BJ3DP成形参数与烧结制度协同调控GH4099组织-性能的作用机制,为实现高性能镍基合金复杂构件提供了新思路和理论支撑。展开更多
High-performance alloys are indispensable in modern engineering because of their exceptional strength,ductility,corrosion resistance,fatigue resistance,and thermal stability,which are all significantly influenced by t...High-performance alloys are indispensable in modern engineering because of their exceptional strength,ductility,corrosion resistance,fatigue resistance,and thermal stability,which are all significantly influenced by the alloy interface structures.Despite substantial efforts,a comprehensive overview of interface engineering of high-performance alloys has not been presented so far.In this study,the interfaces in high-performance alloys,particularly grain and phase boundaries,were systematically examined,with emphasis on their crystallographic characteristics and chemical element segregations.The effects of the interfaces on the electrical conductivity,mechanical strength,toughness,hydrogen embrittlement resistance,and thermal stability of the alloys were elucidated.Moreover,correlations among various types of interfaces and advanced experimental and computational techniques were examined using big data analytics,enabling robust design strategies.Challenges currently faced in the field of interface engineering and emerging opportunities in the field are also discussed.The study results would guide the development of next-generation high-performance alloys.展开更多
文摘增材制造技术(additive manufacturing,AM)的发展为高熔点难熔金属(如钨、钼、钽、铌及其合金)复杂构件的近净成形带来了革命性的新机遇。然而,难熔金属材料因熔点高等固有属性,使其增材制造过程呈现出显著有别于其他金属材料的特殊性。本文基于激光选区熔化(selective laser melting,SLM)和电子束选区熔化(selective electron beam melting,SEBM)等金属粉末床熔融(powder bed fusion,PBF)增材制造技术,系统综述了钨、钼、钽、铌及其合金在增材制造领域的研究进展。重点聚焦于难熔金属粉末原料制备技术,以及成形过程中工艺缺陷(如孔隙率、裂纹、晶粒粗化等)调控策略和组织性能特点。此外,本文还总结了当前增材制造难熔金属在产业化进程中面临的关键挑战,并对未来发展趋势进行了展望。
文摘针对GH4099合金复杂构件对成形精度与服役性能的高要求,本工作开展了基于粘结剂喷射3D打印(binder jetting 3D printing,BJ3DP)的成形工艺优化与组织性能研究。通过正交试验分析层厚、粘结剂饱和度、铺粉速度及干燥时间对生坯表面质量的影响,明确粘结剂饱和度为主控因素,优化参数显著提升了成形均匀性与尺寸稳定性。进一步探究了烧结温度对组织与性能的调控作用,研究发现1345℃条件下相对密度达98.4%,组织致密,析出大量共格的L1_(2)型Ni_(3)(Al,Ti)相,在该条件下表现出了最佳的力学性能,抗拉强度和屈服强度分别为669和590 MPa。研究建立了BJ3DP成形参数与烧结制度协同调控GH4099组织-性能的作用机制,为实现高性能镍基合金复杂构件提供了新思路和理论支撑。
基金supported by the National Natural Science Foundation of China(Nos.52122408 and 52474397)the High-level Talent Research Start-up Project Funding of Henan Academy of Sciences(No.242017127)+1 种基金the financial support from the Fundamental Research Funds for the Central Universities(University of Science and Technology Beijing(USTB),Nos.FRF-TP-2021-04C1 and 06500135)supported by USTB MatCom of Beijing Advanced Innovation Center for Materials Genome Engineering。
文摘High-performance alloys are indispensable in modern engineering because of their exceptional strength,ductility,corrosion resistance,fatigue resistance,and thermal stability,which are all significantly influenced by the alloy interface structures.Despite substantial efforts,a comprehensive overview of interface engineering of high-performance alloys has not been presented so far.In this study,the interfaces in high-performance alloys,particularly grain and phase boundaries,were systematically examined,with emphasis on their crystallographic characteristics and chemical element segregations.The effects of the interfaces on the electrical conductivity,mechanical strength,toughness,hydrogen embrittlement resistance,and thermal stability of the alloys were elucidated.Moreover,correlations among various types of interfaces and advanced experimental and computational techniques were examined using big data analytics,enabling robust design strategies.Challenges currently faced in the field of interface engineering and emerging opportunities in the field are also discussed.The study results would guide the development of next-generation high-performance alloys.
